1. The ion that is isoelectronic with CO is 13.

The compound in which cation is isoelectronic with anion is :

2.
(a) CN (b)
Set of isoelectronic species is
(c) O (d) N (a) NaCI (b) CsF (c) Nal (d) KS
14. What is the ratio of mass of an electron to the mass of a
(6) N2,H S,co proton?
(a)N2,CO2.CN,02 (a) 1:2 (b) 1:1 (c) 1:1837 (d) 1:3
(c) N2,CO,CN",O (d) Ca, Mg.C 15. The increasing order for the values of e/m (charge/mass) is
3. The wave-function (y) for a 2s-electron as a function ofits (a) e.p,n, a (b) n,p, e, a (c) n,p, a, e (d) n, a,p, e
distance from the nucleus (r) can be sketched as: 16. Tfthe mass number of an element is Wand its atomic number
is N, then
a) Number oferl = W-N b) Number of,H = W-N

a) (b) ()Number (d)

ofr'= W-N Number ofn=N
17. According to Bohr's theory the energy required for an electron
in the Li" ion to be emitted from n = 2 state is (given that the
ground state ionization energy of hydrogen atom is 13.6 eV)
(d) (a) 612eV b) 13.6eV (c) 30.6eV (d) 10.2eV
18. Which one is correct for the de-Broglie equation?
4. The combination of three 2p orbitals of one atom and three 2p (a) E=/p (b) p=h/^
orbitals of another atom can give rise to: (d) none of these
() E=hP
(a) three molecular orbitals 19. Which of the following pairs is correctly
(b) six (Tt 2p) molecular orbitals matched ?
(c) four (T 2p) and two (a 2p) molecular orbitals (a) Isoelectronies N, 0,Cr
(d) two molecular orbital which are symmetrical around the
(b) Isotones ,4Si5P 1S
bond axis
5. The species isoclectronic with C,H, is () Isotopes 20Ca0. K40
(a) O (6) CN (d)Isobars o'6.o",,o
20. The spectrum of He is expected to be similar to that of
(c) N,* d) (d) He
6. Cathode rays are deflected by (a) H (b) () Na
21. Which do form
(a) an electric field only (b) magnetic field only ofthe
following statements
model of hydrogen atom ?
not a part of Bohr's
(C) by both (d) by none
(a) Energy of the electrons in the orbits are quantized
7. The number of neutrons in dipositive zinc ion with mass
(b) The electron(s) in the orbit nearest to the nucleus has the
number 70 is
lowest energy
a) 4 (b) 36 (c) 38 (d) 0
c) Electrons revolve in different orbits around the nucleus
8. Which has the highest elm ratio ?
(d) The position and velocity of the electrons in the orbit
(a) He2 (b) H (c) He" (d) D
cannot be determined simultaneously.
9. One would expect proton to have very large:
22. The radius of hydrogen atom in the ground state is 0.53 A.
(a) ionization potential (6) radiuss The radius of Li" ion (atomic number =3) in a similar state is
c) charge (d) hydration energ8Y (a) 0.17A (b) 0.265 A (c) 0.53A (d) 1.06A
10. Which is correct statement about proton ? 23. The Bohr orbit radius for the hydrogen atom (n = 1) is
(a) Proton is nucleus of deuterium approximately 0.530 A. The radius for the first excited state
(b) Proton is a-particle (n 2) orbit is (i
(c) Proton is ionized hydrogen molecule (a) 0.13 (b) 1.06 (c) 4.77 (d) 2.12
(d) Proton is ionized hydrogen atom 24. MO configuration of He
11. Which one of the following is expected to have largest size?
is
(a) ( 1s.(o* Is), (a 2s) (b) (o 1Is}. (o* Is¥. (G*2s)
(c) (a 1s,(o* Is)'. (G 2s) (d) (oa Is¥. (o* Is). (G* 2s
(a) F (b) () A (d) N s.
he quantum number which is responsible for the size of
12. The maximum number of electrons in p-orbital with n =
6;
electron cloud is
Ois
a) (b) 2 (c)14 (d) 10 (a) spin b) azimuthal

