SAFETY DATA SHEET

Flint 1/11
Version 3 / NZ Revision Date: 09.08.2022
102000007798 Print Date: 09.08.2022

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Trade name Flint
Product code (UVP) 05584493

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Fungicide
EPA-Nr. HSR000642

1.3 Details of the supplier of the safety data sheet

Supplier Bayer New Zealand Limited
CropScience Division
B:HIVE Building
74 Taharoto Rd
Smales Farm
Takapuna
Auckland, 0622
New Zealand
Telephone 0800 428 246

Telefax (09) 441 8645

1.4 Emergency telephone no.

Emergency Number 0800 734 607 (24hr)
Global Incident Response +1 (760) 476-3964 (Company 3E for Bayer AG, Crop Science Division)
Hotline (24h)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classified as hazardous according to the criteria in the Hazardous Substances (Minimum
Degrees of Hazard) Notice 2020 as amended
6.5 B
H317 May cause an allergic skin reaction.
6.9 B
H373 May cause damage to organs through prolonged or repeated exposure.
9.1 A
H410 Very toxic to aquatic life with long lasting effects.
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2.2 Label elements

Labelling in accordance with the Hazardous Substances (Safety Data Sheets) Notice 2020 as
amended
Hazard label f or supply/use required.

Signal word: Warning

Hazard statements
H317 May cause an allergic skin reaction.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P321 Specific treatment (see supplemental first aid instructions on this label).
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulation.
2.3 Other hazards
No additional hazards known beside those mentioned.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Chemical nature
Water dispersible granules (WG)
Trif loxystrobin 50 %
Hazardous components
Chemical name CAS-No. Conc. [%]
Trif loxystrobin 141517-21-7 50
Reaction product of naphthalene, butanol, 25417-20-3 > 1 – < 25
sulf onated and neutralized by caustic soda
Diatomaceaous earth 61790-53-2 >1
Sodium lignosulphonate 8061-51-6 >1
Further information
Trif loxystrobin 141517-21-7 M-Factor: 100 (acute), 10 (chronic)

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

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General advice Move out of dangerous area. Remove contaminated clothing

immediately and dispose of safely. Place and transport victim in stable
position (lying sideways).
Inhalation Move to fresh air. Keep patient warm and at rest. Call a physician or
poison control center immediately.
Skin contact Wash off thoroughly with plenty of soap and water, if available with
polyethyleneglycol 400, subsequently rinse with water. Call a physician
or poison control center immediately.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Get medical attention if irritation
develops and persists.
Ingestion Do NOT induce vomiting. Rinse mouth. Call a physician or poison
control center immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms No symptoms known or expected.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment In case of ingestion gastric lavage should be considered in cases of

significant ingestions only within the first 2 hours. However, the
application of activated charcoal and sodium sulphate is always
advisable. There is no specific antidote.
Contact the National Poisons and Hazardous Chemicals Inf ormation center in Dunedin, PO Box 913,
Dunedin. Phone 0800 POISON (0800 764 766).

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Unsuitable High volume water jet

5.2 Special hazards arising In the event of fire the following may be released:, Hydrogen cyanide
from the substance or (hydrocyanic acid), Hydrogen fluoride, Carbon monoxide (CO), Carbon
mixture dioxide (CO2), Nitrogen oxides (NOx)
5.3 Advice for firefighters
Special protective In the event of fire and/or explosion do not breathe fumes. Wear self-
equipment for firefighters contained breathing apparatus and protective suit.
Further information Contain the spread of the fire-fighting media. Do not allow run-off from
f ire f ighting to enter drains or water courses.
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Version 3 / NZ Revision Date: 09.08.2022
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SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Precautions Avoid contact with spilled product or contaminated surfaces. Use
personal protective equipment.

6.2 Environmental Do not allow to get into surface water, drains and ground water.
precautions
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up Sweep up or vacuum up spillage and collect in suitable container for
disposal. Clean contaminated floors and objects thoroughly,
observing environmental regulations. Collect and transfer the product
into a properly labelled and tightly closed container.

