Sure Shot Questions 2024

Chapter – 01
Solutions
Question 8. Blood cells are isotonic with 0.9% sodium chloride
solution. What happens if we place blood cells in a
1. What type of azeotropic mixture will be formed by
solution containing
a solution of acetone and chloroform? Justify on the
(i) 1.2% sodium chloride solution?
basis of strength of intermolecular interactions that
(ii) 0.4% sodium chloride solution?
develop in the solution.

2. Give reasons for the following : (a) Measurement of

9. Non-ideal solutions exhibit either positive or
osmotic pressure method is preferred for the
negative deviations from Raoult’s law. What are
determination of molar masses of macromolecules
these deviations and why are they caused? explain
such as proteins and polymers. (b) Elevation of
with one example for each type.
boiling point of 1 M KC1 solution is nearly double
than that of 1 M sugar solution.
10.Calculate the mass percentage of aspirin (𝐶9 𝐻8 𝑂4 )
in acetonitrile (𝐶𝐻3 𝐶𝑁) when 6.5 𝑔 𝑜𝑓 𝐶9 𝐻8 𝑂4 is
3. 51. Blood cells are isotonic with 0.9% sodium
dissolved in 450 g of 𝐶𝐻3 𝐶𝑁.
chloride solution. What happens if we place blood
cells in a solution containing (i) 1.2% sodium
11.An antifreeze solution is prepared from 222.6 g of
chloride solution? (ii) 0.4% sodium chloride
ethylene glycol, 𝐶2 𝐻4 (𝑂𝐻)2 and 200 g of water
solution?
Calculate the molality of the solution. If the density
of the solution is 1.072 g 𝑚𝐿−1, then what shall be
4. Define the following term: Mole fraction
the molarity of the solution?

5. Some liquids on mixing form ‘azeotropes’. What are

12.Henry’s law constant for the molality of methane in
‘azeotropes’?
benzene at 298 K is 4.27 × 105 mm hg. Calculate
OR
the solubility of methane in benzene at 298 K under
Define the following term: Azeotrope
760 mm Hg.

6. Nalorphine (𝐶19 𝐻21 𝑁𝑂3 ) ,Similar to morphine is 13.What is van’t Hoff factor? What types of values can
used to combat withdrawal symptoms in narcotic it have if in forming the solution the solute
users .dose of nalorphine generally given is 1.5 mg molecules undergo
.Calculate the mass of 1.5 × 10−3 in aqueous (i) van’t Hoff factor (i) > 1 for solutes undergoing
solution required for the above dose dissociation
(ii) van’t Hoff factor (i) < 1 for solutes undergoing
7. Derive an equation to express that relative lowering association
of vapour pressure for a solution is equal to the
mole fraction of the solute in it when the solvent 14.Give Reason:
alone is volatile. Aquatic Species are more comfortable in cold water
than warm water

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If 𝑁2 gas is bubbled through water at 293 K ,how many 23.(i) Out of 1 M glucose and 2 M glucose, which one
millimoles of nitrogen gas would dissolve in 1 litres has a higher boiling point and why?
of water .Assume that nitrogen exert a partial (ii) What happens when the external pressure applied
pressure of 0.987 bar .Given the Henry’s law becomes more than the osmotic pressure of
constant for nitrogen at 293 K is 76.48k solution?
24.Calculate the mass of Ascorbic acid(Vitamin C ,
𝐶6 𝐻8 𝑂6 ) to be dissolved in 75 g of acetic acid to
15.Some ethylene glycol, HOCH2CH2OH, is added to lower its melting point by 1.5 ℃ 𝐾𝑓 = 3.9𝐾𝑔𝑚𝑜𝑙 −1
your car’s cooling system along with 5 kg of water.
If the freezing point of water – glycol solution is - 25.Calculate the depression in the freezing point of
15.00C, what is the boiling point of the solution? water when 10 g of 𝐶𝐻3 𝐶𝐻2 𝐶𝐻𝐶𝐼𝐶𝑂𝑂𝐻 is added
to 250 g of water; 𝐾𝑎 = 1.4 × 10−3 , 𝐾𝑓 =
(Kb = 0.52 K kg mol-1 and Kf = 1.86 K kg mol-1). 1.86𝐾 𝑘𝑔 𝑚𝑜𝑙 −1.

