IJTS
IJTS
Keywords: Low pressure vaporization (LPV) is considered a promising method for rapid cooling and a significant rate
Evaporation of water vaporization. This article presents an experimental investigation for the detailed heat and mass
Superheat characterization of a static water pool exposed to low pressure conditions. An LPV experimental setup has
Low pressure
been fabricated in the lab to investigate the effect of process parameters like initial temperature (𝑇𝑤,0 ), initial
Desalination
vacuum tank pressure (𝑃𝑣,0 ), and the water pool height (𝐻𝑤,0 ) on the non-equilibrium fraction (NEF) and heat
Volumetric heat transfer
transfer coefficient (ℎ𝑣 ). Results shows that NEF initially increased to a high value and then tediously dropped.
The final value of NEF decreased with decreasing the initial vacuum tank pressure and initial water pool height
inside the flash chamber. A maximum value of the ℎ𝑣 existed with the rise of the degree of superheat (𝛥𝑇 ) of
liquid. It is found that with an increase of the degree of superheat by 13.44 ◦ C, the value of ℎ𝑣 is enhanced
by 67%, and the NEF decreased by 46.7%, respectively.
∗ Corresponding author.
E-mail addresses: [email protected] (S. Singh), [email protected] (P.R. Chakraborty), [email protected] (H.B. Kothadia).
https://doi.org/10.1016/j.ijthermalsci.2023.108413
Received 21 December 2022; Received in revised form 7 April 2023; Accepted 5 May 2023
Available online 31 May 2023
1290-0729/© 2023 Elsevier Masson SAS. All rights reserved.
S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
the vacuum tank (𝑃𝑣,0 ) with the help of a vacuum pump. At this manner. The flashing process remains to continue until both tanks
moment, the pressure inside the flash chamber remains equal to the achieve equilibrium pressure. Liquid temperature is taken as the bulk
atmospheric pressure (𝑃𝑣,0 =101.3 kPa). After the preparation of all fluid temperature for the analysis. DAQ system record the variation of
the initial requirements, the valve is instantly opened and flashing temperature and pressure. Each experiment has been performed at least
starts. Due to this flash chamber pressure dropped in a very quick two times.
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
Table 1
Experimental ranges of main parameters and uncertainty analysis.
Parameter Symbol/units Instruments Experimental range Relative uncertainty (%)
Temperature 𝑇𝑤,0 (◦ C) K-type 70–95 0.5
Vacuum tank pressure 𝑃𝑣,0 (kPa)(𝑎𝑏𝑠.) Rosemount 3051C 11.3–41.3 0.12
Volumetric heat transfer coefficient ℎ𝑣 (kWm−3 K −1 ) – – 0.13
NEF – – – 1.08
The uncertainty analysis for all parameters that are measured di- Superheat is defined as the difference between the initial liquid
rectly and indirectly and the experimental ranges for the key parame-
temperature and the equilibrium temperature. It is the driving force for
ters are provided in Table 1. Moffat’s approach is used to evaluate the
the LPV phenomenon. The equilibrium temperature is the saturation
uncertainty [35].
temperature corresponding to the equilibrium pressure in the flash
3. Performance characteristics chamber when both tanks come into equilibrium with each other.
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
as [37]:
𝑚𝑤,𝑣 ℎ𝑓 𝑔
ℎ𝑣 = (4)
𝛥𝑇 × 𝑡𝑓
Further, the equation is simplified as Eq. (5), suggesting that ℎ𝑣 is a
transient function.
1 − 𝑁𝐸𝐹 (𝑡)
ℎ𝑣 = 𝜌𝑐𝑃 (5)
