FINAL JEE–MAIN EXAMINATION – APRIL, 2024

(Held On Saturday 06th April, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A 5 5 2
BD  ˆi  ˆj  kˆ
3 3 3
 3 1
x sin   , x  0
1. If f(x) =  x , then AC  ˆi  ˆj  2kˆ
 0 , x0

2  /4
 2  24 –  cos2 xsin 2 x
(1) f ''(0)  1 (2) f ''   
 2
3.  dx is equal to
cos3 x  sin 3 x 
2
0
2
 2  12 –  (1) 1/12 (2) 1/9
(3) f ''    (4) f ''(0)  0
 2
(3) 1/6 (4) 1/3
Ans. (2) Ans. (3)
1 1 Sol. Divide Nr & Dr by cosx
Sol. f'(x) = 3x 2 sin    x cos  
x x  /4
tan 2 xsec2 xdx
1  dx
1  tan x 
2
3
sin   0
1 1 1 x
f "(x)  6xsin    3cos    cos   
x x x x Let 1 + tan3x = t
2
 2  12  24   tan2x sec2x dx =
dt
f "    
  2 2 3
2
1 dt 1
3 1 t 2 6

5 7 1
2. If A(3,1,–1), B  , ,  , C(2,2,1) and
3 3 3
 10 2 –1  4. The mean and standard deviation of 20 observations
D  , ,  are the vertices of a quadrilateral
 3 3 3  are found to be 10 and 2, respectively. On
ABCD, then its area is respectively, it was found that an observation by
4 2 5 2 mistake was taken 8 instead of 12. The correct
(1) (2) standard deviation is
3 3
(1) 3.86 (2) 1.8
2 2
(3) 2 2 (4)
3 (3) 3.96 (4) 1.94
Ans. (1) Ans. (3)
D C Sol. Mean (x)  10
Sol. x i
  10
A B 20

1 xi = 10×20 = 200

Area = BD  AC
2 If 8 is replaced by 12, then xi = 200 – 8 + 12 = 204
 x Let g(x) = x2 – 4x + 9
 Correct mean (x)  i
20 D<0
204 g(x) > 0 for x  R
  10.2
20
 Standard deviation = 2
x
 Variance = (S.D.)2 = 22 = 4
f( 5)  0
 x 
2    
x 2i f(3)  0
   i   4
20  20  So, f(x) is many-one.
x 2i again,
 10   4
2

20 yx2 – 4xy + 9y = x2 + 2x – 15
x 2i x2 (y – 1) – 2x(2y + 1) + (9y + 15) = 0
  104
20 for x  R  D  0
 xi2 = 2080 D = 4(2y + 1)2 – 4(y –1) (9y + 15) 0
Now, replaced '8' observations by '12' 5y2 + 2y + 16  0
Then, x2i  2080  82  122  2160 (5y – 8) (y + 2)  0
 Variance of removing observations   
2 –2 8/5
x 2i  x i 
  
20  20 
 8
y   –2,  range
2160  5
 10.2  
2

20 Note : If function is defined from f : R  R then
 108 – 104.04 only correct answer is option (3)
 3.96 Bonus
Correct standard deviation
= 3.96 6. Let A = {n [100, 700] N : n is neither a
multiple of 3 nor a multiple of 4}. Then the
x 2  2x – 15 number of elements in A is
5. The function f(x)  , xR is
x 2 – 4x  9 (1) 300 (2) 280
(1) both one-one and onto. (3) 310 (4) 290
(2) onto but not one-one. Ans. (1)
(3) neither one-one nor onto. Sol. n(3)  multiple of 3
(4) one-one but not onto. 102, 105, 108, ..... , 699
NTA Ans. (3) Tn= 699 = 102 + (n – 1)(3)

Ans. Bonus n = 200

n(3) = 200
(x  5)(x  3)
Sol. f(x)   n(4)  multiple of 4
x2  4x  9
 100, 104, 108, ...., 700
Tn = 700 = 100 + (n – 1) (4) 8. For ,   R and a natural number n, let
n = 151
n(4) = 151 n2
r 1 
2
n(34)  multiple of 3 & 4 both
108, 120, 132, ....., 696 Ar  2r 2 n 2 –  . Then 2A10 – A8 is
Tn = 696 = 108 + (n – 1)(12) n(3n – 1)
3r – 2 3
n = 50 2
n(3 4) = 50 (1) 4 + 2 (2) 2 + 4
n(3 4) = n(3) + n(4) – n(3 4) (3) 2n (4) 0
= 200 + 151 – 50
Ans. (1)
= 301
n  3  4  = Total – n(3 4) = neither a multiple r 1
n2

of 3 nor a multiple of 4 2
= 601 – 301 = 300 Sol. Ar  2r 2 n2 – 
n(3n – 1)
3r – 2 3
7. Let C be the circle of minimum area touching the 2
parabola y = 6 – x2 and the lines y = 3 x . Then,
which one of the following points lies on the circle
C? n2 n2
20 1  8 1 
(1) (2, 4) (2) (1, 2) 2 2
(3) (2, 2) (4) (1, 1) 2A10 – A8  40 2 n 2 –  – 16 2 n2 – 
Ans. (1) n(3n – 1) n  3n – 1
56 3 22 3
Sol. 2 2

(0,6) n2
12 1 
(0,6–r) 2
 24 2 n2 – 
n  3n – 1
34 3
2

n2
0 1 
2
Equation of circle
 0 2 n2 – 
x2 + (y – (6 – r))2 = r2
n(3n – 1)
touches 3xy 0 –2 3
2
p=r
 – 2  (n 2 – ) –  n 2  2  
0  (6  r)
r
2  – 2(– – 2)  4  2
|r – 6| = 2r
r=2
 Circle x2 + (y – 4)2 = 4
(2, 4) Satisfies this equation
9. The shortest distance between the lines Sol.
x – 3 y  15 z – 9 x 1 y –1 z – 9 A B
  and   is
2 –7 5 2 1 –3
Manufactured 60% 40%
(1) 6 3 (2) 4 3
Standard quality 80% 90%
(3) 5 3 (4) 8 3
P(Manufactured at B / found standard quality) = ?
Ans. (2)
A : Found S.Q
x – 3 y  15 z – 9 x 1 y –1 z – 9
Sol.   &   B : Manufacture B
2 –7 5 2 1 –3
C : Manufacture A
 a2 .a1  .  b1 .b2  40
S.D = P(E1) =
b1  b2 100
a1 = 3, –15, 9 b1 = 2, –7, 5 60
P(E2) =
a2 = –1, 1, 9 b2 = 2, 1, –3 100
a2 – a1 = –4, 16, 0 90
P(A/E1) =
ˆi ˆj 100
kˆ
80
b1  b2  2 7 5  ˆi(16)  ˆj(16)  k(16)
ˆ P(A/E2) =
100
2 1 3
P  A / E1  P  E1  3
P(E1/A) = 
16(iˆ  ˆj  k)
ˆ P  A / E1  P  E1   P  A / E 2  P  E 2  7

