‘Assam Higher Secondary Education Council Chemistry Syllabus for the year 2023-24 COURSE STRUCTURE HS Second Year (THEORY) Time : 3 Hours: 70 Marks S.No. Title No. of ‘Marks Periods 1 lutions 10 7 2 [Electrochemistry 2 9 3 [Chemical Kinetics 10 7 4 -and f -Block Elements 12 7 5 ‘ordination Compounds 12 7 6 HHaloalkanes and Haloarenes 10 6 7 Alcohols, Phenols and Ethers 10 6 8 Aldehydes, Ketones and Carboxylic Acids 10 8 9 Amines 10 6 70 | Biomolecules 2D 7 Total 70 Unit 1: Solutions 10 Periods Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in liquids, solid solutions, Raoult's law, coligative properties - relative lowering of vapour pressure, elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular masses using colligative properties, abnormal molecular mass, Van't Hoff factor. Unit 2: Electrochemistry 12 Periods Redox reactions, EMF of a cell, standard electrode potential, Nernst equation and its application to chemical cells, Relation between Gibbs energy change and EMF of a cell, conductance in electrolytic solutions, specific and molar conductivity, variations of conductivity with concentration, Kohlrausch's Law, electrolysis and law of electrolysis (elementary idea), dry cell-electrolytic cells and Galvanic cells, lead accumulator, fuel cells, corrosion: Chemical Kinetics 10 Periods Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration, temperature, catalyst; order and molecularity of a reaction, rate law and specific rate constant, integrated rate equations and half-life (only for zero and first order reactions), concept of collision theory (elementary idea, no mathematical treatment), activation energy, Arrhenius equation, Unit 4: d and f Block Elements 12 Periods General introduction, electronic configuration, occurrence and characteristics of transition metals, general trends in properties of the first row transition metals ~ metallic character, ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds, alloy formation, preparation and properties of KaCrsO7and KMnO.. Lanthanoids - Electronic configuration, oxidation states, chemical reactivity and lanthanoid contraction and its consequences. ‘Actinoids - Electronic configuration, oxidation states and comparison with lanthanoids. Unit 5: Coordination Compounds 12 Periods Unit Unit Coordination compounds - Introduction, ligands, coordination number, colour, magnetic properties land shapes, IUPAC nomenclature of mononuclear coordination compounds. Bonding, Werner's theory, VBT, and CFT; structure and stereoisomerism, importance of coordination compounds (in qu: tive analysis, extraction of metals and biological system). 5: Haloalkanes and Haloarenes. 10 Periods Haloalkanes: Nomenclature, nature of C-X bond, physical and chemical properties, optical rotation mechanism of substitution reactions Haloarenes: Nature of C-X bond, substitution reactions (Directive influence of halogen in ‘monosubstituted compounds only). Uses and environmental effects of dichloromethane, trichloromethane, tetrachloromethane, iodoform, freons, DDT. : Alcohols, Phenols and Ethers 10 Periods Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary alcohols only), identification of primary, secondary and tertiary alcohols, mechanism of dehydration, uses with special reference to methanol and ethanol. Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophillic substitution reactions, uses of phenols.Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses. Aldehydes, Ketones and Carboxylic Acids 10 Periods ‘Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical ‘and chemical properties, mechanism of nucleophilic addition, reactivity of alpha hydrogen in aldehydes, uses. Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses. Ar 10 Periods ‘Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary, secondary and tertiary amines. Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry. Unit 10: Biomolecules 12 Periods Carbohydrates - Classification (aldoses and ketoses), monosaccahrides (glucose and fructose), D-L configuration oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, elycogen); Importance of carbohydrates. Proteins -Elerientary idea of - amino acids, peptide bond, polypeptides, proteins, structure of proteins primary, secondary, tertiary structure and quaternary structures (qualitative idea only}, denaturation of proteins; enzymes. Hormones - Elementary idea excluding structure. Vitamins - Classification and functions. Nucleic Acids: DNA and RNA. PRACTICALS Evaluation Scheme for Examination Marks Volumetric Analysis 06 Salt Analysis 2 Content Based Experiment 04 Project Work 04 Class record and viva 04 Total 30PRACTICAL SYLLABUS 60Periods ‘Micro-chemical methods are available for several of the practical experiments. Wherever possible, such techniques should be used. A. Surface Chemistry (a) Preparation of one lyophilic and one lyophobic sol Lyophilic sol - starch, egg albumin and gum Lyophobic sol - aluminium hydroxide, ferric hydroxide, arsenous sulphide. (©) Dialysis of sol-prepared in (a) above. (€) Study of the role of emulsifying agents in stabilizing the emulsion of different oils. 8, Chemical Kinetics (a) Effect of concentration and temperature on the rate of reaction between Sodium Thiosulphate and Hydrochloric acid. (b) Study of reaction rates of any one of the following: () Reaction of lodide ion with Hydrogen Peroxide at room temperature using different concentration of lodide ions. (ii) Reaction between Potassium lodate, (KIO) and Sodium Sulphite: (NazSO:) using starch solution 4s indicator (clock reaction). ©. Thermochemistry ‘Any one of the following experiments 4) _ Enthalpy of dissolution of Copper Sulphate or Potassium Nitrate. fi) Enthalpy of neutralization of strong acid (HCI) and strong base (NaOH). )) Determination of enthaply change during interaction (Hydrogen bond formation) between Acetone and Chloroform. D. Electrochemistry Variation of cell potential in Zn/Zn**| | Cu/Cu with change in concentration of electrolytes (CuSO: or 2n$0,) at room temperature. E. Chromatography i) Separation of pigments from extracts of leaves and flowers by paper chromatography and determination of Rf values. ii) Separation of constituents present in an inorganic mixture containing two cations only (constituents having large difference in Rf values to be provided). F. Preparation of Inorganic Compounds Preparation of double salt of Ferrous Ammonium Sulphate or Potash Alum. Preparation of Potassium Ferric Oxalate. G. Preparation of Organic Compounds Preparation of any one of the following compounds §) Acetanilide ti) Di-benzal Acetone ii) p-Nitroacetanilide iv) Aniline yellow or 2 - Naphthol Anilinedye. H. Tests for the functional groups present in organic compounds:Unsaturation, alcoholic, phenolic, aldehydic, ketonic, carboxylic and amino (Primary) groups. |. Characteristic tests of carbohydrates, fats and proteins in pure samples and their detection in given foodstuffs. J. Determination of concentration/ molarity of KMnO,solution by a standard solution of: i) Oxalic acid, ii) Ferrous Ammonium Sulphate (Students will be required to prepare standard solutions by weighing themselves). Qualitative analysis against Determination of one cation and one anion in a given salt. Cations : Pb?" Cu" As, A, Fe, Mn’, Zn, Cue, Ni, Ca’, Sr, Bal, ag”, NHs! Anions: (C03), S*, (S03), (NOz)', (SOs), Ce’, aBr’, I, (PO4)*, (C204)", 1H 3COO sNOs (Note: Insoluble salts excluded) PROJECT Scientific investigations involving laboratory testing and collecting information from other sources A few suggested Projects. + Study of the presence of oxalate ions in guava fruit at different stages of ripening, + Study of quantity of casein present in different samples of milk. + Preparation of soybean milk and its comparison with the natural milk with respect to curd formation, effect of temperature, etc. * Study of the effect of Potassium Bisulphate as food preservative under various conditions (temperature, concentration, time, etc.) * Study of digestion of starch by salivary amylase and effect of pH and temperature on it. + Comparative study of the rate of fermentation of following materials: wheat flour, gram flour, potato juice, carrot juice, ete. + Extraction of essential oils present in Saunf (aniseed), Ajwain (carum), Illaichi (cardamom). + Study of commen food adulterants in fat, oil, butter, sugar, turmeric power, chilli powder and pepper. Note: Any other investigatory project, which involves about 10 periods of work, can be chosen with the approval of the teacher. Prescribed Books: 1. Chemistry Part-I, Class-Kll, Published by NCERT. 2. Chemistry Part Il, Class-Xil, Published by NCERT. 3. Laboratory Manual of Chemistry, Class XIl, Published by NCERT.