KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD REGION

CLASS: XII WORKSHEET No: 01

CHAPTER: SOLUTION TIME: 35 MINUTES

Q.1 Increasing the temperature of an aqueous solution will cause:

(a) decrease in molality (b) decrease in molarity
(c) decrease in mole fraction (d) decrease in % (w/w)
Q.2 The value of Henry’s constant KH is:
(a) greater for gases with higher solubility (b) greater for gases with lower solubility.
(c) constant for all gases. (d) not related to the solubility of gases
Q.3 Which of the following condition is not satisfied by an ideal solution?
(a) ΔHmixing = 0 (b) ΔVmixing = 0
(c) Raoult’s Law is obeyed (d) Formation of an azeotropic mixture
Q.4 If 2 gm of NaOH is present is 200 ml of its solution, its molarity will be_
(a) 0.25 mol L-1 (b) 0.5 mol L-1
-1
(c) 5 mol L (d) 1.0 mol L-1
Q.5 If two liquids A and B form minimum boiling azeotrope at some specific composition then _____.
(a) A–B interactions are stronger than those between A–A or B–B.
(b) vapour pressure of solution increases because a greater number of molecules of liquids A and B can
escape from the solution.
(c) vapour pressure of solution decreases because a smaller number of molecules of only one of the
liquids escape from the solution.
(d) A–B interactions are weaker than those between A–A or B–B
Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate
answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
Q.6 Assertion (A): Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points
either greater than both the components or less than both the components.
Reason (R): The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.
Q.7 Assertion (A): Soda bottles are sealed under high pressure.
Reason (R): High pressure increases the solubility of carbon dioxide gas
Answer the questions in short
Q.1 (a) Define Mole fraction: (b) Azeotropes
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.2 State the law co-relating the pressure & solubility of a gas in a liquid. State an application of this law.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
___________________________________________________________________________________
___________________________________________________________________________________
Q.3 What type of deviation is shown by mixture of ethanol and acetone? Give reason.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
___________________________________________________________________________________
Q.04 Write two differences between the solutions showing positive & negative deviation from
Raoult’s law.
Ans:
Solutions having Positive deviation Solutions having Negative deviation

Q.05 On mixing liquid X and liquid Y , the volume of the resulting solution increases _
(a) What type of deviation from Raoult’s law is shown by the resulting solution?
(b) What change in temperature would you observe after mixing liquids X and Y?
Ans:
(a) ___________________________________________________
(b) ___________________________________________________
Q.06 A solution of glucose (C6H12O6) in water is labelled as 10% by weight. What would be the molality
of the solution? (Molar mass of glucose = 180 g mol–1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.7 Give reason for followings
(a) Why are aquatic species more comfortable in cold water than in warm water?
(b) Deep sea divers are advised not to come to surface immediately from deep waters. Why?
(c) Cooking is faster in pressure cooker than in cooking pan
(d) Two liquids A and B boil at 120oC and 160oC respectively. Which of them has higher vapour
pressure at 70oC?
(e) Name the substances which are used by deep sea divers to neutralize the toxic effects of nitrogen
dissolved in the blood.

Ans:(a)_____________________________________________________________________________________
_____________________________________________________________________________________
Ans:(b)_____________________________________________________________________________________
_____________________________________________________________________________________
Ans:(c)_____________________________________________________________________________________
_____________________________________________________________________________________
Ans:(d) _________________________________________________
Ans:(e) __________________________________________________
 KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD REGION
CLASS: XII WORKSHEET No: 02
CHAPTER: SOLUTION TIME: 35 MINUTES
Q.1 Colligative properties depend on:
(a) the nature of the solute (b) the number of solute particles in solution
(c) the physical properties of solute (d) the nature of the solvent
Q.2 The most suitable colligative property to determine molecular weight of biomolecules is:
(a) Lowering of vapour pressure (b) Osmotic pressure
(c) Elevation of boiling point (d) Depression of freezing point
Q.3 Which has highest boiling point:
(a) 1 M Glucose (b) 1 M NaCl
(c) 1 M CaCl2 (d) 1 M AlF3
Q.4 A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small amount
of ‘A’ is added to the solution. The solution is _________.
(a) saturated (b) supersaturated
(c) unsaturated (d) concentrated
Q.5 The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are_____.
(a) 2, 2 and 2 (b) 2, 2 and 3
(c) 1, 1 and 2 (d) 1, 1 and 1

Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate
answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
Q.6 Assertion(A): Boiling point of 0.1 M KCl solution is higher than 0.1 M Glucose solution.
Reason: Glucose is a non-electrolyte while KCl molecule dissociates in aqueous state.
.
Q.07 Assertion (A): Human blood cell swell-up when it is placed in a NaCl solution having concentration more
than 0.9%.
Reason (R): Osmosis involves movement of solvent molecules from its higher concentration to its lower concentration.