𝑡𝑓
4.2. Evolution of experimental parameters Fig. 3. Repeatability and variation of the process key parameters.
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
flash chamber [38]. Large depressurization promotes vaporization and initial water height results in an increase in the volume of water. Thus
temperature drop. at the same condition, the same degree of superheat takes place for
The evolution of the degree of the superheat (𝛥𝑇 ) of the liquid both cases, and less volume of water easily gets vaporized and results
with time is drawn in Fig. 4(d) at a different initial temperature of in a rapid temperature drop. This effect becomes more significant as
the water pool. In the flash process, the liquid’s superheat degree is the initial temperature of the water rises. It can be explained on the
approximately stated as Eq. (2). The pressure variation in the flashing basis of Fig. 5(a). It is seen from the graph that at a constant initial
chamber serves as a control for the degree of superheat. The larger back pressure of 11.3 kPa and an initial water pool height of 150 mm,
drop in pressure boosts the superheat value, which promotes the rapid the drop of liquid temperature is 20 ◦ C with an initial temperature
temperature drop and evaporation of water. As the LPV proceeds, the of 95 ◦ C. In contrast, the temperature drop is 17.8 ◦ C and 16.5 ◦ C
pressure differential in between the tanks gradually reduces and, to obtained with an initial temperature of 85 ◦ C and 70 ◦ C, respectively.
some extent, an equilibrium pressure is reached. Superheat reduces This is because a higher value of the initial water pool temperature
with time while flashing and then stabilizes. It can be concluded here and higher depressurization results in high liquid superheats. It induces
that low initial back pressure and higher initial water pool temperature more intense motion of the liquid molecules. The evaporation process
are favourable conditions for improved flashing. in this period takes away a large amount of latent heat, leading to a
more rapid temperature drop. The same sequence of temperature drop
4.3. Evolution of water pool temperature is also obtained in other cases Fig. 5(b, c, & d). For other experiments
with different initial back pressure (𝑃𝑣,0 =21.3, 31.3, and 41.3 kPa),
For an initial water height (𝐻𝑤,0 ) of 150 mm and 250 mm, Fig. 5 the same fashion of temperature curves is obtained. Also, Fig. 5(c)
depicts the temperature distributions of bulk fluid in the flash chamber indicates, at the same initial back pressure of 31.3 kPa and initial
using a thermocouple comb. In Fig. 5(a–d), the impact of initial param- liquid temperature of 95 ◦ C, the temperature decline of the liquid is
eters on the water pool temperature is discussed. As Fig. 5(a) indicates, 20.5 ◦ C with an initial water pool height of 150 mm, while the decline
the variation of the water pool temperature with two different initial is 16 ◦ C with an initial water pool height of 250 mm. Although the
water pool heights and three different initial water pool temperatures final equilibrium temperatures are nearly comparable, the equilibrium
at constant initial back pressure (𝑃𝑣,0 = 11.3 kPa). It can be noticed that temperature is reached in a different period of time. Thus, as Augusto
the lesser the initial height of the water pool, the faster the temperature et al. [8] also state, lesser water pool height and higher water pool
drop takes place. It is attributed to the fact that with an increase in temperature lead to a sharp temperature drop.
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
Fig. 5. Water temperature evolution for several initial vacuum tank pressures and two different initial water heights 𝐻𝑤,𝑜 = 150 mm and 250 mm.
From Fig. 5(b & d), Under the same initial water pool temperature 𝑇𝑤,0 and 𝑃𝑣,0 on flash evaporation to understand flash evaporation
of 85 ◦ C and same initial water pool height of 150 mm but different better and develop flashing control technologies. Fig. 6 shows the
initial back pressure. The temperature drop of 17.4 ◦ C takes place with evaporated mass and evaporated mass flow rate of the vapours at three
an initial vacuum tank pressure of 21.3 kPa while the drop is 11.2 ◦ C different initial water temperatures and 𝑃𝑣,0 = 31.3 kPa. The variation
is obtained with an initial vacuum tank pressure of 41.3 kPa. This is of evaporated mass with time in Fig. 6 is calculated by the relation
because a lesser value of initial back pressure induces a larger vacuum proposed by Saury et al. [32].
