FULL TEST JEE MAIN TEST SERIES

Time : 3 Hours Maximum Marks : 180

ANSWER KEY
&
SOLUTION WITH EXPLANATION

Solution Sheet Available Only for 24 Hours

Part – 1: MATHEMATICS
• This question paper contains two sections, section A & B.
• Section A contains 20 multiple choice questions (MCQs) with four options (A),(B),(C),(D) out
of which only one option is correct.
• Section B contains 10 Numerical Value Type questions, out of which candidate have to
attempt only 5 questions.
Section A
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : +𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

1. Three circles x 2 + y 2 + 2g i x + 2fj y = 0, i = 1,2, 3 are mutually orthogonal. If ∑3i=1 g 2i = 4 and

∑3i=1 fi2 = 5, then the equation of the locus of centroid of the triangle formed by joining the
centres of these three circles, is
(A) x 2 + y 2 = 9
(B) x 2 + y 2 = 3
(C) x 2 + y 2 = 2
(D) x 2 + y 2 = 1
Ans. (D)
Sol. 2g1 g 2 + 2f1 f2 = 2g 2 g 3 + 2f2 f3 = 2g 3 g1 + 2f3 f1 = 0
g12 + g 22 + g 23 = 4, f12 + f22 + f32 = 5
−(g1 +g2 +g3 ) −(f1 +f2 +f3 )
Let the centroid is G(h, k). ⇒ h = ,k =
3 3
2 2 )2 )2
(3h) + (3k) = (g1 + g 2 + g 3 + (f1 + f2 + f3 =4+5
h2 + k 2 = 1 ⇒ Locus of G(h, k) is x 2 + y 2 = 1

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2. The co-ordinates of the foot of perpendicular drawn from point P(1,0,3) to the join of points
A(4,7,1) and B(3,5,3) is
(A) (5,7,1)
5 7 17
(B) (3 , 3 , 3 )
2 5 7
(C) (3 , 3 , 3)
5 2 7
(D) (3 , 3 , 3)

Ans. (B)
Sol. Let D be the foot of perpendicular drawn from P(1,0,3) on the line AB joining (4,7,1) and
(3,5,3).
If D divides AB in ratio λ: 1 then
3λ + 4 5λ + 7 3λ + 1
D=( , , )
λ+1 λ+1 λ+1

D.r's of PD are 2λ + 3,5λ + 7, −2

D.r's of AB are −1, −2,2
−7
∵ PD ⊥ AB; ∴ −(2λ + 3) − 2(5λ + 7) − 4 = 0 ⇒ λ =
4
5 7 17
Putting the value of λ in (i), we get the point D (3 , 3 , 3 ).

3. If the equation x 4 + 4x 3 − 2x 2 − 12x + a = 0 has four distinct real roots, then the number of
integral values of a is
(A) 21 (B) 17 (C) 15 (D) 13
Ans. (C)
Sol. x 4 + 4x 3 − 2x 2 − 12x = (x 2 + 2x − 3)2 − 9
f(x) = x 4 + 4x 3 − 2x 2 − 12x + 9
f(x) = (x 2 + 2x − 3)2
⇒ For four distinct roots
0 < 9 − a < 16
−16 < a − 9 < 0
−7 < a < 9
⇒ Number of integral values of a is 15

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4. The point of intersection of lines
⃗⃗) + λ(2a⃗⃗ + ⃗⃗
r⃗ = (a⃗⃗ − 2b b), r⃗
= (2a⃗⃗ − ⃗⃗ ⃗⃗); a⃗⃗, ⃗⃗
b) + μ(a⃗⃗ + 2b b
being non parallel vectors, is equal to
5
⃗⃗)
(A) 3 (a⃗⃗ − b
1
(B) 3 (a⃗⃗ − ⃗⃗
b)
1
⃗⃗)
(C) (a⃗⃗ − 5b
3
1
(D) 3 (7a⃗⃗ − ⃗⃗
b)

Ans. (A)
⇀ ⇀ ⇀ ⇀ ⇀
Sol. a⃗⃗ − 2b + λ(2a⃗⃗ + ⃗⃗
b) = 2a − b + μ(a + 2b )
⃗⃗ = ⃗0⃗
⇒ (2λ + 1 − μ − 2)a⃗⃗ + (−2 + λ + 1 − 2μ)b
⇒ 2λ − μ − 1 = 0, λ − 2μ − 1 = 0
(∵ a⃗⃗, ⃗⃗
b non − parallel vectors )
1 −1
λ = ,μ =
3 3
∴ The point of the intersection is
1
⃗⃗ + (2a⃗⃗ + ⃗⃗
a⃗⃗ − 2b b)
3
5 5 5
= a⃗⃗ − ⃗⃗ b = (a⃗⃗ − ⃗⃗
b)
3 3 3
dy
5. The solution of the differential equation √a + x dx + xy = 0 is

(A) y = Ae2/3(2a−x)√x+a
(B) y = Ae−2/3(a−x)√x+a
(C) y = Ae2/3(2a+x)√x+a
(D) y = Ae−2/3(2a−x)√x+a
Ans. (A)
dy xy dy −xdx
Sol. Given dx + =0⇒ =
√a+x y √a+x
dy −x
Integrating both sides, ∫ =∫ dx
y √x+a
x+a−a a 2
logy = − ∫ dx = − ∫ √x + adx + ∫ dx ⇒ logy = − 3 (x + a)3/2 + 2a√x + a + logA
√x+a √ x+a
2
3/2 +2a [(√x+a(− (x+a)+2a)]
y = Ae−2/3(x+a) √x+a = Ae 3

−2x−2a+6a
= Ae[√x+a( )]
3 = Ae[−2/3√x+a(x−2a)] or y = Ae[2/3√x+a(2a−x)] .
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6. The standard deviation of the following data is,
xi 1 2 3 4 5 6 7 8 9 10
fi 1 2 3 4 5 6 7 8 9 10
(A) 2
(B) 4
(C) √6
(D) √5
Ans. (C)
∑ff xf 12 +22 +⋯+102
Sol. (x‾) = =
∑ff 1+2+⋯+10

10 × 11 × 21
= =7
10 × 11
6×( 2 )

∑fi x12 t 3 + 23 + ⋯ + 103

= = 55
∑fi 1 + 2 + ⋯ + 10
Standard deviation = √ variance

∑ff xf2
=√ − (∇)2
∑ff

= √55 − 49 = √6
7. A biased coin with probability getting a head is p, (0 < p < 1), is tossed until a head appears
2
for the first time. If the probability that the number of tosses required is even is 5, then p is

equal to
(A) 1/2
(B) 1/3
(C) 1/4
2
(D) 3

Ans. (B)
Sol. Let X denotes the number of tosses required. Then P(X = r) = (1 − p)r−1 ⋅ p, for r = 1,2,3 … …
Let E denote the event that the number of tosses required is even.
Then P(E) = P[(X = 2) ∪ (X = 4) ∪ (X = 6) ∪ … …..
P(E) = P(X = 2) + P(X = 4) + P(X = 6) +……..
1−p
P(E) = (1 − p)p + (1 − p)3 p + (1 − p)5 p + ⋯ = 2−p
2 1
But we are given that P(E) = 5, then we get p = 3.

