Equilibrium

TOPIC WISE TEST (SOLUTION)

Subject : Chemistry Topic : Equilibrium
05_Chemical Equilibriu (Q. No.29) Q.5 (2)
Q.1 (2) For the reaction,
H2(g) + I2(g) 2HI(g) Χn = 1
[ Kp = Kc (RT)Χn =Kc RT
K2 ΧH 1 1
log K =  –  Kp 1.8 ≥ 10,3 atm
1 2.303R  T1 T2  [ Kc < <
RT 0.082 L atm K –1 mol–1 ≥ 700K
50 ΧH  1 1  = 3.13 × 10–5
log =  623 – 721
66 .9 2.303R  
After calculation negative value of ΧH is obtained. Q.6 (4)
A+ B ƒ C + D
Q.2 (3) at t = 0 a a 0 0
ˆˆ† 2C
2A ∗ B ‡ˆˆ ; K=x at t = eq a -x a -x x x
2(a – x) = x
1 ˆˆ†
[ A ∗ B ‡ˆˆ C ; K= x 3x
2 a=
2
1 1
ˆˆ† A ∗
[ C ‡ˆˆ B ; K<
2 x Q.7 (1)
A+B ƒ C+D
Q.3 (3) at t = 0 3n n 0 0
A(g) B(g) + C(g) at t = eq 3n-x n -x x x
n–x=x
At equi. (1,)   ⇑ n = 2x
Total = 1 + 
2 Q.8 (1)
∑  ⌡ 2 CO2 ƒ 2CO + O2
 P
1∗   2 0 0
Kp = 1 ,  2–·8 ·8 ·4
.P
1∗  Q.9 (3)
1
2 Given :- CO(g) + O (g)
2 2
CO2(g)
Kp = P
1, 2
∑1 ⌡
1 P Χng = 1 –  ∗ 1
< 1∗  2 
 2
Kp
1
[ Kp = 2 (Kp + P) Χng = ,
2
[ (3)
as we know
Q.4 (1)
Kp
ˆˆ† NH (g)+H S(g)
NH4 HS(s) ‡ˆˆ Kp = KC ∋RT (Χng ⇑ = (RT)
T)–1/2
3 2 Kc
1 0 0 Q.10 (1)
p p At Q.11 (3)
equilibrium CO2 + C = 2CO
Given, ·5 – x 2x
p + p = 100 atm Total pressure at equilibrium
2p = 100atm ·5 + 2x – x = ·5 + x = ·8
p = 50 atm x = ·3
K p < p NH3 √ p H2s ∋ √6 (2
= 50 × 50 = 250 atm2 k=
·5 ,·3
1
TOPIC WISE TEST : Chemistry

Q.12 (4)
4
2KCN + AgNO ƒ Ζ Ag(CN) 2 ∴ + KNO3 + K + K p2 < P2
-
3
0.1 0.03 0 0
(0.1-0.06) 0 (0.03)
0 (0.03) (0.03)
[ Π K p1 < K p 2 ]

[Ζ Ag(CN)2 ∴ ƒ Ag + +
-
2CN P1 4P2 P1 8
0.03 a 0.04(left from KCN) = ⇑ P <3
(0.03-a) a (0.04 + a)
2 3 2

0.04 ≡ 0.04
Q.17 (2)
∋ 0.04 (
2
≥a N2(g) + 3H2(g) ƒ 2NH3(g)
[ Kc = 4 ≥ 10-19 =
Kp = 1.44 × 10–5
0.03
a = 7.5 ≥ 10-18 From Kp < KC ∋RT (
Χng

Q.13 (2) Χng = np – nR = 2 – 4 = – 2

KP
Q.14 (3) KC <
(RT ) Χng
Water ƒVapour
P ⇐ , more water will be formed & (Boiling 1.44 ≥ 10–5
KC <
point would rise) (0.082 ≥ 773)–2

Q.15 (1) Q.18 (4)

