Final Revision 2
Final Revision 2
Members
ALORO, PAULO J.
DASAL, AMOR B.
HILARIO, ROMEO B.
December 7, 2023
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Introduction
Every year, over 5 million tons of related waste are illegally disposed, causing
severe pollution and environmental damage (Bellei et al., 2023). Oyster shell waste
causes siltation and eutrophication in bays, as well as odors and insect attraction. In the
production of oyster shells, where shell farming is one of the major livelihoods of the
local communities. However, empty seashells are of no use and are commonly ignored
as waste. These shells are thrown everywhere, resulting in a large amount of waste
bagasse burning (calcination) for electricity production. The sugarcane industry plays an
important role and holds a significant share in the economy of many countries. As its
production increases, the amount of ash (waste) generated will also increase,
contributing to the ongoing issue of biomass waste management. These ashes are often
disposed of in landfills without any environmental control or, in some cases, used as
Addressing these problems, studies are focused on the potential use of oyster
shells and sugarcane bagasse ash in the construction industry. This is due to the
chemical composition of these materials. Oyster shells are mostly or approximately 96%
cement (Silva et al., 2019). Sugarcane bagasse ash, on the other hand, is mainly
composed of Silica (SiO2 – 60.94%), Alumina (Al2O3 – 14.83%), and Iron (II) Oxide (FeO
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– 12.81%), which are also found in the chemical composition of cement (Bachtiar et al.,
2019).
In the review of Ruslan et al. (2022), the use of oyster shells is investigated as
cement and substitute in the composition of concrete. Oyster shells are converted into
ash and powder and the experimentation is separately done. The result of the
investigation has the oyster shell powder performing better than oyster shell ash. Oyster
shell powder as cement substitute helped the compressive strength and flexural strength
Furthermore, to Seo et al. (2019), oyster shells are calcinated and used as
shrinkage of mortar.
Additionally, the study of Han et al. (2022) added blast furnace slag to oyster
strength increases with small amount of oyster shell powder and improved the electrical
resistivity of concrete by the synergy of oyster shell powder with the blast furnace slag.
in the study of Thomas et al., (2021). The study concludes that there are improvements
low heat of hydration, and reduced permeability due to pore refinement bagasse ash
blended concrete.
In the study of Hussein and Oan (2022), sugarcane bagasse ash is used as
replacement for cement in mortar and concrete. It is concluded that the optimum
28 days of curing. This is because it showed the highest compression and split tension
While these existing studies and practices addressed the problem of oyster
shells and sugarcane bagasse ash as wastes by using these materials in cement, no
study addressed the use of sugarcane bagasse ash combined into oyster shell in the
bagasse ash and oyster shells as dual constituents in cement for brick production draws
the need for a research study to bridge the gap and provide insights into the feasibility,
benefits, and potential challenges associated with their joint application in sustainable
construction materials.
This present study primarily focuses on the utilization of oyster shells and
sugarcane bagasse ash. The study also aims to further explore the potential of these
wastes in construction. It seeks to address the issue by investigating how the use of
material (SCM) can affect the mechanical properties of the resulting bricks.
the oyster shell cement and sugarcane bagasse ash, the collected data and information
will facilitate the determination of the most optimal ratios for oyster shell with sugarcane
The researchers aim to find the effectiveness of bricks with oyster shell powder
and sugarcane bagasse ash as part components of cement in bricks in terms of its
1. What are the compressive strengths of bricks with the cement component is
incorporated with oyster shell powder and sugarcane bagasse ash given the
different treatments?
2. What are the water absorptiveness percentages of bricks with the cement
3. Are there any significant differences on the compressive strengths and water
incorporated with oyster shell powder and sugarcane bagasse ash given the
Hypothesis
treatments when compared to the control brick in terms of compressive strength and
water absorptiveness.
Conceptual Framework
reactant of Calcium Oxide (CaO) product that is used in Portland cement, is a factor due
to its chemical composition is alike to some compounds found in cement (Bellei et al.,
2023). Sugarcane bagasse ash, on the other hand, is rich in Silica, Alumina, and Iron (II)
This study highlights the use of oyster shell powder and sugarcane bagasse ash
components of cement in bricks for the experiment such as regular cement, oyster shell
powder, and sugarcane bagasse ash with constant sand and other aggregates. Three
ratios are made from these variables. Ratio 1 is composed of 70% cement (469 g), 20%
Oyster Shell Powder (134 g), and 10% Sugarcane Bagasse Ash (67 g). Ratio 2 is
composed of 70% cement, 15% Oyster Shell Powder (100.5 g), and 15% Sugarcane
Bagasse Ash (100.5 g). Ratio 3 is composed of 70% cement, 10% Oyster Shell Powder
The formed bricks out of these ratios will then be tested by its compressive
strength and its water absorptiveness. These parameters are the dependent variables of
the study.