b1  b2  16 3 126 P = 54

  a2  a1  .  b1  b2   16  4  16   (16)(12)
11. Let, ,  be the distinct roots of the equation
(16)(12)
S.D. =
16 3
4 3 x2 –  t 2 – 5t  6  x  1  0, t  R and an = n + n.
a 2023  a 2025
Then the minimum value of is
a 2024
10. A company has two plants A and B to manufacture
motorcycles. 60% motorcycles are manufactured (1) 1/4 (2) –1/2
at plant A and the remaining are manufactured at (3) –1/4 (4) 1/2
plant B. 80% of the motorcycles manufactured at Ans. (3)
plant A are rated of the standard quality, while Sol. by newton's theorem
90% of the motorcycles manufactured at plant B an+2 – (t2 – 5t + 6)an+1 + an = 0
are rated of the standard quality. A motorcycle
 a2025 + a2023 = (t2 – 5t + 6) a2024
picked up randomly from the total production is
a 2025  a 2023
found to be of the standard quality. If p is the   t 2  5t  6
a 2024
probability that it was manufactured at plant B,
2
then 126p is  5 1
t 2  5t  6   t   
(1) 54 (2) 64  2 4
(3) 66 (4) 56 1
  minimum value = 
Ans. (1) 4
12. Let the relations R1 and R2 on the set m 0
X = {1, 2, 3, ..., 20} be given by 9
 13   4m
R1 = {(x, y) : 2x – 3y = 2} and m

R2 = {(x, y) : –5x + 4y = 0}. If M and N be the 9

4m 
minimum number of elements required to be added m  36  4m  9  12
2 m
in R1 and R2, respectively, in order to make the
 OA + OB  25
relations symmetric, then M + N equals
(1) 8 (2) 16
14. The interval in which the function f(x) = xx, x > 0,
(3) 12 (4) 10
is strictly increasing is
Ans. (4)
 1 1 
(1)  0,  (2)  2 ,1 
Sol. x = {1, 2, 3, .......20}  e e 
R1 = {(x, y) : 2x – 3y = 2}
1 
(3) (0, ) (4)  ,  
R2 = {(x, y) : –5x + 4y = 0} e 
R1 = {(4, 2), (7, 4), (10, 6), (13, 8), (16, 10), (19, 12)} Ans. (4)
R2 = {(4, 5), (8, 10), (12, 15), (16, 20)} Sol. f(x) = xx ; x > 0
in R1 6 element needed ny = xnx
in R2 4 element needed
1 dy x
So, total 6+4 = 10 element   nx
y dx x

dy
13. Let a variable line of slope m > 0 passing through  x x (1  nx)
dx
the point (4, –9) intersect the coordinate axes at the
for strictly increasing
points A and B. the minimum value of the sum of
the distances of A and B from the origin is dy
 0 xx (1 + nx)  0
dx
(1) 25 (2) 30
(3) 15 (4) 10 nx  –1
Ans. (1)
x  e–1
Sol. equation of line is
1
y + 9 = m (x – 4) x
e
9  4m 
 A   ,0 
 m  1 
x , 
e 
B = (0, – 9 – 4m)
9  4m
 OA + OB =  9  4m
m
15. A circle in inscribed in an equilateral triangle of 17. Let y = y(x) be the solution of the differential
side of length 12. If the area and perimeter of any dy
equation 1  x 2 
–1
 y  e tan x , y(1) = 0. Then
square inscribed in this circle are m and n, dx
respectively, then m + n2 is equal to y(0) is
(1) 396 (2) 408 1   /2  1
(1) e –1 (2) 1 – e  /2 
(3) 312 (4) 414 4 2
Ans. (2) 1 1   /2 
(3) 1 – e  /2  (4) e –1
4 2
 3a 2 a 12
Sol.  r = =   2 3
s 3a 2 3 2 3 Ans. (2)
4.
2 1
dy y e tan x
Sol.  
dx 1  x 2 1  x 2
1
A  1 x2 dx 1
I.F. = e  e tan x

1  e tan 1 x  1
y.e tan x
    e tan x .dx
 1  x2 
A= r 2 = 2 6
dx
2 Let tan–1x = z   dz
 Area = m = A = 24 1  x2
Perimeter = n = 4A = 8 6
e 2z
 y.ez =  e 2z dz  C
 m + n2 = 24 + 384 2
= 408 1
tan 1 x e 2 tan x
y.e  C
2
16. The number of triangles whose vertices are at the
1
vertices of a regular octagon but none of whose e tan x
C
y 
2 tan 1 x
sides is a side of the octagon is e
(1) 24 (2) 56 e  /4 C e  /2
 y(1) = 0  0    /4  C 
(3) 16 (4) 48 2 e 2
Ans. (3) 1
e tan x
e  /2
Sol.  no. of triangles having no side common with a n  y  1
2 2e tan x

n
C1 . n 4 C2
sided polygon =  1  e  /2
3 y 0 
8
2
C1 . 4 C 2
  16
3
18. Let y = y(x) be the solution of the differential Sol. y = 3x, 2y = 27 – 3x & y = 3x – x x
dy 3
equation  2x loge x   2y  log e x, x > 0 and y
dx x
y(e–1) = 0. Then, y(e) is equal to 2y = 27 – 3x y = 3x
(3,9)
3 2
(1) – (2) –
2e 3e
(4,4)
x
3 2 (0,0) x=4 (9,0)
(3) – (4) –
e e
Ans. (3) 3 9
 27 – 3x  
A   3x –  3x – x x  dx    – 3x – x x   dx
dy y 3  2 
Sol.   2 0 3

dx x n x 2x 3 9
27 9x
1
A   x 3/2 dx   –  x 3/2 dx
 x n x dx 0 3
2 2
 I.F. = e = en(n(x)) = nx
3 9 9
 2x 5/2  27 9 9  x 2   2x 5/2 
3 nx A    x 3 –     
 ynx =  2x 2
dx  5 0 2 2  2 3  5 3
2  5/2  27 9 2
A 3  (6) –  72    95/2 – 35/2 
3 n x 2  3  5 2 4 5

2  x dx    . x 2 dx  dx
 2x  2  5/2  2 2
A 3  81 – 162   35 –  35/2
3 n x 1 3  1 5 5 5
         dx
2  x 2x  x  486 81
A – 81 
3 nx 3 5 5
y.nx =  C 10A = 162
2x 2x
Ans. = 4
 y(e–1) = 0