Answer the questions in short

Q.1 Define (a) Abnormal molar mass: (b) van’t Hoff factor
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.2 Give reasons:
(a) RBC shrink when placed in saline water but swell in distilled water.
(b) 0.1 M KCl has higher boiling point than 0.1 M Glucose.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
______________________________________________________
Q.3 A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of water. This
solution has a boiling point of 100.420C. What mass of glycerol was dissolved to make this solution?
(Kb for water = 0.512 K Kg mol -1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_______________________________________________________________________________
Q.4 A solution containing 15 g urea (molarmass= 60 g mol–1) per liter solution in water has the Same
osmotic pressure (isotonic) as a solution of glucose (molar mass= 180 g mol –l) in water. Calculate the
mass of glucose present in one liter of its solution.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_______________________________________________________________________________
Q.5 Calculate the freezing point of a solution when 20 g of CaCl2 (M=111 g mol -1) was dissolved in 500
g of water, assuming CaCl2 undergoes complete ionization. (Kf for water = 1.86 K kg mol-1)
OR
Calculate the boiling points of solution when 2 gm of Na2SO4 (molecular mass 142 gm/mol) was
dissolved in 50 gm of water assuming Na2SO4 undergoes complete ionization. (Kb for water = 0.52 K Kg
mol-1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_____________________________________________________________________________
Q.6 A 5% solution (by mass ) of cane sugar in water has freezing point of 271 K. Calculate the freezing
point of 5% solution (by mass ) of glucose in water
(Molecular mass: Glucose C6H12O6 : 180 amu; Cane –sugar C12H22O11: 342 amu)
OR
3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62K.
Calculate the van’t Hoff factor and predict the nature of solute (associated or dissociated)
(Given molar mass of benzoic acid = 122 g mol -1, Kf for benzene = 4.9 K kg mol -1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
___________________________________________________________________________
 KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD REGION
CLASS: XII WORKSHEET No: 01
CHAPTER: ELECTROCHEMISTRY TIME: 35 MINUTES

Q.1 The difference between the electrode potentials of two electrodes when no current is drawn through
the cell is called______
(a) Cell potential (b) Cell emf (c) Potential difference (d) Cell voltage
Q.2 An electrochemical cell can behave like an electrolytic cell when ____
(a) Ecell = 0 (b) Ecell > Eext (c) Eext > Ecell (d) Ecell = Eext
Q.3 The positive value of the standard electrode potential of Cu2+/Cu indicates that ____
(I) This redox couple is a stronger reducing agent than the H+/H2 couple.
(II) this redox couple is a stronger oxidising agent than H+/H2.
(III) Cu can displace H2 from acid.
(IV) Cu cannot displace H2 from acid.
Identify the correct statement/s:
(a) Statement I & III (b) Statement I & IV
(c) Statement II & III (d) Statement II &IV
Q.4 Which of the following statement is wrong about a galvanic cell?
(a) cathode is positive charged (b) anode is negatively charged
(c) reduction takes place at the anode (c) reduction takes place at the cathode
Q.5 For the given cell, Incorrect option is:
Mg|Mg2+|| Cu2+|Cu
(a) Mg is Anode (b) The cell reaction is Mg2+ + Cu → Mg + Cu2+
(c) Cu is cathode (d) Cu is the oxidising agent

Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate
answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
Q.6 Assertion : Assertion: Copper sulphate can be stored in zinc vessel.
Reason: Zinc is more reactive than copper.

Q.7 Assertion: ECell should have a positive value for the cell to function.
Reason: for a possible/feasible cell reaction the reduction potential should be in order Ecathode < Eanode.

Answer the questions in short

Q.1 Given that the standard electrode potentials (Eo) of metals are
K+/K=-2.93 V, Ag+/Ag=+0.80 V,Cu2+/Cu=+0.34 V,Mg2+/Mg=2.97 V,Cr3+/Cr=-0.74 V, Fe2+/Fe=-0.44 V.
Arrange these metals in an increasing order of their reducing power.

