PARISHRAM PUBLICATIONS

PUNE
Name of Topic : GOC - 3
Subject : Chemistry Class : XI
Marks :

 (C) –OH (D)–OCH3

1. CH3
is less stable than :-
6. Which resonating structure of vinyl chloride is least
 
(A) CH3— CH2 (B) CH3— CH—CH3 stable :-
..
 
(C) CH2—NO2 (D) CH3— CH—C2H5 (A) CH2 CH— Cl: (B) —CH

2. Most stable carbocation is :- (C) — —Cl

(D) All have equal stability

   CH2
CH2 CH2 CH2 7. The stabilization due to resonance is maximum in

(A) (B) (C) (D) (A) (B) (C) (D)

Cl NO2 OCH3  H 
8. CH 3 CH 2 CH 2 CH 2 — C ; CH3 C CH3 ;
3. Most acidic compound is :- H
H
 H
(A) OH (B) COH 
2 CH3CH2CH2 — C ; CH3
CH3
Among these carbocations :
(C) H3C CO2H (A) One is secondary carbocation
(B) One is tertiary carbocation
(C) Two are primary carbocations
(D) O2N CO2H
(D) Two are tertiary carbocations
4. Decreasing order of –I effect of the triad [–NO2, 9. Most stable carbanion is :-
  
NH 3 , –CN] is :- (A) HC C (B) H2C CH
  CH3
NH3 > –NO2 > –CN (B) NH3 > –CN > NO2  
(A) CH2
(C) CH3–C (D) CH3–C CH
 
(C) –CN > –NO2 > NH3 (D) –NO2 > –CN > NH 3 CH3 CH3
10. (a) CH2 CH—CH CH2
COOH
(b) CH3—CH CH2
(c) CH3—CH3
5. ,pKa value ofthe compound decreases ifX is :- C—C single bond distance would be :-
(A) a (146 pm) b (151 pm) c (153 pm)
X
(B) a (151 pm) b (146 pm) c (153 pm)
(A) –NO2 (B) –NH2 (C) a (146 pm) b (153 pm) c (151 pm)
(D) a (153 pm) b (146 pm) c (151 pm)
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 (C) m–NO2–C6H4NH2 (D) C6H5CH2NH2
11. In HC C1 (acetylide ion) and CH2 CH1 (vinyl 18. Correct acidic nature is :-
anion) :- (A) CH3OH < CH3SH < CH3NH2
(A) HC C1 is less basic (B) CH3NH2 < CH3OH < CH3SH
(B) HC C– is more basic (C) CH3SH < CH3OH < CH3NH2
(C) Basic strength is the same (D) None of these
(D) None
19. Which of the following carbonyl compound is least
12. In which of the following compounds carbon–chlorine reactive towarts N.A.R. :-
bond distance is minimum :- (A) C6H5CHO (B) CH3CHO
(A) CH3—Cl (B) C6H5—CH2—Cl (C) C6H5COCH3 (D) C6H5COC6H5
(C) CH2 CH—Cl
(D) CH2 CH—CH2—Cl 20. Which of the following order is correct for the
decreasing reactivity towards E.S.R. the following
13. Consider the following statements :-
compounds :-
 
(a) CH OCH is more stable than CH 3 C H 2 CH3 COOH NO2
3 2

 
(b) Me2 C H is more stable than CH CH C H I II III IV
3 2 2

 
(A) I > II > III > IV (B) II > III > IV > I
(c)CH2 CH— C H 2 ismorestablethan CH 3 CH2 C H2 (C) I > III > II > IV (D) III > I > II > IV
  21. The correct order of decreasing basic strength is
(d) CH2 C H is more stable than CH3 C H2
NH2
of these statements :-
(A) a and b are correct(B) c and d are correct
(C) a, b and c are correct(D) b, c and d are correct
N N N
14. Consider the following carbocations
  I II III IV
(a) CH3O CH2 (b) CH2 (A) I > II > III > IV (B) II > III > I > IV
(C) II > IV > I > III (D) II > III > IV > I
 