3e 3e
 0 (–1) =  C  C = 0
2 2 f : (– , ) – {0}  R
20. Let be a differentiable
3 nx 3
y=  1
2x 2x function such that f '(1)  lim a 2 f   .
a  a
3 3 3
y e  – 
2e 2e e a(a  1) –1  1  2
Then lim tan    a – 2 loge a is equal
a  2 a

19. Let the area of the region enclosed by the curves to

y = 3x, 2y = 27 – 3x and y  3x – x x be A. Then 3  3 

(1)  (2) 
10 A is equal to 2 4 8 4

(1) 184 (2) 154 5  3 

(3)  (4) 
(3) 172 (4) 162 2 8 4 8
Ans. (4) Ans. (3)
Sol. f : (–,) – {0}  R  ( – 6) – 1( – 6) + 2(2 – 2) = 0

1   – 6 –  + 6 + 4 – 4 = 0
f  (1) = lim a 2 f  
a  a  6 + 4 +  = 55

a  a  1 1  1  2
lim tan    a  2 n  a 
a  2 a 22. Let a conic C pass through the point (4, –2) and

 1  P(x, y), x  3, be any point on C. Let the slope of

 1  a  
lim a 2    tan 1  1   1  2 n  a   the line touching the conic C only at a single point
 
a   2 a a2 
P be half the slope of the line joining the points
1 P and (3, –5). If the focal distance of the point
f(x) = (1 + x) tan–1(x) + 1 – 2x2 n(x)
2
(7, 1) on C is d, then 12d equals_______.
1  1 x  Ans. (75)
f  (x) =  2
 tan 1  x   4x n  x    2x
2 1 x 
Sol. P(x, y) & x  3
1  dy 1  y  5 
f  1   1    2 Slope of line at P(x, y) will be 
2 4 dx 2  x  3 
5  dy 1
f  1   2  dx
2 8 (y  5) (x  3)
Ans. (3)  2n(y + 5) = n(x – 3) + C

Passes through (4, –2)

SECTION-B  2n(3) = n(1) + C

21. Let  = 45 ; ,  R. If x(, 1, 2) + y(1, , 2)  C = 2n(3)

+ z(2, 3, ) = (0, 0, 0) for some x, y, z  R, xyz 
 2n(y + 5) = n(x – 3) + 2n(3)
0, then 6 + 4 +  is equal to_______
  y  5 
 2 n     n(x  3)
Ans. (55)   3 
2
Sol.  = 45,   R  y5
   (x  3)
x(,1,2) + y(1,,2) + z(2,3,) = (0,0,0)  3 
x, y, z  R, xyz  0  (y + 5)2 = 9(x – 3)
x + y + 2z = 0 
x + y + 3z = 0 Parabola
2x + 2y + z = 0 4a = 9
xyz  0  non-trivial 9
a
4
 1 2
1  3 0
2 2 
 (7,11)
d
24. Let x1, x2, x3, x4 be the solution of the equation
(3,–5)
4x4 + 8x3 – 17x2 – 12x + 9 = 0 and

2
 4  x12  4  x22   4  x32   4  x24   125
16
m.
7
d     62
4 Then the value of m is ________.
625 Ans. (221)
d
4 Sol. 4x4 + 8x3 – 17x2 – 12x + 9
25
d = 4(x – x1) (x – x2) (x – x3) (x – x4)
4
12d = 75 Put x = 2i & –2i
64 – 64i + 68 – 24i + 9 = (2i – x1) (2i – x2) (2i – x3)
(2i – x4)
 1 – x  dx , k  N . Then the value of
1 7 k

23. Let rk  10 = 141 – 88i ......(1)

7 k 1
0 1 – x  dx 64 + 64i + 68 + 24i + 9 = 4(–2i – x1) (–2i – x2) (–2i
10
1 – x3) (–2i – x4)
 7r – 1
is equal to _______.
k 1 k
= 141 + 88i .......(2)
Ans. (65) 125 1412  882
m
16 16
Sol. I K   1.(1  x 7 )K dx
m = 221
1
1
I K  (1  x 7 )K x  7K  (1  x 7 ) K 1 x 6 .xdx
0
0 25. Let L1, L2 be the lines passing through the point
1 P(0, 1) and touching the parabola
I K  7K  (1  x 7 )K 1 ((1  x 7 )  1)dx
0 9x2 + 12x + 18y – 14 = 0. Let Q and R be the
IK = –7K IK + 7K IK–1 points on the lines L1 and L2 such that the PQR
K 7K  8 is an isosceles triangle with base QR. If the slopes
 
I K 1 7K  7
of the lines QR are m1 and m2. then 16  m 12  m 22 
7K  8
rK  is equal to _______.
7K  7
Ans. (68)
1
rK  1 
7(K  1) Sol. 9x2 + 12x + 4 = – 18(y – 1)
1 (3x + 2)2 = –18(y – 1)
 7(rK  1) 
K 1  2
2

 x    2(y  1)
10
 3
 (K  1)  11(6)  1  65
K 1
 
 – cot
Q P(0,1) 2
–1 –1
m1  m2  2
2 –1 / 2
1 
16  m 12  m 22   16   4 
4 
R = 4 + 64 = 68

26. If the second, third and fourth terms in the

(0, 1)
10
y = mx + 1 expansion of (x + y)n are 135, 30 and ,
3
2
 2
 x    2(y  1) respectively, then 6  n 3  x 2  y  is equal to
 3
(3x + 2)2 = –18mx _____.

9x2 + (12 + 18m)x + 4 = 0 Ans. (806)

2
4(6 + 9m) = 4(36) Sol. n
C1x n–1y  135 ....(i)
6 + 9m = 6, – 6 n
C2 x n–2 y2  30 ....(ii)
4
m = 0,
3 n 10
C3 x n –3 y 3  ....(iii)
3
Q i
P
By
 ii 

n
C1 x 9
n
 .....(iv)
R C2 y 2
 ii 
By
 iii 
n
4 C2 x
tan    n
9 .....(v)
3 C3 y
  iv 
2 tan By
2  4 v
 3
1  tan 2 n
C1 nC3 1
2 
n n
C2 C2 2
    
 tan – 2  2 tan  1   0
 2  2  2n 2  n – 1 n – 2  n  n – 1 n(n – 1)

 –1 6 2 2
tan  2,
2 2 4n – 8 = 3n – 3
   n5
m QR  tan  90  
 2
put in (v)
 x Tr = 2.(6r – 3r)
9
y

