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23-06-2024
9610WJA801160240006 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Figure shows a block of mass m projected with velocity v0 towards a wedge. Consider all the
surfaces to be smooth. Block does not have sufficient energy to negotiate (over come) wedge. Mark

the correct option(s)

when block is at the maximum height on wedge, block and wedge have velocity equal to velocity
(A)
of centre of mass of block wedge system
wedge acquires maximum speed with respect to ground when block returns to lowest point on
(B)
wedge.
(C) momentum of wedge and block is conserved at all times
(D) centre of mass of wedge and block remains stationary

2) A particle of mass m is projected up from the bottom of an smooth inclined plane with initial
velocity v0 at angle 45° with an inclined plane of inclination 30° as shown in figure. At the same time
a small block of same mass m is released from rest at a height h, the particle hits the block at some
point on inclined plane. (take g = 10 m/s2) (size of the block is negligible)

(A)
The value of height h is .

(B)
The value of height h is .
If the particle stick to the block after collision, the velocity of block parallel to the inclined plane
(C)
just after collision will be .
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If the particle stick to the block after collision, the velocity of block parallel to the inclined plane
(D)
just after collision will be .

3) A particle falls freely near the surface of the earth. Consider a fixed point O (not vertically below
the particle) on the ground.

(A) Angular momentum of the particle about O is increasing.

(B) Torque of the gravitational force on the particle about O is decreasing.
(C) The moment of inertia of the particle about O is decreasing.
(D) The angular velocity of the particle about O is increasing.

4) A rigid uniform bar AB of length L is slipping from its vertical position on a frictionless floor (as
shown in the figure). At some instant of time, the angle made by the bar with the vertical is θ. Which

of the following statements about its motion is/are correct ?

When the bar makes an angle θ with the vertical, the displacement of its midpoint from the
(A)
initial position is proportional to (1 – cosθ)
(B) The midpoint of the bar will fall vertically downward
(C) Instantaneous torque about the point in contact with the floor is proportional to sinθ
(D) The trajectory of the point A is a parabola

5) The moment of inertia of a thin uniform square plate ABCD of uniform thickness about an axis

passing through the centre O and perpendicular to the plate is - where I1 , I2 , I3

, and I4 are respectively the moments of inertia about axis 1, 2, 3, and 4 which are in the plane of the
plate.

(A) I1 + I2
(B) I3 + I4
(C) I1 + I3
(D) I1 + I2 + I3 + I4

6) In the figure shown, A & B are free to move. All the surfaces are smooth.
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(A) The acceleration of A will be more than gSinθ

(B) The acceleration of A will be less than gSinθ
(C) Normal force on A due to B will be more than mgCosθ
(D) Normal force on A due to B will be less than mgCosθ

7) A Freerunner of mass 60 kg starts sliding down a narrow valley of rough walls from rest, friction
coefficient between his gear and walls is μ = 0.5. He is able to push a wall with force of 300N with
he help of other wall, as he doesn’t move horizontally. He has trained his legs to withstand an
Impulse of 600 kgm/s upon impact on ground. Concerning his safety, answer the following.

(A) Maximum height he can start sliding from is 10m

(B) Maximum height he can start sliding from is 6.66 m
(C) Energy dissipated by friction while sliding from Maximum height is 3 KJ.
(D) He can achieve Equilbrium mid-sliding if he pushes the walls with 600N of force.

8) A boy is riding a bicycle on a circular track of radius 49m with a constant speed 7m/s. As a train
800m long approaches a nearby train track with a constant speed of 54km/hr. Each coach (C-1, C-2,
C-3….) of train is 25m long and the train is lead by a 50 m long Engine. Boy only notices the coach
nearest to him as the train passes. Tick the correct answer as seen by boy considering the initial
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situation as shown in figure.

(A) Engine of the train seems slowest to the boy.