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8. In triangle ABC, angles A and B measure 60∘ and 45∘ , respectively. The bisector of ∠A intersect
side BC at T, and AT = 24. The area of △ ABC can be written in the form a + b√c, where a, b and
c are positive integers and c is not divisible by the square of any prime. The value of a + b + c is
(A) 291
(B) 290
(C) 289
(D) 339
Ans. (A)
Sol. Draw AM ⊥ BC
So gn △ ABM -
∠B = 45∘ = ∠MAB
So ∠MAT = 15∘ {∵ ∠TAB = 30∘ }
So gnrt △ MAT
AM √3 + 1
cos15∘ = ⇒ AM = ATcos15∘ ⇒ AM = 24 ×
AT 2√2
AM = 6√2(√3 + 1)
∴ AM = BM
So BM = 6√2(√3 + 1)
Now gnrt. △ AMC
CM
tan15∘ =
AM
√3 − 1
CM = AMtan15∘ = 6√2(√3 + 1) ⋅
(√3 + 1)
CM = 6√2[√3 + 1 + √3 − 1]
So BC = BM + CM = 6√2 × 2√3
= (√3 + 1) = 6√2 × 2√3 = 12√6
1
So Δ = × 12√6 × 6√2(√3 + 1)
3
= 6√6 × 6√2(√3 + 1)
= 36√12(√3 + 1)
= 216 + 36√12
= 216 + 72√3 = a + b√c
⇒ a = 216, b = 72, c = 3
⇒ a + b + c = 291

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9. A variable line L intersects the parabola y = x 2 at P and Q with abscissas x1 and x2 respectively
4
and x1 < x2 . The area of the figure enclosed by the chord PQ and the parabola is always 3 sq.

units. If M is the mid-point of variable chord PQ, then locus of M is S.

Match the entries in List-I to entries in List-II, on the basis of above information.
List-I List-II
P. |x1 − x2 | is equal to 1. 2
3
Q. The y intercept made by chord of contact 2. 2
of tangents from origin to S is
R. Area of region enclosed between S and the 3. 4
two tangent to S from origin is
S. If equation of S is y = k1 + k 2 x 2 then k1 + 4.
3
k2 =
2

(A) P → 2, Q → 1, R → 3, S → 4
(B) P → 2, Q → 1, R → 3, S → 3
(C) P → 1, Q → 2, R → 4, S → 3
(D) P → 2, Q → 2, R → 1, S → 2
Ans. (D)
Sol. As given
x 4
− ∫x 2 (x − x1 )(x − x2 )dx = 3
1

(x−x2 )2 x2 x (x−x2 )2 4
⇒ − ((x − x1 ) | − ∫x 2 dx) =
2 x1 1 2 3

−(x1 −x2 )3 4
⇒ =3
6

⇒ |x1 − x2 | = 2
x1 +x2 x21 +x22
Further h = ,k =
2 2

∵ (x1 + x2 )2 + (x1 − x2 )2 = 2(x12 + x22 )

⇒ k = 1 + h2
⇒ Locus of M is y = 1 + x 2 ≡ S
Tangent from origin S are y = ±2x
1
2
Required area = 2 ∫ (x 2 + 1 − 2x)dx = sq. units
0 3
Obviously chord of contact of tangents from origin to S is y = 2

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10. Rahul starts to paint a fence on one day. On the second day two more friends of Rahul join him.
On the third day 3 more friends of him join him and so on. If the fence is completely painted
this way in exactly 20 days, then the number of days in which Rahul's father along with his 9
friends can paint the fence completely, is (It is given that every adult can paint twice as fast as
Rahul and his friends). Assume that all friends of Rahul's father are adult and friends of Rahul
are not adult.
(A) 77
(B) 45
(C) 62
(D) 90
Ans. (A)
Sol. Let a boy (not adult) does x units of work per day. So total amount of work required to paint the
fence is x[1 + (1 + 2) + (1 + 2 + 3) + (1 + 2 + 3 + 4) + ⋯ 20 terms ]
Let Rahul's father and his friends took n days to complete the work then
2x[n × 10] = x[1 + (1 + 2) + (1 + 2 + 3) + ⋯ 20 terms ]
r(r+1)
⇒ 20n = ∑20
r=1 2
1 20×21×41 20×21
⇒ 20n = 2 [ + ]
6 2
1
⇒ 20n = 2 [10 × 7 × 41 + 10 × 21]
10×7(41+3)
⇒ 20n = 2

⇒ n = 77
4e2iA e−iC e−iB
11. If A, B and C are angles of a triangle ABC, then the value of |e−iC 4e2iB e−iA | is
e−iB e−iA 4e2iC
(where i = √−1 )
(A) 20
(B) 40
(C) 50
(D) 60
Ans. (C)
Sol. A + B + C = π ⇒ ei(A+B+C) = eiπ = −1
4eiA −eiB −eiC
⇒ |−eiA 4eiB −eiC |
−eiA eiB 4eiC
⇒ 4(16 − 1) − 5 − 5 = 60 − 10 = 50

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a b
12. Let T5 be the set of matrices of order 2 × 2 such that T5 the = {A: A = [ ], where a, b, c ∈
c a
{0,1,2,3,4}}n the total number of possible matrices A such that det(A) is not divisible by ' 5 ' is
(A) 51
(B) 100
(C) 101
(D) 115
Ans. (B)
Sol. |A| = a2 − bc
Total number of matrices in A5 = 5 × 5 × 5
= 125,
Now, we will evaluate, number of ' A ' in T5 , so that |A| is divisible by ' 5 '
Case-I: a = 0, ⇒ −bc must be divisible by ' 5 '
(0,0), (0,1), (0,2), (0,3), (0,4), (1,0), (2,0), (3,0), (4,0)
Case-II: a = 1, ⇒ (1 − bc) must be divisible by ' 5 '
⇒ (1,1), (2,3), (3,2), (4,4)
Case-III: a = 2 ⇒ 4 − bc must be divisible by ' 5 ' ⇒ (1,4), (4,1), (2,2), (3,3)
Case-IV: a = 3 ⇒ (9 − bc) must be divisible by ' 5 '
⇒ (3,3), (1,4), (4,1), (2,2)
Case-V: a = 4, so (16 − bc) must be divisible by ' 5 '
⇒ (4,4), (2,3), (3,2), (1,1)
so there are 25 matrices
So required matrices are = 125 − 25 = 100

1−sin2 x π
, x<
3cos2 x 2
π
13. If f(x) = a, x = 2 then f(x) is continuous at x = π if
2
b(1−sin x) π
, x>
{ (π−2x)2 2

(A) a = b = 1
1 8
(B) a = 3 , b = 3
2 8
(C) a = 3 , b = 3
1
(D) a = 3 , b = 2

Ans. (B)

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π
Sol. f(x) is continuous at x = 2
π− π π+
So f ( 2 ) = f ( 2 ) = f ( 2 )
1−sin2 x b(1−sinx)
⇒ lim
π−
= a = lim+
x→ 3cos2 x π (π−2x)2
2 x→
2

1 b(−cosx)
⇒ 3 = a = lim+ 2(π−2x)(−2)
π
x→
2

1 b(sinx) b
a = 3 = lim+ −4(−2) = 8
π
x→
2

1
So a = 3
8
b=
3
14. The position vectors of the four angular points of a tetrahedron ABCD are A(3, −2,1);
B(3,1,5); C(4,0,3) and D(1,0,0). Then the acute angle between the plane faces ADC and ABC is
5
(A) tan−1 (2)
2
(B) cos−1 (5)
5
(C) cosec −1 (2)
3
(D) cot −1 (2)

