INSPIRATION ACADEMY

Class – XI
Chemistry By : ER. ROHIT
KUCKREJA
Date : 29th Jan., 2023
TOPIC – PERIODIC PROPERTIES

SECTION - I (3) Chalcogens and pnicogens

(4) Halogens and pnicogens
1. A plot of v (v = frequency of x-rays 7. Transition metals form a bridge between
emited) against atomic number (z) gave a (1) solids and liquids
straight line. It thereby showed that (2) s-Block elements and less active
(1) the atomic mass is more elements of group 13 and group 14
fundamental property than atomic (3) metals and non-metals
number of an element. (4) conductors and insulators
(2) the atomic number is more 8. Which of the following statements are
fundamental property than atomic incorrect?
mass of an element (1) metals comprise more than 78% of
(3) atomic mass and atomic number all known elements
both are inter related to each other (2) the change from metallic to non-
(4) atomic number is directly proportional metallic character is not abrupt
to wavelength of the emitted x-rays (3) all metals are solid at room
2. The distribution of electrons into orbitals temperature
of.an atom is called (4) gallium & caesium have very low
(1) electronic shells melting point
(2) electronic configuration 9. Non-metals are usually solids or gases at
(3) periodic configuration room temperature with low melting and
(4) transition series boiling points except
3. The period indicates the value of n for (1) carbon & silicon
(1) the innermost shell (2) boron & carbon
(2) the outermost shell (3) boron & aluminium
(3) the intermediate shell (4) nitrogen & oxygen
(4) the inner subshell 10. Metallic radius is taken as
4. The element of s-block that is placed in p- (1) half the internuclear distance
block is between the metal core and mobile
(1) Hydrogen (2) Helium electron
(3) Neon (4) Sodium (2) half the internuclear distance
5. Representative elements are separating the metals cores in the
(1) s-Block elements only metallic crystal
(2) p-Block elements only (3) half the internuclear distance
(3) s and p-Block elements between the two metal atoms
(4) Group 13 to group 17 and s-Block (4) all of these
elements 11. The first ionization enthalpy values (rH) of
6. The two groups of elements which have the third period elements, Na, Mg and Si
high negative electron gain enthalpy are are respectively 496, 737, and 786 kJ mol-
(1) halogens and noble gases 1. The first  H value for Al
i
(2) Chalcogens and halogens
 (1) will be in between 737 and 786 (1) The properties of elements are
kJ/mol periodic function of their atomic
(2) will be more close to 575 kJ/mol number
(3) will be more close to 786 kJ/mol (2) Non-metallic elements are less in
(4) can't predict number than metallic elements
12. The increasing order of negative electron (3) For transition elements, the 3d-
gain enthalpy is orbitals are filled with electrons after
(1) Cl<F<S<P (2) P<S<F<Cl 3p-orbitals and be-fore 4s-orbitals
(3) S<P<F<CI (4) F<P<S<CI (4) The first ionisation enthalpies of
13. The correct order of size is elements generally increase with
(1) Mg < AI < Al3+ < Mg2+ increase in atomic number as we go
(2) Al3+ < Mg2+ < Al < Mg along a period.
(3) Mg2+ < Al3+ < Al < Mg 20. Among halogens, the correct order of
(4) Al3+ < Mg2+ < Mg < Al amount of energy released in electron gain
14. Consider the isoelectronic species, Na+, (electron gain enthalpy) is
Mg2+, F- and O2-. The correct order of (1) F > CI > Br > l (2) F < CI < Br < l
increasing length of their radii is (3) F < CI > Br > I (4) F > CI < Br > I
(1) F- < O2- < Mg2+ < Na+ 21. The elements in which electrons are
(2) Mg2+ < Na+ < F- < O2- progressively filled in 4f-orbital are called
(3) O2- < F- < Na < Mg2+ (1) actinoids
(4) O2- < F- < Mg2+< Na+ (2) transition elements
15. Which of the following is not an actinoid? (3) lanthanoids
(1) Curium (Z = 96) (4) halogens
(2) Californium (Z = 98) 22. Which of the following is correct order of
(3) Uranium (z = 92) size of the given species?