(B) Coach no-6 is the fastest moving coach.
(C) Coach no-12 is the fastest moving coach.
(D) Coach no-26 is the slowest moving coach

SECTION-I (ii)

1) MA = 50 kg, MB = 70 kg, MP = 80 kg

(A) A → R, B →P, C → S, D → Q
(B) A → P, B →S, C → R, D → Q
(C) A → R, B →P, C → Q, D → S
(D) A → R, B → P, C → U, D → T

2) MA = 90 kg, MB = 120 kg, MP = 90 kg

(A) A → R, B →P, C → S, D → Q
(B) A → P, B →S, C → R, D → Q
(C) A → R, B →P, C → Q, D → S
(D) A → R, B → P, C → U, D → T

3) v= t m/s, where t is time in seconds and R = 1m.

(A) P→2, Q→2, R→5, S→3

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(B) P→2, Q→2, R→4, S→6

(C) P→1, Q→2, R→4, S→3
(D) P→1, Q→2, R→3, S→ 4

4) v = t2 m/s where t is time in seconds and R =0.5 m

(A) P→2, Q→3, R→4, S→5

(B) P→3, Q→4, R→5, S→6
(C) P→1, Q→2, R→3, S→6
(D) P→3, Q→4, R→6, S→4

SECTION-II

1) A uniform rod of mass 15 kg and length 5 m is pivoted at one end and is held stationary with the
help of a light string as shown in the figure. The tension in the string is 200x. Find x.

2)

In the pulley system shown, if radii of the bigger and smaller pulley are 2m and 1m respectively and
the acceleration of block A is in the downward direction, then the acceleration of block B will
be then n is

3) Consider the following sketch of potential energy for a particle as a function of position. There are
no dissipative forces or internal sources of energy. The maximum total mechanical energy (in Joule)
that the particle can have if it is to be trapped within the region of x shown is
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4) A ring with mass m is hung vertically at the lower end of a uniform chain of total mass m and
length L. Its upper end A is fixed, as shown in figure (a). The lower end B is raised until it is at the
same position as A, and the ring slides to the midpoint of the chain, as shown in figure (b). The

minimum work required in this process is xmgL. The value of x is

5) A ball is dropped from height 20m. As it keep bouncing off the ground, the number of bounces till
ball covers 33m of distance in its journey is n, then n is. (e = ½ between ball and ground):

6) A smooth track in the form of a quarter circle of radius 6 m lies in the vertical plane. A particle
moves from P1 to P2 under the action of forces and . Force is always toward P2 and is
always 20N in magnitude. Force always acts horizontally and is always 30 N in magnitude. Force
always acts tangentially to the track and is of magnitude 15 N. Let work done by F1, F2 and F3 be

x, y and z. Report the value .

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PART-2 : CHEMISTRY

SECTION-I (i)

1) Select the correct statement :

Thermodynamics equilibrium involves, chemical, mechanical and thermal equilibrium

(A)
simultaneously.
Molar entropy, specific volume, volume, internal energy and heat capacity are extensive
(B)
properties.
(C) Melting point boiling point, pH and EMF of the cell are intensive properties.
(D) Mechanical work is specially important in system that contain gas liquids system.

2) Select the correct statement :

(A)
For an ideal gas,
An ideal gas at pressure P and temperature T in a box, is kept in vacuum with a large container.
(B) The wall of the box is punctured and gas occupies entire container then the temperature of gas
rises.
(C) For the reaction :

A sample of ideal gas is expanded from 1 m3 to 2m3 in a reversible process for which P = KV2
(D)
with K = 3 bar m–6. Work done by the gas is –700 kJ

3) Which of the following statements about a weak acid strong base titration is/are correct ?

The pH after the equivalence point of the weak acid strong base titration is determined by using
(A)
the Kb expression for the conjugate base.
A buffer solution of weak acid and its conjugate base is formed before the equivalence is
(B)
reached.
The pH at the equivalence point of a weak monoprotic acid strong base titration is equal to the
(C)
pH at equivalence point of a strong acid - strong base titration.
The increase in pH in the region near the equivalence point of a weak acid strong base titration
(D)
is grater than the pH change in the same region of a strong acid strong base titration.

4) Aqueous solution of HNO3, CH3COOH, and CH3COOK of identical concentrations are given. The
pair (s) of the solution which may form a buffer upon mixing is (are).

