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3. Physical Chemistry: I.N.

Levine (2010) 5th edition, Tata McGraw Hills Publishing Modern


Electrochemistry: Bockris and Reddy (1998) 2nd edition,Springer

IBS-609: Fundamentals of Molecular Spectroscopy


Contents: Introduction to radiation-matter interaction, Rotational Spectroscopy,Infrared
Spectroscopy, Raman Spectroscopy, Electronic Spectroscopy, Nuclear Magnetic Resonance (NMR)
Spectroscopy, Electron Spin Resonance (ESR) Spectroscopy.

Recommended Readings:
1. Introduction to Molecular Spectroscopy: G.M. Barrow (1988)McGraw-Hill
2. Fundamentals of Molecular Spectroscopy: C.N. Banwell and E.M. McCash (1994) 4thedition,
Tata McGrawHill
3. Modern Spectroscopy: J.M. Hollas (2004) 4th edition, Wiley, NewYork
4. Spectra of Atoms and Molecules: P.F. Bernath (2005) 2nd edition, Oxford University Press, New
York
5. Physical Chemistry - A Molecular Approach: D.A. Mc Quarrie and J.D. Simon (1997) 1st edition,
Viva Books PrivateLimited
6. Physical Chemistry: P.W. Atkins (2010) 9th edition, W.H.Freeman

IBS-610: Transition Metal Chemistry


Contents: Crystal and ligand field theories, crystal field stabilization energies,Irving-Williams series,
10Dq and pairing energies, molecular orbital diagrams for coordination complexes, magnetic
susceptibilities and Jahn-Teller effects. Spectroscopic terms, LS-coupling scheme, ligand field
transitions, charge transfer bands, selection rules, Orgel diagrams, Tanabe-Sugano diagrams and
circular dichroism. Thermodynamic and kinetic factors, labile and inert complexes, ligand
substitutions in octahedral and square planar complexes, stereo chemical effects. Oxidation/reduction
potentials, Nernst equation and redox stability in water, complementary and non-complementary redox
reactions, Inner and outer sphere electron transfer and Marcus theory, electron transfer in
metalloprotiens. Basic terminologies, kinetic factors affecting quantum yield, photochemistry of Co,
Rh, Cr andRu.

Recommended Readings:
1. Inorganic Chemistry: D. Shriver and P. Atkins (2006) 4th edition, Oxford University Press,
International StudentEdition
2. Inorganic Chemistry: J.E. Huheey, E.A. Keiter and R.L. Keiter (2007) 4th edition, Pearson
Education
3. Reaction Mechanisms of Inorganic & Organometallic Systems: R.B. Jordan (2007) 3rd edition,
Oxford UniversityPress

IBS-611: Organic Synthesis – I


Contents: The concept of protecting functional groups, oxidations and reductionsin functional group
transformations, enantioselective reduction and oxidation, diastereofacial selectivity in acyclic

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