(4) Terbium (Z= 65) (1) l > l - > l + (2) I + > l - > l
16. The order of screening effect of electrons (3) I > l + > I - (4) I - > I > I +
of s, p, d and f orbitals of a given shell of 23. The formation of the oxide ion, O2-(g), from
an atom on its outer shell electrons is oxy-gen atom requires first an exothermic
(1) s > p > d > f (2) f > d > p >s and then an endothermic step as shown
(3) p > d > s > f (4) f > p > s > d below
17. The first ionisation enthalpies of Na, Mg, O(g) + e-  O- (g); N = - 141kJ mol-1
Al' and Si are in the order O- (g) + e-  O2- (g); N = + 780 kJ mol-1
(1) Na < Mg > AI < Si Thus process of formation of O2- in gas
(2) Na > Mg > Al > Si phase is unfavourable even though O2- is
(3) Na < Mg < Al < Si isoelectronic with neon. It is due to the fact
(4) Na > Mg > Al < Si that
18. The electronic configuration of gadolinium (1) Oxygen is more electronegative
(Atomic evice4 number 64) is (2) addition of electron in oxygen results
(1) [Xe] 4f3 5d5 6s2 in larger size of the ion
(2) [Xe] 4f7 5d2 6s1 (3) electron repulsion outweighs the
(3) [Xe] 4f7 5d1 6s2 stability gained by achieving noble
(4) [Xe] 4f8 5d6 6s2 gas configuration
19. The statement that is not correct for (4) O- ion has comparatively smaller size
periodic classification of elements is than oxygen atom
PARAGRAPH FOR QUESTIONS NO, 24 - 28 29. Electronic configurations of four elements
A, B, C and D are given below
In the modern periodic table, elements are A. 1s2 2s2 2p6
arranged in order of increasing atomic numbers B. 1s2 2s2 2p4
which is related to the electronic configuration. C. 1s2 2s2 2p6 3s1
Depending upon the type of orbitals receiving D. 1s2 2s2 2p5
the last electron, the elements in the periodic Which of the following is the correct order
table have been divided into four blocks, viz, s, of in-creasing tendency to gain electron?
p, d and f. The modern periodic table consists (1) A < C < B < D (2) A < B < C < D
of 7 periods and 18 groups. Each period begins (3) D < B < C < A (4) D < A < B < C
with the filling of a new energy shell. In 30. Which of the following elements have 6
accordance with the Aufbau principle, the seven electrons in their valence shell?
periods (1 to 7) have 2, 8, 8, 18, 32 and 32 i. Be ii. 0
elements respectively. Seventh period is still iii. S iv. B
incomplete. To avoid the periodic table being (1) ii only (2) ii and iii
too long, the two series of f-block elements, (3) iii only (4) ii and iv
called lanthanoids and actinoids are placed at 31. Which of the following sequences contain
the bottom of the main body of the periodic atomic numbers of only representative
table. elements?
24. The element with atomic number 57 i. 3, 33, 53, 57
belongs to ii. 2, 10, 22, 36
(1) s-block (2) p-block iii. 7, 17, 25, 37, 48
(3) d-block (4) f-block iv. 9, 35, 51, 88
25. The last element of the p-block in 6th (1) iv only (2) ii only
period is represented by the outermost (3) i and iv (4) ii and iv
electronic configuration 32. Which of the following elements will gain
(I) 7s2 7p6 one electron more readily in comparison to
(2) 5f14 6d10 7s2 7p0 other elements of their group?
(3) 4f14 5d10 6s2 6p6 i. S (g) ii. O (g)
(4) 4f14 5d10 6s2 6p4 iii. Na (g) iv. CI (g)
26. Which of the elements whose atomic (1) iv only (2) i and iv
numbers are given below, cannot be (3) i only (4) iii only
accommodated in the present set up of the 33. Which of the following statement are
long form of the periodic table. correct?
