Optimum Numerical Approach of A MSF Desalination P
Optimum Numerical Approach of A MSF Desalination P
MECHANICAL ENGINEERING
KEYWORDS Abstract Nowadays, desalination of salt water is considered as an important industrial process. In
Design; many regions of the world, the multi-stage flash (MSF) water desalination technique has an essen-
Dual-purpose power plant; tial contribution in the production of freshwater. In this study, a (MSF) model is used to design a
Mathematical model; MSF desalination system and, the feasibility of using the MSF desalination process in proximity of
MSF desalination a 650 MW power plant is investigated. This power plant can provide 385.03 kg/s superheated steam
from low pressure (LP) section of heat recovery steam generator (HRSG) for thermal desalting sys-
tem. Three modules were tested with different numbers of heat rejection sections. The optimum
design was 25 stages in the heat recovery section and 3 stages in heat rejection section. The designed
MSF system with gained output ratio (GOR) of 8.76 has 28 flashing stages and can produce
2229 kg/s of freshwater. The expected performance characteristics of the designed MSF desalina-
tion plant are determined.
2014 Production and hosting by Elsevier B.V. on behalf of Ain Shams University.
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001
2 O.A. Kotb
Nomenclature
generator (HRSG) sections of the power plant [1,2]. Vapor rejection section. Each stage usually contains as in Fig. 2 brine
compression (VC), multi-effect distillation (MED) and multi- orifice, condenser/pre-heater tubes, water boxes, distillate tray,
stage flash distillation (MSF) are some conventional thermal venting line, demister and partition walls [10,11]. In the brine
desalination methods in which the MSF desalination system heater (heat input section), the preheated brine is heated
is more common than the other systems [3,4]. Sixty five percent to reach the maximum allowable brine temperature. The
of the world’s desalination plants use MSF desalination tech- brine heater operates as a shell and tube heat exchanger.
nology and more than 80 percent of seawater desalination in Furthermore, a deaerator is connected to stage 28 for prepara-
Gulf countries is performed by MSF desalination technique tion of the make-up flow. The flash chamber shell and the
[5,6]. Kuwait, Qatar, Oman, United Arab Emirates and Saudi brine heater shell are fabricated from stainless steel, while
Arabia are the Middle East countries that considerably use the condenser tubes in the chambers and the tubes of the brine
MSF desalination technique [2,7–9]. heater are made of Cu–Ni 70–30 because it can withstand
The fact that there are some power plants are going to be temperatures higher than 80 C. Its Thermal Conductivity is
built or have been built on the Red Sea, make it highly valu- 29 · 103 kW/m C. The system is provided with three vacuum
able to design and construct some thermal desalination plants pumps. Two of them are considered to operate in heat recov-
in this area. ery section and the third one operates in heat rejection section
The focus of this study to introduce an efficient MSF desa- and deaerator unit.
lination plant in Suez city supplied by a 650 MW power plant
that provides just 385.03 kg/s steam, with respect to the allow- 2.2. Design of the system
able salinity of blow down (79,800 ppm). Thus, practical corre-
lations are defined to design the MSF desalination system and
Usually, the MSF process modeling includes mass and energy
then operating parameters are determined.
balance, heat transfer equations, physical property correla-
tions and the temperature losses due to boiling point variation.
2. Methodology
The system design methodology is presented at this section
[11].
2.1. Process description The seawater temperature, the difference in the temperature
of inlet and outlet recycle streams of the condensers and the
The schematic diagram of the MSF process with brine recircu- temperature difference between the inlet and outlet brine
lation is shown in Fig. 1. The process contains 28 flashing streams in flashing chambers are considered to be 28 C,
stages which have similar layout. Stages 1–25 comprise heat 3.786 C and 3.786 C, respectively. The top brine temperature
recovery section and stages 26–28 are considered as the heat (TBT) and the blow down temperature are assumed to be
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001
Optimum numerical approach of a MSF desalination plant 3
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001
4 O.A. Kotb
The pressure value inside the brine heater and the vapor Tvn ¼ Tn BPEn NEAn DTdn ð27Þ
saturation temperature are 5.837 bar and 156 C, respectively. where BPE is the boiling point elevation in the last stage,
The brine heater area is given by:
BPEn ¼ Xn ðB þ ðXn ÞðCÞÞ103 ð28Þ
Ab ¼ Ms ks =ðUb ðLMTDÞb Þ ð15Þ
2 5 2 3
B ¼ ð6:71 þ 6:34 10 ðTn Þ þ 9:74 10 ðTn Þ Þ 10 ð29Þ
where LMTD is the logarithmic mean temperature difference
and is given by: C ¼ ð22:238 þ 9:59 103 ðTn Þ þ 9:42 105 ðTn Þ2 Þ108 ð30Þ
ðLMTDÞb ¼ ððTs To Þ ðTs T1 ÞÞ= lnððTs To Þ=ðTs T1 ÞÞ ð16Þ The non-equilibrium allowance is then calculated using the
correlation (31), temperature drop in the demister (DTd1) is
The overall heat transfer coefficient Ub is obtained from Eq.
assumed negligible in comparison with the values of BPEn,
(17) as follow.