(c) CH3 CH2 (d) CH3— C H 2 22. Which of the following is most acidic :-
(A) phenol (B) benzyl alcohol
The relative stabilities of these carbocations are such (C) m-chloro phenol (D) cyclohexanol
that :-
(A) d < b < c < a (B) b < d < c < a 23. The correct order of increasing dissociation constant
(C) d < b < a < c (D) b < d < a < c [Ka] of the following compound is :-

15. Hydrogen attached to sp3 carbon in cyclopentadiene can be OH OH OH

OH
easily removed as what :- NO2 NO2 NO2
(A) Hydride ion (B) Hydrogen molecule
(C) Proton (D) Hydrogen atom NO2
NO2 NO2
16. Tautomerism is due to :- I II III IV
(A) Delocalization of sigma electrons (A) II < IV < I < III (B) IV < III < I < II
(B) Delocalization of pi electrons (C) IV < II < I < III (D) IV < I < II < III
(C) Migration active–H–atom
(D) None is correct 24. In which of the following –Cl is not replaceable
(A) CH3Cl (B) CH2 CH—CH2Cl
17. Among the following, the strongest base is :-
(A) C6H5NH2 (B) p–NO2–C6H4NH2 (C) C6H5CH2Cl (D) Cl CH3
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25. Electrophile SO3 attacks the following : 31. Correct order of reactivity of following compound with
CCl3 NO2 an electrophile :-
(I) (II) (I) p—CH3—C6H4—CH3

(II) C6H5—CH3
CHO O (III) p—CH3—C6H4—NO2
(III) (IV)
(IV) p—O2N—C6H4—NO2
in which cases SO3 will attack at meta position (A) I > II > III > IV (B) II > I > IV > III
(A) II and IV (B) I, II and III (C) III > II > I > IV (D) IV > III > II > I
(C) II and IV (D) I only 32. Which one is most stable free radical. :
Me CH2
26. The pair representing valid resonance structure is

.
O O (A) (B)
CH3 CH3 
(A) N C CH3 and N C CH3 
CH3 CH3 (C) CH2 CH— C H 2 (D) CH3–C–CH3
O OH CH3
(B) and 33. Carbanion is a :-
(A) Base (B) Nucleophile
  (C) Both the above (D) None
R R
(C) C O and C O
R R 34. Toluene is more reactive than benzene towards
electrophilic reagents due to :-
(D) and (A) Inductive effect only
(B) Hyperconjugative effect only
27. Arrange in decreasing order of basic strength : (C) Bothinductive as wellashyperconjugative effects
(D) Strong mesomeric effect
NH2 NH2 NH2
35. The most stable carbanion among the following is
NH2  
(I) (II) (III) (IV) CH2 CH2 CH2
(A) (B)
NO2 CN CH3  
CH2 CH2
(A) I > II > III > IV (B) II > III > I > IV
(C) IV > I > III > II (D) IV > I > II > III (C) (D)
28. Which of the following species is an electrophile
(A) RNH2 (B) SO3 OCH3 NO2
(C) NO3 Q (D) ROH 36. Which of the following compounds exhibits
29. The strongest deactivating effect on aromatic ring is hyperconjugation :
(A) –CH2Cl (B) –OCH3 (A) Phenol (B) Ethyne
(C) –CH3 (D) –CCl3 (C) Ethanol (D) Propene
30. Which of the following is maximum reactive towards 37. Among the following the most highly ionised in water
E.S.R. :- is :
(A) CH3CH2CHClCOOH
(A) (B) (B) CH3CH2CCl2COOH
(C)CH3CHClCH2COOH
(D) CH2ClCH2CH2COOH
(C) (D)

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38. Arrange the following in correct order of acidic strength 40. Which of the following is most stable carbocation:-
: 
(I) CH3—NO2 (II) NO2—CH2—NO2 (A) (B) 

(III) CH3—CH2—NO2 (IV) NO2 CH NO2

NO2  
(A) IV > II > I > III (B) IV > II > III > I (C) CH2 (D) CH 2=CH–CH2
(C) III > I > II > IV (D) III > I > IV > II .
39. The correct order of stability of given carbanions will
be :-

CH3–CH2 CH2=CH HC C

(I) (II) (III)
(A) I > II > III (B) III > II > I
(C) I > III > II (D) II > I > III

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