inside the flash chamber. This depressurization results in a higher ( )
⎡ 𝑐𝑝 ⎤
superheat degree which results in an intense vaporization phenomenon. ⎢ 1 + 𝑇 ⎥
ℎ𝑓 𝑔
In addition, the vaporization process absorbs more latent heat, and ⎢
𝑚𝑤,𝑣 (𝑡) = 𝜌𝑙 𝐴𝐻𝑤,0 1 − ( ) ⎥ (7)
the temperature of water drops sharply. This is due to the fact that ⎢ 𝑐𝑝 ⎥
⎢ 1+ ℎ 𝑇𝑤,0 ⎥
flash chamber pressure quickly drops at the rapid evaporation stage, ⎣ 𝑓𝑔 ⎦
which causes violent phase change on the water’s surface that hastens
the evaporation. The abrupt drop in the liquid’s surface temperature From Fig. 6(a & b), it is evident that the mass evaporated by the
creates a significant internal disruption that drives a strong heat trans- flashing increased rapidly with time and become almost linear after
fer process. Because of this disruption, the internal temperature of the a while. It is also seen in Fig. 6(a) when other conditions are fixed,
water also drops rapidly. When the pressure of both the tanks has come a higher water pool temperature induces a larger evaporated mass as
to equilibrium at this time, the water surface and interior temperature compared to other temperatures. It is due to the larger superheat in
progressively inclines to ambient temperature as a result of convective the water. The same trend of the mass evaporated is observed for other
heat transfer with the surrounding environment. The characteristics of initial vacuum tank pressures 𝑃𝑣,0 = 11.3, 21.3 & 41.3 kPa. In order to
temperature drop during depressurization becomes more emphasized as check the impact of height on the mass evaporated, experiments with
the degree of superheat (𝛥𝑇 ) and initial temperature (𝑇𝑤,0 ) increases. the same conditions as for Fig. 6(a) at 𝑇𝑤,0 = 95 ◦ C compared with the
results of Fig. 6(b) at 𝑇𝑤,0 = 95 ◦ C. The result indicated that at a higher
4.4. Mass evaporated and mass flow rate initial height of the water pool larger value of the final mass of vapours
was obtained. It is clear from Fig. 6(a & b) with the increase of initial
The mass evaporation of water and the mass flow rate can vary height of the water pool by 100 mm, the evaporated mass of the vapour
depending on the demand. It is crucial to investigate the effects of enhanced by 26.3%. The final evaporated mass (𝑚𝑓𝑤,𝑣 ) is found to be a
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
Fig. 6. Evolution of evaporated mas and mass flow rate for several initial temperatures of the pool at 𝑃𝑣,0 = 31.3 kPa and two different initial water heights 𝐻𝑤,𝑜 = 150 and
250 mm.
rising function of the height of the water pool within the flash chamber. seen in the figure that a lesser initial pool temperature and a large value
Saury et al. [24] also noted the influence of initial water pool height of back pressure results in a small amount of vapour production. From
ranging between (25 mm and 250 mm) at 𝑃𝑣,0 = 50 mbar and stated that the figure, it is concluded that the final evaporated mass is a decreasing
final evaporated mass is an increasing function of initial water level. function of the initial back pressure and an increasing function of the
This is due to the fact that rising water pool height results in a rise initial pool temperature. The value of final evaporated mass at data
in the initial mass of water inside the flash chamber. Thus the energy point (𝑇𝑤,0 =70 ◦ C & 𝑃𝑣,0 =41.3 kPa), is nearly zero. It is due to operating
stored in the water pool in the form of sensible also gets increased. On conditions are quite less which result into a negligible evaporated mass
depressurization, this energy will get converted into the latent heat and and tends to remain unchanged.
consequently, the growth of vapours takes place. ‘‘𝑞̇ 𝑤,𝑣 ’’ is the mass flow In order to further explore the influence of experimental parameters,
rate of vapours obtained by adopting the relation proposed by Saury the evolution of 𝑃𝑓 , 𝑚𝑤,𝑣 , and 𝑇 (𝑡) are compared in Fig. 8. The evolution
et al. [32]. of parameters is shown for two different values of initial water pool
[ ] height and initial back pressure with constant initial water pool temper-
𝑑𝑚𝑤,𝑣 (𝑐𝑝 ∕ℎ𝑓 𝑔 ) 𝑑𝑇
𝑞̇ 𝑤,𝑣 = = −𝜌𝑙 𝐴𝐻𝑤,0 (8) ature. Fig. 8(a–d). shows that during low pressure exposure of a static
𝑑𝑡 1 + (𝑐𝑝 ∕ℎ𝑓 𝑔 )𝑇𝑤,0 𝑑𝑡
water pool, the rapid pressure drop takes place in the flash chamber and
Fig. 6(c & d) portrays the variation of the evaporated mass flow rate increases both the rate of vapour generation and superheat of liquid. As
at two different initial pool heights and constant initial vacuum tank time passes, the pressure inside the flash tank attains the equilibrium
pressure. A huge number of vapours are produced in the rapid evapo- state which results in decreases of superheat of the liquid and slows
ration stage. This is due to the fact that with the period the pressure the rate of vapour generation. Fig. 8(a & b)indicates the impact of
