AToMI STRUCTURE

SET-I

1. The increasing order for the

values of
and alpha particle charge/mass for electron(e), proton(p),
(o) -
is neutron(n)
(a) e,p, n, o (b) n, p, e, x (c) n, p, o,
2. Correct set of four
e
(d) n, o, p, e
quantum number for the valence electron
of rubridium
(z=37) is
(a) 5,0,0,(b)
b)5,1,0, 5,1,1,a)
3.
Electromagnetic radiation with maximum wavelength is6,0,0, 2
(a) Ultraviolet (b) Radio wave
4. which one of the C)X-ray (d) Infrared
following sets of
quantum numbers represents
arrangement? an
impossible
n
m

(a) 3 2 -2
(b) 0 0
(c) 3
-3
(d) 5
5. The ratio of the
energy
3 0
-
of a photon of 2000 A wavelength radiation to that of 4000 A
radiation is
(a) 4 (b) 4
(); (d) 2
6. The orbital diagram is which the afbau
principle is violated is:
2p 2s
(a) 116)
7. For a d electron, the orbital angular momentum is:
-
(a) v6 (h/2m) (b) V2 (h/2m) (c)
8. The radius of which of the
(h/27) a)h/2)
following orbit is same as that of the first Bohr's
hydrogen atom? orbit of
(a) Het (n = 2)
(b) Li2 (n = 2) (c) Li2* (n 3) (d)
9.ThaHe number of radial nodes of 3s and 2p orbitals are Be3 (n 2) =
=

(a) 2,0 (b) 0,2 (c) 1,2 (d) 2,1 repectively

10. A plot of the kinetic
of incident
energyG of mv-) ejected electron as a afunction of the
frequency (v)
radiation for four alkali metals (M1, M2. M3, Ma) is shwon below.

Page 1
 M M, M M4

Kinetie
energy

The alkali metals Mi, M2. Ma and M4 are respectively:

(a) Li, Na, Kand Rb (b) Na, K, Li, and Rb ()Rb,K, Na, and Li (d) Rb, Li, Na and K
11. What will be the total energyof1 mol ofphotonif each photon has frequency 2500 S-"?
(a) 10 erg (b) 1 (c) 1ev (d) 1 Mev
Kinetic energy o fan electron in the second Bohr orbit of H - atom is
12.
h2 h2 h2 h2
(a) 4T2m r (b) (d)
672mr6 C)32172m r6 6472m r6
The energy of second Bohr orbit of the hydrogen atom is - 328 KJ mol1, Hence the energy
13.
of fourth Bohr orbit would be: --

(a)-41 K mol (b)-1312 KJ mo (-164 K mol (d) -82 KJ mol-

14. Time taken for an electron to completeoi revolütion in the Bohr orbit of hydrogen atom is:

47t2mr2 (b) (d)

(a) nh 4TTmr nh2 2Ttmr
15. At 200°C hydrogen moleeules have velocity 105 cms1 The de - Broglie Wavelength jé this

case is approximately:
(a) 2A (b) 1000 Å c) 100 A (d) 10 A
16. The uncertainty in the position of an electron moving with a velocity of 3 x 10 cm s
aeeturatë upt6 0.001%will be:
(a) 1.93 cm (b) 7.68 cm () 0.175 cm (d) 3.84 cm
17. The radius of hydrogen atom in the ground state is 0.53, the radius of aLi2* is the similar
stateis:
(a) 1.06 A (b) 0.265Å (c) 0.17 A (d) 0.53 ÅA
18. Which of the following ion has maximum magnetic moment ?
(a) Mn2 (b) Fe2 (c) Ti2 (d) Cr2
19. lonization energy of He is 19.6 x 10-18Jatom-1. The energy of first stationary state
(n=1) of Li2* is :
(a) 2.2 10-15 J atom1
x
(b) 4.41 x 10-16 J atom1
( 8.82 x 10-17 J atom1 (d) 4.41 x 10atom
20. Wavelength of light required to excite an electron KH-atom from level n =1 afd n = 2 will
be (Given IE of H atom is 2. 178 x 10-18 J)
(a) 1.214x 10- m (b) 6.5 x 10- m
(c) 2.816 X 10" m (d) 8.5 x 10-7 m