(A) NaOH and CH3COOH

(B) HNO3 and CH3COOK
(C) CH3COOH and CH3COOK
(D) HNO3 + CH3COOH

5) At 90oC pure water has [H+] = 10−6 M. Based on this correct statement is (are) :

(A) Increasing the temperature, increases degree of ionization of water

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(B) At 60oC, pH of pure water will be less than 6

(C) At 90oC, pH of a 10−6 M HCl solution will be less than 6
o −12
(D) Ionization constant (Ka) of H2O at 90 C is 10

6) Let the colour of the indicator HIn (colourless) will be visible only when its ionised form (pink) is
25% or more in a solution. Suppose HIn(pKa = 9.0) is added to a solution of pH = 9.6 predict what
will happen (Take log 2 = 0.3)

(A) pink colour will be visible

(B) pink colour will not be visible
(C) % of ionised form will be less than 25%
(D) % of ionised form will be more than 25%

7) For a reaction N2 + 3H2 ⇌ 2NH3, the value of KC does not depends upon :

(A) Initial concentration of the reactants

(B) Pressure
(C) Temperature
(D) catalyst

8) In an evacuated vessel of capacity 100 litres, 4 moles of Argon and 5 moles of PCl5 were
introduced and equilibrated at a temperature of 227 °C. At equilibrium, the total pressure of the
mixture was found to be 4.8 atm. Select the correct relation about the reaction.
PCl5(g) PCl3(g) + Cl2(g); at this temperature. (R = 0.08 L atm/mol.K)

(A) Degree of dissociation of PCl5 is 0.6

(B) KP = 1.8 atm
(C) Degree of dissociation of PCl5 is 0.5
(D) Total mole at Equilibrium = 12

SECTION-I (ii)

1)

List–I List–II

(P) Constant boiling mixture (1) 2nd order reaction

(Q) Cryoscopic constant (2) Azeotrope

(R) t3/4 = 2t1/2 (A → B, single step) (3) 1st order reaction

(S) (4) Solvent

(5) zero order reaction

(6) solute
(A) P → 3;Q → 2;R → 1;S → 4
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(B) P → 1;Q → 2;R → 3;S → 4

(C) P → 2;Q → 4;R → 3;S → 1
(D) P → 4;Q → 2;R → 1;S → 3

2)

List-I
List-II
(Consider the following reaction at 25°C)

(P) N2(g) + 3H2(g) 2NH3(g) (1) Δng > 0

(Q) PCl5(g) PCl3(g) + Cl2(g) (2) Kp < Kc

(R) 2SO3(g) 2SO2(g) + O2(g) (3) Kp not defined

(S) CH3COOC2H5(ℓ) + H2O(ℓ) C2H5OH(ℓ) + CH3COOH(ℓ) (4) Kp > Kc

(A) P → 1;Q → 2;R → 1;S → 4
(B) P → 2;Q → 1;R → 4;S → 1
(C) P → 2;Q → 1;R → 1;S → 4
(D) P → 2;Q → 1;R → 4;S → 3

3)

Match the thermodynamic processes given list I with the expressions given under list II.

List-I List-II

(P) Melting of ice at 273 K and 1 atm (1) q = 0

(Q) Expansion of 1 mol of an ideal gas into a vacuum under isolated conditions (2) w = 0

Mixing of equal volumes of two ideal gases at constant temperature and

(R) (3) ΔSsys > 0
pressure in an isolated container

Reversible heating of H2(g) (ideal) at 1 atm from 300 K to 600 K, followed by

(S) (4) ΔU = 0
reversible cooling to 300 K at 1 atm

(5) ΔG = 0
(A) P → 4,5;Q → 3,4;R → 2,3,4;S → 2,4,5
(B) P → 1,4,5;Q → 2,3,4;R → 3,4;S → 1,5
(C) P → 1,2,3,4,5;Q → 1,2,3;R → 3,4;S → 1,5
(D) P → 3,5;Q → 1,2,3,4;R → 1,2,3,4;S → 1,2,4,5

4) Note : log2 = 0.3 : All data are at 25°C

List-I List-II

1 M XOH(aq.)
(P) (1) [H+] > [OH–]
[(pKb (XOH) = 6)]

0.1M C6H5NH2(aq.)
(Q) (2) pH = 2.4
[pKb(C6H5NH2) = 7]
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At equivalence point when 20 ml of