(1) 107 (2) 118 i. Helium has the highest first ionisation
(3) 126 (4) 102 enthalpy in the periodic table
27. The electronic configuration of the element ii. Chlorine has less negative electron
which is just above the element with gain enthalpy than flourine
atomic number 43 in the same group is iii. Mercury and bromine are liquids at
(1) 1s2 2s2 2p6 3s2 3p=3d5 4S2 room temperature
(2) 1s2 2s2 2p6 3s2 3p6 3d5 4s2 4p6 iv. In any period, atomic radius of alkali
(3) 1s2 2s2 2p6 3s2 3p6 3d6 4s2 metal is the highest
(4) 1s2 2s2 2p6 3s2 3p6 3d7 4s2 (1) All are correct (2) i and ii
28. The elements with atomic numbers 35, 53 (3) i, iii (4) ii and iii
and 85 are all 34. Which of the following sets contain only
(1) noble gases (2) halogens isoelectronic ions?
(3) heavy metals (4) light metals i. Zn2+, Ca2+, Ga3+, Al3+
 ii. K+, Ca2+, Sc3+, CI- (1) 72, 160 (2) 160, 160
iii. P3-, S2-, Cl-, K+ (3) 72, 72 (4) 160, 72
iv. Ta4+, Ar, Cr3+, V5+
(1) i and ii (2) iii and iv 41. Arrange the elements N, P, 0 and S in the
(3) i and iii (4) ii and iii order of increasing first ionisation enthalpy
35. In which of the following options order of (1) S < P < N < O (2) S < P < O < N
arrangement does not agree with the (3) P < S < O < N (4) O < N < P < S
variation of property indicated against it? 42. Arrange the elements N, P, 0 and S in the
i. Al3+ < Mg2+ < Na+ < F- (increasing order of increasing non-metallic character
ionic size) (1) S < P < N < O (2) S < P < O < N
ii. B < C < N < 0 (increasing first (3) P < S < O < N (4) O < N < P < S
ionisation enthalpy) 43. Match the following element with their
iii. I < Br < CI < F (increasing electron atomic radius (pm)
gain enthalpy) i. Be p. 74
iv. Li <Na < K < Rb (increasing metallic ii. C q. 88
radius) iii. O r. 111
(1) i and iv (2) ii and iii iv. B s. 77
(3) iii and iv (4) i and ii v. N t. 66
36. Which of the following have no unit? (1) i -r, ii-s, iii-t, iv-q, v-p
i. Atomic radius (2) i-r, ii-t, iii-s, iv--q, v-p
ii. Electron gain enthalpy (3) i-q, ii-s, iii-t, iv-r, v-p
iii. Ionisation enthalpy (4) i-r, ii-s, iii-q, iv-t, v-p
iv. Metallic character 44. Electronic configuration of some elements
(1) i only (2) iv only is given in column-1 and their electron gain
(3) i and iv (4) ii and iii enthalpies are given in column-II. Match
37. Ionic radii vary in the electronic configuration with electron
i. inverse proportion to effective nuclear gain enthalpy
charge Column-I Column-II
ii. inverse proportion to square of Electron configuration Electron gain
effective nuclear charge enthalpy/KJ mol-1
iii. direct proportion to the screening i. 1s2 2s2 2p6 A. -53
effect ii. 2 2 6
1s 2s 2p 3s B. -3281

iv. direct proportion to square of iii. 1s2 2s2 2p5 C. -141

screening effect iv. 1s2 2s2 2p4 D. +48
(1) i and iii (2) i and ii (1) i-A, ii-D, iii-B, iv-C
(3) ii and iii (4) i and iv (2) i-B, ii-D, iii-A, iv-C
38. Among the element B, Al, C and Si which (3) i-C, ii-D, iii-A, iv-B
element has highest IE? (4) 1-D, ii-A, iii-B, iv-C
(1) B (2) C 45. Match the correct ionisation enthalpies
(3) Al (4) Si and electron gain enthalpies of the
39. Among B, Al, C and Si which has highest following elements
metallic character? Elements H1 H2 egH
(1) Al (2) Si i. Most reactive A. 419 3051 -48
(3) C (4) B non-metal
40. Choose the correct order of atomic radii of ii. Most reactive B. 1681 3374 328
fluorine and neon (in pm) out of the options metal
given below
 iii. Least reactive C. 738 1451 -40 52. The statement that is not true for the long
element form of the periodic table is
iv. Metal forming D. 2372 5251 48 (1) It reflects the sequence of filling the