Ans. (A)
Sol. v1 = (3 − 3)î + (1 + 2)ĵ + (5 − 1)k̂ = ⃗⃗⃗⃗
⃗⃗⃗⃗ v1 = (3 − 3)î + (1 + 2)ĵ + (5 − 1)k̂ = 0î + 3ĵ + 4k̂
v2 = (4 − 3)î + (0 + 2)ĵ + (3 − 1)k̂ = î + 2ĵ + 2k̂
⃗⃗⃗⃗
v3 = (1 − 3)î + (0 + 2)ĵ + (0 − 1)k̂ = −2î + 2ĵ − k̂
⃗⃗⃗⃗
Let ⃗⃗⃗⃗⃗
n1 be a vector normal to plane ABC and ⃗⃗⃗⃗⃗
n2 be the other vector normal to the plane ADC let θ
⃗⃗⃗⃗⃗⃗⋅n
n ⃗⃗⃗⃗⃗⃗
be the acute angle between the plane faces ABC and ADC then cosθ = ||n⃗⃗⃗⃗⃗⃗||n
1 2
⃗⃗⃗⃗⃗⃗|
|
1 2

î ĵ k̂
Where ⃗⃗⃗⃗⃗
n1 = ⃗⃗⃗⃗
v1 × ⃗⃗⃗⃗
v2 = |0 3 4| = î(6 − 8) − ĵ(0 − 4) + k̂(0 − 3) = −2î + 4ĵ − 3k̂
1 2 2
î ĵ k̂
n2 = ⃗⃗⃗⃗
⃗⃗⃗⃗⃗ v2 × ⃗⃗⃗⃗
v3 = | 1 2 2 | = î(−2 − 4) − ĵ(−1 + 4) + k̂(2 + 4)
−2 2 −1
= −6î − 3ĵ + 6k̂
12−12−18 −18 2
∴ cosθ = | |=| |=
√4+16+9√36+9+36 √29⋅9 √29

√29 − 4 5 5
∴ tanθ = = ⇒ θ = tan−1
2 2 2

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15. If it is possible to draw a line which belongs to all the given family of lines
y − 2x + 1 + λ1 (2y − x − 1) = 0,
(3y − x − 6) + λ2 (y − 3x + 6) = 0,
ax + y − 2 + λ3 (6x + ay − a) = 0,
then a can be
(A) 3
(B) 2
(C) -2
(D) 4
Ans. (D)
Sol. First two families of lines pass through (1,1) and (3,3) respectively and points of intersection of
lines belonging to third family of lines will lie on line y = x.
2
⇒ ax + x − 2 = 0 ⇒ x = a+1
a
and 6x + ax − a = 0 ⇒ x = b+a
2 a
∴ a+1 = 6+a

⇒ 12 + 2a = a2 + a
⇒ a2 − a − 12 = 0
⇒ a = −3,4
16. If √6cosθ − √2sinθ = 2√2, then the value of θ can be
(A) 45∘
(B) −60∘
(C) −30∘
(D) 60∘
Ans. (C)
Sol. √6cosθ − √2sinθ = 2√2
Divide the above equation by 2√2 we get:
√3 1
cosθ − sinθ = 1
2 2
⇒ cos30∘ cosθ − sin30∘ sinθ = 1
⇒ cos(30∘ + θ) = 1[∵ cos(A + B) = cosAcosB − sinAsinB]
⇒ cos(30∘ + θ) = cos0∘
⇒ 30∘ + θ = 0
⇒ θ = −30∘

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1 1 2 1 3
17. The sum to infinity of the series, S = 1 + 2 (1 − 3) + 3 (1 − 3) is +4 (1 − 3) + ⋯

(A) 1
(B) 3
(C) 6
(D) 9
Ans. (D)
1 1 2 1 3
Sol. S = 1 + 2 (1 − 3) + 3 (1 − 3) + 4 (1 − 3) + ⋯

1 1 2 1 3 1 1 2 1 3
1 (1 − 3) + 2 (1 − 3) + 3 (1 − 3) + ⋯ 1 + (1 − 3) + (1 − 3) + (1 − 3) + ⋯
S (1 − ) = =
3 S ⇒ S = 9
3
S 1
⇒3 = 2
1−
3

18. Let A(0,1), B(1,1), C(1, −1), D(−1,0) be four points. If P be any other point, then
PA + PB +PC + PD ≥ d, where d is equal to,
(A) 4√5
(B) 2√5
(C) 3√5
(D) 5
Ans. (B)
Sol. (AP + PC) is minimised when P lies on AC and BP + PD is minimised when P lies on BD Thus
AP + PB + PC + PD = AC + BD = 2√5
kx2 +6x−8
19. A function f: R → R is defined by f(x) = k+6x−8x2 for which f(x) is onto. Then k belongs to

(A) (2,14)
(B) (3,15)
(C) (1,13)
(D) (0,15)
Ans. (A)
Sol. x 2 (k + 8y) + x(6 − 6y) − (8 + ky) = 0
x∈R
⇒D≥0
⇒ (8k + 9)y 2 + (k 2 + 46)y + 8k + 9 ≥ 0
⇒ D < 0,8k + 9 > 0
⇒ a ∈ (2,14)

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20. The tangent at any point P(x, y) on a curve meets the x-axis at A. If OP = PA, where O being the
origin, then the curve may be
(A) A circle
(B) A parabola
(C) An ellipse
(D) A hyperbola
Ans. (D)
dy dx
Sol. The tangent at p(x, y) is : Y − y = (X − x) dx It meet x-axis at A = (x − y dy , 0)

dx 2 dy
∵ OP 2 = PA2 ⇒ x 2 + y 2 = y 2 (dy) + y 2 ⇒ x dx = ±y

⇒ xy = c 2 or y = cx, where c is constant

Section B
• This Section contain 10 questions (Q. No. 21 to Q. No. 30) whose answer to be filled as
numerical value (Attempt any five)
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : +𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

(x + 2)3 ; −3 < x ≤ −1 x
21. Let f(x) = { 2/3
and g(x) = ∫−3 f(t)dt; −3 < x < 2
x ; −1<x<2
Number of points of extremum of g(x) is
Ans. 1
Sol.

g(x) has extrema at x = −2 So, only one extrema

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22. If a, b, c are in arithmetic progression, then ax + by + c = 0 must passes through the point
(α, β), then |α| + |β| equals
Ans. 3
Sol. a − 2b + c = 0 on comparing with ax + by + c = 0 we get (1, −2) i.e. (α = 1&β = −2)
23. If the value of 19 ! is 1216 T510040M832H00, where, T, M&H are single digit integers, then the
value of T + M + H is
Ans. 12
Sol. Clearly 19 ! ends in three zeros ⇒ H = 0
∵ 19 ! is divisible by 9
∴ Sum of digits must be divisible by 9 ⇒ T + M + 33 is multiple of 9 ...(i)
∵ 19 ! is divisible by 11
∴ The alternating sum of digits must be divisible by 11 .
1 − 2 + 1 − 6 + T − 5 … … . = multiple of 11 ⇒ M + 7 − T is divisible by 11 ...(ii)
from (i) and (ii) T = 4 and M = 8 ⇒ T + M + H = 12.
24. If f(x) = (sinx + cosecx)2 + (cosx + secx)2 , then the minimum value of f(x) is
π
(where x ∉ {nπ, (2n + 1) 2 } )

