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Acidic & Basicstrength

Acid are acidic bases or basic

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18 views6 pages

Acidic & Basicstrength

Acid are acidic bases or basic

Uploaded by

madhavibandari09
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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CHEMISTRY Max.

Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.

37. Most acidic phenol derivative is

a) b)

c) d)
38. Shown below are four comparisons of acid strengths. Which one of the comparisons is
incorrect?

a) is more acidic than

b) is more acidic than

c) is more acidic than

d) is more acidic than


39. The compound having most basic nitrogen is

a) b) c) d)
40. Examine of the following resonating structures of formic acid for their individual
stability and then answer the question given below.

Which of the following arrangements gives the correct order of decreasing stability of
the above –mentioned resonance contributors?
a) II>I>III>IV b) I>II>III>IV
c) IV>III>I>II d) IV>III>I>II
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.

41. Which of the following statements regarding aniline is (are) correct?


a) aniline is a weaker base than ethyl amine
b) C-N bond in aniline is shorter than that in ethyl amine
c) anilinium ion C6 H 5 NH 3 does show resonance effect
d) aniline is a stronger base than NH3
42. The hyper conjugative stabilities of tert-butyl cation and 2-butene, respectively, are due
to
a)   p (empty) and   π* electron delocalisations
b)    * and    electron delocalisations
c)   p (filled) and   * and   π * electron delocalisations
d) p (filled )   * and   π * electron delocaisations
43. Which can exhibit tautomerism here

a) b) c) d)

44. Which of the following is/are incorrect?


a) acidic nature CH 4 <NH3 <H 2O<HF
b) stability order of conjugate base F   Cl   Br   I 
c) acidic nature H 2O  H 2 S  H 2 Se  H 2Te
d) acidic nature HCOOH  CH 3COOH  H 2CO3  H 2O
45. Which of the following is/are correct statements
a) Benzoic acid is more acidic than cyclo hexane carboxylic acid
b) P ka1 of maleic acid is greater than fumaric acid
c) Benzyl carbocation is more stable than allylic carbocation
d) Aniline more basic than methyl amine

HO X

46. Acidic nature of is decreased if X is:


a)  NO2 b) CH 3 c) OCH 3 d) NH 2
47. Among the following which compound is /are having lower pKa value than benzoic
acid?
a) HCO 2 H b) Picric acid c) CH 3CO 2 H d) o-nitrophenol
48.

COOH OH

I II

Among the following which statements are correct?


a)Conjugate base of (I) is more stable than that of Phenol (II)
b) Conjugate base of (II) is more stable than that of benzoic acid (I)
c) Magnitude of positive charge on H atom of – OH group is greater in (I) than (II)
d) None of these
SECTION – III
(NUMERICAL VALUE ANSWER TYPE )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.

49. How many enol forms are possible for (including stereoisomers)?
50. Among the following how many of them will show keto-enol tautomerism?

51. Among the following how many of them is/are more acidic than phenol?

, HCOOH,H 2 CO3 ,CH3  COOH,CH3  OH


52. How many of the following molecules have greater P ka value than P ka of Benzonic acid
1) Ortho chloro benzoic acid
2) Ortho methoxy benzoic acid
3) Ortho methyl benzoic acid
4) Para chloro benzoic acid
5) Para methoxy benzoic acid
6) Ortho amino benzoic acid
7) Para amino benzoic acid
53. How many of the following compounds are more acidic than ethyne?
CH 2  CH 2 ,NH 3 H 2 O;CH 3 -CH 3 ,HF,CH3CH 2  OH,CH3  CH 2  SH,

54. Number of resonance structures for tri phenyl carbocation ?

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