The findings of this research will prove useful to the following entities:
Construction Companies.
The result of this study will benefit construction companies by integrating these
This study provides innovative and effective strategies for architects and
industry.
This study will benefit cement and brick manufacturers by providing a new
Future Researchers.
This will benefit future researchers by helping them understand effective methods
This study focuses on the utilization of oyster shells and sugarcane bagasse ash
from Panay Island Western Visayas, as an alternative component for cement in brick
production. The study is limited to the direct utilization of oyster shell waste and
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sugarcane bagasse ash in cement brick production, and findings may not be directly
The study will collect the oyster shell samples from the area of Villa, Iloilo City,
specifically from the restaurants that sell oysters. Sugar Cane Bagasse Ash (SCBA) will
be collected from leftovers of processed sugar canes in URC Passi Sugar Milling Plant,
oyster shell waste and sugarcane bagasse ash as dual components in cement for brick
production, and other factors influencing brick production are not extensively addressed.
The durability testing which includes compressive, tensile strength, and absorptiveness
is limited to the assessment of oyster shell cement and sugarcane bagasse ash in brick
production materials and does not include a comprehensive evaluation of the entire
water ratio of bricks. This is derived from the DPWH Class A Mixture that can produce 75
Definition of Terms
that, when combined with water, becomes a paste that may bind solid matter
Bagasse Ash.
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used in analyzing the strength and durability of the brick by applying compressive
components are cement, sand, and other aggregates with a small amount of
In this study, “Concrete Brick” refers to the type of brick where its cement
4. Oyster Shell (OS) - a residue rich in calcium carbonate, which can be reused as
substitutes in the cement component of bricks that focuses mainly on the CaO
component of cement.
the milling of sugarcane (Webber III et al., 2015) that is rich in Silica, Alumina,
one of the substitutes in the cement component of bricks that focuses mainly on
calculated as the ratio of the weight of water absorbed to the weight of the dry
Standard and conventional bricks are made by mixing the earth-based or raw
materials, molding the bricks, drying then firing, or by using ordinary Portland cement
(OPC) to produce bricks (Al-Fakih et al., 2018). In the study of Lanante et al. (2020) that
is based in Biliran, Philippines, traditional cement bricks have a 1:5 cement to sand
volumetric ratio. However, there is a different ratio that is also put into practice but in the
December 7, 2023), a licensed civil engineer based on Roxas City, Capiz, Western
Visayas, Philippines, the Department of Public Works and Highways Class A mixture for
In terms of its size, the dimension of the brick is 7.625 in. by 3.625 in. by 2.25 in. in
length-width-height.
international standard codes, depending upon the importance of structures and the
severity of environmental conditions (Murmu & Patel 2018). They can also be classified
based on their constituent materials such as common burnt clay bricks, sand lime bricks,
engineering bricks, concrete bricks, fly ash clay bricks, etc. (Hossain, 2021).
weight.
Concrete Bricks
Concrete bricks or concrete blocks are made with cement, sand, and other
aggregates with a small amount of water, then blowing the mixture into molds (Sahu et
al., 2016). In the study of Hossain (2021), concrete brick is one of the classifications of
bricks with its own features in terms of compressive strength and absorptiveness. It had
Oyster Shells
composed of calcium carbonate, which provides strength and rigidity to the shell. Oyster
shells are commonly used in various applications, such as poultry feed supplements,
gardening and landscaping, soil amendments, and calcium supplements for humans and
animals. They can also be crushed and used as a natural source of calcium in
agricultural practices to improve soil pH and promote plant growth. Additionally, oyster
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shell can be used in construction materials, such as concrete, to enhance durability and
One of these construction materials where oyster shells were incorporated is the
lateritic soil from the study of Etim et al. (2020). The emphasized purpose of lateritic soil
in the study is for road construction and oyster shells, in ash form, improved the
condition of the lateritic soil, specifically its plasticity index. The ash decreases the
plasticity or softness of the soil, providing more stable base for road construction. This is
due to the Calcium Carbonate present in oyster shells, that is a need in a deficient
lateritic soil.
explored in the study of Liao et al. (2022). Oyster shells are calcinated and powdered
and made as partial replacement of cement in mortar in varying ratios. The addition of
oyster shell powder improves durability and reduces water absorption, permeability, and
chloride ion diffusion coefficients. Optimal WOS powder content is 8%, resulting in
Sugarcane is a crop cultivated globally, with over 1.5 billion metric tons produced
annually. After extracting juice for sugar production, the fibrous residue left behind is
sugarcane industry. SCB has a high silica content, making it a useful pozzolanic material
with a crystalline and amorphous structure. The amorphous silica in bagasse ash is a
2017).