Ans. 9
Sol. f(x) = sin2 x + cosec 2 x + cos 2 x + sec 2 x + 4
f(x) = 5 + 1 + tan2 x + 1 + cot 2 x
f(x) = 7 + tan2 x + cot 2 x
∵ A.M. ≥ G.M. ∴ f(x) ≥ 9
25. If f(x) + f(y) + f(xy) = 2 + f(x)f(y) ∀x, y ∈ R − {0} and f(x) is a polynomial with f(D) = 17 and
f(A) ≠ 1, then value of f(5) is equal to
Ans. 26
Sol. Put x = y = 1, we get f(A) + f(A) + f(1.1) = 2 + f(A)f(A)
(f(A))2 − 3f(A) + 2 = 0 ⇒ (f(A) − 1) − (f(A) − 2) = 0 ⇒ (f(A)) = 2 ∵ f(A) ≠ 1
1
Put y = x
1 1 1
we get f(x) + f (x) + f (x ⋅ x) = 2f(x)f (x)
1 1
f(x) + f ( ) = f(x)f ( )
x x
∴ f(x) = 1 + x n or f(x) = 1 − x n
f(D) = 17
satisfied by f(x) = 1 + x n for n = 2 ∴ f(5) = 1 + 52 = 26

APNI KAKSHA 13
FULL TEST JEE MAIN TEST SERIES
n(1+2+3+⋯+n)(12 +22 +32 +⋯+n2 )(13 +23 +33 +⋯+n3 ) k
26. If the value of limn→∞ (14 +24 +34 +⋯+n4 )2
is p (where k and p are

coprime) then value of k + p is

Ans. 49
n(n+1) n(n+1)(2n+1) n2 (n+1)2
n⋅ ⋅ ⋅
Sol. limn→∞ 2
4 4
6
4
4
2
8 1 2 3 n4
n [ 4 + 4 + 4 +⋯.+ 4 ]
n n n n

1 1 1 1 1 1 1 2
(1+ ) (1+ )(2+ ) (1+ )
2 n 6 n n 4 n
limn→∞ 2
1 14 24 34 n4
[ 4 + 4 + 4 +⋯.+ 4 ]
n2 n n n n

1 1 1 1 1 1 1 2
(1+ ) (1+ )(2+ )⋅ (1+ )
2 n 6 n n 4 n
limn→∞ 2
1 r 4
( ∑nr=1 ( ) )
n n

1 1 1 1 1 1 1 2
(1+ ) (1+ )(2+ )⋅ (1+ )
2 n 6 n n 4 n
limn→∞ 1 2
(∫0 x4 dx)

1 1 1 25
= 2 × 6 × 2 × 4 × 25 = 24
tan54∘ −tan2∘
27. The value of sin2∘ sin6∘ sin18∘ is_________.
+ +
cos6∘ cos18∘ cos54∘

Ans. 2
Sol. We know that,
3tanθ−tan3 θ
tan3θ − tanθ = − tanθ
1−3tan2 θ
3−tan2 θ
= (tanθ) [1−3tan2θ − 1]
2+2tan2 θ
= (tanθ) [1−3tan2θ]
2sinθ cos2 θ+sin2 θ
= [ ]
cosθ cos2 θ−3sin2 θ
2sinθ 1 2sinθ
= [ ] = cos3θ
cosθ 4cos2 θ−3
(tan54∘ −tan18∘ )+(tan18∘ −tan6∘ )
∴ sin2∘ sin6∘ sin18∘
+ +
cos6∘ cos18∘ cos54∘

sin18∘ sin6∘ sin2∘

2( + + )
cos54∘ cos18∘ cos6∘
= sin2∘ sin6∘ sin18∘
+ +
cos6∘ cos18∘ cos54∘

=2

28. Let L = 0 be a common normal to the circle C ≡ x 2 + y 2 − 2ax − 36 = 0 and the curve
S ≡ (1 + x)y + exy = y drawn at a point x = 0 on S, then the value of r − a, where r is radius of
circle, is equal to________.
Ans. 2

APNI KAKSHA 14
FULL TEST JEE MAIN TEST SERIES
Sol. Given curve is S ≡ (1 + x)y + exy = y
Put x = 0 in equation (A)
(1 + 0)y + e0 = y ⇒ 1 + 1 = y ⇒ y = 2
∴ Any point on curve S is (0,2) when x = 0
Again differentiating both sides of (A), we get
1 dy dy dy
(1 + x)y (y ⋅ 1+x + log(1 + x) dx) + exy (x dx + y × 1) = dx
y
⇒ (1 + x)y (1+x + log(1 + x)y ′ ) + exy (xy ′ + y) = y ′

Put x = 0
2
(1 + 0)y (1+0 + log(1 + 0)y ′ (0)) + e0 (0 ⋅ y ′ + 2) = y ′ (0)
2
⇒ 1 (1 + 0 ⋅ y ′ (0)) + eo (0 + 2) = y ′ (0) ⇒ y ′ (0) = 4
1 1
Slope of normal at (0,2) = − y′ (0) = − 4
1
∴ Equation of normal at (0,2) to the curve is y − 2 = − 4 (x − 0) ⇒ x + 4y = 8 … (B)

⇒ L ≡ x + 4y − 8 = 0 is also the normal to the circle

C ≡ x 2 + y 2 − 2ax − 36 = 0...(C)
∴ Normal (B) will pass through its centre (a, 0)
∴a+0−8=0⇒a=8
Also radius of circle (C) is r = √(−a)2 + 0 − (−36) = √82 + 36 = 10
∴ r − a = 10 − 8 = 2
29. r th term of a series is the sum of r th term of an A.P. and r th term of a G.P., whose first terms are
equal to one each and the common difference of the A.P. and common ratio of the G.P. are equal
to n each, n ∈ N. Number of such terms in this series which are perfect squares of a natural
number for all n, is
Ans. 1
Sol. Series is 1 + 1, (1 + n) + n, (1 + 2n) + n2 , (1 + 3n) + n3 , …, here 1 + 2n + n2 = (n + 1)2 is only
perfect square for all n ∈ N
dy 1
30. Equation of the curve passing through (3,9) which satisfies the differential equation dx = x + x2

is 6xy = 3x 3 + kx − 6, then value of k is equal to

Ans. 29
x2 1 9 1 29
Sol. y= − x + c ⇒ As (3,9) satisfies it, 9 = 2 − 3 + c ⇒c=
2 6
x2 1 29
∴y= −x+ ⇒ 6xy = 3x 3 − 6 + 29x
2 6

Hence k = 29
APNI KAKSHA 15
FULL TEST JEE MAIN TEST SERIES
PART – 2: PHYSICS
• This question paper contains two sections, section A & B.
• Section A contains 20 multiple choice questions (MCQs) with four options (A),(B),(C),(D) out
of which only one option is correct.
• Section B contains 10 Numerical Value Type questions , out of which candidate have to
attempt only 5 questions.

Section-I
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : +𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

31. Two particles execute simple harmonic motion of the same amplitude and frequency along
close parallel lines. They pass each other moving in opposite directions each time their
displacement is half of their amplitude. Their phase difference is
5π 4π π 2π
(A) (B) (C) 6 (D)
6 3 3

Ans. (D)
Sol. x = Asin (ωt + ϕ)
A π 5π
t = 0, x = 2 , ϕ = 6 , 6

5π π 2π
∴ Δϕ = − =
6 6 3

32. Four bodies R: ring, C: cylinder, S: solid sphere and H: hollow sphere are placed at the top of an
inclined plane of inclination θ. All the bodies have same mass M and radius R. If the surface of
the incline is smooth, then choose the correct statement related to the time taken in reaching
the foot of the incline
(A) t S < t C < t H < t R (B) t S > t C > t H > t R
(C) t R = t C < t S < t H (D) t C = t S = t H = t R
Ans. (D)
Sol. time taken by all the bodies will same because friction is absent.