binary halide electrons in the order of sub-energy
(1) I-B, II-A, III-C, IV-D levels s, p, d and f
(2) I-B, II-A, III-D, IV-C (2) It helps to predict the stable valency
(3) I-A, II-B, III-D, IV-C states of the elements
(4) I-A, II-B, III-C, IV-D (3) It reflects trends in physical and
chemical properties of the elements
SECTION-II (4) none of these
53. Element X belongs to 4th period. It
46. Modern periodic law states that properties contains 18 and 1 electron in the
of elements are periodic function of penultimate and ultimate or-bit. The X
(1) Ionisation energy should be
(2) atomic mass (1) a normal element
(3) atomic number (2) a transition element
(4) atomic volume (3) an inert gas
47. Identify incorrect statement (4) an inner-transition element
(1) periodicity is recurrence of similar 54. 14 elements that has been placed in VI
outer electronic configuration period and Ill group of the periodic table
(2) recurrence of properties is after are called
2,8,8,18,18 & 32 elements (1) Alkaline earth metals
(3) recurrence of similar outer electronic (2) Rare earth metals
configuration results in similar (3) Alkali metals
properties (4) inert gases
(4) all are correct 55. Which of the following elements does not
48. Which of the following property did belong to the family indicated?
Moseley related with atomic number (1) 37Rb - Alkali metal
(1) wavelength (2) wave number (2) 47Ag - Coinage metal
(3) frequency (4) velocity (3) 34Se - Pnicogens
49. Classification of elements in modern (4) 52Te - Chalcogens
periodic. table is based on 56. Element with atomic number 33 belongs
(1) Bohr's model to
(2) Mendeleev's periodic law (1) 3rd group, 3rd period
(3) Moseley's law (2) 15th group, 4th period
(4) de-Broglie's law (3) 11th group, 4th period
50. The eighteenth element of periodic table (4) 13th group, 4th period
resemble with 57. On the basis of electronic configuration,
(1) 11th element the known elements are grouped in
(2) 2nd element (1) 3 blocks
(3) 10th element (2) s-blocks
(4) both (2) and (3) (3) 4 blocks + Lanthanoids
51. An element having electronic (4) 3 blocks + Lanthanoids + Actinoids
configuration. [Ar] 3d2 4s2 belongs to 58. Among the following the element with
(1) d-block (2) f-block lowest atomic number having a ground
(3) s-block (4) p-block state electronic configuration of (n-1)
d6ns2 is located in the
 (1) fifth period (2) 2.31 and 0.64 Å
(2) sixth period (3) 0.64 and 2.31 Å
(3) fourth period (4) 2.31 and 1.34 Å
(4) third period 67. The correct ionic radii order is
59. If each orbital can take maximum of three (1) N3- > O2-> F-> Na+
electrons (elements), what are the (2) N3- > Na+ > O2- >F-
number of elements in 2nd period and 4th (3) Na+ >O2- >N3- > F-
period are (4) O2- > F- > Na+ >N3-
(1) 11, 20 (2) 12, 27 68. Which of the following statements is correct
(3) 5, 25 (4) 16, 30 (1) radius of CI atom is 0.99 Å, while that
60. In terms of period and group where would of CI+ ion is 1.54 Å
you locate the element with Z = 114? (2) radius of CI atom is 0.99 Å, while that
(1) Period – 6th Gp – 13th of Na atom is 1.54 Å
(2) Period – 5th Gp – 13th (3) the radius of Cl atom is 0.95 Å, while
(3) Period – 7th Gp – 14th that of CI- ion is 0.81 Å
(4) Period – 4th Gp – 17th (4) radius of Na atom is 0.95 Å, while that
61. Atomic number of Ag is 47, in the same of Na+ ion is 1.54 Å
group the atomic number of element 69. The sizes of A, A+ and A- follows the order
placed above and below Ag will be (1) A+ > A- > A (2) A- > A+ > A
(1) 37, 67 (2) 29, 79 (3) A- > A > A+ (4) A > A- > A+
(3) 39, 69 (4) 18, 28 70. Which of the ions has the largest ionic radius?