(R) 0.5 M BOH is titrated with 2M HCl (3) pOH = 3
[Kb(BOH) = 1/4 × 10–9 M]

20 ml 0.125 M, C5H5NHCl + 5 ml,

(S) 5 × 10–3 M HCl (4) pH = 10
[Kb (C5H5N) = 5 × 10–10 M]

(5) pH = 13

The correct option is

(A) P → 3;Q → 4;R → 1,2;S → 1
(B) P → 1,4;Q → 3;R → 1,3;S → 3
(C) P → 1,3;Q → 2,4;R → 1,2;S → 4
(D) P → 3,4;Q → 1;R → 1,2;S → 2

SECTION-II

1) A 1 molal K4Fe(CN)6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of
another solution which contains 18.1 weight percent of a non electrolytic solute A. The molar mass
of A is_____ g/mol.
(Round off to the Nearest Integer).
[Density of water = 1.0 g cm–3]

2) What is the percentage composition of oxygen in zincphosphate Zn3(PO4)2? (Answer up to nearest

integer)
(Zn = 65.5, P = 31, O = 16)

3) The efficiency of Carnot cycle is . On decreasing the temperature of the sink by 65°C, the

efficiency increases to . The ratio of temperature (in °C) of source to sink is : [Given 1°C = 274 K]

4) For the formation of C (g) at 300 K. A (g) + 3 B (g) → 2C (g)

Calculate the magnitude of ΔG (Kcal) if given data :

A B C

ΔfH (Kcal mol-1) 0 0 -10

ΔfS (Cal K–1 mol-1) 40 30 45

5) The direct conversion of A to B is difficult, hence it is carried out by the following shown path :

Given:
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ΔS(A → C) = 50 e.u.
ΔS(C → D) = 30 e.u.
ΔS(B → D) = 20 e.u.
Where e.u. is entropy unit then ΔS(A → B) in e.u is :

6)

Given that

P4(s) + 3Cl2(g) → 2PCl3(ℓ) ΔH = –600 kJ

PCl3(ℓ) + Cl2(g) → PCl5(s) ΔH = –200 kJ
Heat of formation of PCl5(s) is (–x × 102 kJ), value of x is :

PART-3 : MATHEMATICS

SECTION-I (i)

1) If ƒ(x) is defined from [2, 4] → [8, 16] is bijective function, then

(A)
domain of ƒ(2x + 3) is
(B) range of 2ƒ(x + 1) is [8, 16]
(C) domain of ƒ(x + 1) is [1, 3]
(D) range of ƒ(2x + 3) is [8, 16]

2) Let ƒ : R → (0, π) be defined as then which of the following statement(s)

is/are true

(A) ƒ(x) is neither injective nor surjective

(B) ƒ(x) is continuous on R
(C) ƒ(x) is both even function and aperiodic function

(D)

3) Let < Tn> be the sequence of number such that T1 = 1. Let . If Sm+n – Sm – Sn = mn.
Then which of the following holds good ?

(A) S100 = 5050

(B) S10 = 50
(C) T100 = 100
(D) T10 = 50
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4) If is an odd function ∀ x ∈ , (where [.]

is greatest integer function) then possible integer value(s) of m is (are) -

(A) 4
(B) 5
(C) 6
(D) 9

5) If ƒ : R → R be a derivable function such that ƒ'(0) = ℓn2 and ƒ(x + y) = 2xƒ(y) + 22yƒ(x) ∀ x, y ∈ R,
then

(A) ƒ(x) is a one-one function

(B) ƒ(x) is a many one function
(C) equation ƒ(x) = 2 has exactly two solutions
(D) equation ƒ(x) = 2 has exactly one solution

6) Let P and Q are two sets defined as P = and Q = {x | sin x + cos

x = 1}. Then :

(A) P = Q
(B) P ⊂ Q
(C) Q ⊂ P
(D) P = ϕ

7) If is a sequence of positive numbers which are in A.P. with common difference d

and then and

Maximum value of (where S and W are coprime), then :

(A) M = 49
(B) N = 98
(C) S = 49
(D) W = 2

8) Let , then choose correct option(s)

(A)
∀ x ∈ [–2, 2]

(B)
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(C)
∀x∈

(D)
∀ x ∈ [–3, 3]

SECTION-I (ii)

1) Which of the following options is the only CORRECT combination ?

