Scribd
Upload
11 views

Document 12

Uploaded by

Ravi Verma
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
11 views

Document 12

Uploaded by

Ravi Verma
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 4

Chemical Bonding (NEET) (3) 50% (4) 66%

1. Which of the following pair of species are iso Sol. (D)


structrual ?
6. In ICl4 , shape is square planar. The number of
(A) ICl2 & l3 (B) NO2 & CO2 bond pair  lone pair repulsion at 90° are:-

(C) XeF4 , ICI4 (D) SO32 , ClO4 (1) 6 (2) 4

Sol. (C) (3) 12 (4) 8

2. When iodine is dissolved in aqueous potassium Sol. (D)


iodide KI3 is formed the shape of the Anionic part :-
7. Which of the following set of molecules have
(1) Linear (2) Angular same shape but different hybridisation ?

(3) Triangular (4) See-Saw (1) XeO4, SF4 (2) XeO3, BrF3

Sol. (A) (3) H2O, SnCl2 (4) I3 , I3

3. Which of the following pairs of species have Sol. (C)


largest difference in spin only magnetic moment ?
8. The molecule which contain  bonds,  bonds and
(A) O2 , O2 (B) O2 , O22 lone pairs in 1 : 1 : 1 ratio :-

(1) C2N2 (Cyanogen) (2) C6H6 (Benzene)


(C) O2 , O22 (D) O2 , O2
(3) C(CN)4 (Tetracyano methane)
Sol. (B)
(4) C3O2 (Carbon suboxide)
4. Which of the following statements is not correct
from the point of view of molecular orbital theory? Sol. (D)

(1) Be2 is not a stable molecule 9. In CO2, SO2, SiO2 each central atom is covalently
bonded with :-
(2) He2 is not stable but He2 is expected to exist
(1) 2,2,4 oxygen atoms respectively
(3) Bond strength of N2 is maximum amongst the
homonuclear diatomic molecules (2) 2,2,2 oxygen atoms respectively

(4) The order of energies of molecular orbitals in F2 (3) 2,4,4 oxygen atoms respectively
molecule is π 2px  π 2p y  σ 2pz
(4) 4,4,4 oxygen atoms respectively

Sol. (D) Sol. (A)

5. Two hybrid orbitals have a bond angle of 120°. 10. The incorrect order of bond angle :-
The percentage of p-character in the hybrid orbital is
nearly:- (A) CO2  CO23  CF2Cl2

(1) 25% (2) 33% (B) NO2  NO3  NO2


(C) XeF2  XeO3  XeO4 (4) Size of orbital decreases

Sol. (A)
(D) PH3  AsH3  SbH3
14. Which of the following molecule has two lone
Sol. (C)
pairs and bond angle < 109°28' ?
11. Which of the following combination of orbitals is
(1) SF2 (2) KrF4
correct ?
(3) ICl4 (4) All of these
(A)
Sol. (D)
(B)
15. Which of the following does not contain PX4 type
cation in solid phase ?
(C)
(X=halogen atom)

(1) PF5 (2) PCl5


(D) (3) PBr5 (4) None of these
Sol. (C) Sol. (A)
12. Which of the following statements is not correct 16. Incorrect order of bond angle is :-
regarding bonding molecular orbital ?
(1) NH3 > PH3 > AsH3 (2) H2O > H2S > H2Se
(1) Bonding molecular orbitals possess less energy
than the atomic orbitals from which they are (3) BCl3 > AlCl3 > GaCl3 (4) NO2  NO2  NO2
formed.
Sol. (C)
(2) Bonding molecular orbitals have low electron
density between the two nucleus 17. Correct order of Bond angle is

(3) Every electron in bonding molecular orbitals (A) NO2  NO2  NO2 (B) BeCl2  BF3  CF4
contributes to the attraction between atoms
(C) NH4  NH3  NH2 (D) OF2  OCl2  OBr2
(4) They are formed when the lobes of the
combining atomic orbitals have same sign Sol. (C)

Sol. (B) 18. Which of the following statements is incorrect?

13. Which of the following statement is correct. As (1) CF3 has T-shape
the %s- character of a hybrid orbital decreases?
(2) In SF4, F-S-F equatorial bond angle is less than
(1) The bond angle decreases
120°
(2) The bond strength increases
(3) In [IC4] , C-I-C bond angle is 109°
(3) The bond length decreases
(4) Shape of XeF2 molecule is linear
Sol. (C) (3) All diatomic molecules with polar bonds have
dipole moment.
19. Which of the following is not correctly match
between given species and type of overlapping ? (4) Four half filled pure orbital of carbon form same
kind of bonds in CH4
(1) XeO3 : Three (dp) bonds
Sol. (D)
(2) H2SO4: Two (dp) bonds
24. Select in which both have sea-saw shape :-
(3) SO3 : Three (dp) bonds
(A) XeO2F2, SiF4
(4) HClO4 : Three (dp) bonds
(B) XeO2F2 , IO2F2
Sol. (C)

20. In which of the following molecules no. of (C) TeCl4 , ICl4


lonepairs and bond pairs on central atom are not
(D) BrO3F, XeOF2
equal ?
Sol. (B)
(A) H2O (B) I3
25. Which of the following have same geometry ?
(C) O2 F2 (D) SCl2
(A) SbF52 , XeF5 , IF5
Sol. (B)
(B) SF4 , XeOF4 , PCl4
21. In which pair both are not isostructural ?

(A) BH4 & AlH4 (B) NH4 & PH4 (C) SF6 , PF6 , IOF5

(D) COCl2 , SOCl2 , XeOF2


(C) PCl6 & [SiF6 ]2 (D) BCl4 & ICl4

Sol. (D) Sol. (C)

22. Which of the following set do not have sp3d 1. The total number of electrons in all bonding
hybridization ? molecular orbitals of O22 is : _____

(A) PF4 & BrF3 (B) ICl2 & SF4 2. The total number of lone pairs of electrons in N2O3
is____
(C) XeF2 & I3 (D) AsF4 & SCI4
3. The total number of lone pairs of electrons in N2O3
Sol. (D) is :

23. Which of the following statement is not correct ? 4. Among H2 , He2 , Li2 , Be2 , B2 , C2 , N2 , O2 and F2 , the
number of diamagnetic species is_______.
(1) PCl3F2 has zero dipole moment
(Atomic numbers : H = 1, He = 2, Li = 3, Be = 4, B = 5,
(2) PH4 is having tetrahedral geometry with sp3 C = 6, N = 7, O = 8, F = 9)
hybridisation of central atom.
5. Consider the following compounds in the liquid
form :
O2, HF, H2O, NH3, H2O2, CCl4, CHCl3, C6H6, C6H5Cl.

When a charged comb is brought near their flowing


stream, how many of them show deflection as per
the following figure?

You might also like