6.4 Reference to other Inf ormation regarding safe handling, see section 7.
sections Inf ormation regarding personal protective equipment, see section 8.
Inf ormation regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling Use only in area provided with appropriate exhaust ventilation.
Advice on protection Keep away f rom heat and sources of ignition.
against fire and explosion
Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes
separately. Wash hands immediately after work, if necessary take a
shower. Remove soiled clothing immediately and clean thoroughly
bef ore using again. Garments that cannot be cleaned must be
destroyed (burnt).
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage Store in a place accessible by authorized persons only. Store in original
areas and containers container. Keep containers tightly closed in a dry, cool and well-
ventilated place. Keep away from direct sunlight.
Advice on common storage Keep away f rom food, drink and animal feedingstuffs.
Suitable materials Aluminium composite film (min. 0,007 mm Aluminium)
7.3 Specific end use(s) Ref er to the label and/or leaflet.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components CAS-No. Control parameters Update Basis
Trif loxystrobin 141517-21-7 2.7 mg/m3 OES BCS*
(SK-SEN)
Diatomaceaous earth 61790-53-2 10 mg/m3 06 2016 NZ OEL
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(TWA)
Silicon dioxide 7631-86-9 10 mg/m3 11 2020 NZ OEL
(TWA)
(Inhalable dust.)
Silicon dioxide 7631-86-9 3 mg/m3 11 2020 NZ OEL
(TWA)
(Respirable dust.)
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
8.2 Exposure controls
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
f ollowing recommendations would apply.
Respiratory protection Wear respirator with a particle filter mask (protection factor 4)
conf orming to European norm EN149FFP1 or equivalent.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

Hand protection Please observe the instructions regarding permeability and

breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion, and the
contact time.
Wash gloves when contaminated. Dispose of when contaminated
inside, when perforated or when contamination on the outside cannot
be removed. Wash hands frequently and always before eating,
drinking, smoking or using the toilet.
Material Nitrile rubber
Rate of permeability > 480 min
Glove thickness > 0.4 mm
Protective index Class 6
Directive Protective gloves complying with EN
374.
Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection Wear standard coveralls and Category 3 Type 4 suit.
If there is a risk of significant exposure, consider a higher protective
type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Form water-dispersible granules

Colour light brown
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Odour weak, characteristic

Odour Threshold No data available
pH 8.5 - 10.5 (1 %) (23 °C) (deionized water)
Melting point/range No data available
Boiling Point No data available
Flash point Not applicable
Flammability does not ignite
Auto-ignition temperature No data available

Minimum ignition energy No data available

Self-accelarating No data available
decomposition temperature
(SADT)
Upper explosion limit No data available
Lower explosion limit No data available
Vapour pressure No data available
Evaporation rate No data available
Relative vapour density No data available
Relative density No data available
Density No data available

Water solubility dispersible

Partition coefficient: n- Trif loxystrobin: log Pow: 4.5 (25 °C)

octanol/water

Viscosity, dynamic No data available

Viscosity, kinematic No data available
Impact sensitivity Not impact sensitive.
Oxidizing properties No oxidizing properties
Explosivity Not explosive
9.2 Other information Further saf ety related physical-chemical data are not known.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity Stable under normal conditions.

Self heating not self-heating
10.2 Chemical stability Stable under recommended storage conditions.
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10.3 Possibility of No hazardous reactions when stored and handled according to

hazardous reactions prescribed instructions.

10.4 Conditions to avoid Extremes of temperature and direct sunlight.

10.5 Incompatible materials Store only in the original container.

10.6 Hazardous No decomposition products expected under normal conditions of use.

decomposition products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute oral toxicity LD50 (Rat) > 2,000 mg/kg
Test conducted with a similar formulation.
Acute inhalation toxicity
During intended and foreseen applications, no respirable aerosol is
f ormed.
Acute dermal toxicity LD50 (Rat) > 2,000 mg/kg
Test conducted with a similar formulation.
Skin corrosion/irritation Slight irritant effect - does not require labelling. (Rabbit)
Test conducted with a similar formulation.
Serious eye damage/eye Slight irritant effect - does not require labelling. (Rabbit)
irritation Test conducted with a similar formulation.
Respiratory or skin Skin: Sensitising (Guinea pig)
sensitisation OECD Test Guideline 406, Magnusson & Kligman test
Test conducted with a similar formulation.
Skin: Non-sensitizing. (Guinea pig)
OECD Test Guideline 406, Buehler test
Test conducted with a similar formulation.
Assessment STOT Specific target organ toxicity – single exposure
Trif loxystrobin: Based on available data, the classification criteria are not met.
Assessment STOT Specific target organ toxicity – repeated exposure
Trif loxystrobin did not cause specific target organ toxicity in experimental animal studies.
Diatomaceous earth did not cause specific target organ toxicity in experimental animal studies.
Assessment mutagenicity
Trif loxystrobin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.
Diatomaceous earth was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.
Assessment carcinogenicity
Trif loxystrobin was not carcinogenic in lifetime feeding studies in rats and mice.
Diatomaceous earth was not carcinogenic in lifetime feeding studies in rats and mice.
Assessment toxicity to reproduction
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Trif loxystrobin caused reduced body weight development in offspring during lactation only at doses also
producing systemic toxicity in adult rats.
Diatomaceous earth did not cause reproductive toxicity in a two-generation study in rats.
Assessment developmental toxicity
Trif loxystrobin caused developmental toxicity only at dose levels toxic to the dams. The developmental
ef f ects seen with Trif loxystrobin are related to maternal toxicity.
Diatomaceous earth did not cause developmental toxicity in rats and rabbits.
Aspiration hazard
Based on available data, the classification criteria are not met.
Further information
No f urther toxicological information is available.
11.2 Information on other hazards