(A) P 4
(B) Q 1
(C) R 3
(D) S - 2

2) Which of the following options is the only CORRECT combination ?

(A) P 1
(B) Q 2
(C) R 3
(D) S - 1

3) Which of the following is the only CORRECT combination?

(A) (II), (R), (S)

(B) (I), (Q), (U)
(C) (II), (Q), (T)
(D) (I), (P), (R)

4) Which of the following is the only CORRECT combination?

(A) (IV), (P), (R), (S)

(B) (III), (P), (Q), (U)
(C) (IV), (Q), (T)
(D) (III), (R), (U)

SECTION-II

1) If sin–1(x2) = cos–1x, then x4 + x2 is :-

2) Let ƒ : → ,ƒ be a function such that x = m is the solution of ƒ(x) +

2ƒ–1(x) + 2 = ƒ(ƒ(x)), then m is equal to

3) If ƒ(x) = x11 + x9 – x7 + x3 + 1, then ƒ(sin–1(sin3)) + ƒ(tan–1(tan3)) is equal to

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4) If x = y cos = z cos , then xy + yz + zx is equal to

5) If S denotes the sum of first 24 terms of series then is equal to

6) If 's' is sum of the roots of the equation 2[x + 15] + 5x – 1 = 17{x + 3}; where [ . ] represents
greatest integer function and { . } represents fractional part function, then the values of (4|s|) is
equal to :
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ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7 8
A. A,B A,D A,C,D A,B,C A,B,C A,D A,C,D A,C,D

SECTION-I (ii)

Q. 9 10 11 12
A. A A C B

SECTION-II

Q. 13 14 15 16 17 18
A. 0.50 2.50 6.00 0.75 3.00 345.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24 25 26
A. A,C,D A,C,D A,B A,B,C A,C A,D A,B,D A,B,D

SECTION-I (ii)

Q. 27 28 29 30
A. C B D A

SECTION-II

Q. 31 32 33 34 35 36
A. 85.00 33.00 2.25 8.00 60.00 5.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42 43 44
A. A,C,D A,B,C,D A,C A,B,C,D B,D B,D A,B,C,D A,B,C

SECTION-I (ii)

Q. 45 46 47 48
A. A B C A
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SECTION-II

Q. 49 50 51 52 53 54
A. 1.00 2.00 2.00 0.00 6.00 25.00
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SOLUTIONS

PART-1 : PHYSICS

1)

(i) in horizontal direction momentum is conserved. when block is at maximum height it would
be stationary w.r.t. plank.
So vblock = vplank = vcm
(ii) PE + KE = constant
(iii) momentum is not conserved at all time.
(iv) vcm ≠ 0

2)

since x1 + x2 = 2h

From conservation of momentum along the inclined plane

mvx + mvx' = 2mvf

3)

L = mvl
as v↑ ∴ L↑
L = Iω ⇒ L↑, ⇒ ω↑
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τ same

4) When the bar makes an angle θ; the height of its COM (mid point) is

∴ displacement = –
Since force on COM is only along the vertical direction, hence COM is falling vertically
downward.
Instantaneous torque about point of contact is

Mg × sinθ
Now;

x = sinθ
y =Lcosθ

Path of A is an ellipse.

5)

Using perpendicular theorem

I0 = I4 + I3 I3 = I4
I0 = I1 + I2 I2 = I1
I3 = I2
so, (I0 = I1 + I3)

6)
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acceleration of A

7) Max impulse = 600 Kg m/s max velocity

Normal at each wall = 300 N
Friction at each wall = 300 × 0.5 = 150 N

max height =
energy dissipated
Equilibrium Fnet = 0 = mg – F
F = mg = μN × 2

8) VB = 7 m/s VT = 54 ×
Boy will see a coach to be moving slowest when he is at the far right point, and fastest when

he is at left most point. Time for 1 circle

Slowest Time = 11 Sec, 11 + 44 sec, 11 + 44 + 44 ...
Fastest Time = 33 Sec, 33 + 44 Sec, 33 + 44 + 44 sec.
at T = O, front of train is at x = –149
Slowest :
at T = 11 sec, x = – 149 + 15 × 11 = 16 m i.e. Engine (50 m)

at T = 55 sec, x = – 149 + 15 × 55 = 676 i.e. 26th coach.