(C) principal d) magnetic

26. "Electrons are filled in energy orbitals, in increasing order of 37. Correctset of four quantum numbers for valence electron of
energy." This statement is related to rubidium (Z= 37)js
(a) Planck's rule (b) Hund's rule
(c) Pauli's rule (d) Aufbau principle (a) 5,0,0. b) 5,1,0,+
27. The energy of second Bohr orbit of the hydrogen atom is
328 kJ mol-; hence the energy of fourth Bohr orbit would
be: (c)5,11+ (d) 6,0,0,+
(a) 41 k mol- (b)-82 kJ mol-
38. Zeeman effect refers to the:
(c) -164 kJ mol (d) -1312 kJ mol
in the
28. The orbital angular momentum for an electron revolvng in an (a) splittingup of the lines in an emission spectrum
presence ofan external electrostatic field
orbit is given by i + ) This momentum for an
(b) random scattering of light by colloidal particles

s-electron will be given by (C) splitting up of the lines in an emission spectrum in a

magnetic field
(a) zero (b) (d) emission of electrons from metals when light falls upon
29. The wavelength of the radiation emitted, when in a hydrogen them
atom electron falls from infinity to stationary state 1, would 39. The energy of clectron in first energy level is -21.79 x 10-2
be (Rydberg constant =1.097*10' m") electron in second energy level
(6) 192 nm erg per atom. The energy of
(a) 406 nm
IS
(c) 91 nm (d) 9.1x10* nm
30. The frequency of radiation emitted when the electron falls (a) -54.47x107 erg atom
from n=4ton=l in ahydrogen atom will be (Given: ionization
h =6.625x 103*Js) (b) -5.447x10 erg atom
energy of H=2.18 x10"J atom'and
(a)1.54x1o5s (b) 1.03x10l5 s- ()-0.5447x107ergatom
(c) 3.08x1o5 s ()2.00x10lS s- (d)-0.05447x10 erg atom
40. Which of the following statements about the electron is
Bohr's theory, the angular momentum of an
an
31. According to incorrect?
electron in 5h orbit is
(a) Itis negatively charged particle
(a) 10hlT b) 2.5 h/n (c) 25 h/n (d) 1.0 h/t neutron.
32. Which of the following transitions ofelectrons in the hydrogen
(6) The mass of electron is equal to the mass of
(c) It is a basic constituent ofall atoms.
atom will emit maximum energy (d) It is a constituent of cathode rays.
(a) ns"4 (b) M4nz
from
41. In a Bohr model of an atom, when an electron jumps
n=
(c) n n2 (d) all will emit same energy
33. The allowed values of m for l=2 is 3 ton= 1, how much energy will be emitted?

(a) 0, t1 (b) t1, t2 (a) 2.15x 10-1" ergs (b) 2.389x 10- ergs
(d) 0.1936 x 10-0 ergs
(c) 0, 1 , t2 (d) 0, +2 (c) 0.239x 10-10 ergs
34. Pick out the isoelectronic structure from the following: alpha particles, only, a
42. When atoms are bombarded with
few in million suffer deflection, others pass out undeflected.
) HO
CH This is because
(iv) CH the moving alpha particle is
NH (a) the force of repulsion on

(b) ii and iv small

a) i and i and
(d) ii, iv and i
(c) ii, ii and iv (b) the force of attraction between alpha particle
in the
35. The first emission line of hydrogen atomic spectrum oppositely charged electrons is very small
Balmer series appears is (R= Rydberg constant) number of electrons
(c) there is only one nucleus and large
volume compared to
(a)Rcm (b)R cm (d) the nucleus occupies much smaller
4 the volume of the atom
is-13.6 eV. What
7 (d) R cm 43. The ionisation potential of a hydrogen atom
(c) Rcm' 400 will be the energy of the atom corresponding to
n =2.
144
-1.7 eV (d) -2.7eV
36. Identify the correct statement (a) -3.4eV (b) -6.8 eV (c)
(a) sand p orbitals are degenerate photon is given as: 3.03 1
= 0 J then, the
x