S n  2 6 r  3r 
x = 9y
 6.(6 n  1) 3.(3n  1) 
put in (i) Sn  2.   
 5 2 
5 x
C1x 4    135
9  12(6 n  1)  15(3n  1) 
Sn  2  
x5 = 27 × 9  10 
1 3
 x = 3, y Sn   4.6 4  5.3n  1
3 5
6  n3  x2  y   n2 – 12n + 39 = 3
n2 – 12n + 36 = 0
 1
 6  125  9   n=6
 3
= 806 
28. For n  N, if cot–13 + cot–14 + cot–15 + cot1 n  ,
4
then n is equal to ________.
27. Let the first term of a series be T1 = 6 and its rth
term Tr = 3 Tr–1 + 6r, r = 2, 3, ....., n. If the sum of Ans. (47)

1 2 
the first n terms of this series is n – 12n  39  Sol. cot–13 + cot–14 + cot–15 + cot1 n 
4
5
1 1 1 1 
 4.6n – 5.3n  1 . Then n is equal to ______. tan 1  tan 1  tan 1  tan 1 
3 4 5 n 4
Ans. (6)  46  1 
r
tan 1    tan 1 
Sol. Tr = 3Tr–1 + 6 , r = 2, 3, 4, … n  48  n 4
T2 = 3.T1 + 62  23  1 
2 tan 1    tan 1 
T2 = 3.6 + 6 …(1)  24  n 4
3
T3 = 3T2 + 6 1 23
3 tan 1  tan 1 1  tan 1
T3 = 3T2 + 6 n 24
T3 = 3(3.6 + 62) + 63  23 
2
T3 = 3 .6 + 3.6 + 6 2 3
…(2) 1 1 1
 1  24 
tan  tan  
Tr = 3 .6 + 3 .6 + … + 6r
r–1 r–2 2 n  1  23 
 24 
r 1
 6  6 2 6 
r 1
Tr  3  6 1      ...      1 
 3  3   3   1  
tan 1  tan 1  24 
Tr = 3r–1.6(1 + 2 + 22 + … + 2r–1)
n  47 
 24 
(1  2 r )
Tr  6  3r 11. 1 1
(1) tan 1  tan 1
n 47
Tr = 6.3r–1.(2r – 1) n = 47
r
63
Tr  .(2 r  1)
3
29. Let P be the point (10, –2, –1) and Q be the foot of
the perpendicular drawn from the point R(1, 7, 6)
 
13a  16b  3c  a  ˆi  8jˆ  13kˆ 
on the line passing through the points (2, –5, 11)    
13a  b  16b2  3b  c  a  ˆi  8jˆ  13kˆ  b
and (–6, 7, –5). Then the length of the line segment
PQ is equal to ________. 2 3 4
Ans. (13)   13 26   16(50)  3b  c  1 8 13
3 4 5
Sol.
 462  3b  c  396
P(10,–2,–1)
Q
 b  c  22

(–6, 7,–5) Hence 24 – b  c  46

(2,–5,11) R(1,7,6)

x6 y7 z5

Line :  
8 12 16
x6 y7 z5
  
2 3 4
Q(2 – 6, 7 – 3, 4 – 5)
QR  2  7, 3,4  11

QR · dr’s of line = 0
4 – 14 + 9 + 16 – 44 = 0
29 = 58   = 2
Q(–2, 1, 3)
PQ  144  9  16  169  13

30. Let a  2iˆ – 3jˆ  4k,

ˆ b  3iˆ  4ˆj – 5k,
ˆ and a vector

c be such that a   b  c   b  c  ˆi  8jˆ  13kˆ .

If a  c  13 , then (24 – b  c) is equal to ______.

Ans. (46)

Sol. a  b  a  c  b  c  (1,8,13)

 
a  a  b  a  a  c   a  b  c  

 a  ˆi  8jˆ  13kˆ 
 a  b a  a b  a  c  a  a c  a  c  b  a  b  c  a   ˆi  8jˆ  13kˆ 
2 2

 26a  29b  13a  29c  13b  26c  a  ˆi  8jˆ  13kˆ  

 PHYSICS TEST PAPER WITH SOLUTION
SECTION-A 33. The ratio of the shortest wavelength of Balmer
31. To find the spring constant (k) of a spring series to the shortest wavelength of Lyman series
experimentally, a student commits 2% positive
for hydrogen atom is :
error in the measurement of time and 1% negative
(1) 4 : 1 (2) 1 : 2
error in measurement of mass. The percentage
error in determining value of k is : (3) 1 : 4 (4) 2 : 1
(1) 3% (2) 1% Ans. (1)
(3) 4% (4) 5%
n=
Ans. (4)
m Sol
Sol. T  2 Balmer
k n=2
Lyman n=1
m
T2 
k
1  1 1 
2T m k  Rz2  2  2 
% % % 
T m k  n1 n 2 
k m 2 T 1 1
% % %  Rz 2  2 
k m T L 1 
k 1  1 
%  (1)%  2(2)%  | 5% |  5%  Rz 2  2 
k B 2 
32. A bullet of mass 50 g is fired with a speed 100 m/s
B
on a plywood and emerges with 40 m/s. The  4 :1
L
percentage loss of kinetic energy is :
(1) 32% (2) 44% 34. To project a body of mass m from earth's surface
(3) 16% (4) 84% to infinity, the required kinetic energy is (assume,
Ans. (4) the radius of earth is RE, g = acceleration due to
1 gravity on the surface of earth) :
Sol. K i  m(100)2
2
(1) 2mgRE (2) mgRE
1
K f  m(40)2 1
2 (3) mgRE (4) 4mgRE
| Kf  Ki | 2
%loss  × 100
Ki Ans. (2)

1 1 1 2 GMm
m(40)2  m(100) 2 Sol. mve 
2 2 2 RE
=  100
1 2
m(100) GM
2 g
R 2E
|1600  100  100 |
= = 84%
100 K  mgR E
35. Electromagnetic waves travel in a medium with Sol. MSR = 1mm, CSR = 42, pitch = 1 mm
8 –1
speed of 1.5 × 10 ms . The relative permeability pitch  1 
LC    0.01mm
of the medium is 2.0. The relative permittivity will No. of CSD  100 
be : Diameter = MSR + LC × CSD
(1) 5 (2) 1 Diameter = 1 + (0.01) × 42 mm
(3) 4 (4) 2 x
Diameter = 1.42 mm =
Ans. (4) 50
x = 71
1
m  m v2 38.  is the uniform surface charge density of a thin
Sol.  spherical shell of radius R. The electric field at any
0  0 1
c2 point on the surface of the spherical shell is :
(1) /0R (2) /20
c2
r  r  (3) /0 (4) /40
v2
Ans. (3)
(3  108 )2
r  2  Gaussin Surface
(1.5  108 )2 
 E
r  2  4 E=0
Sol. dA
r  2
36. Which of the following phenomena does not
explain by wave nature of light.
(A) reflection (B) diffraction
q in
(C) photoelectric effect (D) interference By Gauss law  E ·dA 
0
(E) polarization
  dA
Choose the most appropriate answer from the EdA 
0
options given below :