Ans:____________________________________________________________________________________

Q.2 Fluoride does not exhibit any positive oxidation state. Why?
Ans:____________________________________________________________________________________

Q.3 Depict the galvanic cell in which the following reaction takes place:
Zn (s) + 2Ag+ (aq) → Zn+2 (aq) + 2Ag (s) Also indicate that in this cell:
(i) Which electrode is negatively charged?
(ii) What is the carrier of the current in the cell?
(iii) What is the individual reaction at each electrode?
Ans:(i)________________________________________________________________________________
(ii)__________________________________________________________________________________
(iii) __________________________________________________________________________________
Q.04 Calculate the standard cell potentials of galvanic cell in which the following reaction take place:
2Cr(s) + 3Cd2+(aq) → 2Cr3+(aq) + 3Cd
Calculate the ΔrG0 value for the reaction. Given E0(Cr3+/Cr) = -0.74 V ; E0 (Cd2+/Cd) = -0.40 V , F= 96500 C mol-1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.05 The cell where the following reaction occurs
2Fe3+ ( aq) + 2 I- (aq)  2 Fe2+ (aq) + I2 (s) has E0(cell) = 0.236 V at 298 K .
Calculate the standard Gibbs energy of the cell reaction. (Given: 1 F = 96500 C mol -1)

Ans:_______________________________________________________________________________________
_____________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
____________________________________________________________________________________
Q.06 A voltaic cell is set up at 250C with the following half cells:
Al| Al3+ (0.0010 M) and Ni | Ni2+ (0.50 M)
(i) Write the equation for the cell reaction that occurs when the cell generates an electric current.
(ii) Determine the cell potential. (Given E0 (Ni2+/Ni) = - 0.25 V , E0 (Al3+/Al) = -1.66 V)
(iii) Write the direction of flow of current when an external opposite potential applied is
(a) less than 1.41 V and (b) greater than 1.41 V
Ans:(i)______________________________________________________
Ans:(ii)_____________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
___________________________________________________________________________
Ans:(iii) (a) ___________________________________________________________
Ans:(iii) (b) ____________________________________________________________
Q.7 Calculate the log Kc for the given reaction at 298K :
Ni (s) + 2 Ag+ (aq) ↔ Ni2+ (aq) + 2 Ag (s)
Given: E0 Ni2+/Ni = -0.25 V, E0Ag+/Ag = +0.80 V , 1F = 96500 C mol-1

Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________
 KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD REGION
CLASS: XII WORKSHEET No: 02
CHAPTER: ELECTROCHEMISTRY TIME: 35 MINUTES

Q.1 Which of the statements about solutions of electrolytes is not correct?

(a) Conductivity of solution depends upon size of ions.
(b) Conductivity depends upon viscosiy of solution.
(c) Conductivity does not depend upon solvation of ions present in solution.
(d) Conductivity of solution increases with temperature.
Q.2 The quantity of charge required to obtain one mole of aluminium from Al2O3 is ___________.
(a) 1F (b) 6F (c) 3F (d) 2F
Q.3 The cell constant of a conductivity cell _____________.
(a) changes with change of electrolyte. (b) changes with change of concentration of electrolyte.
(c) changes with temperature of electrolyte. (d) remains constant for a cell.
Q.4 Saturated solution of KNO3 is used to make 'salt bridge' because
(a) velocity of K+ is greater than that of NO3- (b) velocity of NO3- is greater than that of K+
(c) velocity of both K+ and NO3- are nearly the same (d)) KNO3 is highly soluble in water
Q.5 The electrolyte used in Leclanche cell is
(a) paste of KOH and ZnO (b) 38% solution of H2SO4
(c) moist paste of NH4Cl and ZnCl2 (d) moist sodium hydroxide
Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate
answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true

Q.6 Assertion: For measuring resistance of an ionic solution an AC source is used.

Reason: Concentration of ionic solution will change if DC source is used.

Q.7 Assertion: Conductivity of all electrolytes decreases on dilution.

Reason: On dilution number of ions per unit volume decreases.

Answer the questions in short

Q.1 Name the type of cell which was use in Apollo space programme for providing electrical power
Ans: ____________________________________________________________________________________

Q.2 Write two advantages of fuel cell.

Ans (1) _________________________________
(2) _________________________________
Q.3 (a) What type of cell is a lead storage battery?
(b) Write the anode and cathode reactions and the overall cell reaction occurring in the use of a lead storage
battery?
Ans: (a)_______________________________________
(b)________________________________________________________________________________________
______________________________________________________________________________________
Q.04 Calculate the time to deposit 1.17 g of Ni at cathode when a current of 5 A was passed through the
solution of Ni(NO3)2. (Molar mass of Ni=58.5 g mol-1, 1F = 96500 C mol-1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.05 (a) What is the role of ZnCl2 in a dry cell?
(b) Account for the following: -
(i) Alkaline medium inhibits the rusting.
(ii) Iron does not rust even if zinc coating is broken down at any point in a galvanized pipe.
Ans:
(a)______________________________________________________________________________________