NEAn
Ub ¼ 1:7194 þ 3:2063 103 Ts þ 1:5971 105 T2s 6
NEAn ¼ ð0:9784ÞTn1 ð15:7378ÞHn1 ð1:3777ÞVb10 ð31Þ
7
þ 1:9918 10 T3s ð17Þ
The gate height and the height of the brine pool in the last
stage are assumed equal to those in the previous stage. The
2.5. The condenser area in the heat recovery section, Ar gate height in the stage n 1, GHn1, is calculated from
equation:
Ar is determined for the first stage. Determination of this value GHn1 ¼ Mrn1 ð2qDP1 Þ0:5 =ðCd WÞ ð32Þ
requires calculations of the vapor condensation temperature,
Tv1, the logarithmic mean temperature difference (LMTD)r, Aj ¼ ðMf þ Mcw ÞCp ðTjn Tcw Þ=Uj ðLMTDÞj ð33Þ
and the overall heat transfer coefficient, Ur. The vapor temper-
ature is given by Eq. (18). where
Tv1 ¼ T1 BPE1 NEA1 DTd1 ð18Þ Uj ¼ 1:7194 þ 3:2063 103 Tvn þ 1:5971 105 T2vn
where BPE is the boiling point elevation in the first stage and is þ 1:9918 107 T3vn ð34Þ
given by:
and
BPE1 ¼ Xr ðB þ ðXr ÞðCÞÞ103 ð19Þ
ðLMTDÞj ¼ ððTvn Tjn Þ ðTvn Tcw ÞÞ= lnððTvn Tjn Þ=ðTvn Tcw ÞÞ
where
ð35Þ
B ¼ ð6:71 þ 6:34 102 ðT1 Þ þ 9:74 105 ðT1 Þ2 Þ 103 ð20Þ
The mentioned mathematical models can be used to design
C ¼ ð22:238 þ 9:59 103 ðT1 Þ þ 9:42 105 ðT1 Þ2 Þ108 ð21Þ a new MSF desalination plant. According to these models, the
And NEA, is the non-equilibrium allowance, the tempera- effect of different operating parameters on performance of the
ture drop in the demister (DTd1) is assumed negligible in com- plant can be investigated.
parison with the values of BPE1, NEA1 is given by:
2.7. Studying the effect of different numbers of heat rejection
6
NEA1 ¼ ð0:9784ÞTo ð15:7378ÞH1 ð1:3777ÞVb10 ð22Þ stages on the power plant performance
The gate height in the first stage, GH1, is calculated from Three modules of 28 stages distillation power plant were
Eq. (23): tested, the first of 26 heat recovery section and 2 stages for
GH1 ¼ Mr ð2qDP1 Þ0:5 =ðCd WÞ ð23Þ rejection section. The second one involves 3 stages for rejection
section, and the last one has 4 stages for the rejection section
The corresponding brine pool height (H1) is obtained by using Eqs. (1)–(5), (7)–(13), (15)–(35). The following table
simply adding 0.2 m to the value of GH1. shows the effect of number of stages in heat rejection section
on the power plant performance and the optimum design of
Vb at the first stage is:
the system.
Vb = Mr/W
Table 1 reveals that increasing the number of rejection
Also; Ar ¼ Mr Cp ðTr1 Tr2 Þ=Ur ðLMTDÞr ð24Þ stages will decrease the heat transfer area of the brine heater,
where heat rejection section, and heat recovery section, decrease the
gain output ratio, and decrease the brine salinity. It also clears
Ur ¼ 1:7194 þ 3:2063 103 Tv1 þ 1:5971 105 T2v1 þ 1:9918 107 Tv1 ð25Þ that the produced freshwater will decrease by 19.4% from 2 to
3 stages while it decreases by 49.02% from 2 to 4 stages, on the
and other side the Brine salinity decreases by 9.98% from 2 to 3
stages and it decreases by 23.25% from 2 to 4 stages. Aj Rejec-
ðLMTDÞr ¼ ððTv1 Tr1 Þ ðTv1 Tr2 ÞÞ=lnððTv1 Tr1 Þ=ðTv1 Tr2 ÞÞ ð26Þ
tion section heat transfer area is decreased dramatically from 2
to 3 stages by 50.99% and from 2 to 4 stages by 68.5%. Ar
2.6. The condenser area in the heat rejection section, Aj Recovery section heat transfer area is decreased dramatically
from 2 to 3 stages by 72.32% and from 2 to 4 stages by
It is determined for the last stage. Determination of this value 89.34%. The most important parameter affects the design of
requires calculations of the vapor condensation temperature, plant is the produced freshwater, the analysis shows that the
Tvn. decrease in the freshwater in the 3 stages is more less than in
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001
Optimum numerical approach of a MSF desalination plant 5
Table 1 Effect of different numbers of heat rejection stages on the power plant performance.