(1) E only (2) C only E
0
(3) B, D only (4) A, C only
39. The value of unknown resistance (x) for which the
Ans. (2)
potential difference between B and D will be zero
Sol. (Theory)
in the arrangement shown, is :
Photoelectric effect prove particle nature of light. B
24 1
37. While measuring diameter of wire using screw
gauge the following readings were noted. Main 12
A 12 1 C
scale reading is 1 mm and circular scale reading x
is equal to 42 divisions. Pitch of screw gauge is 12
0.5
1 mm and it has 100 divisions on circular scale. The 12
D
x
diameter of the wire is mm . The value of x is :
50 14.5V
(1) 142 (2) 71 (1) 3  (2) 9 
(3) 42 (4) 21 (3) 6  (4) 42 
Ans. (2) Ans. (3)
 B B
24 1 Sol. [ ]  [r  F]  [ML2 T 2 ]
0.5
12
A 12 1 C A C
[F]  [qVB]
x
Sol. 12   F   MLT 2 
0.5 0.5  B    1 
 [MA 1T 2 ]
12  qV   ATLT 
D D

14.5V 14.5V [M] = [I × A] = [AL2]

In case of balanced Wheatstone Bridge  0 Idlsin 
B
VAB VBC 12 0.5 4 r 2
  
VAD VCD 6  x 0.5  Br 2   MT 2 A 1  L2 
x= 6
 []     
 Idl   AL 
40. The specific heat at constant pressure of a real gas
obeying PV2 = RT equation is :  [MLT 2 A2 ]
R 42. Given below are two statements :
(1) CV  R (2)  C V
3
Statement I : In an LCR series circuit, current is
R
(3) R (4) C V  maximum at resonance.
2V
Ans. (4) Statement II : Current in a purely resistive circuit
Sol. dQ = du + dW can never be less than that in a series LCR circuit
CdT = CVdT + PdV …..(1)
when connected to same voltage source.
 PV2 = RT
P = constant In the light of the above statements, choose the
P(2VdV) = RdT correct from the options given below :
RdT
PdV = (1) Statement I is true but Statement II is false
2V
(2) Statement I is false but Statement II is true
Put in equation (1)
R (3) Both Statement I and Statement II are true
C  CV 
2V (4) Both Statement I and Statement II are false
41. Match List I with List II
Ans. (3)
LIST I LIST II
Sol. Statement-I
A. Torque I. [M1 L1T 2 A 2 ]
B. Magnetic field II. Vm
[L2 A1 ] Im  at resonance XL = XC
R 2  (X L  X C )2
C. Magnetic moment III. [M1T 2 A 1 ]
D. Permeability of IV. [M1L2 T 2 ] Vm
Thus, I m 
free space R
Choose the correct answer from the options given Impendence is minimum therefore I is
below :
maximum at resonance.
(1) A-I, B-III, C-II, D-IV
(2) A-IV, B-III, C-II, D-I Statement-II
(3) A-III, B-I, C-II, D-IV V
(4) A-IV, B-II, C-III, D-I I    in purely resistive circuit.
R
Ans. (2)
43. The correct truth table for the following logic 45. A light string passing over a smooth light
circuit is : pulley connects two blocks of masses m1 and m2
(where m2 > m1). If the acceleration of the system
A Y g m1
is , then the ratio of the masses is :
B 2 m2
Options : 2 1 1 5
(1) (2)
A B Y A B Y 2 1 5 1
0 0 0 0 0 1 1 5 3 1
(1) 0 1 1 (2) 0 1 1 (3) (4)
2 1 2 1
1 0 0 1 0 0
Ans. (1)
1 1 1 1 1 1
 M  M1 
Sol. a  2 g
A B Y A B Y  M1  M 2 
0 0 1 0 0 0
g  M  M1 
(3) 0 1 1 (4) 0 1 0  2 g
2  M1  M 2 
1 0 0 1 0 0
1 1 0 1 1 1  M1  M2   2M 2  2M1 a M1 M2
a

Ans. (2) M1  2  1 
 
M2  2  1 
Sol. NOT
A Y m
B 46. Four particles A, B, C, D of mass , m, 2m, 4m,
OR 2
AND
have same momentum, respectively. The particle
44. A sample contains mixture of helium and oxygen
with maximum kinetic energy is :
gas. The ratio of root mean square speed of helium
(1) D (2) C
and oxygen in the sample, is :
(3) A (4) B
1 2 2 Ans. (3)
(1) (2)
32 1
p2
1 1 Sol. KE 
(3) (4) 2m
4 2 2 Same momentum, so less mass means more KE.
Ans. (2) m
So will have max. KE.
3RT 2
Sol. Vrms  47. A train starting from rest first accelerates
Mw
uniformly up to a speed of 80 km/h for time t, then
VO2 Mw,He it moves with a constant speed for time 3t. The
 
VHe Mw,O2 average speed of the train for this duration of
journey will be (in km/h) :
4 1 (1) 80 (2) 70
= 
32 2 2 (3) 30 (4) 40
VHe 2 2 Ans. (2)

VO2 1
 total distance Sol. mg – FB – Fv = ma
Sol. Average speed =
time taken a = 0 for constant velocity
80  t
mg – FB = Fv
 80  3t m   
= 2 = 70 km/hr. Fv = mg – v 0 g = mg – 0 g  mg  1  0 
4t    
48. An element l  xiˆ is placed at the origin and 50. In photoelectric experiment energy of 2.48 eV
carries a large current I = 10A. The magnetic field irradiates a photo sensitive material. The stopping
potential was measured to be 0.5 V. Work function
on the y-axis at a distance of 0.5 m from the
of the photo sensitive material is :
elements x of 1 cm length is :
(1) 0.5 eV (2) 1.68 eV
y (3) 2.48 eV (4) 1.98 eV
P Ans. (4)
Sol. eVs = h– 
0.5 m 0.5 V = 2.48 – 
work function () = 2.48 V – 0.5 V = 1.98 V
x SECTION-B
x 51. If the radius of earth is reduced to three-fourth
(1) 4  108 T (2) 8  10 8 T of its present value without change in its mass
then value of duration of the day of earth will be
(3) 12  10 8 T (4) 10  10 8 T ______ hours 30 minutes.
Ans. (1) Ans. (13)
y Sol. By conservation of angular momentum
I11  I22
Sol. P 2
2 2  2 2  3  2
 5 MR  T  5 M  4 R  T
  1   2
1 9

x T1 16T2
0 I (dl  r) 1 9 9 27
dB  (Tesla)   T1   24hr  hr = 13 hr 30 mins.
4 r 3 T2 16 16 2
52. Three infinitely long charged thin sheets are placed
1 1  ˆ
10 7  10    ( k) as shown in figure. The magnitude of electric field
 2 100  ˆ
 = 4  10 8 T ( k) x
 