(b) sp and sps orbitals are degenerate

44.Ifthe energy of a
wavelength (2) of the photon is
(c) p and sp$ orbitals are degenerate 65.6nm (c) 656nm (d) 0656nm
(a) 6.56nm (b)
(d) All sp orbitals are degenerate
45. In the photo-electron emission, the energy of the emitted 56. The mass of a photon with a wavelength equal to
electron is 1.54x 10-3cm is
(a) greater than the incident photon (a) 0.8268x 10-34kg (b) 1.2876 x 10-35kg
(b) same as than of the incident photon (c) 1.4285 x 10-kg (d) 1.8884 x 10kg
()smallerthan the incident photon
(d) proportional to the intensity of incident photon 57. When a metal surface is exposed to solar radiations
28 (a) The emitted electrons have energy less than a maximum
46.
Uncertainty in position ofa electron (mass=9. 1x 10rg)
n
moving with a velocity of 3 x 10 cm/s accurate upto 0.001% value of energy depending upon frequency of incident
will be (use h/47) in uncertainty expression where radiations
h =6.626x10" erg-Second). (b) The emitted electrons have energy less than maximum
(a)193 cm b) 3.84 cm (c) 5.76cm (d) 7.68 am value of energy depending upon intensity of incident
radiation
47. The configuration ls*, 2s 2p, 3s'shows:
(c) The emitted electrons have zero energy
(a) excited state of O (d) The emitted electrons have energy equal to energy of
b) excited state of neon atom photons of incident light
() excited state of fluorine atom 58. The wavelength ofa moving electron having 4.55 x 10*5Jof
(d) ground state of fluorine atom kinetic energy is
48. Positron is
(a) electron with positive charge
(a) 7.27x 10 metre
(c) 7.27x 10 metre
(b) 72.7x 10 metre
(d) 72.7 x 10*" metre
(6) a nucleus with one neutron and one proton 59. Which one of the following represents noble gas
(c) a nucleus with two protons
(d) a helium nucleuss
configuration
(a) 1s, 2s2ps, 3s 3p 3d10, 4s4p 4d0,5s Sps 5d, 6s
49. The position of both, an electron and a helium atom is (b) ls, 2s 2p°, 3s 3p° 3d0, 4s4p° 4d", 5s* 5p° 5d', 6s
known within 1.0 nm. Further
momentum of the
the electron c) 1s, 2s2p, 3s3p 3d0, 4s 4p 4d0, 5s2 5p
is known within 5.0 x 10-40 kg m s . The minimum (d) 1s, 2s2p5,3s3p 3d0, 4s2414, 5s2 5p$ 5d
uncertainty in the measurement of the momentum of the 60. Number of unpaired electrons in N4" is
helium atom is (a) 2 (b) 0 C) (d). 3
(a) 50kg ms (b) 80 kg ms 61. The total number of electrons that can be accommodated in
(c)8.0x I0-26 kg ms- (d) 5.0x 102 kg ms- all orbitals having principal quantum number 2 and azimuthal
50. Ifelectron,hydrogen, helium and neon nuclei are all moving quantum number I is
with the velocity of light, then the wavelength associated
(a) 2 b) 4 (c) 6 (d) 8
with these particles are in the order
62. An ion has 18 electrons in the outermost shell, it is
(a) Electron> hydrogen> helium> neon (b) Th* (c) Cs*
(6) Electron> helium> hydrogen> neon (a) Cu (d) K*
(c) Electron < hydrogen < helium < neon
63. For azimuthal quantum number (t =3, the maximum number of
(d) Neon < hydrogen <<helium < electron
electrons will be
51. The de Broglie wavelength ofa tennis ball of mass 60 g moving
with of 10 metres per
(a) 2 (b) 6 (c)0 (d) 14
a
(a) 10
velocity
metres
secondis approximately
(b) 107 metres 64. Ifmagnetic quantum number of a given atom represented by-
(c) 10 metres 3, then what will be its principal quantum number?
(d1033metres (a) 2 (b) 3 (c) 4 (d) 5
Planck's constant, h
=
6.63 x 10-34 Js
52. Which of the following is related with both wave nature and 65. For which one ofthe following sets offour quantum numbers,
an electron will have the heighest energy?
particle nature?
(a) Interference (b) E=mc
(C) Diffraction (d) E= hv (a) 3 1/2
53. If the radius of first Bohr orbit be a, then the radius of the (b) 4 2 /2
third orbit would be (C) 4 -1/2
(a) 3 *a
(b) 6*3 (d) -1/2
(c) 9x a (d) 1/9x a
54. The ratio of the radius of the first Bohr orbit for the electron o6. which ofthe following should be the possible sub-shells, for
n+l=7?
orbiting the hydrogen nucleus to that of the electron orbiting
the deuterium nucleus (mass nearly twice that of the hydrogen (a) 7s,6p, Sd, 4f (b) 4, 5p, 6s, 4d
nucleus) is approximately (c) 7s, 6p, 5Sd, 6d (d) 4s, Sd, 6p, 7s
a) 2:1 (b) 1:1 67. Wavelength associated with electron motion
(c) 1:2 (d) 4:1 (a) increases with increase in speed of electron
55. The de-Broglie wavelength of an electron in the ground state (b) remains same irrespective of speed of electron
ofhydrogen atom is: [K.E. = 13.6eV; 1eV= 1.602x I0-19 J]
(c) decreases with increase of speed of e" (electron)
(a) 3328 nm (b) 3.328 nm (c) 03328 nm(d) 0.0332 nm
(d) s zero.
68. Which ofthe following is not correct for electronic distribution 80. The electronic configuration of element with atomic number
in the ground state ? 24is:
(a) s,22p,3s3p°3a*,4s3
(a) Co

