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5.3 Stream 2017 DB

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0% found this document useful (0 votes)
9 views

5.3 Stream 2017 DB

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© © All Rights Reserved
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Available Formats
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OC/DB/PG (Stream)

Safety Data Sheet


according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Date of issue: 01/24/2017 Revision date: n/a Supersedes: n/a Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Trade name : OC/DB/PG (Stream)
Product code : n/a
SDS ID : WL2017-002
1.2. Relevant identified uses of the substance or mixture and uses advised against
Self defense device
1.3. Details of the supplier of the safety data sheet
Fox Labs International, Inc.
310 Church Street
Mount Clemens, MI 48043

1.4. Emergency telephone number


Emergency number : CHEMTREC (800) 424-9300
Outside USA: +1 703-527-3888
24 hours
Customer ID: CCN13561

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
GHS-US classification
Compressed gas
Eye damage/irritant 2A

2.2. Label elements


GHS-US labelling
Hazard pictograms (GHS-US) :

GHS04 GHS07
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : Contains gas under pressure; may explode if heated
Causes serious eye irritation

Precautionary statements (GHS-US) : Wear eye protection/face protection


If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing
If eye irritation persists: get medical advice/attention
Protect from sunlight. Store in a well-ventilated place

2.3. Other hazards


No additional information available
2.4. Unknown acute toxicity (GHS-US)
Not applicable

SECTION 3: Composition/information on ingredients


3.1. Substance
Not applicable
3.2. Mixture

01/24/2017 EN (English) SDS ID: WL2017-002 1/7


OC/DB/PG (Stream)
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)

Name Product identifier % GHS-US classification


Resins, oleo-, capsicum (CAS No) 8023-77-6 2% Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Diethylene glycol monobutyl ether (CAS No) 112-34-5 Proprietary Flam. Liq. 4, H227
Eye Irrit. 2A, H319
Nitrogen (CAS No) 7727-37-9 Proprietary Compressed gas, H280

Full text of H-phrases: see section 16

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing
is difficult, give oxygen. If not breathing, give artificial respiration. Call a POISON CENTER or
doctor/physician if you feel unwell.
First-aid measures after skin contact : Wash with plenty of soap and water. Do not apply salves or creams to affected area. If skin
irritation persists, seek medical attention.
First-aid measures after eye contact : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutes
minimum). Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. If the person is fully conscious, make him/her drink
water. Never give an unconscious person anything to drink. Contact the Poison Control Centre
at 1-800-222-1222.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Shortness of breath.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : May cause irritation to mouth, throat and stomach upon direct contact.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Non known.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Non-flammable aerosol. Contains combustible liquid.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of
burns and injuries.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment. DO NOT fight fire when fire
reaches explosives. Evacuate area.
Protective equipment for firefighters : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
General measures : No open flames. No smoking. Isolate from fire, if possible, without unnecessary risk. Remove
ignition sources. Use special care to avoid static electric charges.

6.1.1. For non-emergency personnel


Emergency procedures : Evacuate unnecessary personnel. For further information refer to section 8 : Exposure-
controls/personal protection.

6.1.2. For emergency responders


Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters.

01/24/2017 EN (English) SDS ID: WL2017-002 2/7


OC/DB/PG (Stream)
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)

6.3. Methods and material for containment and cleaning up


Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Additional hazards when processed : Hazardous waste due to potential risk of explosion. Pressurized container: Do not pierce or
burn, even after use.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. Do not spray on an open flame or other ignition source. Avoid breathing
dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area.
Hygiene measures : Wash hands thoroughly after handling. Wash hands and other exposed areas with mild soap
and water before eating, drinking or smoking and when leaving work place.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Storage conditions : Keep only in the original container in a cool, well-ventilated place. Do not expose to
temperatures exceeding 50 °C/ 122 °F. Keep in fireproof place. Keep container tightly closed.
Incompatible products : No additional information available.
Incompatible condition : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Resins, oleo-, capsicum (8023-77-6)


ACGIH Not applicable
OSHA Not applicable

Diethylene glycol monobutyl ether (112-34-5)


ACGIH ACGIH TWA (ppm) 10 ppm (inhalable fraction and vapor)

8.2. Exposure controls


Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure. Provide adequate ventilation.
Personal protective equipment : Protective goggles. Gloves. Protective clothing. Insufficient ventilation: wear respiratory
protection.

Hand protection : Wear protective oil and chemical gloves if prolonged skin contact is likely.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing (Oil / chemical resistant).
Respiratory protection : In case of insufficient ventilation wear appropriate respiratory protection.
Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Thin liquid/ Aerosol
Color : Light amber
Odor : Pungent, highly irritating
01/24/2017 EN (English) SDS ID: WL2017-002 3/7
OC/DB/PG (Stream)
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : 78 °C (172 °F)
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Solubility : Completely soluble in water
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available

9.2. Other information


No additional information available

SECTION 10: Stability and reactivity


10.1. Reactivity
Thermal decomposition generates : Carbon dioxide, carbon monoxide and hydrocarbons.
10.2. Chemical stability
Stable at ambient temperature and under normal conditions of use.
Contains gas under pressure; may explode if heated. Extreme risk of explosion by shock, friction, fire or other sources of ignition.
10.3. Possibility of hazardous reactions
Hazardous polymerization may occur if exposure to fire conditions

10.4. Conditions to avoid


Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating.
10.5. Incompatible materials
No additional inforation available.
10.6. Hazardous decomposition products
Fume. Carbon monoxide. Carbon dioxide, hydrocarbons.