1
3 at the point P is . The value of x is _________
2 0
  (all quantities are measured in SI units).
49. A small ball of mass m and density is dropped in
a viscous liquid of density 0 . After sometime, the – Y –2 
ball falls with constant velocity. The viscous force P
on the ball is :
–X O X
    
(1) mg  0  1  (2) mg  1  
    0 
Z X = –a X = a X = 3a
  
(3) mg 1  0  (4) mg  1  0 
   Ans. (2)
Ans. (4)
 Sol. For DC voltage
– Y –2 
V 100
R   20 
P I 5
Sol. for AC voltage
–X O X
X L  20 3 
R = 20 
Z X = –a X = a X = 3a
Z  X2L  R2  3  400  400 = 40

  2   ˆ Power = i 2rms R
Ep      ( i)
 2 0 2 0 2 0  2
 200 
2  Vrms 
2  
   2   20  250W
=  î =  R
0  Z   40 
 
53. A big drop is formed by coalescing 1000 small  
droplets of water. The ratio of surface energy of 55. The refractive index of prism is   3 and the
10 ratio of the angle of minimum deviation to the
1000 droplets to that of energy of big drop is .
x angle of prism is one. The value of angle of prism
The value of x is _________. is _________°.
Ans. (1) Ans. (60)
Sol. For min
Sol.  i=e
A
r1  r2  A
1000 drops Big drop 2 e
i
4 4  min r r2
1
1000 r 3  R 3 1
3 3 A
10r = R 2i  A
1
R = 10r A
S.E. of 1000 drops 1000(4r 2 )T 2i = 2A
 i=A
S.E. of Big drop 4R 2 T
Snell's law
1000  r 2 10
 2
 10  1 × sin i =  sin r
(10r) x
A
x = 1 sin i   sin  
2
54. When a dc voltage of 100V is applied to an
A
inductor, a dc current of 5A flows through it.
sin A   sin  
2
When an ac voltage of 200V peak value is A A A
2sin cos  3 sin  
connected to inductor, its inductive reactance is 2 2 2
found to be 20 3  . The power dissipated in the A 3
cos   
2 2
circuit is _________W.
A
Ans. (250)   30
2
A = 60°
56. A wire of resistance R and radius r is stretched till 58. A circular coil having 200 turns, 2.5 × 10– 4 m2 area
its radius became r/2. If new resistance of the and carrying 100 A current is placed in a uniform
stretched wire is x R, then value of x is _________. magnetic field of 1 T. Initially the magnetic dipole
moment (M) was directed along B . Amount of
Ans. (16)
work, required to rotate the coil through 90° from
l l
Sol. We know R  , R 2 its initial orientation such that M becomes
A r
perpendicular to B , is _________ J.
As we starch the wire, its length will increase but
Ans. (5)
its radius will decrease keeping the volume
M
constant M B
Vi  Vf Sol. B

r2
r 2 l   lf initial final
4
We know
lf  4l
 
Wext = U + KE  P.E.  M ·B
R new  4l  r 2  M ·Bf  M ·Bi  0
  2   16
R old r  l = –MB cos 90 + MB cos 0
 
 4  = MB
Rnew = 16R = NIAB
5
 x = 16  200  100  10 6   10 4  1 = 5J
2
57. Radius of a certain orbit of hydrogen atom is 59. A particle is doing simple harmonic motion of
8.48 Å. If energy of electron in this orbit is E/x, amplitude 0.06 m and time period 3.14 s. The
then x = _________. maximum velocity of the particle is _______ cm/s.
(Given a0 = 0.529Å, E = energy of electron in Ans. (12)
Sol. We know
ground state)
vmax = A at mean position
Ans. (16) 2 2
= A=  0.06 = 0.12 m/sec
Sol. We know T 
vmax = 12 cm/sec
n2 n2
r  0.529  8.48  0.529 60. For three vectors A  (xiˆ  6ˆj  2k)
ˆ ,
Z 1
B  (ˆi  4ˆj  3k)
ˆ and C  (8iˆ  ˆj  3k)
ˆ , if
n2 = 16 n = 4
A·(B  C)  0 , them value of x is _________.
We know Ans. (4)
ˆi ˆj kˆ
1
E
n2 Sol. B  C  1 4 3  15iˆ  21jˆ  33kˆ
8 1 3
E
E n th 
16 A ·(B  C)  (xiˆ  6ˆj  2k)
ˆ ·(15iˆ  21jˆ  33k)
ˆ
0 = –15x + 126 – 66
x = 16
15x = 60
x=4
 CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 63. Given below are two statements :
61. Functional group present in sulphonic acid is : Statement I : Picric acid is 2, 4, 6-trinitrotoluene.
(1) SO4H (2) SO3H Statement II : Phenol-2, 4-disulphuric acid is
(3) – S – OH (4) – SO2 treated with conc. HNO3 to get picric acid.
O In the light of the above statement, choose the
Ans. (2) most appropriate answer from the options given
O below :
Sol. S OH (1) Statement I is incorrect but Statement II is
correct.
O
(2) Both Statement I and Statement II are
Group present in sulphonic acids incorrect.
(3) Statement I is correct but Statement II is
62. Match List I with List II :
List I List II incorrect.
(Molecule / Species) (Property / Shape) (4) Both Statement I and Statement II are correct.
A. SO2Cl2 I. Paramagnetic Ans. (1)
B. NO II. Diamagnetic OH
C. III. Tetrahedral Sol. O2N
NO– 2
NO2
D. I3– IV. Linear

Choose the correct answer from the options given NO2

below :
picric acid
(1) A-IV, B-I, C-III, D-II
(2) A-III, B-I, C-II, D-IV (2, 4, 6 – trinitrophenol)
(3) A-II, B-III, C-I, D-IV OH OH
(4) A-III, B-IV, C-II, D-I SO3H
Conc. H2SO4
Ans. (2)
Sol.
(A) SO2Cl2 sp3 O SO3H
Tetrahedral
S Cl
Conc. HNO3
O Cl
(B) NO Paramagnetic OH
(C) NO  Diamagnetic O2N NO2
2

(D) I 3 sp3d I –
I
NO2
I Linear Picric acid
64. Which of the following is metamer of the given Ans. (3)
compound (X) ? NH2
O N C
NH – C Sol. C N  Adenine
HC
(X) N C CH
N
O H
(1)
NH – C O

