re | c m dot X .| Particulars Date of | _ Date of Remarks. No. Practical_| Submission Uihimation total hovrdmens | 11-11-2004 1-1-2028 q} waters by mao fitvation ws ba 20 Vetowminadion a) acid value} 1-11-2024 18-11-2004 4. | © aaNet ci a given oil sample es To detesimine the velocily gslulaa|as-n-20l% | 9 |Z Asi constant of tho hydvolyrie | cl ey te by sodym| —_ = hydvoxida L = ane 7 enieeicteca 23] a]2a{ 3-01-23} tol w |. aes: teeta = omebyjo_titvation | Nat __ 5 To deleinine 6-7. of phenol 20 rafon | r}oi}as | 92 | v3 | : akes_syetem 4OSTECTIVE: Estimation a) fetal hosdness jo camblexomebyic tityation PSY Oren ae REAGENTS ane es ea 1 Standard hasid woter pita See PERU on solutions) pH 10 Semen ce. Ses Ss Eviochromel Black= Ti indicnter, 4. EDTA solution, Ee = 5. Unknown water samble 2 ee __| appara a Burette Pipette, Conica flak. fi nnel. a | |__| THEoRY_ANgy REACTIONS: ioe | Total _hasidnese s} the given water _samble can be detesimined by __|_titvating the Ca and Mg? jon _puiexent in_an_aliquot of the |_sample_“at pl 19 with “standasd ESTA sclution uring Eyich | Black-T oe indicator. When black-T ix added to hisd wates | at pH 10, it producer wine-ved_eclouved unetable comblex swith Ce? ond Mgt ions] the wates_samble, L | 02% ond Mg? + Black=T ——> [g* my nck T] | ps _ a ee complex]@ SLi faa Thix wine vied coloxed complex when titrated againgt FSTA_ solution [eb known stxength) the _colox_| the tomblex ae From coine- ved to oxiginal hue color shoving the end_hoin cf ESTA] + Black-T Led. 1g! Block T] + ESTA Si pele Mini Wales lead} Enlace __ | PROCEDURE pa : 9) Take 10m 6} standard hand wales sample ina 250 el = conical flask. : a Le —_o| Add ils tes tube full ules: golution and 5-6 deh | Friochsome Rlack-"T__indicatox to it. Beets . | When a_i xed _calox abbeose , kee the flark on a | white poner 4 titrate sith SE ais th dd iti rps) EDTA se a il the colo thang tt frorn_ajine- a pure blue with n fa Ahoy emaing_tach_indeedtey toe endpoint. apt i a a “the titvation yi coneexdart | values. lala “Raed simi fa the unknown hand twalex_ 9 a i’CALCULATIONS Yor Nosmality 4 given E®TA olution , Nia = No\e CWates) (EDTA) > Axio = Nexttd 50 3 Nez gg ty Noxmality gh unknown hard water, ' NoVp = N3Vz (edT») + (Water) ' a hex = fgXso 3 \P9G Ng Spebees: 59.5X5D - Total haydnese : oe % Cad, : SER 50 XU Xi on ~N “ = 21» orn ais oa taeey 1 thi! Thble-t: Titration | _standasid hari ween ample again a given E®TA_ solution, ___ big. aa sas | Volume} Standoaid Hod bales (ml) | Volume e} ETA connumned (ml) __| Oe A AA) ee = 4o {igineiny 40 is 9 Nes | Aable-2.: Titrati nasi woken sample againe— cera a aoa | standand E6TA solution uxing Bl Is. No.| Volume _¢) Unknown, Hosid Wates(m!| Volume e ESTA contumed (ml) Lem 50 z 12:5 ee 50 - 42-5 7 3. 50 12. ae = | toneoxdant xeading Bom _toble-1 = ies ent é se oe I Coneoxdant ead fiom table:2 = _12:5 mt | am 7 | Basu: ae Tt toe ie ngs, faun_ta be oe be x 8 Teacher's Signature...