62. An element X is placed in group number (1) Be2+ (2) Sr2+
17 and 5th period, its outer most (3) Ca2+ (4) Mg2+
configuration is 71. The decreasing order of the size of following
(1) 5s2, 5p5 (2) 3d5, 4s2 ions is
(3) 4d5, 5s2 (4) 4d5, 5s1 (1) Li+ > H+ > H- (2) H+ > H- > Li+
63. A : The third period contains only (3) H- > Li+ > H+ (4) H- > H+ > Li+
8electrons and not 18 like 4th period. 72. Which of the following configuration
R : In III period of filling starts from 3s1 corresponds to largest radius
and complete at 3p6 whereas in IV (1) 1s2, 2s2, 2p6, 3s2
period it starts from 4s1 and (2) 1s2, 2s2, 2p6, 3s2, 3p1
complete after 3d10 and 4s2 4p6. (3) 1s2, 2s2, 2p6, 3s2, 3p3
64. Which of the following is the correct (4) 1s2, 2s2, 2p6, 3s2, 3p5
match? 73. IUPAC name of elements with atomic no. 112
(1) Ununnilium (Uun) - transition is
element (1) unnilbium (2) unbibium
(2) Ununquadium (Uuq) - s-block (3) ununbium (4) unbinilium
(3) Ununoctium (Uuo) - Halogen 74. Select the incorrect statement
(4) Unbinilium (Ubn) - p-block (1) metallic radius is larger than covalent
65. The atomic number of element Unq is radius but smaller than vander waal’s
(1) 102 (2) 103 radius
(3) 104 (4) 105 (2) covalent radius is larger than metallic
66. If the ionic radii of K and F- are about
+ radius but smaller than vander wall’s
1.34 Å each, then the expected values of radius
atomic radii of K and F should be (3) vander waal’s radius is larger than both
respectively covalent and metallic radius
(1) 1.34 and 1.34 Å
 (4) covalent radius is the smallest among (2) 1s2, 2s2 2p6, 3s2, 3s1
the three radii (3) 1s2, 2s2, 2p6, 3s2, 3p2
75. A : Na+ and Al3+ are isoelectronic but ionic (4) 1s2, 2s2, 2p6, 3s2
radius Al3+ is less than that of Na+ 82. Which of the following electronic
R : The magnitude of effective nuclear configuration of the element would be
charge on the outershell electrons in associated with maximum ionization energy?
AI3+ is greater than that in Na+. (1) [Ne] 3s2 3p1 (2) [Ne] 3s2 3p2
76. A : The ionic size of O2- is bigger than that (3) [Ne] 3s2 3p3 (4) [Ar] 3d10 4s2 4p3
of F- ion. 83. Which of the following requires highest
R : O2- and F- are isoelectronic ions. amount of energy?