(2) OHC C
NH H3C – C NH
 Thymine
O HC N C
(3) H O
NH – C
NH2
O
(4) C
NH – C HC N
 Cytosine
Ans. (4) HC N C
Sol. Metamer Isomer having same molecular H O
formula, same functional group but different
Are bases of DNA molecule. As DNA contain four
alkyl/aryl groups on either side of functional
group. bases, which are adenine, guanine, cytosine and
thymine.
65. DNA molecule contains 4 bases whoes structure
are shown below. One of the structure is not 66. Match List I with List II :
correct, identify the incorrect base structure.
LIST I LIST II
NH2
(Hybridization) (Orientation in
N C
(1) C N Space)
HC
N C CH A. sp3 I. Trigonal
N
H bipyramidal
O B. dsp2 II. Octahedral
3
C C. sp d III. Tetrahedral
(2) H3C – C NH
D. sp d3 2
IV. Square planar
HC N C
H O Choose the correct answer from the options given
O
below :
(1) A-III, B-I, C-IV, D-II
N C
(3) C NH (2) A-II, B-I, C-IV, D-III
H3C – C
N C C (3) A-IV, B-III, C-I, D-II
N NH2
H (4) A-III, B-IV, C-I, D-II
NH2 Ans. (4)
C Sol. sp3  Tetrahedral
HC N 2
(4) dsp  Square planar
HC N C 3
sp d  Trigonal Bipyramidal
H O 3 2
sp d  Octahedral
67. Given below are two statements : 69. Match List I with List II :
Statement I : Gallium is used in the LIST I LIST II
manufacturing of thermometers. (Compound / (Shape / Geometry)
Statement II : A thermometer containing gallium Species)
is useful for measuring the freezing point (256 K)
A. SF4 I. Tetrahedral
of brine solution.
B. BrF3 II. Pyramidal
In the light of the above statement, choose the
C. BrO3– III. See saw
correct answer from the options given below :
(1) Both Statement I and Statement II are false. D. NH4 IV. Bent T-shape
(2) Statement I is false but Statement II is true.
(3) Both Statement I and Statement II are true. Choose the correct answer from the options given
(4) Statement I is true but Statement II is false. below :
Ans. (4) (1) A-II, B-III, C-I, D-IV
Sol. Statement - I  Correct (2) A-III, B-IV, C-II, D-I
Statement - II  False (3) A-II, B-IV, C-III, D-I
Ga is used to measure high temperature (4) A-III, B-II, C-IV, D-I
68. Which of the following statements are correct ? Ans. (2)
A. Glycerol is purified by vacuum distillation Sol.
because it decomposes at its normal boiling (A) SF4 sp3d F
point. F
hybridisation S F
B. Aniline can be purified by steam distillation as
F
aniline is miscible in water.
C. Ethanol can be separated from ethanol water (B) BrF3 sp3d F
mixture by azeotropic distillation because it hybridisation Br F
forms azeotrope. F
D. An organic compound is pure, if mixed M.P. is Bent T-Shape
remained same. (C) BrO3 sp
3
Pyramidal
Choose the most appropriate answer from the hybridisation Br
options given below : O–
O
(1) A, B, C only
(2) A, C, D only (D) sp3
NH 4 H +
(3) B, C, D only hybridisation N
(4) A, B, D only Tetrahedral
H
Ans. (2)
Sol. Option (B) is incorrect because aniline is
immisible in water.
70. In Reimer - Tiemann reaction, phenol is converted 72. Consider the following complexes.
into salicylaldehyde through an intermediate. The [CoCl(NH3)5]2+, [Co(CN)6]3–,
structure of intermediate is ______.
(A) (B)
– +
ONa [Co(NH3)5(H2O)]3+, [Cu(H2O)4]2+
CH3
(C) (D)
(1)
The correct order of A, B, C and D in terms of
OH wavenumber of light absorbed is :
CHCl2
(2) (1) C < D < A < B
(2) D < A < C < B
– + (3) A < C < B < D
ONa
CHO (4) B < C < A < D
(3)
Ans. (2)

– + Sol. As ligand field increases, light of more energy is

ONa
CHCl2 absorbed
(4)
Energy  wave number

 
Ans. (4)
73. Match List I with List II :
OH O Na+
Sol. CHCl2 LIST I LIST II
CHCl3+ aq NaOH
(Precipitating reagent and (Cation)
conditions)
Intermediate
A. NH4Cl + NH4OH I. Mn2+
NaOH
B. NH4OH + Na2CO3 II. Pb2+
OH O Na+ C. NH4OH + NH4Cl + H2S gas III. Al3+
C–H C–H
H
+ D. dilute HCl IV. Sr2+
O O
Choose the correct answer from the options given
below :
71. Which of the following material is not a
semiconductor. (1) A-IV, B-III, C-II, D-I
(1) Germanium (2) A-IV, B-III, C-I, D-II
(2) Graphite (3) A-III, B-IV, C-I, D-II
(3) Silicon
(4) A-III, B-IV, C-II, D-I
(4) Copper oxide
Ans. (2) Ans. (3)

Sol. Graphite is conductor Sol. Theory based question

74. The electron affinity value are negative for : 77. Which among the following aldehydes is most
A. Be  Be – reactive towards nucleophilic addition reactions?
B. N  N– O O
C. O  O2– (1) H – C – H (2) C2H5 – C – H
D. Na  Na– O O
–
E. Al  Al (3) CH3 – C – H (4) C3H7 – C – H
Choose the most appropriate answer from the Ans. (1)
options given below : O
(1) D and E only (2) A, B, D and E only
Sol. H – C – H has low steric hindrance at carbonyl
(3) A and D only (4) A, B and C only
carbon and high partial positive charge at carbonyl
Allen Ans. (4)
carbon.
NTA Ans. (1)
Sol. (A) Be + e–  Be– , E.A = –ive 78. At –20 °C and 1 atm pressure, a cylinder is filled
– –
(B) N + e N E.A = –ive with equal number of H2. I2 and HI molecules for
(C) O + e –
O – the reaction
O– + e–  O–2 E.A = –ive H2(g) + I2(g) 2HI(g), the KP for the process is
(D) Na + e –
 Na –
E.A = +ive x × 10–1. x = _________.
[Given : R = 0.082 L atm K–1 mol–1]
(E) A + e–  A– E.A = +ive
(1) 2 (2) 1
Ans. A,B and C only (3) 10 (4) 0.01
75. The number of element from the following that Ans. (3)
n g
do not belong to lanthanoids is : (n HI )2  PT 
Sol. ng = 0 Kp =  
Eu, Cm, Er, Tb, Yb and Lu n H2 n I 2  nT 
(1) 3 (2) 4
n HI  n H2  n I2 so KP = 1
(3) 1 (4) 5
1 = x × 10–1 x = 10
Ans. (3)
Sol. Cm is Actinide
79. Match List I with List II :
LIST I LIST II
76. The density of 'x' M solution ('x' molar) of NaOH (Compound) (Uses)
is 1.12 g mL–1. while in molality, the concentration A. Iodoform I. Fire extinguisher
of the solution is 3 m (3 molal). Then x is B. Carbon II. Insecticide
(Given : Molar mass of NaOH is 40 g/mol) tetrachloride
(1) 3.5 (2) 3.0 C. CFC III. Antiseptic
(3) 3.8 (4) 2.8 D. DDT IV. Refrigerants
Ans. (2) Choose the correct answer from the options given
1000  M below :
Sol. Molality =
1000  d  M  (Mw)solute (1) A-I, B-II, C-III, D-IV
1000  x (2) A-III, B-II, C-IV, D-I
3= (3) A-III, B-I, C-IV, D-II
1000  1.12  (x  40)
(4) A-II, B-IV, C-I, D-III
x=3 Ans. (3)
Sol. Iodoform – Antiseptic Sol. HX  H+ + X– Ka = 1.2 × 10–5
CCl4 – Fire extinguisher 0.03M
CFC – Refrigerants 0.03 – x x x
x2
DDT – Insecticide Ka = 1.2 × 10–5 =
0.03  x
80. A conductivity cell with two electrodes (dark side)
0.03 – x  0.03 (Ka is very small)
are half filled with infinitely dilute aqueous solution x2
= 1.2 × 10–5
of a weak electrolyte. If volume is doubled by 0.03
adding more water at constant temperature, the x = 6 × 10–4
Final solution : 0.03 – x + x + x
molar conductivity of the cell will - = 0.03 + x = 0.03 + 6 × 10–4
 = (0.03 + (6 × 10–4)) × 0.083 × 300
(–)
= 76.19 × 10–2  76 × 10–2
(+)