® 18/122, EXPERIMENT? W OBIECTIVEs Geleimination | acid values} o given sample 1 ‘REACT LONS : i RCOOW + KOH + RCOOK + HO vive eee. (Yiee hyghen Fatly (Petarxium sak 6 higher {otty acid) ane acid present in © ba plies za dil sample. ) ies Peete. 8 CHEMICALS : ttt se RM aan 1 Potaraium hydaoride solution - N/to Capbroximately) 2. Oxalic. acid eerdaad SSAVULiOMaN ts (\xcar-) ie samen 4 Ancticalow -DPhenolpthalein solution (4-5 dope) 4 Methanol 10 mt (one tert tube full). st) Theory pica Me | Acid Value: Tie: deamaad un "KOK ind ad “The acid value an oil ix the numberof millignams of Potasrium hydroxide equived to neutaalize the free “fatty acid prverert i : on in one gevam of the oil @ fat, NON MR ESEmm @ ator 418 111/22" PRocEBURE 1) Standosidization ) KOH solution cuith Oyalic Addl: a e ae out 10. mo} the standosic_oxalic acid solution in, « con lork. t 0 Adda few daobe of phenalphthalein. ia | Titrate it against — KOH solution till a paimeoed bark eoloy __|_abbeasiz. ie ____0|.Note down the _volurne ep KOH _ ured. _This__exbetiment ix to be Se three time, Tals 2 ed oa only“ —__smnfll_beak’y add 10 ml methane cont i eden 4p dizzolve te fre tory cia 0] Add a few oh pe] enlist args “ee et -og.airt KOHL solution added + | a _bustelte till 0 poarmanent light ink _colox ak eh eiie -wyeading ,odhich indicates a ee ae ee = her's SignatureCALCULA LONS 1. Strength o} KOH solution : Na X Va No X Vo (oxalic qeid) NM x35: Ny 10 >a "| ae 2 Acid Valus 1000 mL o 1N KOH solution containg = 564r0 KOH > 4000 mL j NL KOH solution cordaing = 26. rr) yf Kou FZ ad 3 by N skoH solu inka es Oy ‘ous ‘olution contains = 182 gm oH 10 rane ae Aig foe KOH _ fey 2s Pe oll viequixes 2s Kory ce 2 a ii I nexthea) ine Scldsetain of Kou sf KOH ia in neubyolized by “ag o 7SERVATIONS. esowe : a] Volume ¢ acid taken (rat) ] | 10 10 Volume of alkali (KOH) coramed (eit) 15.8 15.8 no @_ 4 1B) gat per Stendogidiczabion of fabty ac) weight oil taken = volume Csamble- 8) KoH solution ured = PX i! eae eae Standasdization_s} KOH solution i Volumes} N/i0 oxalic acid solution: 120ml Volume KOH solution used ce a | Bee 18 we Teacher's Signature rccneneneOBTECTIVE “To delesimine the velocity conetant of the hydrolysie || sania op set as sodium Se ____Crenare.s use se M/40 -obhy| acetate A da ‘Theory + QS Naa EXPCRIMENT+9 ____@N/40 _scdium es yh 2cun tC ae @Phenolphthalein_indicatox mika! Huds yg “ acetate | dium, oxide takes Ht hlo.ce = a.c00s the —xeaation: i. ye i CHec00e, I. + NaOH ——> CHscoo 4 Nh + CpH.OH the i e sine asus li wsith tine The _velooit ee _ in cale slated by using the eX 5r1.22 | Ort se ial_concentxation Seon HydaoxidtDROCEHURE + @ ‘Take 50 ml each of M/40. cthy| acetate 2 N[40__ sodium, hydvoxide in teoo rebesiate conical Parka mix them together in a xtobbexred conical flask. @ Now take owt 10 ml 9} the vieastion mixtusie ‘in_anothen_ conical flork ¢ add {0 ml a Ni2o Hed. © Stad the stopaatch immediately. “after ‘the_additi tong. te . acid to the oteaction mixtuste ___ a z @ | “Tityate the exceat oeid spit “N40 Nadlt tuning th see phe ax__indicatox, ns | Take 10 ml 4 the veaedion mixture of abbrox 5. 