Endocrine disrupting properties

Assessment The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or
Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.036 mg/l
Exposure time: 96 h
Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 0.01 mg/l
invertebrates Exposure time: 48 h

LC50 (Mysidopsis bahia (mysid shrimp)) 0.00862 mg/l

Exposure time: 96 h
The value mentioned relates to the active ingredient trifloxystrobin.

Toxicity to aquatic plants EC50 (Raphidocelis subcapitata (freshwater green alga)) 0.15 mg/l
Growth rate; Exposure time: 72 h
EC10 (Desmodesmus subspicatus (green algae)) 0.0025 mg/l
Growth rate; Exposure time: 72 h
The value mentioned relates to the active ingredient trifloxystrobin.
12.2 Persistence and degradability
Biodegradability Trif loxystrobin:
Not rapidly biodegradable
Koc Trif loxystrobin: Koc: 2377
12.3 Bioaccumulative potential
Bioaccumulation Trif loxystrobin: Bioconcentration factor (BCF) 431
Does not bioaccumulate.
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12.4 Mobility in soil

Mobility in soil Trif loxystrobin: Slightly mobile in soils
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment Trif loxystrobin: This substance is not considered to be persistent,
bioaccumulative and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulative (vPvB).
12.6 Endocrine disrupting properties
Assessment The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or
Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.
12.7 Other adverse effects
Additional ecological No other effects to be mentioned.
information

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product Dispose of this product only by using according to the label, or at an

approved landfill or other approved facility.
Contaminated packaging Triple rinse containers. Recycle if possible. If allowed under local
authority, burn if circumstances, especially wind direction permit,
otherwise crush and bury in an approved local authority facility. Do not
use container for any other purpose.

SECTION 14: TRANSPORT INFORMATION

This transportation information is not intended to convey all specific regulatory information relat ing to
this product. It does not address regulatory variations due to package size or special trans portat ion
requirements.

ADR/RID/ADN
14.1 UN number 3077
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(TRIFLOXYSTROBIN)
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES
Hazchem Code 2Z

IMDG
14.1 UN number 3077
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(TRIFLOXYSTROBIN)
14.3 Transport hazard class(es) 9
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14.4 Packaging Group III

14.5 Marine pollutant YES

IATA
14.1 UN number 3077
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(TRIFLOXYSTROBIN )
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES

14.6 Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
No transport in bulk according to the IBC Code.

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Further information
HSNO approval-Nr. HSR000642
HSNO Controls See www.epa.govt.nz
ACVM Reg. P5112
ACVM Condition See www.f oodsafety.govt.nz

SECTION 16: OTHER INFORMATION

Abbreviations and acronyms

ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE Acute toxicity estimate
CAS-Nr. Chemical Abstracts Service number
Conc. Concentration
ECx Ef fective concentration to x %
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
EN European Standard
EU European Union
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code)
ICx Inhibition concentration to x %
IMDG International Maritime Dangerous Goods
LCx Lethal concentration to x %
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LDx Lethal dose to x %

LOEC/LOEL Lowest observed effect concentration/level
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships
N.O.S. Not otherwise specified
NOEC/NOEL No observed effect concentration/level
OECD Organization for Economic Co-operation and Development
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
TWA Time weighted average
UN United Nations
WHO World health organisation

The data given here is based on current knowledge and experience. The purpose of this Safety Data
Sheet is to describe products in terms of their safety requirements. The above details do not imply
any guarantee concerning composition, properties or performance of the product.

Changes since the last version are highlighted in the margin. This version replaces all previous
versions.