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The effects of sugarcane bagasse ash were also explored to other construction
materials such as pavement concrete and stone mastic asphalt. Chindaprasirt et al.
(2019) explored the use of bagasse ash in pavement concrete. The pavement concretes
containing bagasse ash of 20 and 40 % with compressive strengths not less than 17.5
MPa as required by ACI 211 for a normal weight concrete showed good durability in
terms of abrasion resistance and acid resistance. Another study is from Ganesh and Rai
(2020) where bagasse ash is used in stone mastic asphalt. Bagasse ash is used as a
filler material in different ratios. The mix containing up to 5% bagasse ash performed
better than conventional mixes. Bagasse ash can decrease drain down of bitumen for
In the study of Bunyamin and Mukhlis (2020), oyster shells are used as substitute
part of cement and fine aggregate of concrete. The general objective of the study is to
utilize oyster shells that are wasted from Krueng Neng, Aceh Besar, Indonesia.
Moreover, the specific objectives of the study are to determine the density and the
compressive strength of hardened concrete with the addition of oyster shell ash and
grain. The study used quasi-experimental research design which compared the results
of different tests in the product bricks. The independent variables include the amounts or
ratios of oyster shell ash and grains to be substituted to cement and the water-cement
ratios, and the dependent variables are the resulting compressive strengths and
densities of the bricks to be formed out of oyster shell cement. The type of oyster shell
used is Crassostrea Gigas. The oyster shells were burned at a temperature of 200˚C in
a drum or burn barrel. The burned oyster shells were then crushed in a Los Angeles
Abrasion Test machine. The process followed a manual pressing through a crusher. After
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crushing, the oyster shells were sieved at a #200 sieve for cement and 2.36 mm sieve
The replacement of cement and fine aggregate with ash and oyster shell grain at
5%, 10%, and 15% content affected the compressive strength of the concrete. With a
0.50 water-cement ratio (50 lbs. water: 100 lbs. cement), out of the other 0.40 and 0.60
33 MPa (4786.25 psi). This study only explores the effects of oyster shell ash and grains
oyster shells can be utilized as substitute and additive for cement content. Yet, it lacks to
explore the effects of oyster shells to other aspects of concrete bricks such as tensile
In the investigation of Ruslan et al. (2022), oyster shells are used as replacement
for cement and are converted into both ash in temperatures 900˚C to 1100˚C and
converted into fine powder. The study on the oyster shell ash is separate from the oyster
shell fine powder. In the findings, the incorporation of oyster shell ash to cement
component of concrete decreased its compressive strength and flexural strength as the
ratio of oyster shell ash goes higher. However, in the incorporation of oyster shell fine
powder, the highest compressive strength of concrete is in 10% oyster shell fine powder
with about 35 N/mm2 (~5076.32 psi). In flexural strength, it was 5% oyster shell fine
powder that had the highest result with about 4 N/mm2 (~580.15 psi). Overall, the study
concluded that oyster shells have the potential to be a partial substitute for cement and
In a different concept, the study of Hussein and Oan (2022) used sugarcane
bagasse ash as partial replacement of cement in both mortar and concrete. The study
aims to investigate the use of sugarcane wastes in concrete, where the wastes turned
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into ash and are used as replacement for cement. The design of the study is in quasi-
experimental where the results focused on comparison of the produced bricks in terms
The sugarcane bagasse is burned at 600˚C until it is converted into ashes, then it
was heated again in an oven in 200˚C. The ashes were then ground to obtain finer
particles. The ratios of sugarcane bagasse ash to cement were 5%, 7.5%, and 10% of
the total weight of cement. The results showed that the best ratio of using sugarcane
bagasse ash as a partial replacement for cement was 5% with compressive strength of
32.54 MPa (4719.53 psi) and split tensile strength of 2.97 MPa (430.76 psi).
Moreover, the study of Thomas et al. (2021) explores the physical and chemical
SCBA in terms of both fresh and hardened properties. Additionally, the study aimed to
chloride penetration, electrical resistivity, thermal conductivity, acid, and sulfate attack.