8.5
[NH3 ] < = 1 mole/litre Q.19 (2)
17 ≥ 0.5
PCl5(g) ƒ PCl3(g) + Cl2(g)
Initiallly 2 0 0
Q.16 (3)
At eq. 2–0.8 0.8 0.8
N2O4 ˆˆ† ˆ 2NO2
‡ˆˆ ˆ 1.2 0.8 0.8
t=0 1 0 < < <
2 2 2
t = eq. 1 – 1/3 2 × 1/3 [Π 33% = 1/3]
nT = 2/3 + 2/3 = 4/3
KC <
ΖPr oduct ∴ < 0.8 ≥ 0.8 ≥ 2
2/3 ΖRe ac tan t ∴ 2 2 1.2
x= = 1/2
4/3
0.64
< < 0.266
1/ 2 ≥ 1/ 2 ≥ P12 2.4
Kp1 < Q.20 (3)
1/ 2 ≥ P1
1 ˆˆˆ
†
1 CO ∗ O ‡ˆˆ ˆ CO 2
K p1 < P1 (g) 2 (g)2 (g)
2 Kp = Kc (RT)Χng
N2O4 ˆˆ† ˆ 2NO2 1
‡ˆˆ ˆ Χ ng < –
t=0 1 0 2
t = eq. 1 – 1/2 2 × 1/2 [50% = 1/2]
= 1/2 1 kp
< (RT)–1/2
nT = 3/2 kc
1 2 1 1 2
x= ≥ = & xNO < ≥ 2 < kp 1
2 3 3 2
3 3 <
kc RT
2 2
≥ ≥ P22
K p1 < 3 3 Q.21 (2)
1
≥ P2 K f 2.38 ≥ 10 –4
3 KC < <
K b 8.15 ≥ 10 –5
4 3 4
× = P = 2.92
9 1 3 2

2
 Equilibrium

Q.22 (4) 1 0 0
2SO2 + O2 ƒ 2SO3 1–  
1.5 1 0 Total mole = 1 –  +  + 
⇑ 1+
1.5 , x 1, x / 2 x
2 2 2 ×
KPCl3 (mole fraction) =
1∗ ×
x
= 0.35 P
2  × 
[ (partial pressure) PPCl3 <  
x = 0.70 1∗ × 
1.5 , 0.7 Q.28 (1)
[SO2] ⇑ < 0.4 We know,
2
Kp = Kc (RT)Χn
1, 0.7 / 2 In the reaction,
[O2] ⇑ = 0.325 Χn = 2 – (1 + 3) = – 2
2
[ Kp = (RT)–2 × Kc
(0.35)2
KC = 1
(0.4)2 ≥ 0.325 = Kc
R T2
2

KC = 2.35
Q.29 (1)
Q.23 (2) Highest value of KC means does reactions maximum
Equilibrium constant for the reaction, approaches completion
ˆˆ† C, is
3A+2B ‡ˆˆ
Q.30 (1)

K<
Ζ C∴  2C 0 . 01
2
 0 . 01 
K< ; < ≡ 1 [ K <  2C <   ≥1
Ζ A ∴3 Ζ B∴2 1 , 100  100 
Q.24 (2) < 1 ≥ 10 ,8 .
ˆˆ† 3C(g)+D(s)
2A(g) ‡ˆˆ
Q.31 (2)
For this reaction, Χng = 3 – 2 = 1
For pure water [H ∗ ] < [OH , ] , [ K w < 10 ,12 s
[ Kp = Kc(RT)1
Kp
or K C < Q.32 (4)
RT (1) HCI. NaOH
No. of mili eq. = × 100 = 10 × 100 = 10
Q.25 (4)
So solution is Neutral
4 2 ·P
KP = < const. (2) × 55 = 5.5 × 45 = 4.5
1 , 2 [H+] = = 10–2 M,pH = 2
4 ≥ (0.15) 2 ≥ 4 4 ≥ (0.25) 2 ≥ P (3) × 10 = 1 × 90 = 9Basic
or, < (4) × 75 = 15 × 25 = 5
1 , (0.15) 2 1 , (0.25) 2
[H+] = 0.1 M, pH = 1
P = 1.38 atm Q.33 (4)
Q.26 (3)
NaClO4 is a salt of strong acid HClO 4 . So it is a strong
ˆˆ† C
A + B ‡ˆˆ acid salt.