77. Alkali metals in each period have (1) Al  Al+ + e- (2) Al+  Al2+ + e-
(1) smallest size (3) Al2+  Al3+ + e- (4) Na  Na+ + e-
(2) lowest IE1 84. The ionisation energy will be maximum for the
(3) highest IE1 process
(4) highest electron affinity (1) Ba  Ba2+ (2) Be  Be2+
78. The elements on right side of periodic table (3) Cs  Cs+ (4) Li  Li+
are 85. The ionization potential of nitrogen is more
(1) metals than that of oxygen because of
(2) transition elements (1) Greater attraction of electrons by the
(3) non-metals nucleus
(4) inner transition elements (2) The extra stability of the half-filled p-
79. The incorrect statement among the following orbitals
is (3) The smaller size of nitrogen
(1) The first ionization potential of Al is (4) More penetration effect.
less than the first ionization potential of 86. The maximum tendency to form unipositive
Mg ion is for the element with the electronic
(2) The second ionization potential of Mg is configuration
greater than the second ionization (1) 1s2, 2s2, 2p6, 3s2
potential of Na (2) 1s2, 2s2, 2p6, 3s1
(3) The first ionization potential of Na is (3) 1s2, 2s2, 2p6, 3s2, 3p3
less than the first ionization potential of (4) 1s2, 2s2, 2p6, 3s2, 3p3
Mg 87. Among the following the third ionization
(4) The third ionization potential of Mg is energy is maximum for
greater than the third ionization potential (1) aluminium (2) boron
of Al (3) magnesium (4) beryllium
80. Which of the following configuration 88. Which of the following statements is
represents atom having highest second incorrect?
ionisation energy (1) The second ionization energy of sulphur
(1) 1s2, 2s2 2p4 is greater than that of chlorine
(2) 1s2, 2s2 2p6 (2) The third ionization energy of
(3) 1s2, 2s2 2p6, 3s1 phosphorus is greater than that of
(4) 1s2, 2s2 2p6, 3s2 aluminium
81. A sudden large jump between the values of (3) The second ionization energy of neon is
second and third ionisation energy of an less than first ionisation energy of
element would be associated with the nitrogen
electronic configuration (4) The second ionization energy of boron is
(1) 1s2, 2s2, 2p4 greater than that of carbon
89. The value of IP1, IP2, IP3, IP4 of an atom are (3) B, E (4) B, C
respectively 7.5 eV, 25.6 eV, 48.2 eV, 170.6 98. Select the correct option with reference to the
eV. The configuration of atom is following:
(1) 1s2, 2s2, 2p6, 3s1 Column-I Column-II
(2) 1s2, 2s2, 2p6, 3s2, 3p1 i. Halogen present in 4th p. Cs
(3) 1s2, 2s2, 2p6, 3s2, 3p3 period
(4) 1s2, 2s2, 2p6, 3s2 ii. an element similar to q. Sb
90. The ionisation energy of B and Al as sulphur chemical
compared to Be and Mg are property
(1) higher (2) equal iii. the most reactive r. Xe
(3) lower (4) none th
metal in 6 period
The first three successive ionisation energies iv. an element that is s. Br
of five elements are given below. Based on th
present in 15 group
given information answer the question from and 5th period
47-51. v. an element with t. Se
Atom I.E. (in kcal/mol) atomic number t. Se
I II III greater than 50 and is
A 300 549 920 similar to element
B 99 734 1100 with atomic number
C 118 1091 1652 18.
D 176 347 1848
(1) i-r, ii-t, iv-q, v-s
E 497 947 1500
(2) i-s, ii-t, iv-q, v-r
91. Which element is a noble gas?
(3) i-s, ii-p, iv-q, v-r
(1) A (2) C
(4) i-s, ii-q, iv-t, v-r
(3) E (4) D
99. A : IE2 of oxygen is lower than IE2 of
92. Which element form stable unipositive ion?
nitrogen.
(1) B (2) A
R : N+ has half filled 2p subshell which is
(3) C (4) both (1) & (3)
an extra stable configuration.
93. The element whose most stable oxidation
100. A : Greater is the difference between two
state is +2 is
successive ionisation energies of an
(1) D (2) B
element, the lower oxidation state is
(3) C (4) E
more stable.
94. The element whose most stable oxidation
R : Successive ionisation energies are the
state is + 1 is
energies required to remove the
(1) E (2) A
successive electrons from an atom of an
(3) B (4) D
element.