(b)
1,2 2p$.3s*3p°34to
() 2 2p,33p°346
(c) Cu (d) 1,22p,3s*3p°3a'4s
81. Which of the following represents correct set of the four
(d) All of the above
69. The electronic configuration of gadolinium (Atomic number
quantum numbers for an electron in a 4d subshell ?
(a) 4,2,1,0 (5) 4,2, 1,- 12
64) is
(b) [Xe]4/3 sd 6s? (c) 4,3,2,+1/2 (d) 4,3,-2,-12
(a) [Xe]4r8 sd0 6s2 82. The de Broglie wavelength associated with a ball of mass
(c) [Xe]4/fo sd~ 6s (d) [Xe]4/' sd' 6s 200 g and moving at a speed of 5 m/h, is of the order of
70. The following quantum numbers are possible for how many (h =6.625 x 10* Js)

orbital(s) n =3,/=2, m=+2? (a) 10m (b) 10m (c) 10m (d) 10m
a) (b) 3 (c) 2 (d) 4 83. An electron has principal quantum number 3. The number of
71. The number of spherical nodes in 3p orbitals are its (i) subshells and (ii) orbitals would be respectively
a) one (6) three (b) 3 and 7 (c) 3 and 9 (d) 2and 5
(a) 3 and 5
(C) two (d) None of these 84. The number of nodal planes 'd' orbital has
72. The order of filling of electrons in the orbitals of an atom will be (a) 1 (b) 2 (C) 3 (d) 0
(a) 3d, 4s, 4p, 4d, Ss (b) 4s, 3d, 4p, 5s, 4d 85. An element M has an atomic mass 19 and atomic number 9, its
(C) 5s, 4p, 3d, 4d, Ss (d) 3d, 4p 4s, 4d, Ss ion is represented by
73. The orbitals are called degenerate when
(a) they have the same wave functions (a) M (b) M4" (c) M (d) M
(b) theyhave the same wave functions but different energies 86. The measurement of the electron position is associated with
(c) they have diferent wave functions but same energy anuncertainty in momentum, which is equal to 1x10"g cms
(d) they have the same energy The uncertainty in electron velocity is, (mass ofan electron is
74. The uncertainties in the velocities of two particles, A and B 9x 1028 g)
are 0.05 and 0.02 ms respectively. (a) 1x 10 cm s- (b) 1x 100cms
1The mass of B is five times
to that of the mass of A. What is the ratio of uncertainties (c) 1x 10 cms (d) 1 x 10" cm s