(b)(i) ___________________________________________________________________________________

(ii) _____________________________________________________________________________________

Q.06 During the construction of some public building, the contractor intends to fix iron frames for windows and
railings to reduce the cost of construction. After due considerations, it is finally recommended to use
aluminium frames for windows and steel railings instead of iron.
Answer the following questions:
(i) As a chemist, do you agree with the new recommendations? (ii) Give reasons for your choice.
Ans:
(i)______________________________________________________________________________________
(ii)______________________________________________________________________________________
________________________________________________________________________________________
Q.7 The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905 × 10-5 S cm-1. Calculate its molar
conductivity and degree of dissociation(α).
Given λ0(H+) = 349.6 S cm2mol-1 and λ0(CH3COO-) = 40.9 S cm2 mol-1.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________
Q.8 Out of the following pairs, predict with reason which pair will allow greater conduction of electricity:
(i) Silver wire at 30oC or silver wire at 60oC.
(ii) 0·1 M CH3COOH solution or 1 M CH3COOH solution.
(iii) KCl solution at 20oC or KCl solution at 50oC.
Ans:(i)_____________________________________________________________________________________
______________________________________________________________________________________
Ans:(ii)_____________________________________________________________________________________
_____________________________________________________________________________________
Ans:(iii)____________________________________________________________________________________
______________________________________________________________________________________

Q.9 Predict the products of electrolysis in each of the following:

(i) Molten NaCl. (ii) An aqueous solution of NaCl.
Ans: (i) _________________________________________________________________________________

(ii)
_______________________________________________________
_____________________
 KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD REGION
CHEMICAL KINETICS CLASS-XII (CHEMISTRY) WORKSHEET-I

1 The rate constant of a reaction is 2.5x10-2 Lmol-1s-1,.What is the order of reaction is:
(A) Zero (B) one (C) half (D) Two
2 The differential rate law of the above first order reaction is: 2A  B
𝑑𝑥 1 𝑑𝑥 1
(A) = ln{[𝐴0] /[𝐴]} (B) = ln{[𝐴0] /[𝐴]}
𝑑𝑡 2𝑘 𝑑𝑡 𝑘

𝑑𝑥 1 𝑑𝑥 1
(C) = ln{[𝐴] /[𝐴0]} (D) = log{[𝐴0] /[𝐴]}
𝑑𝑡 2𝑘 𝑑𝑡 2𝑘
3 The rate of reaction, A+B→Products, is given by the equation, r=k[A][B],if B is taken in large excess,
the order of the reaction would be;
(a) 2 (b) 1 (c) 0 (d) Unpredictable
4 The rate law for the reaction, RCl+NaOH(aq.) →ROH+NaCl is given by, Rate=k[RCl], the rate of
reaction will be:
(a) Unaffected by increasing the temperature of the reaction\
(b) Doubling on doubling the concentration of NaOH
(c) Halved on reducing the concentration of NaOH to one half
(d) Halved on reducing the concentration of RCl to one half.

5 The hypothetical reaction, A2+B22AB, follows the following mechanism:

A2↔A+A (fast)
A+B2AB+B (slow)
A+BAB (fast)
The order of the overall reaction is:
(a)zero (b)1 (c) 2 (d)3/2
6- In each of the following questions, an Assertion (A) is followed by a corresponding
7 Reason(R). Use the following keys to choose the appropriate answer:
(A) If both (A) and (R) are correct and (R) is the correct explanation of (A)
(B) If both (A) and (R) are correct and (R) is not correct explanation of (A)
(C) If (A) is correct and (R) is wrong
(D) If (A) is wrong and (R) is correct
6 (A) : The rate constant of a zero order reaction has same unit as that of the rate of the reaction
(B) : The concentration of reactants is taken to be unity while determining rate Constant
7 (A): Increase in temperature increases rate of a chemical reaction.
(B): Increase in temperature decreases activation energy of the reaction
8 P + Q -------- R, the rate of this reaction quadruples when concentration of P
is doubles and remains same when concentration of Q is doubled.
(a) Write differential rate law of the reaction
(b) What is the order of the reaction and unit of rate constant of reaction?
Ans:…………………………………………………………………………………………………………

………………………………………………………………………………………………………………

………………………………………………………………………………………………………………

………………………………………………………………………………………………………………
9 A first order reaction completes 90% in 50 minutes. How long will it take to complete 20% ?
Ans:…………………………………………………………………………………………………………

………………………………………………………………………………………………………………

………………………………………………………………………………………………………………

………………………………………………………………………………………………………………

………………………………………………………………………………………………………………

10 It is observed that on increasing temperature of the reaction by 10K, the rate of reaction
doubles. By what factor the rate of a reaction will increase if temperature of a reaction is raised
from 500C to 1000C?
11 For the reaction R(s) --------- P(g) , the potential energy diagram is given below:

(a) What is the activation energy of the reaction?