5 minutes — | inteaval_a_kitwnte as above often _ pre oe = eantdewon yes tk\iemee eee el ‘the _infinit = a — tsa sthe wer aes Faia ai 90 mink — 3 (NGie rat nota ae Teacher's SignatureQpseRVATIONS Table-1+ Obeesvation fox the titvation utior Nolume. $ NaOH | 9% ks © Lamol"' min! used (mi) (VeWo)) ata-at Aggie 20 0 0 0 30:8 1:3 | 5.4x]07] 4.084107 320 | 2b | yxtd’] 4uxto? ak 32-9 34 | Aono] 1-84X107 BB5 4.0 [446x157] 2.232107 342 At [933x162] Stzexio® 348 | 58 Wyg.yio"} 4-96-1072 31 Gl 56 = eS een Ae ze ne _Henes Vp = 28.5 mL, ae 4 Nox = 35-1 mL2t a a og = VeorVo= 35-41-29.5= 5.6 mb oi | am Menke fib wus tataane Tatas) m0 2 a ssxipe ieee ap sei ata oo 2.23 X10? 23 X10® L mal: Sa ees =e a = Lor! mint! —s} she given veaction ig 2:55X 107 Limal mine! 2.25 x107 Lmol'mint fom graph.OBSERVATIONS + Obatsivation deta fox the theymoretyic trtvation (Volume ) a\kali taken in theymor flask = 400ml) dan acid by an alec; Sia laure of | Teopertne an, [me | Tarbert Acid (ml) |g crixture (*) Acie (mL) of sopstune (*) i 0 5 9 80 22.8 2 i) 18.0 1B - 5 23 3 10 10-5 19 90 234 4 Is 19.0 20 95 232 5 20 tay 2 100 Ise 6 25 19-9 Ey los” 235 a 30 203 2% Ho 236 Cs 206 eo us 23-6 aeons zig | 20 236 Pelee uty Org | 5 235 y EY Be ca po be 23-4 2 55 218 28 135 ae (sey aed a9 | tap a eae ay % [45 23a 5 aT) 225 3 1150 259 we) 5 226 23-0See PRIME Nea tes EUTEvE.: “To _ddewnine the Mevmalily sf given alk elution | resem | eee mn ib yad tory ee ae aes Phe een Use ess __Q@_Naolt Solution) _unknovin con cont gation ____ —@)_ an atid solution. | Arppasadur |_Thexmot flaxk Weel ihe ee | pole the initial —termbesiahune is Teacher's Signature@ Add S mL o} the ocio rolution witha pipette into the theymor Flask, shake it well and note the ite in tembertadure. a ete Fl ain add 5 mie} ocid solution and note the temperiahuxe afte, thovugh rain __ © Reheat the vada ion sf acid in _dosen_of Gmioba tre till som —ocid har heen oolded. ee ee CALCULATIONS | Noxeality_s)allai sin = AN pee ae __| Noxmalit id@ernutiones Nee = ee ee ___|| Volurne of “arlkali__uuged_= 100 eal A Volume_c} acid solution ured = sus Cha tt) peers toe MY, = Nae (Ali) (Reid Ny = Nao 2 z : vy, SA a Ea oe uae sn | | }oo eS | ce as e fase: iT Seo lll ain si Pan A ba crea Teacher's SignatureEXXPERIMENT=5 + “OBTECTIVE: Yo Ace thle critica nitical solution “Tempwadune | 08T wid Wt phenol= inten buster ipsa) Spies 9 + CHEMICALS AND APPARATUS UEEEs @ Phenol solution : o@ Distilled Wotes sa @ Pipette @ Duet, Teacher's Signature“Table-2 a f Obyenvation data fox CST elemination Comborition ¢ Mie ‘eam ci ae Gls weight phenol ee ee t 40 36.5 36 