No more slowest coaches as train will have passed through.
fastest:

at T = 33 sec, x = –149 + 15 × 33 = 346 i.e. 12th coach.

at T = 77 sec, x = –149 + 15 × 77 = 1006 > Train length = Train has passed.

9) (A) zero

(B)
(C)
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(D) x – 2 = –1.8m(Left)

10) (A) zero

(B)
(C)
(D)

11)
(v = t m/s)
aT = (αR) = (1)

12) v = t2 m/s aT = 2t = 2 m/s2

13)
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T = 100 N

14)

15) For particle to be trapped, TME ≤ 6 J

16)

17)

height ...
Total distance = h0 + 2h1 + 2h2 + 2h3 + ...
h0 + 2h1 + 2h2 + 2h3 = 33.125 > 33
Between 3rd and 4th bounce, ball will reach a total distance travelled of 33 m.

18)

PART-2 : CHEMISTRY

19)

Statement (2) is incorrect

Correct (2) Molar entropy and specific volume are intensive but entropy and volume are extensive
properties.
Explanation for (1, 3, 4)
1. If a system is subjected to chemical equilibrium mechanical and thermal equilibrium then system
is considered in thermodynamic equilibrium.
3. All of them are independent of the amount of substance present.
4. Work involves, changes in volume, which is possible only in gas-liquid system
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It is not important when the system contain liquid-liquid solid-solid and amalgam.

20)

Statement (2) is incorrect .

Correct (2) its temperature remains the same
Work in vacuum = 0
∴ w = – PΔV = 0
∴ ΔU = q + w = 0
Explanation of (1, 3, and 4)
1. For an ideal gas, no intermolecular force act between gaseous molecules.
3. Δng = (2 – 1) = 1
∴ ΔH = ΔU + Δng RT (∴ ΔH > ΔU)

4.

=–3 bar. m3.

21) Factual statements

22) Since concentrations are identical

If V1 is the volume of CH3COOH and V2 is the volume of NaOH.

1. CH3COOH + NaOH Buffer is formed if V1 > V2

V1 V2
M1 M2
mmol of CH3COOH(M1V1) > mmol of NaOH (M2V2).
So WA is left and buffer is formed.

2. CH3COOK + HNO3 → CH3COOH + KNO3

V1 V2
M1 M2
Buffer is formed V1 > V2
mmol of salt (CH3COOK) > mmol of HNO3.
Some salt is hydrolysed to give CH3COOH and some salt CH3COOK is left

3. CH3COOH + CH3COOK
V1 V2
Forms always a buffer. Mixture of WA and salt of WA/SB.

4. HNO3 + CH3COOH] It is a mixture of SA and WA

23) Increasing the temperature, increases degree of ionization of water.

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At 90oC, pH of a 10−6 M HCl solution will be less than 6.

24) HIn → H+ + In–

25)

Equilibrium const. is temp. dependent only.

26)

nTotal =

nTotal = 5 – 5α + 5α + 5α + 4 = 12
α = 0.6

27)

Match the column :-

(P) Constant boling mixture → Azeotrope
(Q) Cryscopic constant is property of solvent.
(R) A → B first order reaction

(S) 2A → P second order reaction.

So First

After first t1/2 :-

So, 2nd t1/2 =

After 2nd t1/2 :- [A] = So 3rd

So Ist t1/2 :2nd t1/2 : 3rd t1/2 = 1 : 2 : 4
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28)

Kp = Kc (RT)Δn g

29) (P) H2O(s) ⇌ H2O(ℓ)1 atm and 273 K.