APNI KAKSHA 16
FULL TEST JEE MAIN TEST SERIES
33. A copper wire is held at the two ends by rigid supports. At 30∘ C, the wire is just taut, with
negligible tension. The approximate speed of transverse waves in this wire at 10∘ C is
(Given Young's modulus = 1.3 × 1011 N/m2 , Coefficient of linear expansion, α = 1.7 × 10−5 / ∘ C
density of wire, p = 9 × 103 kg/m3 )
(A) 70 m/s (B) 20 m/s (C) 40 m/s (D) 110 m/s
Ans. (A)
T YAαΔθ YAαΔθ⋅L YαΔθ
Sol. v = √μ = √ =√ =√ = 70 m/s
μ M ρ

34. The potential energy of a particle is determined by the expression U = α(x 2 + y 2 ), where α is a
positive constant. The particle begins to move from a point with the coordinates (3,3)(m), only
under the action of potential field force. Then its kinetic energy T at the instant when the
particle is at a point with the coordinates (1,1)(m) is
(A) 8α (B) 24α (C) 16α (D) zero
Ans. (C)
Sol. be conserved. So ΔT + ΔU = 0 ( T stands for kinetic energy)
or, ΔT = −ΔU = Ui − Uf = α(32 + 32 ) − α(12 + 12 ) = 18α − 2α = 16α.

35. A ball is released from the top of a building 180 m high it takes time t to reach the ground. With
5t
what speed should it be projected down so that it reaches the ground in time 6 .

(A) 50 ms −1 (B) 61 ms −1 (C) 11 ms −1 (D) 2 ms −1 .

Ans. (C)
2h 5 1
Sol. t = √ g , t ′ = 6 t and h = ut ′ + 2 gt ′2

36. Two semicircular rings having same mass m and radius r are joined as shown in the figure. The
moment of inertia of system about an axis passing through centre of mass of system and
perpendicular to the plane of figure is

(A) 2mr 2 (B) 4mr 2 (C) mr 2 (D) (3/2)mr 2

Ans. (B)
APNI KAKSHA 17
FULL TEST JEE MAIN TEST SERIES
37. An ideal diatomic gas undergoes a process (PV x ) in which the heat absorbed by the gas is twice
the increment of its internal energy. Then the polytropic exponent (x) of the process is
(A) 2 (B) 3/5 (C) 2/5 (D) 5/2
Ans. (B)
Sol. ΔQ = 2ΔU
R
ncdT = 2nCVdT ⇒ CV + 1−x = 2CV
R 5
= 2 R ⇒ x = 3/5
1−x

38. An organ pipe of cross sectional area 100 cm2 resonate with a tuning fork of frequency 1000 Hz
in fundamental tone. The minimum volume of water to be drain out so that the pipe again
resonate with the same tuning fork is (take velocity of wave = 320 m/s)
(A) 800 cm3 (B) 1200 cm3 (C) 1600 cm3 (D) 2000 cm3
Ans. (C)
v 3v
Sol. 1000 = 4ℓ = 4ℓ
1 2

⇒ ℓ2 = 3ℓ1
⇒ ℓ1 = 8 cm and ℓ2 = 24 cm
⇒ minimum volume = 16 × 100 = 1600 cm3

39. A block of mass m is gently placed over a massive plank moving horizontally over a smooth
surface with velocity 6 m/s. The coefficient of friction between the block and plank is 0.2 . The
distance travelled by the block with respect to plank till it slide on the plank is ( g = 10 m/s 2 )
(A) 4 m (B) 6 m (C) 9 m (D) 12 m
Ans. (C)
Sol. v 2 = u2 + 2as
(0)2 = (6)2 − 2 × 2 × s
S= 9m

40. The wavelength of characteristic X-ray K α line emitted by hydrogen like atom is 0.32Å. The
wavelength of K β line emitted by the same element is
(A) 0.18Å (B) 0.48Å (C) 0.27Å (D) 0.38Å
Ans. (C)
1 1 1 1 1 1 λ Kβ 27
Sol. = R(z − b)2 (12 − 22 ) ⇒ λ = R(z − b)2 (12 − 32 ) ⇒ λ = 32 ⇒ λKβ = 0.27Å
λ Kα Kβ Kα

APNI KAKSHA 18
FULL TEST JEE MAIN TEST SERIES
41. An electron in a hydrogen atom makes a transition from n1 to n2 . The time period of the
electron in the initial state is eight times that in the final state. The possible value of n1 and n2
are
(A) n1 = 6, n2 = 4 (B) n1 = 8, n2 = 2
(C) n1 = 8, n2 = 1 (D) n1 = 6, n2 = 3
Ans. (D)
Sol. We know time, T ∝ n3
T1 n 3
So, = (n 1 )
T2 2

So, we get, n1 = 2n2

42. There is a conducting ring of radius R. Another ring carrying current i and radius r(r << R) is
kept on the axis of bigger ring such that it's a centre lies on the axis of bigger ring at a distance
x from the centre of bigger ring and its plane is perpendicular to that axis. The mutual
inductance of bigger ring due to smaller ring
μ πR2 r2 μ πR2 r2 μ πR2 r2 μ πR2 r2
(A) (R20+x2)3/2 (B) 4(R02+x2)3/2 (C) 16(R02+x2)3/2 (D) 2(R02+x2)3/2

Ans. (D)
μ iR2
Sol. Let current i flows in bigger ring then the magnetic field on its axis B = 2(R20+x2)3/2
μ iR2 μ πR2 r2
flux linked with smaller ring ϕ = Bπr 2 ⇒ ϕ = 2(R20+x2)3/2 ⋅ πr 2 = Mi ⇒ M = 2(R02+x2)3/2.

43. The figure below shows the path of white light's rays which leave in phase from two small
sources S1 and S2 and travel to a point X on a screen. The path difference is S2 X − S1 X =
10 × 10−7 m. What wavelength of light give complete destructive interference at X ?

(A) 4 × 10−7 m (B) 3 × 10−7 m (C) 6 × 10−7 m (D) 5 × 10−7 m

Ans. (A)
λ λ 20×10−7
Sol. For destructive interference Δx = n 2 ; 10 × 10−7 = n 2 ; λ = for n = 5; λ = 4 × 10−7 m
n

APNI KAKSHA 19
FULL TEST JEE MAIN TEST SERIES
44. A capacitor of capacitance C is charged by a battery of emf V and then disconnected. The work
done by an external agent to slowly insert a dielectric of dielectric strength k of half the length
of the capacitor is

1 k−1 1 1−k
(A) 2 CV 2 (k+1) (B) 2 CV 2 (k+1)
1 1
(C) 4 CV 2 (k − 1) (D) 4 CV 2 (1 − k)

Ans. (B)
Sol. Charge remains conserved
KC C
q = CV (C1 = = and C2 = 2)
2

1C 2V 2 1
q = (C1 + C2 )V ′ Uf − Ui = 2 2 (1 + k) (1+k) − 2 CV 2
C CV2 1
⇒ CV = 2 (k + 1)V ′ = 1+k − 2 CV 2
2V 1 2 1 1−k
⇒ V′ = = CV 2 ( − 1) = CV 2 ( )
k+1 2 1+k 2 1+k

45. A choke coil is needed to limit the current to operate an arc lamp at 250 V (rms) and 50 Hz. The
lamp has an effective resistance of 15Ω when running at 10 A(rms). The inductance of the
choke coil is
1 1
(A) 10πH (B) 10π H (C) 5π H (D) 5πH.