(b) What is ΔH of the reaction?
(c) Predict the sign of the ΔG of the reaction
(d) Draw PE diagram for the reverse reaction of this.

12 A---------.>B , For the given reaction the plot between concentration of reactant
against time has been shown below:

(a) What is the order of the reaction

(b) What does the slope of the line indicate in this graph?

13 2A + B -------- 4C, In the given reaction the rate law is given by, rate = k [A]2[B]
If value of k is 2.0 x 10-2 l2/mol2/s then:
(i) Find initial rate of reaction when [A]= 0.5 M and [B] = =0.4 M
(ii) Find the rate of reaction when B is reduced to 0.2 M
(iii) Write rate law when B is taken in excess, what will be order of reaction in this
case?
 KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD
CHEMICAL KINETICS CLASS-XII (CHEMISTRY) WORKSHEET-II

1 Which of the following is the correct graph for the first order reaction?
(A) (B)

(C) (D)

2 75% of a first order reaction was completed in 32 minutes., when was 50% of the reaction completed?
a)4min (b) 8 min. (c)24 min. (d)16 min.
3 Activation Energy of a chemical reaction can be determined by:
(a) changing concentration of the reactants
(b) evaluating rate constant at standard temperature.
(c) evaluating rate constants at two different temperatures.
(d) evaluating velocities of reaction at two different temperatures.
4 According to the collision theory of reaction rates:
(a) Every collision between reactant molecules leads to a chemical reaction.
(b) Rate of reaction is proportional to the velocity of the molecules.
(c) Rate of reaction is proportional to the average energy of the molecules.
(d) Rate of reaction is proportional to the number of collisions per second.
5 A catalyst
(a) increases the rate of reaction by decreasing ΔG of a reaction.
(b) increases the rate of reaction by increasing ΔG of a reaction.
(c) increases the rate of reaction by decreasing activation energy of the forward reaction.
(d) increases the rate of reaction by providing an alternative pathway via an intermediate with lower
activation energy
6-7 In each of the following questions, an Assertion (A) is followed by a corresponding
Reason(R). Use the following keys to choose the appropriate answer:
(A) If both (A) and (R) are correct and (R) is the correct explanation of (A)
(B) If both (A) and (R) are correct and (R) is not correct explanation of (A)
(C) If (A) is correct and (R) is wrong
(D) If (A) is wrong and (R) is correct
6. (A) : The rate of reaction always depend on concentration of reactant
(R) : For zero order reactions concentration of reactant does not affect rate
7 (A) : The order of a reaction may be fractional but molecularity is never
(B) : The order of reaction is experimental but molecularity depends on stoichiometric co-
efficient of the reactants in the balanced chemical equation.
8 The value of rate constant of reaction is as below given, identify the order of the
reaction: (a) mol/L s-1 (b) L/mol s-1
A)…………………………. B)……………………………
9 The rate constant of a reaction is given by:
log k = 13.25 – (1.28 x103)K/T
Find activation energy and pre-exponential factor
10 Analyse the given graph, drawn between concentration of reactant vs. time

(a) Predict the order of reaction.

(b)Theoretically, can the concentration of the reactant reduce to zero after infinite time?
Explain.
ANS: (A)………..
(B) ……………………………………………………………………………

11 Half life of a reaction at two temperatures 300K and 320K are observed as 69.3 minutes and
17.325 minutes. Find activation energy of the reaction.

12 Suppose 50 bacteria are placed in a flask containing nutrients for the bacteria so that
they can multiply. A study at 35°C gave the following results
Time (minutes) 0 15 30 45 60
Number of bacteria 100 200 400 800 1600 Then
(i) This multiplication of bacteria follows a
(a) zero order reaction (b) 1st order reaction
(c) 2nd order reaction (d) 3rd order reaction
(ii) The rate constant for the reaction is
(a) 0.0462 min–1 (b) 0.462 min–1 (c) 4.62 min–1 (d) 46.2 min–1
(iii) The rate of the reactions initially is
(a) 4.62 bacterias per minute (b) 23.1 bacterias per minute
(c) 23.1 bacterias per sec (d) 0.231 bacterias per sec
(iv) The t1/2 for the reaction is
(a) 1.5 sec (b) 1.5 min (c) 150 min (d) 15 min
(v) The expression used for calculating the rate constant value in this experiment is

Ans: (i) ….. (ii) …… (iii) ….. (iv) ….. (v)……..