No. of stages Ab brine Ar recovery Aj rejection Md Mr recycle Xb brine (GOR)
heater section heat section heat distilled brine water salinity gain
transfer area transfer area transfer area water (kg/ (kg/s) (ppm) output
(m2) (m2) (m2) s) ratio
2 stages in 21396.54 54819.73 26777.28 2765.844 16831.16 88648 10.87
rejection and
26 in rec. sec.
3 stages in 19200.92 15169.22 13123.75 2229.201 13452 79800 8.76
rejection and
25 in rec. sec.
4 stages in 17497.15 5845.574 8427.853 1410.015 8411.13 68040 5.54
rejection and
24 in rec. sec.
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001
6 O.A. Kotb
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001
Optimum numerical approach of a MSF desalination plant 7
Table 6 Temperature values (C) for the different streams within the chambers.
Stage Temperature of intake Temperature of effluent Temperature of Temperature of
number recycle brine recycle brine intake brine effluent brine
1 130.864 134.65 146 142.214
2 127.078 130.864 142.214 138.428
3 123.292 127.078 138.428 134.642
4 119.506 123.292 134.642 130.856
5 115.72 119.506 130.856 127.07
6 111.934 115.72 127.07 123.284
7 108.148 111.934 123.284 119.498
8 104.362 108.148 119.498 115.712
9 100.576 104.362 115.712 111.926
10 96.79 100.576 111.926 108.14
11 93.004 96.79 108.14 104.354
12 89.218 93.004 104.354 100.568
13 85.432 89.218 100.568 96.782
14 81.646 85.432 96.782 92.996
15 77.86 81.646 92.996 89.21
16 74.074 77.86 89.21 85.424
17 70.288 74.074 85.424 81.638
18 66.502 70.288 81.638 77.852
19 62.716 66.502 77.852 74.066
20 58.93 62.716 74.066 70.28
21 55.144 58.93 70.28 66.494
22 51.358 55.144 66.494 62.708
23 47.572 51.358 62.708 58.922
24 43.786 47.572 58.922 55.136
25 40 43.786 55.136 51.35
26 36 40 51.35 47.564
27 32 36 47.564 43.778
28 28 32 43.778 40
Table 7 Calculated pressure and brine salinity for all flashing Table 8 Values of some of the calculated performance
stages. parameters.
Stage number Pressure (bar) Brine salinity (ppm) Parameter Value
1 3.6367 67,000 Distillate capacity, ton/d 192602.88
2 3.25 67444.91 GOR 8.76
3 2.923 67891.61 Intake seawater flow rate, kg/s 6109.24
4 2.60937 68340.16 Blow down flow rate, kg/s 2271
5 2.32353 68790.63 Recycle brine flow rate, kg/s 13452
6 2.066313 69243.08 Make-up flow rate, kg/s 4500
7 1.834 696975.8 Rejected coolant flow rate, kg/s (Mcw + Mf) 10609.24
8 1.62483 70154.18 Distillate flow rate, kg/s 2229.48
9 1.433 70612.94 Steam flow rate to brine heater, kg/s 254.5
10 1.26 71073.93 Steam temperature to brine heater, C 156
11 1.10849 71537.2 Steam flow rate to deaerator, kg/s 130.53
12 0.96875 72002.78 Steam temperature to deaerator, C 275.9
13 0.84375 72470.75 Blow down concentration, ppm 79800
14 0.732 72941.14 Heat transfer area for heat rejection section, m2 13123.23
15 0.64368 73413.99 Heat transfer area for heat recovery section, m2 15169.22
16 0.5479 73889.35 Heat transfer area for brine heater, m2 19200.92
17 0.4689 74367.25
18 0.40 74847.74
19 0.3443 75330.84
20 0.29 75816.58
21 0.25 76304.99 The table shows that the stage length is decreasing initially
22 0.20 76796.09 and then increasing, this referred to the steam density which
23 0.1742 77289.9 decreased with decreasing the pressure at the first 7 stages with
24 0.15 77786.44
high percentage, after that it decreased with low percentage.
25 0.1217 78285.72
26 0.10 78787.75
As mentioned earlier, total height of each chamber is
27 0.08174 79292.53 divided into four segments. The results of calculated gate
28 0.067274 79800.06 height, brine depth and demister height are presented in
Table 5. The distance between brine level and demister and
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001
8 O.A. Kotb
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001
Optimum numerical approach of a MSF desalination plant 9
Please cite this article in press as: Kotb OA, Optimum numerical approach of a MSF desalination plant to be supplied by a new specific 650 MW power plant located on
the Red Sea in Egypt, Ain Shams Eng J (2014), http://dx.doi.org/10.1016/j.asej.2014.09.001