a 60 89 583 i a 69 69 i 40 15 at : wD WH 70-2 ; a 65 645 : = 409 | yea “Table=1 * Composition of vostious phenel- water xolutions Armoynt q distilled Creel cou Merde ene iets = as { wale to be added (m1) ae] | __ Pipette out § ml_sf phenol golution -ris.o_hovel olan tent congaining ____o shiver ond 9 theximomedore. ee ag Uning the _valussgiven_to_oble_4 add the required amounds | dlisted wate fitm a turelte to bring the comborition ef the | | ___tystome to the devived value. eeEXPERIMENT— 6 ORTECTIVE: deteumine the concentrations) fessor ond fysic 0 in the given olution i “CHEM CALS USER ecm ag L FeSO. (Nig), 804» BH 0 (Mohals Salt) a =o = E Kg el ones eS ie eens. Hulgealiee ee N-phonylanttrsallie ovid (4ndieatoy) © ConentNOecand: dils Ha SOpmaie ete er: Csaeien Potteries “ees = ° oZn-dust ies Ee — aa Sengran : # oa Paton ro Pi In presence g (.HoSO, oxiditee texxout 109 feunic ione on follows s L — BPs ante adh T= Ah wp se | Bp ifon= electron equation « —__ B= Pant Bis Ai ae cs 2 Oxidation hale: [k** = setae] x6 ce [7 Reduntion half: [Cx,0% stunt eee <== ace ving 0 a mea ont OLA ee stad Gat Sonof 4M Ht = gee + 2 cet H0 3 ‘The xedev indicator N-pheny! eocid i coloyslen in the reduced foxm ond violet “ved in pore form. ‘Thefore, wheniar solution, pipette _| indo a conical Me mL. © fod bn be of + HyS04,, 2 dreds | ili indicator ond titnote cae Mg Crna Bites uf a solution tuyry 10d-vinlet pi ne Bie © Veeck the titvotion oe tyin conpocutive Ttoncordant. pect : 9 Prgedte out 10 mb + supblied xolution into ee di toif tent tube) dile HyQly and 2 dnb oth indtestor ord titvote inet the KoCx,0q yolution to get 4hs_osnourd ino op FE" reeset in, the solution "| © 9d 9 pinch zine dust ond oboud Semi @ half test tube — 4 cpt, $4504 19 the titwted solution. ace Wie,© Allow to atand until the vine hapr_dissolved and no moxe bubbles § Eypenge dat_seern._to “rise and the red-violet colours) the Aitvated rolution ditabheaxs. fell Titvate furthest with KoCv,04 40 get total ion content. © Rebead the rome to get tue consecutive concordant burelte_ “aeadinge. ae BP eloeswarrig Fb oan ee [EW tttes taht. y Kale0y_ ogni chandood Yenour Fane Slphaty Sl [ue [itd wading [Fa audit) | Volume o Kabasby LVs) (ml) t Sth |e eee | eee 40-4 oe — a 2. 0 10-8 10.9 “) 2 ‘Ee 0° 10-8 io.9 | EE bsnl apa ie gan TPC bb as Pe No| tnitiod | 4ak reading volume | 2° readin es | Rendingl)| KaCs0q requivtd fo _| requir wating total _| S titrating ¥* Vs (mt) N 0 SES 40-2 0 +5 10.2 Teacher's SignatureKola, Ny: Mw Na Qo . Vie domb Voz 10.8 mL 3 No > NV, oN yo) OR aeeee ores Baan OMOTC) Qs Vo IN dil KyCr0, = 55-849 y ke Vs wl gf KQuPs (Na) = Wun BS BAN gm of FO EN, X55+BU%Ny % J000 mJ \o00 lo = 1934 | amb " (eV) mL oxy Or) (Na) = Ww Vy) 55-64 xy ¥ we Ye gn loop = SASS ext ing \e0oamount ep fuoviourefer tic ion in the given_solution ase: 1.434 gm|ml_—4 0-421 gm/L__sresbecdively Teacher's Signature