Ans. (C)
Sol. (Vrms )R = irms R = 150 volt
2
(Vrms )L = √Vrms − (Vrms )2R = 200 volt
(Vrms )L = irms xL = irms 2πfL
200 1
L = 10×2π×50 = 5π H.

APNI KAKSHA 20
FULL TEST JEE MAIN TEST SERIES
46. A conducting flexible distorted loop of total length 22 cm carrying a current i is placed in a
uniform magnetic field B as shown in the figure. The loop will
(A) form into a circular loop of radius 3.5 cm (approximately).
(B) form into a lump.
(C) remain in its original shape.
(D) Nothing can be said.
Ans. (A)
Sol. Force is exerted outward. So, a circular loop is formed.
22
2πr = 22 ⇒ 2 × r = 22 ⇒ R = 3.5 cm
7

47. A uniform conducting wire of the length, ℓ = (10 ± 0.2)cm and radius of cross-section
r = (1 ± 0.01)cm respectively, is cut to form a resistor. The maximum percentage error in the
resistance is (assume that the resistivity of the material of the wire is known very accurately)
(A) 1% (B) 2% (C) 4% (D) 8%
Ans. (C)
l
Sol. R = ρ A [ρ is constant]
dR dl 2r
= + [For max error]
R l r
dR 0.2 2×0.01
× 100 = × 100 + × 100 = 4%
R 10 1

48. A point charge q is placed at a distance 2r from the centre O of a conducting uncharged sphere
of radius r. Potential of induced charges at point P (lying in a line joining the point charge and
centre of sphere) is

Kq Kq Kq
(A) (B) (C) (D) None of these
2r 3r 6r

Ans. (C)
Kq
Sol. Vp = (= V0 );
2r
Kq Kr Kq
Now = + Vr ⇒ Vin =
2r 3r 6r

APNI KAKSHA 21
FULL TEST JEE MAIN TEST SERIES
49. A rod of length L is pulled with a force F as shown on a smooth horizontal surface. If A is the
area of cross-section and Y the Young's modulus of the material of the rod, the elastic potential
energy stored in the rod is

F2 L F2 L F2 L F2 L
(A) 3YA (B) 6YA (C) 2YA (D) YA

Ans. (C)
T 1
Sol. Stress = A E = 2 Stress × Strain × Volume

Stress 1 ( Stress )2
=Y= × Volume
Strain 2 Y
1 L−xF 21
L
F = ma = ∫ ( ) Adx
o 2 L A Y
F F2L L − x
T = (L − x)λ = = F
M 6YA L

50. In figure, infinite conducting rings each having current i in the direction shown are placed
concentrically in the same plane as shown in the figure. The radius of rings are r, 2r, 22 r, 23 r ∞.
The magnetic field at the centre of rings will be

μ0 i μ0 i μ0 i
(A) Zero (B) (C) (D) .
r 2r 3r

Ans. (D)
μ0 i μ i μ i
Sol. B= 0
− 2(2r) + 2(202r) … … ∞
2r

μ0 i 1 1 1 μ0 i 1 μ0 i
B= [1 − 2 + 22 − 23 + ⋯ . ∞] ⇒ B = [ 1 ]⇒B= .
2r 2r 1−(− ) 3r
2

APNI KAKSHA 22
FULL TEST JEE MAIN TEST SERIES
Section-II
• This Section contain 10 questions (Q.No. 21 to Q.No. 30) whose answer to be filled as
numerical value (Attempt any five)
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : +𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

51. The current flowing through 1kΩ resistance in the following circuit is p mA. The value of p is:

Ans. (5)
Sol. The P.D. across 1kΩ resistance is Vz = 5 V
VZ 5
IL = = 3
= 5 × 10−3 A = 5 mA
R L 1 × 10

52. Find the mean binding energy per one nucleon in 016 nucleus in MeV. Given m(O16 ) =
15.9994amu, m(H1 ) = 1.007823amum(n′ ) = 1008665amu 43 ) with
Ans. (8)
Sol. Mass defect
Δm = [(1.007823)8 + (1.008665)8 − 15.9994] Δm = 0.1425
0.1425×931.5
B.E. per nucleon = ≃ 8MeV
16

53. The wavelength of first lines of Balmer series and Lyman series are related as λB /λL = 27/n;
then n is:
Ans. (5)
1 1 1 3R
Sol. = R [12 − 22 ] =
λL 4

Dividing Eqn. (i) by Eqn. (ii),

λB 27
=
λL 5

∴ n=5
APNI KAKSHA 23
FULL TEST JEE MAIN TEST SERIES
54. Two polaroids are oriented at an angle of 30∘ w.r.t. each other. The fraction of incident
3
unpolarised light that is transmitted through both the polaroids is found to be −. The value of n

is:
Ans. (8)
2
I I0 √3 3
Sol. I = ( 20) cos2 30∘ = ( ) = 8 I0
2 2
I 3
∴I =8⇒n=8
0

55. Radii of curvature of a converging lens are in the ratio 1: 2. Its focal length is 6 cm and refractive
index is 1.5. Then, radius of curvature (in cm ) of the second surface of the lens is:
Ans. (9)
Sol. Let radii of curvature of the two surfaces of the lens are R and 2R. Using lens maker's formula,
1 1 1
= (μ − 1) [R − R ]
f 1 2

1 1 1
= (1.5 − 1) [R − −2R]
6
1 1 1 1 1 1 3
= 2 [R + 2R] ⇒ 6 = 2 [2R]
6

R = 4.5 cm
∴ R 2 = 2R = 2 × 4.5 = 9 cm

56. A wooden stick of length 3l is x rotated about an end with constant x angular velocity ω in a
uniform magnetic field B perpendicular to the plane of motion. If the upper x one third of its
length is coated with copper, the potential difference across the whole length of the stick is
nBωl2
. Find n.
2

Ans. (5)
ε 3L
Sol. dε = Bvdx ⇒ ∫0 dε = ∫2L Bωxdx
Bω
Ε= (9L2 − 4L2 )
2
5Bωl2
⇒ε= 2

⇒n=5
APNI KAKSHA 24
FULL TEST JEE MAIN TEST SERIES
2
57. A circular loop of radius R = ( π) m is placed in a uniform magnetic field B = 1 T in x − y plane
√

as shown in figure. The loop carries a current i = 1.0 A in the direction shown in figure. Find
the magnitude of torque acting on the loop.

Ans. (4)
Sol. M = IA = I(πR2 )
4
=1×π× = 4 A − m2
π
∴ τ = MBsin 90∘
=4×1×1= 4N−m

58. Two short magnets A and B of magnetic moment 2Am2 and 5Am2 respectively are placed along
two lines drawn mutually perpendicular to each other (Fig.). At the point of intersection of
their axes, the magntidue of magnetic field is x × 10−5 T. The field is approximate value of x is:

Ans. (2)
Sol. B = √B12 + B22
2 2
μ0 2M1 2M2
= ( ) √( 3 ) + ( 3 )
4π d1 d2

2 2
4 × 4π × 10−7 2 5
= √( ) + ( )
4π (0.3)3 (0.4)3

= 2.15 × 10−5 T
∴ n≃2
APNI KAKSHA 25
FULL TEST JEE MAIN TEST SERIES
59. Five capacitors are connected as shown in Fig., The charge across 4μF capacitor is found to be
10n microfarad. The value of n is:

Ans. (4)
Sol. Three capacitors 6μF, 4μF and 8μF are in parallel.
Ceq. = 6 + 4 + 8 = 18μF
Thus, three capacitors, each of 18μF are in series. Therefore, P.D. across each of capacitor
6μF, 4μF and 8μF is 10 V each.
∴ Charge on 4μF capacitor = 4 × 10 = 40μF
∴ n=4

