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Kinetics Neet DPP 6,7

Kinetics dpp

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58 views6 pages

Kinetics Neet DPP 6,7

Kinetics dpp

Uploaded by

pravinmaresh49
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Physical Chemistry Chemical Kinetics DPP: 6 The rate of first order reaction is 0.04mol.L's"! at 10 seconds and 0.03 mol.L“'s~! ct 20. seconds after initiation of the reaction. The half-life period of the reaction is (4ais (54.15 (9) 24.18 (0)34.1s According to collision theory of reaction rates (A) Every collision between reactants leads to chemical reaction (8) Rate of reaction is proportional to velocity of molecules (C) All reactions which occur in gaseous phase are zero order reaction (0) Rate of reaction is directly proportional to collision frequency. Activation energy of a reaction is (A) The energy released curing the reaction (8) The energy evolved when activated complex is formed {C] Minimum extra amount of energy needed to ‘overcome the potential barrier of reaction (0) The energy needed to form one mole of the product The minimum energy for molecules to enter into chemical reaction is called. (A) Kinetic energy (8) Potential energy (C) Threshold energy (0) Activation energy The rate constant ky of a reaction is found to be double that of rate constant kz of another reaction. The —_ relationship —_between corresponding activation energies of the two reactions at some temperature (E &E» ) can be represented as : (A)E; > Ey ()E, 4NO»( g) + Oo( g) activetion energy = Ey N205(g) + 2NO2(g) + 302(g) ‘activation energy = E,’ then (NE, = 2E,, (@E, > Ey’ (OE, < By’ (OE, = E,’ @10 For a reaction in which case the activation ‘energies of forward and reverse reactions ore equal (a) AH =0 (BAS =0 (C) The order is zero {D) There is no catalyst Il The energy of activation of a forward reaction is 50kCal The energy of activation of its backward reaction is (A) Equal to 50kCal (8) Greater than 50kCal (C)Less than 50kCal (0) Either greater or less than 50kCal @12_ An exothermic reaction XY has an cctivation energy 30kJmol~'. if energy change (AE) during the reaction is -20 kJ, then the activation energy for the reverse reaction is (A) 10 kJ (8) 20 kJ (C) 50kI (D) —30 kJ @I3_The activation energy for a chemical reaction depends upon: (A) Temperature (8) Nature of reacting species (C) Concentration of the reacting species (0) Collision frequency @14 The rate constont, the activation energy and ‘the Arrhenius parameter of a chemical reaction ot 25°C ore 3x 10-s-';104.4kJ mol ond 6.0 x 10's respectively, the value of ‘the rate constant os T — 00 is (a)2x 108s + (86x 10's? (C) Infinity, (0) 3.6 x 10™ 5? @15For an endothermic reaction where AH represents the enthalpy of the reaction in kJ/mol; the minimum vaiue for the energy of ‘activation will be (A) Less thon AH (B) Zero (C) More than AH (0) Equal to AH @16 The rate of reaction increases to 2.3 times when the temperature is raised from 300 K to 310 K. If K is the rate constant at 300 K then the rate constant at 310 K will be equal to (a) 2k @k (9) 2.3k (0) 3k? gaeeaR8 82 2 8 (c) (D) (c) (c) (8) (c) (0) (0) Answer Key (0) a) (0) (c) (8) (8) (c) () Physical Chemistry Chemical Kinetics DPP: 7 For a reaction, activation energy E, = 0 and the rate constant at 200 K is 1.6 x 10% s-! The rate constant at 400 K will be [Given that gas constant R = 8.314 J K™ mol '| (4) 3.2 x 10¢ st (8)1.6 x 10° st (C)1.6 x 10s? (0) 3.2 x 10° st The addition of a catalyst during o chemical reaction alters which of the following quantities? (A) Enthalpy (8) Activation energy (C) Entropy {D) Internal energy The activation energy of a reaction can be determined from the slope of which of the following graphs? (a) Ink ws (8) yy sy (lnk vs T vsT What is the activation energy for o reaction if its rate doubles when the temperature is rcised from 20°C to 35°C ? (R=8.314J mol! K™) (A) 34.7 kJ mol (8) 15.1 kJ mol” (C)342 kJ mol (0) 269kJ mol? In a zero-order reaction, for every 10°C rise of temperature, the rate is doubled. If the temperature is increased from 10°C to 100°C, the rate of the reaction will become (A) 256 times (C) 64 times (8) 512 times (0) 128 times Rate of reaction () is plotted against temperature (T) for an enzyme catalyzed reaction. Which of the following is conect representation? The rate of the reaction,2NO + Cl, > 2NOCI ato an = KINO}? [Cl]. The value of the rate constant ‘can be increased by (A) increasing the temperature (B) incteasing the concentration of NO (C) increasing the concentration of the Cl (D) doing all of these ‘The rate constants ky and ky for two different recctions are. 10 200/T —ong 10° - e~10/T espectively. The temperature ‘at which ky = ke is (a) 2000 K (eK (c) 1000K (0) aK Consider figure and mark the correct option. Activated complex (A) Activation energy of forward reaction is E,+ Ey and product is less stable than reactant. (8) Activation energy of forward reaction is By + E, and product is more stable than reoctant (C) Activation energy of both forward and backward reaction is Ey + Ep reactant is more stable than product. (0) Activation energy of backward reaction is E, and product is more stable than reactant, The activation energy for a simple chemical reaction AB is Ea in forword directionThe ‘octivation energy for reverse reaction (Ais negative of Ea (8) is olways less than Eo (C) con be less than or more than Ea (D)is always double of Ea When a biochemical reoction is carried out in laboratory, outside the human body in absence a2 as a as of enzyme, then rate of reaction obtained is 10-6 times, the activation energy of reaction in ‘the presence of enzyme is. (a) 6/RT (8) Pistequired (C) different from E, obtcined in laboratory (0) can't say anything How enzymes increases the rate of reactions? (A) By lowering activation energy (8) By increasing activation energy (C) By changing equilibrium constant (0) By forming enzyme substrate complex For a reaction, temperature coefficient = 2, if the temperature is increased from 25°C to 35°C, then, calculate the activation energy (in kJ) of the reaction. (A) 52.8 kJ (8) 70kJ (C) 100 kJ (0) OkJ For reaction: A-+B, the rate constant ki =A; (e Fal?) ond for the reaction X= Y, the rate constant ky = Az (e-E/""). if A, = 10", Ap = 10" ‘and E,, = 1200cal/mol ond E,, = 1800cal/mol, then the temperature at which ky = ky is (Given R= 2cal/K — mol) (4) 300K (6) 300 x 2.303 K (Sk (D) None of these The activation energies of the forward and backward reactions in the case of a chericcl reaction cre 305 ond 45.4 kJ/mol respectively. The reaction is (A) exothermic. (8) endothermic (C) neither exothermic nor endothermic (0) independent of temperature Answer Key geeenge ere an a as as (c) (ce) (c)

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