SECTION 11: Toxicological information


11.1. Information on toxicological effects

Acute toxicity : Not classified

Resins, oleo-, capsicum (8023-77-6)


LC50 inhalation rat (mg/l) > 10000 g/m³ (Exposure time: 4 h)

Diethylene glycol monobutyl ether (112-34-5)


LD50 oral rat 5660 mg/kg
LD50 dermal rabbit 2700 mg/kg
ATE US (oral) 3384.000 mg/kg body weight
ATE US (dermal) 2700.000 mg/kg body weight

01/24/2017 EN (English) SDS ID: WL2017-002 4/7


OC/DB/PG (Stream)
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified


Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated : Not classified


exposure)

Aspiration hazard : Not classified


Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/injuries after inhalation : Shortness of breath.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after skin contact : Causes skin irritation.

SECTION 12: Ecological information


12.1. Toxicity

Diethylene glycol monobutyl ether (112-34-5)


LD50 oral rat 5660 mg/kg
LD50 dermal rabbit 2700 mg/kg
ATE US (oral) 3384.000 mg/kg body weight
ATE US (dermal) 2700.000 mg/kg body weight

12.2. Persistence and degradability

Not established.

12.3. Bioaccumulative potential


Not established.
Diethylene glycol monobutyl ether (112-34-5)
BCF fish 1 (no bioconcentration expected)

12.4. Mobility in soil


No additional information available

12.5. Other adverse effects


Effect on ozone layer : No additional information available

Effect on the global warming : No additional information available

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Container under
pressure. Do not drill or burn even after use.
Additional information : Flammable vapors may accumulate in the container.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information


In accordance with DOT
Transport document description (ADR) : Consumer commodity
UN-No.(DOT) : ORM-D
01/24/2017 EN (English) SDS ID: WL2017-002 5/7
OC/DB/PG (Stream)
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)
Proper Shipping Name (DOT) : Consumer commodity
Hazard Classes (DOT) : -
Hazard labels (DOT) : None

DOT Packaging Exceptions (49 CFR 173.xxx) : 156, 306


DOT Packaging Non Bulk (49 CFR 173.xxx) : 156, 306
DOT Packaging Bulk (49 CFR 173.xxx) : None
DOT Quantity Limitations Passenger aircraft/rail : 30 kg
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : Forbidden
CFR 175.75)
Additional information
Other information : No supplementary information available.

ADR
No additional information available
Air transport
UN-No.(IATA) : 8000
Proper Shipping Name (IATA) : Consumer commodity
Class (IATA) : 9 - Miscellaneous Dangerous Goods

Transport by sea
UN-No.(IMDG) : 1950
Proper Shipping Name (IMDG) : AEROSOL
Class (IMDG) : 2.2 - Class 2.2 - Non-flammable, non-toxic gases
(each not exceeding 1 L capacity)
Hazard labels (IMDG) :

Excepted Quantity code (IMDG) : E0 (Not permitted as Excepted Quantity)


EMS : F-C, S-V

SECTION 15: Regulatory information


15.1. US Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory

This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable concentration as specified in 40
CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act
of 1986 and 40 CFR Part 372.
Resins, oleo-, capsicum (8023-77-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Diethylene glycol monobutyl ether (112-34-5)
EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA
Y2 - Y2 - indicates an exempt polymer that is a polyester and is made only from reactants
included in a specified list of low concern reactants that comprises one of the eligibility criteria
for the exemption rule

15.2. International regulations


CANADA

01/24/2017 EN (English) SDS ID: WL2017-002 6/7


OC/DB/PG (Stream)
Safety Data Sheet
according to the federal final rule of hazard communication revised on 2012 (HazCom 2012)

Resins, oleo-, capsicum (8023-77-6)


Listed on the Canadian DSL (Domestic Sustances List)
Diethylene glycol monobutyl ether (112-34-5)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Class B Division 3 - Combustible Liquid
Class D Division 2 Subdivision B - Toxic material causing other toxic effects

EU-Regulations

Classification according to Regulation (EC) No. 1272/2008 [CLP]


No information available
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
No information available
15.2.2. National regulations

Resins, oleo-, capsicum (8023-77-6)


Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
\

Diethylene glycol monobutyl ether (112-34-5)


Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
\

15.3. US State regulations


California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer,
developmental and/or reproductive harm

SECTION 16: Other information


Revision date : Not applicable
Other information : None.
Indication of changes : Not applicable

Full text of H-phrases:


Compressed gas Gases under pressure : Compressed gas
Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A
Flam. Liq. 4 Flammable liquids Category 4
Skin Irrit. 2 Skin irritation, Category 2
H227 Combustible liquid
H280 Contains gas under pressure; may explode if heated
H315 Causes skin irritation
H319 Causes serious eye irritation

The information presented herein is believed to be correct but is not purported to be all inclusive and shall be used only as a guide. AMSPEC Chemical shall not be held liable for any damage resulting
from handling or from contact with the above product.

01/24/2017 EN (English) SDS ID: WL2017-002 7/7

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