60. An electric field ⃗E⃗ = (20î + 30ĵ)N/C exists in the space. If the potential at the origin is taken to
be zero, the potential at (2m, 2m) is found to the −20x volts. Find x.
Ans. (5)
B
Sol. Apply VB − VA = −∫A ⃗E⃗ ⋅ ⃗⃗⃗⃗⃗
dr
⃗⃗ = 20î + 30ĵ and ⃗⃗⃗⃗⃗
E dr = dxî + dyĵ
∴ − ∫ ⃗E⃗ ⋅ ⃗⃗⃗⃗⃗
dr = −20x − 30y
Putting limits,
VB − VA = −20(xB − xA ) − 30(yB − yA )
= −20(2 − 0) − 30(2 − 0)
VB − 0 = −100 V ⇒ VB = −100 V
⇒ x=5

APNI KAKSHA 26
FULL TEST JEE MAIN TEST SERIES
PART – 3: CHEMISTRY
• This question paper contains two sections, section A & B.
• Section A contains 20 multiple choice questions (MCQs) with four options (A),(B),(C),(D) out
of which only one option is correct.
• Section B contains 10 Numerical Value Type questions , out of which candidate have to
attempt only 5 questions.

Section-I
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : +𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

61. Which of the following statements is not correct with reference to analysis of Cu+2 and Cd+2 ?
(A) Both can form precipitate in acidic medium by passing H2 S gas
(B) Both form water soluble complex of type [Cu(CN)4 ]−3 , [Cd(CN)4 ]−2 with excess of KCN
(C) Both the [Cu(CN)4 ]−3 and [Cd(CN)4 ]−2 can form precipitate with H2 S
(D) Only [Cd(CN)4 ]−2 forms precipitate with H2 S
Ans. (C)
Sol. a. In acidic medium both Cu2+ and Cd+2 will be precipitated as CuS and CdS.
b. Both Cd+2 and Cu+2 form complex [Cu(CN)4 ]3− and [Cd(CN)4 ]2− with excess of KCN. Only
[Cd(CN)4 ]2− give yellow ppt with H2 S but not [Cu(CN)4 ]3− .
62. Out of following in which pair, electron affinity of 1st element is greater than electron affinity of
2nd ?
(A) F, Cl (B) N, O (C) Si, C (D) O, S
Ans. (C)
Sol. Electron affinity of silicon is higher than carbon because of small size and high electron density
of carbon.
63. The number of electron in cobalt that are present in subshell which have zero radial node are x,
x
the value of 3 is

(A) 4 (B) 5 (C) 3 (D) 2

Ans. (B)

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FULL TEST JEE MAIN TEST SERIES
Sol. Co (Z = 27)1s2 2s 2 2p6 3s 2 3p6 4s2 3d7
No. of spherical nodes for 1s2 2p6 and 3d7 are zero So total electron = 15
64. Major product of following mentioned reaction is

(A) (B)

(C) (D)
Ans. (D)

Sol.

65. For the reaction

A+B ⇌ C+D

The rate of reaction at any instant is written as

Rate = 2.8 × 103 [ A][B] − K[C][D]

If the equilibrium constant for the reaction is 1.87 × 104 then the numerical value of K is
(A) 6.67 (B) 3.33 (C) 1.56
(D) 0.15
Ans. (D)
Sol. Rate = K f [A][B] − K b [C][D]
Kf
= K eq.
Kb

2.8×103
⇒ = 1.87 × 104
K

⇒ K = 0.15

APNI KAKSHA 28
FULL TEST JEE MAIN TEST SERIES
66. What is pH of 0.02M solution of [(CH3 )2 NH2 ]+ Cl− and what type of hydrolysis takes place?

[K b = 6 × 10−4 for (CH3 )2 NH][log 3 = 0.48]

(A) pH = 7.3, Cationic hydrolysis

(B) pH = 4.23, Anionic hydrolysis
(C) pH = 6.10, Anionic hydrolysis
(D) pH = 6.24, Cationic hydrolysis
Ans. (D)
1
Sol. pH = 7 − 2 [pK b + log C]
1
= 7 − 2 [3.22 − 1.7]

= 7 − 0.76
= 6.24
67. All the elements of Group 15 form hydrides of the type EH3. From the following given
statements with respect to EH3, select the incorrect one.
(A) Basicity as well as reducing strength is maximum for NH3
(B) Standard enthalpy of formation is negative only for NH3 while for others it is positive
(C) HEH bond angle follows the order : NH3 > PH3 > AsH3 > SbH3
(D) Boiling point follows the order : PH3 < AsH3 < NH3 < SbH3
Ans. (A)
Sol. Basicity follows the order: NH3 > PH3 > AsH3 > SbH3 ≥ BiH3
Reducing strength follows the order: NH3 < PH3 < AsH3 < SbH3 < BiH3
68. Statement-1 : Equal amount of glucose and sucrose dissolved in 1 kilogram water show
different depression in freezing points.
and
Statement-2 : K f value is different in both cases.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
Ans. (C)
Sol. K f is a property of the solvent. Therefore, it is constant.

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69. 60% of a first order reaction was completed in 60 minute. When was 50% of reaction
completed?
(A) 50 minute
(B) 45.22 minute
(C) 40 minute
(D) 80 minute
Ans. (B)
2.303 ∣A]0
Sol. K= log ]
t [A]t

2.303 100
K= log ( 40 )
60
1
K = 1.52 × 10−2 min−1
0.693 0.693
t1/2 = = 1.52×102 min−1
k

t1/2 ≅ 45.22 minute

70. For the reaction 2 A( g) + 3 B( g) ⇌ 4C(g) the equilibrium constant, K c was found 100 then the
K p is
(A) 100(RT)1
(B) 100(RT)2
(C) 100(RT)−1
(D) 100(RT)−2
Ans. (C)
Sol. K P = K C (RT)Δng
71. One mole of Marshall's acid on hydrolysis forms compound A and B. Compound A on hydrolysis
forms compound B and C. The correct molecular formula of A, B and C respectively are
(A) H2 S2 O7 , H2 SO4 and H2 O2
(B) H2 SO5 , H2 SO3 and SO2
(C) H2 SO5 , H2 SO4 and H2 O2
(D) H2 SO5 , H2 SO4 and H2 SO3
Ans. (C)
Sol.

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72. Match each coordination compound in List-I with an appropriate pair of characteristics from
List-II and select the correct answer using the code given below the lists.
{en = H2 NCH2 CH2 NH2; atomic numbers : Ti = 22, Cr = 24; Co = 27; Pt = 78}.

Code:

(A) A (B) B (C) C (D) D

Ans. (B)
Sol.

73. An organic compound A has only H, C and O. Compound A give red solid on reaction with 2, 4
D.N.P reagent. A react with OH − /Δ to give B as one of product

Then most probable structure of A can be

(A) (B)

(C) (D)
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Ans. (B)
Sol.

74. From the standard potentials shown in the following diagram, calculate the potentials E1∘ and
E2∘ .

(A) 0.52 ∨ ,0.61 V

(B) −0.52 V, 0.61 V
(C) 0.41 V, 0.52 V
(D) −0.61 V, 0.41 V
Ans. (A)
Sol. BrO3− + 4e + 4H + → BrO− + 2H2 O
Δ∘ G1 = −4 F(0.54)
1
BrO− + 1e + 2H + → 2 Br2 + H2 O

Δ∘ G2 = −F(0.45)
1
BrO3− + 5e + 6H + → 2 Br2 + 3H2 O

Δ∘ G3 = −5FE1∘
Δ∘ G3 = Δ∘ G1 + Δ∘ G2
E1∘ = 0.52 V

−5 × F(0.522) − F(1.07) = −6F2∘

E2∘ = 0.61V

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75. Consider the graph for the reaction
A⟶B
(At and A0 are concentration of A at time t and initial)

Select the correct statement.