87. Maximum number of electrons in a subshell of an atom is

ANA in their positions? determined by the following:
AXg (a) 21+1 (b) 4/-2 (c) 2n (d) 41+2
(a) 2 (b) 0.25 ( c ) 4 ) 88. Which of the following is not permissible arrangement of
75. The orientation of an atomic orbital is governed by electronsin an atom?
(a) Spin quantum number (a) n 5 , /=3, m=0, s=+ 1/2
(6) Magnetic quantum number (b) n= 3,l=2, m-3, s=-1/2
(c) Principal quantum number
(c)n=3,=2,m=-2, s- 1/2
(d) Azimuthal quantum number (d) n=4,/l=0, m= 0,s=- 1/2
76. The number of d-electrons retained in Fe~* 89. The total number of atomic orbitals in fourth energy level of
(At. no. of Fe= 26) ion is an atom S
(a) 4 (6)5 (c) 6 d) 3 (a) (b) 6 (c) 32 (d) 4
77. The angular speed of the electron in n" orbit of Bohr hydrogen 90. Caleulate the wavelength (in nanometer) associated with a
atom is proton moving at 1.0 x 10° ms

(a) Directly proportional to n (Massof proton = 1.67 x 102 kg and h=6.63 x 104 Js)

(b) Inversely proportional of n (a) 0.40nm (b) 2.5nm (c) 14.0nm (d) 0.32nm
91. The frequency oflight emitted for the transition n = 4 to n=2
(c) Inversely proportional to n
(d) Inversely proportional to n' ofthe He" is equal to the transition in Hatom corresponding
78. The energy ratio ofa photon of wavelength 3000A and 6000A to which of the following?
S. (a) n=2 to n= 1 (b) n= 3 to n =2
a) 1:1 (b) 2:1 (c) 1:2 (d) 1:4 (c) n=4 ton=3 (d) n=3 to n= 1|
79. What is the correct orbital designation of an electron with the 92. The increasing order of the ionic radii of the given

quantum number, n =
4, ( =3,m=-2,s =
1/2? isoelectronic species Is
(a) s (6) 4 (c) 5p (d) (a) C, Ca**, K", S* (b) S2,Cr,Ca2*,K*
(c) Ca**, K",CF, S2 (d) K", S,Ca*,Cr
 Exemplar Questions The density of dots in a region represents the probability
Which of the following conclusions could not be derived density of finding electrons in the region.
On the of diagram which of the following
from Rutherford's a-particle scattering experiment? basis above
statements is incorrect?
(a) Most of the space in the atom is empty.
(a) Is and 2s orbitals are spherical in shape.
b) The radius of the atom is about 10-10 m while that of
nucle sis 10-1 m. (6) The probability of finding the electron is maximum near
move in a circular path of fixed energy called
the nucleus.
(c) Electrons
orbits. (c) The probability of finding the electron at a given
(d) Electrons and the nucleus are held together by distance is equal in all directions.
electrostatic forces ofattraction. (d) The probability density of electrons for 2s orbital
decreases uniformly as distance from the nucleus
2. Which of the following options does not represent ground increases.
state electronic configuration of an atom?
4. Which of the following statement is not correct about the
(a) ls-2s-2po3s-3p3d4s characteristics of cathode
(b) Is2s*2p53s3p63d'4s rays?
(a) They start from the cathode and move towards the
(c) 1s22s22p 3s23pb3d104s! anode.
d) Is22s*2p63s23p63d*4s' (b) Theytravel in straight line in the absence ofan external
3. The probability density plots of ls and 2s orbitals are given
in figure.
electrical or magnetic field.
(c) Characteristics of cathode rays do not depend upon
the material of electrodes in
cathode ray tube.
(d) Characteristics ofcathode rays depend upon the nature
Is of gas present in the cathode ray tube
5. Which of the following statements about the electron is
incorrect?
(a) It is a negatively charged particle. 17. According to law of photochemical equivalence the energy
(b) The mass of electron is equal to the mass of neutron. absorbed (in ergs/mole) is givenas(h=6.62 x 10 ergs, c
= 3 x 100 cm s,N=6.02x 10 mol-l)
() It is a basic constituent ofall the atoms.
(d) It is a constituent of cathode rays. INEET Kar 2013
6. Which ofthe following properties of atom could be explained (b)196x10*
correctly by Thomson model of atom? (a)
L196x106
(a) Overall neutrality of atom
(b) Spectra of hydrogen atom 2.859x10 2.859x106
(c) (d)
(c) Position of electrons, protons and neutrons in atom
(d) Stability of atom
7. Two atoms are said to be isobars if
same atomic number but different mass
18. Based on equation E = -