gap decreases between the vacuum tank and flash chamber, resulting in the initial condition of water pool height on the variation of 𝑃𝑓 , 𝑚𝑤,𝑣 ,
a decrement in the liquid superheat degree which is the primary cause and 𝑇 (𝑡) with time. The initial mass of water increases as the water
of this rapid phase change process. From Fig. 6(c & d), it is clear that a pool height rises and consequently increases the energy supplied as
high mass flow rate takes place in the case of higher initial pool height sensible energy. Thus higher energy conversion takes more flash time,
and high initial pool temperature. Fig. 7(a & b) plots the relationship and higher vapour generation takes place. Fig. 8(a & b) also shows that
between the final evaporated mass with initial back pressure (𝑃𝑣,0 ) and a high temperature drops and higher vapour generation takes place in
initial water pool temperature (𝑇𝑤,0 ). The water mass evaporated for a the case of lower water pool height. This is because the pressure drop in
period of 600 s is taken as the final evaporated mass in this study. It is the flash chamber regulates the amount of superheat that is accessible
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
Fig. 7. Evolution of final evaporated mass vs initial pressure and initial temperature.
Fig. 8. Evolution of temperatures, mass evaporated and flash chamber pressure, when the initial temperature 𝑇𝑤,0 is 95 ◦ C and two different initial water heights 𝐻𝑤,𝑜 = 150 and
250 mm.
and accelerates the production of steam. Fig. 8(a & c) also considers the because the driving potential of the flashing phenomena is the pressure
effect of initial back pressure with other fixed conditions of temperature difference between the vacuum tank and the flash chamber. A lesser
and water pool height. It is clear from the figures that at the lesser value of vacuum tank/back pressure (absolute 𝑃𝑣,0 =21.3 kPa) creates
value of initial back pressure, the pressure inside the flash chamber more pressure difference between the tank and the chamber. This
decreases dramatically. This drop in pressure results in an increase in results in a dramatical drop in the flash chamber pressure. Lesser initial
the superheat which results in a severe and violent phenomenon. This is back pressure indicates more depressurization. Thus, more will be the
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
Fig. 9. Variation of NEF with time for different pressures and different water initial pool heights.
pressure drop in the flash chamber and faster the equilibrium will quickly in an exponential manner and reaches a lower equilibrium
achieve [27,34,38]. The rate of evaporation increases which induces value at last. As shown in Fig. 9(a & c), when the degree of superheat
the rate of vapour generation and faster temperature drop. is low, as in a static water pool, high temperature water exits the flash
chamber as less sensible energy is converted into latent energy. But
4.5. Non-equilibrium fraction (NEF) evolution With rising superheat, the rapid flash evaporation duration is extended,
and NEF falls to a low equilibrium value. Thus the degree of static flash
NEF is taken as a dimensionless parameter to evaluate the com- evaporation’s completeness can be enhanced by increased superheat.
pletion degree of flash evaporation [21] and defined as the ratio of Fig. 9(a & b) indicates the evolution of NEF vs. time at different
residual theoretical temperature drop of water pool at any given time initial water pool heights. Here, it is evident that the rapid evaporation
to its superheat (Eq. (3)). NEF represents the change in temperature stage would last longer as height increases. NEF gradually diminishes
during the flashing phenomenon. In other words, the value of NEF until it achieves a high equilibrium value. It is attributed to the fact
shows how well liquid extra thermal energy is changed into latent that an increase in initial water pool height can increase hydrostatic
energy of evaporation after the flash evaporation process has ended. head which suppresses the flash evaporation and weakens the liquid
Comparison of NEF evolution under different superheats (𝛥T), initial superheat. Fig. 9(b & d) portrays the effect of back pressure on the
water pool heights (𝐻𝑤,0 ), initial water pool temperature (𝑇𝑤,0 ), and evolution of NEF; it is reported that with the increase in the value
initial back pressure (𝑃𝑣,0 ) are presented in Fig. 9(a–d). The NEF curves of initial back pressure of the vacuum tank a higher value of NEF is
in Fig. 9 shows the variation of NEF with time and in all the cases obtained which results in incomplete flashing. It is concluded from the
exponential decay of NEF with time obtained. NEF significantly varies results of Fig. 9(a–d) that higher (𝛥T), lower (𝐻𝑤,0 ) and lower (𝑃𝑣,0 )
for smaller superheats, and negative values are sometimes attained. can make the flashing process faster and more thoroughly.