(A) Rate constant of the reaction is 5 × 10− 3 Ms −1
(B) Half life of reaction is 138.6 s
(C) Rate of reaction at t = 0 is 5 × 10−3 Ms − 1
(D) Rate of reaction does not depend on concentration of reactant (A)
Ans. (B)
Sol. From the graph, order is 1
A 1−0.5
so, k. t = ln ( A0) = = 5 × 10−3 s−1
t 100
0.693
t1/2 = = 138.68sec
k

76. The osmotic pressure of an aqueous solution of sucrose at 303 K is 2.47 atm, the molar volume
of water at this temperature is 18.10 cm3 . Calculate the elevation in boiling point of this.
(ΔHvap = 539cal/gm)
(A) 0.51 K (B) 0.12 K (C) 0.051 K (D) 0.72 K
Ans. (C)
Sol. π = CRT
2.47 = C × 0.082 × 303
2.47
C = 0.082×303 = 9.94 × 10−2 (M)

Volume of solution = volume of solvent [as solution is quit dilute]

1000
Number of moles of water present = 18.1
1000
Amount of water present = × 18 = 994.475gm
18.1
9.94×10−2
m= × 103 = 9.995 × 10−2
994.475

ΔTb = k b × m
RT2b 1.98×(373)2
ΔT = ΔH ×m= × 9.995 × 10−2 = 0.051 K
vap ×1000 539×1000

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77. A tripeptide contains Glycine, Alanine and Valine. On complete hydrolysis of tripeptide, it form
xα-amino acid that has chiral carbon and y a-amino acid that are categorised into essential
amino acid. The value of (x + y) is
(A) 1
(B) 2
(C) 3
(D) 4
Ans. (C)
Sol. Glycine is only optically inactive α–amino acid while valine is essential amino acid
78. The IUPAC name of ferrocence is
(A) bis (μ5 -Cyclopentadienyl) iron(0) (B) bis (μ10 -Cyclopentadienyl) iron(II)
(C) bis (η5 -Cyclopentadienyl) iron(II) (D) bis ( 10 -Cyclopentadienyl) iron(0)
Ans. (C)
Sol.

bis (η5 -Cyclopentadienyl) iron (II)

79. In third period of modern periodic table, the number of valence electrons present in that
element which has positive electron gain enthalpy out of the following is
(A) 8 (B) 6 (C) 4 (D) 5
Ans. (A)
Sol. Ar has positive electron gain enthalpy.
80. Consider the reaction.

The structure of B is

(A) (B) (C)

(D)

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Ans. (B)
Sol.

Section-II
• This Section contain 10 questions (Q.No. 21 to Q.No. 30) whose answer to be filled as
numerical value (Attempt any five)
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : +𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

81. A second order reaction moves as A(g) → B(g) and follows the following type of curve at 300 K

The t1/2 of the reaction (in minutes) is

Ans. (15.00)
Sol. ∵ At 15 minute, PA = PB
∴ Half of A is consumed at 15th minute.
82. An acidic solution of dichromate is electrolyzed for 8 minutes using 2 A current As per the
following equation Cr2 O2− + −
7 + 14H + 6e → 2Cr
3+
+ 7H2 O The amount of Cr 3+ obtained was
0.104 g. The efficiency of the process (in%) is
(Take : F = 96000C, At. mass of chromium = 52) ______.
Ans. (60.00)

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Sol. Cr2 O2− + −
7 + 14H + 6e → 2Cr
3+
+ 7H2 O
I = 2 A, t = 8 min
2×8×60
Q= F
96000
960 1
Moles of Cr2 O2−
7 ions reduced = 96000×6 = 600
1×2
Moles of Cr 3+ ions obtained = 600
2×52 104
Mass of Cr 3+ ions obtained = = 600
600

Mass of Cr 3+
ions actually obtained = 0.104gm
600×0.104×100
Efficiency = = 60%
104

83. In the compound PtCl4 ⋅ 2HCl, the number of moles of AgCl precipitated per mole of the
compound with excess of AgNO3 is zero. Then the primary valency of Pt in the given compound
is _____.
Ans. (04.00)
Sol. Since no AgCl is precipitated. All chloride ions will be inside the coordination sphere.
So, CN = secondary valency = 6 and primary valency = +4 and the compound ≡ H2 [PtCl6 ]
84. If x is the number of d orbital involved in the hybridisation of IF7 and y is the bond order of O2−
2

and then the value of (x + y) is

Ans. (04.00)
Sol. x=3
y=1
85. Consider the following sequence
H2 OH+ red hot NBS/CCI4
Magnesium carbide → A → B → C
fe tube (excess)

The IUPAC name of B is x, y, z - tri methyl benzene and the value of x + y + z = 9.

The number of tri bromo derivatives possible for C is
Ans. (03.00)
Sol.

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86. The molar entropies of HI(g), H(g) and I(g) at 300 K are 206.5, 114.8 and 180.7JK −1 mol− 1
respectively. Using the ΔG∘ given below the bond energy of HI is found as xJ/mol. Find out the
x
value of 5.

HI(g) → H(g) + I(g); ΔG∘ = 273.3 kJ

Ans. (60.00)
Sol. ΔS ∘ = 114.8 + 180.7 − 206.5 = 89 J/K/mol
ΔG∘ = ΔH ∘ − TΔS ∘
300×89
ΔH ∘ = ΔG∘ + TΔS ∘ = 273.3 + 1000

x = 300 kJ/mol

87. Consider the following reaction sequence

If the molar mass of P3 is M, The value of M is

Ans. (60.00)
Sol.

88. Two reactions R1 and R 2 have identical preexponential factors. Activation energy of R1 exceeds
that of R 2 by 10 kJ mol−1 . If k1 and k 2 are rate constants for reactions R1 and R 2 respectively at
300 K, then In (k 2 /k1 ) is equal to (R = 8.314 J mole−1 K −1 ) (Nearest integer)
Ans. (04.00)
Sol. k1 = Ae−E21 /RT
k 2 = Ae−E22 /RT
1
k2
= eRT(E21 −E22 )
k1

k2 E21 −E22 10×103

ln = = 8.314×300 ≈ 4
k1 RT

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89. In a given reaction sequence,

Let number of −COOH group in compound H is x and number of σ (sigma) bonds in compound
I is y.
Then find the value of (x 2 + y 2 ).
Ans. (53.00)
Sol.

Number of −COOH is H is 2, number of σ bonds = 7,

then x = 2 and y = 7, x 2 + y 2 = 4 + 49 = 53

90. An aqueous solution of sodium acetate is subjected to Kolbe's electrolysis to prepare ethane. If
a current of 5 A is passed for 1930 second, then total volume of all gases collected at 0∘ C and
1 atm( F = 96500, molar volume at STP = 22.4 lit)
Ans. (04.48)
Sol. 2CH3 COO− → CH3 − CH3 + 2CO2 + 2e−
2H2 O + 2e− → H2 + 2OH −
q = 1930 × 5
1930×5
F= = 0.1
96500

∴ nCO2 = 0.1
nC2 H6 = 0.05
nH2 = 0.05

APNI KAKSHA 38