∵ Endohtermic reaction ∴ q > 0
also volume decrease ∴ w > 0
∴ ΔSsys > 0 ΔU > 0
Also since reaction is at equilibirum ∴ ΔG = 0
(Q) ∵ isolated condition ∴ q = 0, also expansion against vacuum ∴ w = 0 ∴ ΔU = 0, also Ideal
gas
∴ Temperature remains constant.
Also, entropy increases
Also for physical process
dG = VdP – SdT
∴ it will be < 0
(R) ∵ isolated container ∴ q = 0 and w = 0
∵ Gases are gettting mixed ∴ entropy of system is increasing
Also ΔU = 0 (∵ ΔU = q + w)
Also ∵ mixing is spontaneous ∴ ΔG < 0
(S) ∵ Reversible heating and cooling
∴ initial and find state will be same.
hence all state functions will remain same.
Also q and w for heating and cooling will be opposite of each other
∴ overall q = 0
∴ overall w = 0

30)

(P) 10–6 = ⇒ x = 10–3 ; pOH = 3 ; pH = 11

(Q) 10–7 = ⇒ x = 10–4 ; pOH = 4 , pH = 10

(R) BOH + HCl → BCl + H2O
20 × 0.5 2×V 20 × 0.5

[BCl] =

pH = 7 -

(S) ⇒ x = 10–3
+ –3 –3 –3
[H ] = 10 + 10 = 2 × 10 ⇒ pH = 2.7

31)

K4 Fe(CN)6 4K+ + Fe(CN)64–

Initial conc. 1m 0 0
Final conc. (1 – 0.4)m 4 × 0.4 0.4m
= 0.6 m = 1.6 m
Effective molality = 0.6 + 1.6 + 0.4 = 2.6m
 Page 25 of 31

For same boiling point, the molality of another solution should also be 2.6 m.
Now, 18.1 weight percent solution means 18.1 gm solute is present in 100 gm solution and hence,
(100 – 18.1 =) 81.9 gm water.

Now, 2.6 =
∴ Molar mass of solute, M = 85

32)

Mw of Zn3(PO4)2 = 65.5 × 3 + 2[31 + 16 × 4]

= 196.5 + 2 × 95 = 386.5

% Zn =

% of P =

% of O =

33)

⇒ ⇒

⇒ ....(1)

⇒ ⇒

⇒ ....(2)
by equation (1) & (2)

T1 = 390 K = 117°C

and = 325K = 52°C

34)

ΔHf = 2 × (– 10) = – 20

ΔS = 90 – (40 + 90) = – 40
ΔG = ΔH – TΔS = – 20 + 12 = – 8

35)

A→C; ΔS=50;C→D; ΔS = 30;

D→B;ΔS=−20
For A→B; ΔS = 50 + 30−20 = 60
 Page 26 of 31

36) PCl5(s) ....(1)

+ 3Cl2 → 2PCl3(ℓ) ....(2)

PCl3(ℓ) + Cl2(g) → PCl5(s) ....(3)

On applying thermodynamic operation (1) = (3) + (2)

= –200 + (– 600)
= – 500 kJ = – 5 × 102 kJ

PART-3 : MATHEMATICS

37)

Domain of ƒ(x) = [2, 4]

⇒2≤x≤4
Range of ƒ(x) = [8,16] ⇒ 8 ≤ ƒ(x) ≤ 16

for ƒ(2x + 3) : 2 ≤ 2x + 3 ≤ 4 ⇒
Range of ƒ(2x + 3) 8 ≤ ƒ(2x + 3) ≤ 16
for ƒ(x + 1) : 2 ≤ x + 1 ≤ 4 ⇒ 1 ≤ x ≤ 3
8 ≤ ƒ(x + 1) ≤ 16 ⇒ 16 ≤ 2ƒ(x + 1) ≤ 32

38)

Now check the options

39) Put m = 1
So, Sn+1 – Sn – S1 = n(1)
⇒ Tn+1 = n + S1 = n + 1
⇒ Tr = r
⇒ T100 = 100

and
Aliter :
 Page 27 of 31

Sm+n – Sm – Sn = mn
⇒ S2 – S1 – S1 = 1 ⇒ S2 = 1 + 2 = 3
⇒ T2 = 2
and S3 – S2 – S1 = 2(1)
⇒ T3 = S3 – S2 = 3
and S4 – S2 – S2 = (2) (2)
⇒ S4 = 10 ⇒ T4 = S4 – S3 = 4
⇒ S4 = 4 + 6 = 10
So the given sequence is 1,2,3,4