26.(a) State Henry's law and mention its two

16.Heptane and octane form an ideal solution. At 373
applications.
K, the vapour pressures of the two liquid
(b) 5% aqueous solution of a non-volatile solute was
components are 105.2 kPa and 46.8 kPa,
made and its vapour pressure at 373 K was found to
respectively. What will be the vapour pressure of a
be 745 mm. Vapour pressure of pure water at this
mixture of 26.0 g of heptane and 35.0 g of octane?
temperature was 760 mm. Calculate the molar
mass of solute.
17.Henry’s law constant for 𝐶𝑂2 in water is 1.67 ×
27.A 10 % solution (by mass) of sucrose in water has a
108 𝑃𝑎 at 298 K .Calculate the quantity of 𝐶𝑂2 in
freezing point of 269.15 K. Calculate the freezing
500 ml of soda water when packed under 2.5 atm
point of 10 % glucose in water if the freezing point
𝐶𝑂2 pressure at 298 K
of pure water is 273.15 K Molar mass of sucrose
=342 g𝑚𝑜𝑙 −1 molar mass of Glucose =180 g𝑚𝑜𝑙 −1

18.In non-ideal solution, what type of deviation shows

the formation of minimum boiling azeotropes?
28.At 300 K , 36 g of glucose present in a litre of its
solution has an osmotic pressure of 4.98 bar .If the
19.Calculate the freezing point depression expected
osmotic pressure of the solution is 1.52 bars at the
for 0.0711 m aqueous solution of 𝑁𝑎2 𝑆𝑂4 . If this
same temperature , what would be its
solution actually freezes at – 0.320𝑜 C, what would
concentration?
be the value of van’t Hoff factor?
(𝐾𝑓 𝑓𝑜𝑟 𝑤𝑎𝑡𝑒𝑟 𝑖𝑠 1.86 𝐾 𝑘𝑔 𝑚𝑜𝑙 −1 ).
29.Define azeotropes. What type of azeotrope is
20.State Raoult’s law for the solution containing formed by negative deviation from Raoult’s law?
volatile components. Give an example.

21.Define molal elevation constant or ebullioscopic 30.Nisha took two aqueous solutions - one containing
constant 7.5 g of urea (Molar mass = 60 g/mol) and the other
containing 42.75 g of substance Z in 100 g of water,
22. 𝐻2 𝑆, a toxic gas with rotten egg-like smell, is respectively. It was observed that both the
used for qualitative analysis. If the solubility of𝐻2 𝑆 solutions froze at the same temperature. Calculate
in water a STP is 0.195 m, calculate Henry’s law the molar mass of Z.
constant.

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31.Calculate the amount of 𝐶𝑎𝐶𝑙2 (Molar masss=-111 32. A 10% solution (by mass) of sucrose in water has
g𝑚𝑜𝑙 −1) which must be added to 500 g of water to freezing point of 269.15 K. Calculate the freezing
added to 500 g of water to lower its freezing point point of 10% glucose in water, if freezing point of
by 2K , assuming 𝐶𝑎𝐶𝑙2 is completely dissociated pure water is 273.15 K. (Given : Molar mass of
.(𝐾𝑓 𝑓𝑜𝑟 𝑤𝑎𝑡𝑒𝑟 = 1.86 𝐾 𝐾𝑔𝑚𝑜𝑙 −1 sucrose = 342 g 𝑚𝑜𝑙 −1molar mass of glucose = 180
g 𝑚𝑜𝑙 −1)

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