95. Which is the most reactive metal?
101. The process requiring the absorption of
(1) A (2) B
energy is
(3) C (4) D
(1) F  F- (2) Cl  Cl-
96. If B reacts with fluorine and oxygen, the
(3) O  O2- (4) H  H-
molecular formula of fluoride and oxide will
be respectively. 102. Second electron gain enthalpy (in KJ/mol) of
(1) BF2, BO (2) BF, BO2 oxy-gen and sulphur respectively are
(3) BF, B2O (4) BF2, B2O3 (1) -780, + 590 (2) -590, + 780
97. Which of the above pair represents elements (3) + 590, + 780 (4) + 780, +590
of same group? 103. Which of the following statement is true?
(1) A, C (2) B, D (1) Mendeleev's periodic law is based on
atomic number of elements
 (2) The table presented by Mendeleev did This is because
not have the zero group (1) oxygen is more electronegative
(3) Each group in Mendeleev's table was (2) oxygen has high electron affinity
divided into two sub groups (3) O- ion will tend to resist addition of
(4) Mendeleev's periodic table consists of 8 another electron
horizontal rows (4) O- has comparatively large size than
104. Fluorine has lower electron affinity than oxygen atom
chlorine because of 111. egH values of elements A, B, C and D are
(1) smaller radius of fluorine, high respectively -135,-60, -200 and -348 kJ mol-1.
interelectronic repulsion The outer electronic configuration of element
(2) smaller radius of chlorine, high B is
interelectronic repulsion (1) 3s2. 3p5 (2) 2s2, 3p4
(3) bigger radius of fluorine, less (3) 3s2, 3p3 (4) 3s2, 3p2
interelectronic repulsion 112. The electronic configurations of four elements
(4) smaller radius of chlorine, less are given below Arrange these elements in the
interelectronic repulsion correct order of their electron gain enthalpy?
105. Which has almost zero electron affinity? i. 2s2, 2p5 ii. 3s2, 3p5
(1) II group (2) Nitrogen iii. 2s2, 2p4 iv. 3s2, 3p4
(3) Zero group (4) All of these (1) i < ii < iii < iv (2) iii < i < iv < ii
106. Amongst the following electronic (3) i < iii < iv < ii (4) ii < i < iv < iii
configurations which one will have the 113. A : Conversion of CI (g) into Cl- (g) is
highest electron affinity? exothermic while the conversion of O (g)
(1) 1s1 (2) 1s2 2s1 into O2- (g) is endothermic.
(3) 1s2 2s2 2p4 (4) 1s2 2s2 2p5 R : Cl- (g) & O2- (g) are isoelectronic.
107. The correct order of electron affinity of the 114. A : Second E.A. for halogens is almost zero.
elements of oxygen family in the periodic R : Fluorine has maximum value of electron
table is affinity.
(1) O > S > Se (2) S > O > Se 115. Electronic configuration of f-block elements
(3) S > Se > O (4) Se > O > S is
108. Which statement is not true? (1) (n-2)f1-14 (n-1)d0-2 ns2
(1) Ionisation enthalpy is always positive (2) (n-2)f1-14 (n-1)d1-10 ns2
(2) Electron gain enthalpy is always (3) (n-2)f0-1 (n-1)d1-10 ns1-2
negative (4) (n-2)f1-14 (n-1 )d0-1 ns1-2
(3) Second electron gain enthalpy is always 116. For the general configuration (n-2)f1-14
positive (n-1)d°-1ns2, if the value of n = 7, the
(4) IE2 is always higher than IE1 configuration will be of
109. Which of the following arrangement (1) lanthanoid
represents the correct order of electron gain (2) actinoid
enthalpy (with negative sign) of the given (3) transition element
atomic species? (4) representative element
(1) S < O < CI < F (2) Cl < F < S < O 117. Which property of halogens increase from F
(3) F < CI < O < S (4) O < S < F < CI to I?