This is because, after a significant period of time, the liquid temperature
begins to fluctuate gradually around its equilibrium value (𝑇𝑒 ). This is 4.6. Variation of heat transfer coefficient
described by the process of boiling, which influences the flash cham-
ber’s temperature values significantly. Fig. 9(a) illustrates the variation Low pressure vaporization is considered as the volumetric heat
of NEF vs time at different degrees of superheat. NEF decays more transfer process. Volumetric heat transfer coefficient (ℎ𝑣 ) is expressed
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
Fig. 10. Evolution of ℎ𝑣 versus time for different pressures and different initial water pool heights.
as Eq. (4) and is defined as the average heat flux released from the height of 250 mm. Thus with the increase of initial water pool height
unit volume of the water pool under unit superheat [37]. The equation by 66.6%, the heat transfer coefficient is reduced by 43.8%. Graphs
is further simplified to obtain the heat transfer coefficient as time- in Fig. 10(a & c) shows the variation of ℎ𝑣 vs time at different initial
dependent function in the form of NEF as Eq. (5). In the equation, back pressures. It is clear that the heat transfer coefficient is high with
𝑡𝑓 is the flashing time, i.e. 100 s, and according to it, ℎ𝑣 may be a small value of initial back pressure. This can be explained on the
computed using the experimental results. By using this relation, the
basis of superheat; less value of pressure creates a high depressurization
intensity of volumetric heat transfer for low pressure vaporization
inside the flash chamber. So the water became more turbulent and
can be measured. Variations of ℎ𝑣 vs time at different experimental
more violent resulting in a more amount of energy in the sensible form
parameters are presented in Fig. 10(a–d). The graphs suggest that ℎ𝑣
immediately increases to a peak value as the flashing time increases changed to the latent heat of vaporization and high heat transfer was
and afterwards drops gradually. ℎ𝑣 increases when 𝛥T is increased. As obtained. Regarding Fig. 10(a & c), it is shown that at the same initial
shown in Fig. 10(a), under the same 𝐻𝑤,0 , ℎ𝑣 rise with the increase of water pool height of 150 mm, the volumetric heat transfer coefficient
𝛥T. This is due to the fact that as superheat is large, corresponding to a obtained after 100 s is 25.79 kWm−3 K −1 with the degree of superheat
static water pool, the presence of vortexes extends the hot water’s time of 37.32 ◦ C, while the coefficient is 15.40 kWm−3 K −1 with the degree
in the flash chamber. Thus, flash evaporation is intensified further, and of superheat of 23.88 ◦ C. Thus with the rise of the degree of superheat
greater heat transfer occurs. by 56.28%, the heat transfer coefficient is enhanced by 67%. Fig. 10(b
Variations of ℎ𝑣 vs. time at different water pool heights are pre- & d) portrays the comparison of the effect of initial back pressure on
sented in Fig. 10(a & b) at the same conditions of initial back pressure
the heat transfer during constant water pool height (𝐻𝑤,0 = 250 mm),
and liquid superheat. The heat transfer coefficient increases with de-
and it is seen that heat transfer is improved at a low value of back
creasing water pool height. It is due to the reason that a high water
pressure which means a high vacuum created in the flash chamber. It
pool height conquers the superheat of the water at the bottom of the
flash chamber. This hinders flash evaporation and alters the value is attributed to the fact that at high depressurization, a higher value
of ℎ𝑣 . As Fig. 10(a & b) portrays, at the same initial pressure of of superheats existed, which promotes the flashing process. For the
11.3 kPa, the volumetric heat transfer coefficient obtained after 100 s experiments with (𝑃𝑣,0 =31.3 kPa and 41.3 kPa), NEF and volumetric
is 40.16 kWm−3 K −1 with the water pool initial height of 150 mm, heat transfer coefficient profiles are similar to those presented in Figs. 9
while the coefficient is 22.55 kWm−3 K −1 with the initial water pool and 10.
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S. Singh et al. International Journal of Thermal Sciences 192 (2023) 108413
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