1cm 82. The difference in the 'spin-only' magnetic moment

values of KMnO4 and the manganese product
1cm formed during titration of KMnO4 against oxalic
1cm acid in acidic medium is _____ BM. (nearest
integer)
(1) increase sharply Ans. (6)
(2) remain same or can not be measured accurately Sol. Spin only magnetic moment of Mn in KMnO4 = 0
Spin only value of manganese product fromed
(3) decrease sharply
during titration of KMnO4 aganist oxalic acid in
(4) depend upon type of electrolyte acidic medium is = 6
Ans. (2) Ans. 6
83. Time required for 99.9% completion of a first
Sol. Solution is already infinitely dilute, hence no
order reaction is _____ time the time required for
change in molar conductivity upon addition of completion of 90% reaction.(nearest integer).
water Ans. (3)
1  100  1  100 
Sol. K= n  n
t 99.9%  0.1  t 90%  10 

SECTION-B
n(103 )
81. Consider the dissociation of the weak acid HX as t99.9% = t90%
n10
given below t99.9% = t90% × 3
HX(aq) H+(aq) + X– (aq), Ka = 1.2 × 10–5
84. Number of molecules from the following which
[Ka : dissociation constant] can exhibit hydrogen bonding is ______. (nearest
The osmotic pressure of 0.03 M aqueous solution integer)
NO2
of HX at 300 K is _____ × 10–2 bar (nearest CH3OH, H2O, C2H6, C6H6, HF, NH3
integer). OH
[Given : R = 0.083 L bar Mol–1 K–1] Ans. (5)
NO2
Sol. CH3OH, H2O, HF, NH3
Ans. (76) OH
Can show H–bonding.
85. 9.3 g of pure aniline upon diazotisation followed 87. Frequency of the de-Broglie wave of election in
by coupling with phenol gives an orange dye. The Bohr's first orbit of hydrogen atom is ____ × 1013 Hz
mass of orange dye produced (assume 100% (nearest integer).
[Given : RH (Rydberg constant) = 2.18 × 10–18 J.
yield/ conversion) is ________g. (nearest integer)
h (Plank's constant) = 6.6 × 10–34 J.s.]
Ans. (20)
Allen Ans. (661)
NH2 +
N2 Cl NTA Ans. (658)
h
NaNO2 + HCl Sol. =
mv
Sol. T < 5°C
hv
=
OH mv 2
mv 2 v
   (frequency)
h 
1
Given mv2 = 2.18 × 10–18 J
2
N=N
h = 6.6 × 10–34

HO 4.36  10 18
= = 660.60 × 1013 Hz
Orange dye 6.6  10 34

Reaction suggests that 1 mole of aniline give 1  661 × 1013 Hz

mole of orange dye.

88. The major products from the following reaction
so (mol)aniline = (mole)orange dye
sequence are product A and product B.
9.3g mass of orange dye
1
 B
(i) Br2 (i) Br2
A
93g mol 199g mol 1 (ii) alc. KOH (3 eq.) (ii) O– Na+ (1.0 eq.)

mass of orange dye = 19.9 g 20 g The total sum of  electrons in product A and
product B are ______ (nearest integer)
86. The major product of the following reaction is P. Ans. (8)

CH3C  C – CH3   'P'

(i)Na/liq.NH3
(ii)dil.KMnO4 Br
273K Br2
Sol.
Number of oxygen atoms present in product 'P' is Br
_______ (nearest integer). +
HCC–CH2–O Na
Ans. (2)
Br
Sol. CH3 – C  C–CH3 
Na /liq.NH 3
 CH3 H
C=C
H CH3 O–CH2–CCH
(A)
dil. KMnO4

H H Br
alc KOH
CH3 C C CH3 (3 eq)
OH OH Br (B)
(Product P)
89. Among CrO, Cr2O3 and CrO3, the sum of spin-only 5
90. An ideal gas, CV  R , is expanded adiabatically
2
magnetic moment values of basic and amphoteric
against a constant pressure of 1 atm untill it
–2
oxides is ______ 10 BM (nearest integer). doubles in volume. If the initial temperature and
pressure is 298 K and 5 atm, respectively then the
(Given atomic number of Cr is 24)
final temperature is ______ K (nearest integer).
Ans. (877) [ CV is the molar heat capacity at constant volume]
Ans. (274)
Sol. CrO Basic oxide
Sol. U = q + w (q = 0)
Cr2O3 Amphoteric oxide nCVT = –Pext (V2 – V1)
V2 = 2V1
In CrO, Cr exist as Cr+2 and have  only = 4.90
nRT2 2nRT1

In Cr2O3, Cr exist as Cr+3 and have  only = 3.87 P2 P1
P1 = 5, T1 = 298
Sum of spin only magnetic moment
5T2
P2 =
= 4.90 + 3.87 = 8.77 2  298
5  nRT2 nRT1 
only = 877 × 10–2 n R(T2 – T1) = – 1   
2  P1 P1 
Ans. 877 Put T1 = 298
5T2
and P2 =
2  298
Solve and we get T2 = 274.16 K
T2  274 K