K<
Ζ C∴ Q.34 (3)
Salt of weak acid & weak base
Ζ A ∴Ζ B∴ [H+] =
mol L,1 pH = [pK + pK – pK ]
∋ (
,1 w a b
< < mol L,1 = mol–1 L = [14 + 4.8 – 4.78]
mol L,1 ≥ mol L,1
pH = 7.01

Q.27 (1) Q.35 (4)

PCl5 dissociation a closed container Calculate the solubility ‘s’ for each option,
PCl5 (g) PCl3 (g) + Cl2 (g) Higher the value of ‘s’ Higher the solubility.
3
TOPIC WISE TEST : Chemistry

Q.36 (2) 1 1
[Salt]= 0.1 M, [Acid]= 0.1 M pH = 7 + pKa – pKb
2 2
[Salt]
K a < 1 .8 ≥ 10 ,5 ; pH < ,logK a ∗ log [Acid] 1 1
pH = 7 + ×5.76 – × 5.25
2 2
0 .1
< ,log1 . 8 ≥ 10 , 5 ∗ log < ,log 1 .8 ≥ 10 ,5
0 .1 1
pH = 7 + × 0.51
pH < 4 . 7 . 2
pH = 7.255
Q.37 (1)
M of HCl = 25 × 0.5 = 12.5 Q.45 (1)
eq
M of NaOH = 10 × 0.5 = 5 Ag2CrO4ƒ 2Ag+ + CrO 4–2
eq
M of HCl remaining 12.5 – 5 = 7.5
eq 2S S
[H+] = = 0.15
Ksp = [2S]2[S]
pH = – log 0.15
= 0.8239 K sp
1.1≥ 10 –12
S3 < <
4 4
Q.38 (3) S = 6.43 × 10–5
H 2 PO4, ˆˆ† H ∗ ∗ HPO 2 , action.
Conjugate acid
‡ˆˆ 4 Q.46 (3)
For conjugate acid-base
Q.39 (1) pka + pkb = 14
pka = 14 – 9.26 = 4.74
[Salt] 10 ≥ 1
pH < pK a ∗ log < , log 2 ≥ 10 ,5 ∗ log <4.
[Acid] 50 ≥ 2 1 1
pH = pk a – logc
2 2
Q.40 (2)
4.74 log10 –3
pH = –
Alkaline, CH 3 COONa ∗ H 2 O ˆˆ†
‡ˆˆ 2 2

CH 3 COOH ∗ NaOH 3log10

Strong base
< 2.37 ∗ < 3.87
Weak acid 2
pOH = 14 – pH = 14 – 3.87 = 10.13
Q.41 (4)
A X 2A3+ + 3X2– Q.47 (2)
2 3
2y 3y
K = (2y)2 (3y)3
sp
∋K ( Mg(OH)
sp 2 = 10–12
K = 108y5 Mg Cl2 = 0.01 M
sp
For a precipitating form
Q.42 (2) Kionic Product > Ksolubility Product
C = 0.005 M At limiting pH consider that kip = ksp
pH = 5 Ksp = [Mg+2] [OH–]2
[H+] = 10–5 10–12 = 0.01 [OH–]2
And [H+] = c [from ostwald dilution law] [OH–]2 = 10–10 ,
[OH–] = 10–5
H∗  10 –5
<  < < 0.2 ≥ 10 –2 POH = – log10 (10–5)
C 0.005 POH = 5
PH = 14 - 5 = 9
Q.43 (4) limiting pH = 9
K w increases with increase in temperature
Q.48 (4)
Q.44 (1) Q.49 (1)
Q.50 (3)