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SECTION - A
ALPHA ENTRANCE ACADEMY-ALAPPUZHA
GENIUS - +1, +2 SCIENCE INTEGRATED SCHOOL - ALAPPUZHA
ALPHA MED./ENGG. ENTRANCE ACADEMY-ALAPPUZHA
29. The increasing order of electronegativity in the SECTION - B following elements a. C,N,Si,P b. N,Si,C,P c. Si,P,C,N d. P,Si,N,C 30. One element has atomic weight 39. its elec- tronic configuration is 1s2,2s2,2p6,3s2,3p6,4s1. The true statement for that element is (more than one option is correct) a. More (IE) b. transition element c. isotone with 18Ar 38 d. stable oxide M2O 31. The number of paired electrons in oxygen is a. 6 b. 16 c. 8 d. 32 32. Which of the following oxide is neutral a. CO b. SnO2 c. ZnO d. SiO2 33. Which of the following has the maximum number of unpaired electrons a. Mg2+ b. Ti3+ c. V3+ d. Fe2+ 34. The following acids have been arranged in the order of decreasing acid strength , identify the correct order
a. I > II > III b. II > I > III
c. III > II > I d. I > III > II 35. The incorrect statement among the following is a. the first ionisation potential of Al is less than the first ionisation potential of Mg b. the second ionisation potential of Mg is greater that the second ionisation potential of Na c. the first ionisation npotential of Na is less than the first ionisation potential of Mg d. the third ionisation potential of Mg is greater 36. than the third ionisation potential of Al Which of the following statement (s) are correct A. The electronic configuration of Cr is [Ar] 3d54s1(atomic no . of Cr = 24) B. The magnetic quantum number may have a negative value C. In silver atom , 23 electrons have a spin of one type and 24 of the opposite type (Atomic no. of Ag= 47) CHEMISTRY D. The oxidation state of nitrogen in HN3 is -3 SECTION - A Element Hg has two oxidation states Hg+2 & 37. Ionic radii of (more than one option is correct) 26. a. Ti4+ < Mn7+ b. 35Cl- > 37Cl- Hg+1. The right order of radius of these ions: c. K > Cl + - d. P3+ > P5+ a. Hg+1 > Hg+2 b. Hg+2 > Hg+1 Directions : The questions below consist of an c. Hg = Hg +2 +1 d. Hg +2 Hg +1 ‘assertion ‘ and in column 1 and the reason in 27. An element with atomic number 106 has been column 2 against the specific question number, discovered recently. Which of the following write in appropirate space electric configuration will it possess? (A) If both assertion and reason are CORRECT , a. [Rn]5f146d47s2 b. [Rn]5f146d57s1 and the reson is the CORRECT explanation of c. [Rn]5f146d67s2 d. [Rn]5f146d47s27p1 the assertion 28. Moving from right to left in a periodic table , the (B) If both assertion and reason are CORRECT, atomic size is : but reason is not the CORRECT explanation of a. increased b. decreasesd the assertion c. remains constant d. none of these (C) If assertion is CORRECT but reason is INCORRECT (D) If assertion is INCORRECT reason is MATHEMATICS CORRECT SECTION - A 38. ASSERTION : F atom has a less negative electron affinity than Cl atom REASON : Additional electron are repelled more 51. effectively by 3p electron in Cl atom than by 2p electron in F atom 39. ASSERTION : Al(OH)3 is amphoteric in nature REASON : Al-O and O-H bonds can be broken with equal ease in Al(OH)3 40. ASSERTION : LiCl is predominatly a covalent compound REASON : Electronegativity difference between LI and Cl is too small 41. ASSERTION : The first ionisation energy of Be is greater than that of B REASON : 2p orbital is lower in energy than 2s 52. 42. The correct order of radii is a. N< Be < B b. F- < O2- < N3- c. Na < Li < K d. Fe3+ < Fe2+ < Fe4+ 43. The correct order of acidic strength is a.Cl2O7>SO2>P4O10 b. CO2 >N2O5 <SO3 c. Na2O>MgO >Al2O3 d. K2O >CaO >MgO 44. Identify the least stable ion amongest the follow- ing a. Li- b. Be- c. B- d. C- 45. Identify the correct order of acidic strengths of CO2, CO, CuO,CaO,H2O 53. a. CaO<CuO<H2O<CO2 b. H2O <CuO<CaO<CO2 c. CaO<H2O<CuO<CO2 d. H2O < CO2 <CaO <CuO
SECTION - B
46. How much energy in Joules must be needed to
54. convert all the atoms of sodium to sodium ions present in 2.3 mg of sodium vapours (I.P of sodium is = 495 KJ/Mol) 47. Element having six electrons in its outermost shell generally form ............ion 48. The bond distance between C- Cl in CCl4 is 1.76 . If atomic radius of C is 0.77Ao . Determine the atomic radius of Cl. 49. Solutions of equal strength of XOH and QOH are prepered . The I.P s of X and Q are 5.1 and 13.0 ev respectively. Whereas their E.N’s are 0.9 and 3.2 respectively. Compare the PH of 55. XOH and QOH 50. IP1 and IP2 of Mg are178 and 348 KCalmol-1. The I.P required for the reaction Mg Mg2+ + 2e- is ............. 56.