The findings from this comprehensive review highlighted the unique properties of SCBA,
including its asymmetrical shape and colossal size. Various treatments, such as grinding
and calcination, were found to enhance its pozzolanic properties. The study revealed
bridging the gap between academic research and practical application in the
construction industry.
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The synthesis of the studies by Bunyamin and Mukhlis (2020), Ruslan et al.,
(2022), Hussein and Oan (2022), and Thomas et al. (2021) collectively addresses the
potential for sustainable alternatives and the need for further exploration of their effects
byproducts as substitute for the components of concrete brick, especially cement. The
research gap identified is the lack of exploration of oyster shells and other agricultural
byproduct as both substitutes of cement component, and the lack of testing for quality of
oyster shell cement bricks. The existing studies relates to the research questions of the
study as these serve as foundational references and are used in formulation of the
research hypothesis.
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Methodology
Research Design
oyster shells and sugarcane bagasse ash as alternative components for cement in brick
and controlled fashion so that precision is maximized, and specific conclusions can be
drawn regarding a hypothesis statement. Generally, the purpose is to establish the effect
incorporating sugarcane bagasse ash (SCBA) with oyster shell cement on the
compressive strength, tensile strength, and absorptiveness of bricks. This design allows
different oyster shell and sugarcane bagasse ash ratios on cement bricks, especially one
a control brick.
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The methods in this procedure are based on the study of Bunyamin and Mukhlis
(2020).
The process begins with the collection of oyster shells, followed by a deep
cleaning to get rid of organic material and drying. Subsequently, the shells are burned at
200°C for one hour in a steel barrel or drum to achieve brittleness. The burned oyster
shells are then crushed using a Los Angeles abrasive machine and ground into a fine
powder using a crusher. The final step involves sieving the oyster shells through a #200
The methods in this procedure are based on the study of Hussein and Oan
(2022).
The sugarcane bagasse (SCB) is collected from sugar mills and is then dried to
temperature of 600°C until it transforms into ashes. The ash undergoes an additional
step of reheating in an oven, this time at 200°C. Following the heating processes, the
ash is finely ground using a ball mill. The final step involves sieving the ash through a
Formulation of Treatments
From the 50 kg: 150 kg: 20 L cement-sand-water ratio of the DPWH Class A
Mixture that can produce 75 bricks, it’ll take 0.67 kg: 2 kg: 0.27 L ratio of cement-sand-
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water to create one brick. To convert the following units into grams and with a liquid
water to mass factor of 1 L = 1 kg, the resulting derived ratio is 670 g: 2000 g: 270 g of
cement-sand-water.
The total wet weight of 2.94 kg (2940 g) is within the range of the standard wet
weight of concrete bricks which is from 2.34 kg to 3.47 kg according to the study of
Hossain (2021).
With constant sand, and water, the ratios only cover the cement component of
brick which covers 670 g of total weight. These ratios replace the cement component of
exactly 30% of the weight and is formatted as 469 g cement (70%) - OS Powder (g) -
SCBA treatment.
Testing of Bricks
the use of a compression testing machine. For each treatment, three bricks are selected,
and the testing procedure is repeated three times to ensure comprehensive and reliable
Water Absorptiveness Test. The water absorption test involves weighing the
three treatments of the bricks for the basis of results and soaking them in room-
temperature water for 24 hours. The bricks are then weighed again to calculate the
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percentage increase in mass. This will determine the water absorption capacity of the
brick.
Data Analysis
The study aligns the criteria for compressive strength test in the descriptions of
Hossain (2021) about the classes of bricks in terms of its compressive strength.
To compute for compression strength, the Pressure formula will be used. The
required data for the formula is the top surface area of the brick and the force it takes to
make the brick fail. The initial unit for compression strength is newton per square
millimeter (N/mm2). To evaluate according to compression strength criteria (Table 2), the
Absorptiveness Test.
The study aligns the criteria for water absorptiveness test in the descriptions of
Hossain (2021) about the classes of bricks in terms of its water absorptiveness.
To compute for water absorptiveness, the data available should be the dry weight
of the brick and its weight after it had been soaked in water for 24 hours. The formula to
Statistical Tools.
Mean. The mean is used to represent a group of values into one value. This is
calculated by summing all values included in the group and divide the sum by the total
number of values in the group. In this study, the groups are the values of each trial in
Standard Deviation. The standard deviation is used to see the spread of values
and how far each value lies from the mean. A higher standard deviation shows wider
spread of values from the mean, while a lower standard deviation shows that the values
of two or more independent groups if there are significant differences among each
group. It is to determine if the differences in results are caused by true group differences
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