Page 2
 Atomic Structure -I
Co
Full marks 25 X4 Time - 35 min

Which of the following does not express the mathematical form of the Hisenberg
uncertainty principle ?
h h h
(a) Ax.ap»(b) Ax .Av> am (c) AE.At > (d) AE. Ax
47 4TTm 4TT
2. Energy of the electron of Li2* in the first excited state - ( in eV unit)
a) -122.4 (b) 30.6 (C)-30.6 (d) -13.6
3. Which of the following has minimum wave length for electronic transition
From n= 2 to n =
1?
(a) Li2 (b) He (c) H (d) H
4 Identifythe charged species having 16 protons 18 electrons and 16 neutrons
(a) S (b) Si2 c) p3- d) $2
For Which of the following orbitals probability of finding electron in theyz plane is zero
(a) P (b) P () P (d) dyz
. Amount of total energy of 1 mol of photon (frequency of each photon = 2500 S-!)
(a) 10 erg (b) 1 (c) 1ev (d) 1 MeV
For which of the following positive charge and mass are respectively one unit and 1 amu
(a) Electron (b) Neutron (c) Proton (d) None
. Electronic configuration of Gd (atomic no. 64) =

(a) 4f854°6s2 (b) 4f5d 6s2 (c) 4f75di 6s/2L (d) 4f35d 6s2
9. Angular momentum of elctron in the 5th orbit -

(e)
25(b)()10 (d) 2.5
10. Energies of two radiations are respectively E1 = 25 eV and E2 = 50 eV. Relationship between
their wavelength A1 and Az is

(a) ( b ) A =Az (c) A1 =24 (d) a1 =4 A2

11. Which has electronic configuration [Ar]3d6 .
(a) Co3 (b) Ni3 (c) Mn3 (d) Fe
12. If uncertainty in position and momentum be the same,
uncertainty in velocity will be -
(a)m (b) (c) m VT (d)
(d)
13. For H -

atom, Ez = -

328 kJmol. E^ = ? kJmol-1.

(a)-41 (b) +41 c)-164 (d) - 82
14. Frequency of energy for electronic transition from n = 4 to n = 1 of H -

atom is
(Given, IE of H atom 2.18 x 10-18 J atom-1)
-

a) 1.54x 1015 s-1 (b) 1.03x 105 s- (c) 3.08 x 1015 s

15. No. of (d) 2 x 1015 s
unpaired electrons in Fe2
a)3 (b) 2 (c) 4 (d) 5
1. Energy of photon a is 3x 107 erg. Its wavelength in nm is--
(a) 662 (b) 1324 (c) 66.2 (d) 6.62
17. If wavelength of a photon be 2.2 x
107 m, then momentum of the
(a) 3 x 10-23 kgm s1 photon will be--
(b) 3.33x 104 kgm s (c) 1.452
(d) 6.89 x 1043 kgm s x 10-** kgm s
18. de Broglie wavelength ofa particle having mass of 1 kg
(a) 6.6 10-33 m and velocity of 100 ms-
x
(b) 6.6 x 10-36 m (c) 3.3x 1033 n (d) 3.3 x 10-36 n
9. Ratio of area of 2nd and 1st
orbit is-.
d 1:2 (b) 1:16 (c) 8:1 (d) 16:1
V
20. = ??(Vn =potential energy of electron kine
inn th orbit and
K potenttal energy of
electron in n th orbit )
(a) 0 (b)-1 (c)-2 (d) 1
1
21 x Z Y =?

Where Z atomic number and r = radius of nth orbit

=

a) 0 (b) -1 (c) -2 (d) 1

22
22. No. of radial nodes of
3s and 2p orbitals
(a) 2,0 (b) 0,2 (c) 1,2 (d) 2,1
23. The hydrogen like species Li2* is in a spherically symmetric state S1 with one radial node.
Upon absorbing light the ion undergoes transition to a state S2. The state S2 has one radial
node and its energy is equal to the
ground state energy of the H atom.
. The state S1 is
(a) 1s (b) 2s (c) 2p (d) 3s
Energy of the state S1 in units of the H - atom ground state energy is -
(a) 0.75 (b) 1.50 (c) 2.25 (d) 4.50
1I. The orbital angular momentum quantum number of the state S2 is -
ta0b)1 c) 2 (d) 3