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11 views

Adobe Scan 01 Dec 2022

Sst notes

Uploaded by

nimishajain13
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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L Law of conservation o f ~ :This law was stated by Lavoisier in 1744.

It states that " In


all physical and chemical changes, the total mass of reactants is equal to total mass of
products."

2. Law of constant proportions (or constant com-position) : This law was first stated by
Proust in 1797. According to the law "a chemical compound is always found to be made up of
the same elements combined together in the same proportions by weight" e.g. the ratio of
hydrogen and oxygen in pure water is always 1: 8 by weight. This law is also called law of
definite proportions.

3. Dalton's Atomic theory : Postulates of Dalton Atomic Theory

• Matter is made up of extremely small indivisible particles called atoms.


• Atoms of the same substance are identical in all respects i.e., they possess same size,
shape, mass, chemical properties etc. Atoms of different substances are different in all
respects i.e., they possess different size, shape, mass etc.
• Atom is the smallest particle that takes part in a chemical reaction.
• Atoms of different elements May combine with each other in a fixed simple, whole
number ratio to form compound atoms.
• Atoms can neither be created nor destroyed i.e., atoms are indestructible.

4. Atom : It is the smallest particle of an element which can take part in a chemical change. It
may or may not be capable of independent existence.

S. Symbol: The abbreviation used for lengthy names of elements are termed as their symbols.

The symbol of an element is the first letter or the first and another letter of English name or
Latin name of the element. While writing a symbol, the first letter is always capital and the
second is always s mall.

6. Molecule : It is the smallest particle of an element or compound that is capable of inde-


pendent existence and shows all the properties of that substance.

[The molecules of an element is made up of only one and same type of atoms, while the
molecule of a compound is made up of dissimilar atoms]

7. Atomicity : The number of atoms present in a molecule of an element or a compound is


known as its atomicity. e.g. the atomicity of oxygen is 2 while atomicity ozone is 3.

8. Ion : It is an electrically charged atom or group of atom. It is formed by the loss or gain of
electrons by an atom. Ions are of two types :
(i) Cation : It is positively charged ion and is formed by the loss of electron from an atom e.g.
H\ Na+, ca2+, A1 3+, NH/ etc.

(ii) Anion : It is negatively charged ion and is formed by the gain of electrons by an atom,
e.g. er, 0 2·, c·. F, co/· rol · etc.

9. Valency: The combining power (or capacity) of an element is known as its valency.

10. Formula of simple and molecular compounds Binary compounds are those compounds
which are made up of two different elements e.g. NaCl, KBr, CaO etc. Following rules are to
be followed for writing the fonnula.

(i) The valencies or charges on the ions must be balanced.

(ii) For a compound made up of a metal and a non-metal, the symbol of metal is written first.

(iii) In compounds formed with polyatomic ions, the ion is enclosed in a bracket before writing
the number to indicate the ratio.

11. Atomic mass of an element : The atomic mass of an element is the numerical number
which indicates how many ti.mes an atom of an element is heavier than 1/12 of mass of an
atom 12 of carbon-I 2. For example, the atomic mass of magnesium (Mg) is 24 which indicates
that one atom of magnesium is 24 times heavier than I/ 12 of a carbon-12 atom.

12. Gram atomic mass : The atomic mass of an element expressed in grams is known as gram
atomic mass. (Gram atomic mass is also known as gram atomic weight)

13. Molecular mass : The number of times a molecule of a compound is heavier than the
1/ 12 of the mass of C-12 atom, is known as its molecular mass.

The molecular mass is equal to the sum of the atomic masses of all atoms present in one
molecule of the substance. For example H2 contains two atoms of hydrogen, so molecular mass
of H2 is 2 (2 x I =2)

14. Formula unit mass : It is equal to the sum o atomic masses of all the atoms in a formul
unit.

In case of ionic compounds like NaCl formul mass is 58.5 (23 + 35.5 = 58.5)

15. Molecular Mass and Mole Concept: Mole the unit of a substance. It is a collection of 6.023
x I023 particles.

The mass of I mole particles is equal to its mass in grams.

Thus I mole = 6.023 x 1023 farticles


I mole atoms = 6.023 x 102 atoms
1 mole electrons= 6.023 x 1<>23 electrons
1 mole protons = 6.023 x 1023 protons
1 mole ions = 6.023 x 1<>23 ions
1 mole molecules = 6.023 x 1<>23 molecules

16. Avogadro's constant or Avogadro's number: The number of particles present in one
mole (i.e. 6.023 x 1023 particles) is called Avogadro's number or Avogadro's constant.

17. Mole

1 mole = 6.023 x 1023 particles.

= mass of 1 mole particles in grams

= 22.4L of a gas at N.T.P.

1 mole atoms = gram atomic mass

1 mole molecules = gram molecular mass

N.T.P. stands for normal temperature (0°C) and normal pressure (I atomsphere or 76 mm of
mercury.)

18. Formulas of number of moles :

Number of moles = Mass of substance in grams/grams mole.cular mass

Number of moles = Volume of gas in litre (at N.T.P.)/22.4

Number of moles = number of particles/ 6.023 x 1023

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