T100 = 100 and S100 =

40)

f(–x) + f(x) = 0

2
0≤ < 1 ⇒ 2m + 1 > x & 2m + 1 > 0
as 2m + 1 > 8

as x2 ∈ [0, 8] or m > &

41)

ƒ(x + y) = 2xƒ(y) + 4yƒ(x) ...... (i)

Replace x by y and y by x :
ƒ(x + y) = 2yƒ(x) + 4x.ƒ(y) ...... (ii)
By (i) and (ii)
2xƒ(y) + 4yƒ(x) = 2yƒ(x) + 4xƒ(y)

⇒
⇒ ƒ(x) = k.(4x – 2x)
∴ ƒ'(x) = k(4xℓn4 – 2xℓn2)
∵ ƒ'(0) = ℓn2 ⇒ k = 1
∴ ƒ(x) = 4x – 2x
Many one function.
ƒ(x) = 2 ⇒ (2x)2 – 2x = 2 ⇒ x = 1 only

42)

sin3 x + cos3 x – 1 = –3 sin x cos x

⇒ sin x + cos x – 1 = 0
⇒ sin x + cos x = 1

⇒
 Page 28 of 31

⇒ or 2nπ, n ∈ I
∴x∈ϕ { sin 2x ≠ 0}
⇒ P = ϕ,

43)

Using

∴
⇒ S = 49 and W = 2

...(1)

Also,

44)

cos–1sin(cos–1x) + sin–1cos(sin–1x)

∴ h(x) = 1
∀ x ∈ domain

45)

(P) ƒ(x) = ƒ(x + 8)

⇒ Periodic function with period 8

ƒ(–89) – ƒ(–67) + ƒ(46)

= ƒ(–1) – ƒ(–3) + ƒ(–2)
=3–1+2=4
(Q) 2ƒ(x) + ƒ(–x) = cosx ...I
replace x by –x
2ƒ(–x) + ƒ(x) = cosx ...II

solving I & II
|3ƒ(π)| = 1
 Page 29 of 31

(R)
(S) (log2x) (log2x) .....∞ = 0 for 1 < x < 2
⇒ ƒ(x) = 4

46)

(P) ƒ(x) = ƒ(x + 8)

⇒ Periodic function with period 8

ƒ(–89) – ƒ(–67) + ƒ(46)

= ƒ(–1) – ƒ(–3) + ƒ(–2)
=3–1+2=4
(Q) 2ƒ(x) + ƒ(–x) = cosx ...I
replace x by –x
2ƒ(–x) + ƒ(x) = cosx ...II

solving I & II
|3ƒ(π)| = 1

(R)
(S) (log2x) (log2x) .....∞ = 0 for 1 < x < 2
⇒ ƒ(x) = 4

48)

cosx = 0, cosx = 1
 Page 30 of 31

⇒ I – (P), (Q)
II – (Q), (T)
III – (R))
IV – (P), (R), (S)

49)

As sin–1(x2) = cos–1x ⇒ x>0

–1 2 –1
sin (x ) = sin
⇒ x4 + x2 = 1

50)

ƒ–1(x) = ⇒ ƒ(x) = ƒ–1(x)

⇒ ƒ(ƒ(x)) = x
⇒ ƒ(x) + 2ƒ–1(x) + 2 = ƒ(ƒ(x))

reduces to

⇒
⇒ 2(x – 2)(2 – x) = 0 ⇒ x = 2

51)

sin–1(sin3) = π – 3
tan–1(tan3) = 3 – π
so ƒ(π – 3) + ƒ(3 – π)
Let (π – 3) = t
ƒ(t) + ƒ(–t) = 2

52)

xy + yz + zx

Given

53)
 Page 31 of 31

∴ Sum of first 24 terms

54)

2[x + 15] + 5x – 1 = 17 {x + 3}
⇒ 2[x] + 30 + 5[x] + 5{x} – 1 = 17{x}

⇒ {x} = …(i)
but {x} ∈ [0, 1) so

but [x] is an integer, so possible value of [x] are –4, –3

for [x] = –4, {x} = so x =

for [x] = –3, {x} = so x =

s=