GEAR GARD SUPER 80W90, API GL-5 4 - 4 L 000000000000692076 Singapore - English
GEAR GARD SUPER 80W90, API GL-5 4 - 4 L 000000000000692076 Singapore - English
2. HAZARDS IDENTIFICATION
GHS Classification
Skin sensitisation : Category 1
Precautionary statements :
Prevention:
P261 Avoid breathing mist or vapours.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
P391 Collect spillage.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
3. COMPOSITION/INFORMATION ON INGREDIENTS
5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Unsuitable extinguishing : High volume water jet
media
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.
Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
4 / 18
SAFETY DATA SHEET
Appearance : liquid
pH : No data available
Solubility(ies)
Water solubility : No data available
Viscosity
Viscosity, dynamic : No data available
6 / 18
SAFETY DATA SHEET
Acute toxicity
Not classified due to lack of data.
Product:
Acute inhalation toxicity : Acute toxicity estimate: > 20 mg/l
Exposure time: 4 h
Test atmosphere: vapour
Method: Calculation method
Components:
DI-TERT-BUTYL POLYSULFIDE:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Method: OECD Test Guideline 401
Assessment: The substance or mixture has no acute oral
toxicity
Remarks: No mortality observed at this dose.
AMINES, C12-14-TERT-ALKYL:
Acute oral toxicity : LD50 (Rat): 612 mg/kg
Method: OECD Test Guideline 401
Skin corrosion/irritation
Not classified due to lack of data.
Product:
Remarks : May cause skin irritation and/or dermatitis.
Components:
DI-TERT-BUTYL POLYSULFIDE:
Result : Mild skin irritation
AMINES, C12-14-TERT-ALKYL:
Species : Rabbit
Result : Corrosive after 3 minutes to 1 hour of exposure
8 / 18
SAFETY DATA SHEET
Components:
DI-TERT-BUTYL POLYSULFIDE:
Result : Slight, transient irritation
AMINES, C12-14-TERT-ALKYL:
Species : Rabbit
Result : Corrosive
Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
Not classified due to lack of data.
Product:
Remarks : Causes sensitisation.
Components:
DI-TERT-BUTYL POLYSULFIDE:
Test Type : Maximisation Test
Species : Guinea pig
Assessment : The product is a skin sensitiser, sub-category 1B.
Method : OECD Test Guideline 406
AMINES, C12-14-TERT-ALKYL:
Test Type : Buehler Test
Species : Guinea pig
Assessment : The product is a skin sensitiser, sub-category 1A.
9 / 18
SAFETY DATA SHEET
DI-TERT-BUTYL POLYSULFIDE:
Genotoxicity in vitro : Test Type: in vitro assay
Result: Positive results were obtained in some in vitro tests.
AMINES, C12-14-TERT-ALKYL:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Carcinogenicity
Not classified due to lack of data.
10 / 18
SAFETY DATA SHEET
Components:
Reproductive toxicity
Not classified due to lack of data.
STOT - single exposure
Not classified due to lack of data.
Components:
AMINES, C12-14-TERT-ALKYL:
Assessment : May cause respiratory irritation.
Aspiration toxicity
Not classified due to lack of data.
Components:
11 / 18
SAFETY DATA SHEET
Further information
Product:
Remarks : No data available
Ecotoxicity
Components:
DI-TERT-BUTYL POLYSULFIDE:
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.24 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Method: OECD Test Guideline 202
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 2.5 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
12 / 18
SAFETY DATA SHEET
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.98 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Method: OECD Test Guideline 202
Remarks: The toxicological data has been taken from
products of similar composition.
Components:
DI-TERT-BUTYL POLYSULFIDE:
Biodegradability : Result: Not readily biodegradable.
Biodegradation: 13 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
AMINES, C12-14-TERT-ALKYL:
Biodegradability : Result: Not readily biodegradable.
Biodegradation: 22 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Bioaccumulative potential
Components:
DI-TERT-BUTYL POLYSULFIDE:
Partition coefficient: n- : log Pow: 5.6 (20 °C)
octanol/water pH: 7
AMINES, C12-14-TERT-ALKYL:
Partition coefficient: n- : log Pow: 2.9
octanol/water
(Z)-octadec-9-enylamine, C16-18-(even numbered, saturated and unsaturated)-alkylamines:
Partition coefficient: n- : log Pow: estimated 6 - 8
octanol/water
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological : An environmental hazard cannot be excluded in the event of
14 / 18
SAFETY DATA SHEET
Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
International Regulations
UNRTDG
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(DI-TERT-BUTYL POLYSULFIDE)
Class : 9
Packing group : III
Labels : 9
IATA-DGR
UN/ID No. : UN 3082
Proper shipping name : Environmentally hazardous substance, liquid, n.o.s.
(DI-TERT-BUTYL POLYSULFIDE)
Class : 9
Packing group : III
Labels : Miscellaneous Dangerous Goods
Packing instruction (cargo : 964
aircraft)
Packing instruction : 964
(passenger aircraft)
Environmentally hazardous : yes
IMDG-Code
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(DI-TERT-BUTYL POLYSULFIDE, )
Class : 9
Packing group : III
15 / 18
SAFETY DATA SHEET
Labels : 9
EmS Code : F-A, S-F
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
Workplace Safety and Health Act and Workplace Safety and Health (General Provisions)
Regulations: This product is subjected to the SDS, labelling, PEL and other requirements
in the Act/Regulations.
Environmental Protection and Management Act and : Not applicable
Environmental Protection and Management
(Hazardous Substances) Regulations
16 / 18
SAFETY DATA SHEET
Inventories
AIIC (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TECI
(Thailand), TSCA (USA)
AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land
of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from
Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable
Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC -
New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and
Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical
Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC)
No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition
Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG -
Transportation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
17 / 18
SAFETY DATA SHEET
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
SG / EN
18 / 18