2.178 x 108 in
(a) they have
number
(b) they have same number of electrons but different conclusions are written. Which of them is not correct
number of neutrons 2013
(c) they have same number of neutrons but different (a) Larger the value of n, the larger is the orbit radius.
(b) Equation can be used to calculate the change in energy
number of electrons
(d) sum of the number of protons and neutrons is same
(c)
when the electron changes orbit.
For n =1, the electron has a more negative energy than
of different
but the number protons is
it does for n = 6 which mean that the electron is moree
8. Thenumber of radial nodes for 3p orbital is .
loosely bound in the smallest allowed orbit.
(a) 3 (b)
(d) The negative sign in equation simply means that the
(c) 2 (d)
9. Number of angular nodes for 4dorbital is . *
energy or electron bOund to the nucleus is lower than
(b) be
it would ifthe electrons were at the infinite distance
(a) 4
2 (d) from the nucleus.
(c) 19. numbers of electrons that can be
10.
Which of the following is responsible to rule out the existence What is the maximum
of definite paths or trajectories of electrons? associated with the following set of quantum numbers?
(a) Pauli's exclusion principle n=3,1l and m=- /2013
(c) 2 10
(b) Heisenberg's uncertainty principle (a) 6 ( b ) 4 (d)
(c) Hund's rule of maximum multiplic1ty 20. The value of Planck'snmconstant
oflight is 3x 10
is 663 10- Js. The speed
s , Which value is closest to the
x

(d) Aufbau principle

11. Total number of orbitals associated with third shell will wavelength in
nanometer of a quantum of light with
requency of 6
x
10 s-l? 2013
( 75 (d) 10
a) 2 (b) 4 (a) (b)
9 (d) 3 21. What is the maximum number
with the following quantum numbers?
oforbitals that can be identified
2014
12. Orbital angular momentum depends on. ******
(a) (6) n and / n=s,F 1, m=0 4
C ) n and m (a) (b) 2 c) 3 (d)
(d) mands
13. Chlorineexists in two isotopic forms C1-37 and Cl-35, but its 22. Calculate the cnergy in joule corresponding to light of
wavelength 45 nm:
atomic mass
is 35.5. This indicates the ratio of CI-37 and
C-35 is approximately
(Planck's constant h = 6.63 x 10- Js; speed of light

a) (b)1:
C=3 x 10 m s )
/2014
(c) 1:3 (d) (a) 6.67 x 10 (b) 6.67x 10
(c) 4.42 x 10-5 a ) 4.42x 10-18
14. The pair of ions having same electronic configuration
IS.****'
23. Twoelectronsoccupying the same orbital aredistinguished
[2016
by
(a) Cr, Fes* (b) Fe3*, Mn2 (a) Principal quantum number
(c) Fes*, Co3+ (d) Sc*,Cr3* (6) Magnetic quantum number
15. For the electrons of oxygen atom, which of the following (C) Azimuthal quantum numbe
statements is correct (d) Spin quantum number
(a) Ze for an electron in a 2s orbital is the same as 2Zer for 24. Which one is the wrong statement ? /20171
an electron in a 2p orbital. (a) The uncertainty principle is AExAt 2 h/4
(b) An electron in the 2s orbital has the same energy as an (b) Halffilled and fully filled orbitals have greater stability
electron in the 2p orbital. due to greater exchange energy, greater symmetry and
(c) Zefr tor an electronin Is orbital is the same as
7Zeff for more balanced arrangement.
an electron in a 2s orbital. (C) The energy of 25 orbital iIs less than the energy of 2p
(d) The two electrons present in the 2s orbital have spin
orbital in case of Hydrogen like atoms
quantum numbers m, but of opposite sign.
16. Iftravelling at same speeds, which of the following matter (d) de-Broglies's wavelengthisgiven by
waves have the shortest wavelength? where m mass of the particle, v
mv
= group velocity of
(a) Electron
(b) Alpha particle (He*) the particle
(c) Neutron (d) Proton