110. The formation of oxide ion O2- requires first (1) Valency
an exothermic and then an endothermic step (2) First ionisation energy
as shown below (3) Atomic radius
O + e-  O- Ho = -142 KJ/mol (4) Electron affinity
O- + e-  O2- Ho = 844 KJ/mol
118. Elements which generally exhibit multiple i. s-block a. Radioactive
oxidation states and whose ions are usually elements
coloured are ii. p-block b. Paramagnetic
(1) Metalloids compounds
(2) Transition elements iii. d-block c. non-metals
(3) Non-metals iv. f-block d. strong tendency
(4) Gases to lose the electrons
119. Which of the following has highest valency (1) i – d, ii – c, iii – b, iv - a
w.r.t. to oxygen? (2) i - d, ii – c, iii – d, iv – a
(1) 15P (2) 16S (3) i – d, ii – c, iii – d, iv – a
(3) 17Cl (4) 14Si (4) i – c, ii – d, iii – b, iv – a
120. The valency shell of element A contains three 124. Among the elements of third period of
electrons, while the valence shell of elements periodic table match the following:
B contains 6 electrons. If A and B combines i. Highest first ionization enthalpy a. Na
the probable formula of compound is ii. Reactive metal b. Cl
(1) AB2 (2) A2B iii. Most reactive non-metal c. Ar
(3) A2B3 (4) A3B2 (1) i – a, ii – b, iii – c
121. s-block elements are characterized by (2) i - c, ii – b, iii – a
following properties except (3) i – c, ii – a, iii – b
(1) soft metals (4) i – a, ii – c, iii – b
(2) lower ionization energy 125. The attempt for classify elements by ploting
(3) low melting point an boiling point atomic masses of elements against the volume
(4) variable valency was made by
122. What is true about Lother Meyer’s Curve? (1) Doebereiner (2) Newland
(1) Elements present on descending positing (3) Lother Meyer (4) Mendeleev
are non-metals 126. Which of the following is a defect in the
(2) Elements present an ascending position Mendeleev’s periodic table?
are metals (1) The position of alkali metals
(3) Noble gases were represented on (2) The position of transition metals
descending limbs (3) The position of isotopes
(4) Alkali metals are placed on the top of (4) All of these
the peaks
123. Match the following:
 ANSWERS

1. (2) 21. (3) 41. (2) 61. (2) 81. (4) 101. (3) 121. (4)
2. (2) 22. (4) 42. (1) 62. (1) 82. (3) 102. (4) 122. (4)
3. (2) 23. (3) 43. (1) 63. (1) 83. (3) 103. (2) 123. (1)
4. (2) 24. (3) 44. (4) 64. (1) 84. (2) 104. (1) 124. (3)
5. (4) 25. (3) 45. (2) 65. (3) 85. (2) 105. (4) 125. (3)
6. (2) 26. (3) 46. (3) 66. (2) 86. (2) 106. (4) 126. (3)
7. (2) 27. (1) 47. (4) 67. (1) 87. (4) 107. (3)
8. (3) 28. (2) 48. (3) 68. (2) 88. (3) 108. (2)
9. (2) 29. (1) 49. (3) 69. (3) 89. (2) 109. (4)
10. (2) 30. (2) 50. (4) 70. (2) 90. (3) 110. (3)
11. (2) 31. (1) 51. (1) 71. (3) 91. (3) 111. (3)
12. (2) 32. (2) 52. (2) 72. (1) 92. (4) 112. (4)
13. (2) 33. (3) 53. (2) 73. (3) 93. (1) 113. (3)
14. (2) 34. (4) 54. (2) 74. (2) 94. (3) 114. (3)
15. (4) 35. (2) 55. (3) 75. (1) 95. (2) 115. (1)
16. (1) 36. (2) 56. (2) 76. (2) 96. (3) 116. (2)
17. (1) 37. (1) 57. (4) 77. (2) 97. (4) 117. (3)
18. (3) 38. (2) 58. (3) 78. (3) 98. (2) 118. (2)
19. (3) 39. (1) 59. (2) 79. (2) 99. (4) 119. (3)
20. (3) 40. (1) 60. (3) 80. (3) 100. (2) 120. (3)