AL39UL-L 01/12/18

Safety Data Sheet

Copyright,2018,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 29-4962-6 Version Number: 2.01

Issue Date: 01/12/18 Supercedes Date: 08/27/14

SECTION 1: Identification
1.1. Product identifier
AL39UL-L

1.2. Recommended use and restrictions on use

Recommended use
EMI grounding

1.3. Supplier’s details

MANUFACTURER: 3M
DIVISION: 3M Korea
Electrical Markets Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification
Skin Sensitizer: Category 1.
Carcinogenicity: Category 2.
Specific Target Organ Toxicity (repeated exposure): Category 1.

2.2. Label elements

Signal word
Danger

Symbols
Exclamation mark | Health Hazard |

Pictograms

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Hazard Statements
May cause an allergic skin reaction.
Suspected of causing cancer.

Causes damage to organs through prolonged or repeated exposure:

respiratory system |

Precautionary Statements

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.

Storage:
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt
POLY(ETHYLENE TEREPHTHALATE) 25038-59-9 30 - 50
ACRYLIC COPOLYMER Trade Secret* 15 - 40
POLYURETHANE FOAM 9009-54-5 10 - 30
CARBON BLACK 1333-86-4 <5
COPPER 7440-50-8 <5
Nickel 7440-02-0 <5

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:
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Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms
develop, get medical attention.

Eye Contact:
No need for first aid is anticipated.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

5.3. Special protective actions for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Sweep up. Place in a closed container approved for transportation by
appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible in
accordance with applicable local/regional/national/international regulations.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
For industrial or professional use only. Do not handle until all safety precautions have been read and understood. Do not
breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when
using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective
equipment (gloves, respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities

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Store away from acids.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
CARBON BLACK 1333-86-4 ACGIH TWA(inhalable fraction):3 A3: Confirmed animal
mg/m3 carcin.
CARBON BLACK 1333-86-4 OSHA TWA:3.5 mg/m3
Nickel 7440-02-0 ACGIH TWA(inhalable fraction):1.5 A5: Not suspected
mg/m3 human carcin
Nickel 7440-02-0 OSHA TWA(as Ni):1 mg/m3
COPPER 7440-50-8 OSHA TWA(as Cu dust or mist):1
mg/m3;TWA(as Cu, fume):0.1
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
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of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Roll of Tape
Odor, Color, Grade: Odorless black roll
Odor threshold Not Applicable
pH Not Applicable
Melting point Not Applicable
Boiling Point Not Applicable
Flash Point Not Applicable
Evaporation rate Not Applicable
Flammability (solid, gas) Not Classified
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Density 2.5 - 3.5 g/cm3
Specific Gravity 2.5 - 3.5
Solubility In Water Not Applicable
Solubility- non-water Not Applicable
Partition coefficient: n-octanol/ water Not Applicable
Autoignition temperature Not Applicable
Decomposition temperature Not Applicable
Viscosity Not Applicable
Molecular weight No Data Available

SECTION 10: Stability and reactivity

10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

Strong acids

10.6. Hazardous decomposition products

Substance Condition
Carbon monoxide Not Specified
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Carbon dioxide Not Specified

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
May cause additional health effects (see below).

Skin Contact:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Contact with the eyes during product use is not expected to result in significant irritation.

Ingestion:
No known health effects.

Additional Health Effects:

Prolonged or repeated exposure may cause target organ effects:

Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart
rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

Ingredient CAS No. Class Description Regulation

CARBON BLACK 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer
Nickel 7440-02-0 Grp. 2B: Possible human carc. International Agency for Research on Cancer
Nickel 7440-02-0 Anticipated human carcinogen National Toxicology Program Carcinogens

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
POLY(ETHYLENE TEREPHTHALATE) Dermal LD50 estimated to be > 5,000 mg/kg
POLY(ETHYLENE TEREPHTHALATE) Ingestion Rat LD50 > 5,000 mg/kg
Nickel Dermal LD50 estimated to be > 5,000 mg/kg
Nickel Inhalation- Rat LC50 > 2.55 mg/l
Dust/Mist
(4 hours)
Nickel Ingestion Rat LD50 > 9,000 mg/kg
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CARBON BLACK Dermal Rabbit LD50 > 3,000 mg/kg

CARBON BLACK Ingestion Rat LD50 > 8,000 mg/kg
COPPER Dermal Rat LD50 > 2,000 mg/kg
COPPER Inhalation- Rat LC50 > 5.11 mg/l
Dust/Mist
(4 hours)
COPPER Ingestion Rat LD50 > 2,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

POLY(ETHYLENE TEREPHTHALATE) Human No significant irritation

Nickel Rabbit Minimal irritation
CARBON BLACK Rabbit No significant irritation
COPPER Rabbit No significant irritation

Serious Eye Damage/Irritation

Name Species Value

POLY(ETHYLENE TEREPHTHALATE) Human No significant irritation

Nickel Rabbit Mild irritant
CARBON BLACK Rabbit No significant irritation
COPPER Rabbit Mild irritant

Skin Sensitization
Name Species Value
POLY(ETHYLENE TEREPHTHALATE) Human Not classified
Nickel Human Sensitizing

Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

Name Route Value

POLY(ETHYLENE TEREPHTHALATE) In Vitro Not mutagenic

CARBON BLACK In Vitro Not mutagenic
CARBON BLACK In vivo Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
Nickel Inhalation similar Carcinogenic
compoun
ds
CARBON BLACK Dermal Mouse Not carcinogenic
CARBON BLACK Ingestion Mouse Not carcinogenic
CARBON BLACK Inhalation Rat Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

For the component/components, either no data are currently available or the data are not sufficient for classification.

Target Organ(s)

Specific Target Organ Toxicity - single exposure

For the component/components, either no data are currently available or the data are not sufficient for classification.

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Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
POLY(ETHYLENE Ingestion heart | skin | Not classified Rat NOAEL Not 13 weeks
TEREPHTHALATE) endocrine system | available
bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system
Nickel Inhalation respiratory system Causes damage to organs through Rat LOAEL 13 weeks
prolonged or repeated exposure 0.001 mg/l
CARBON BLACK Inhalation pneumoconiosis Not classified Human NOAEL Not occupational
available exposure

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

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SECTION 15: Regulatory information

15.1. US Federal Regulations
Contact 3M for more information.

EPCRA 311/312 Hazard Classifications:

Physical Hazards
Not applicable

Health Hazards
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Nickel 7440-02-0 <5
Nickel (Nickel) 7440-02-0 <5
COPPER 7440-50-8 <5
COPPER (Copper) 7440-50-8 <5

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 29-4962-6 Version Number: 2.01

Issue Date: 01/12/18 Supercedes Date: 08/27/14

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
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whether it is fit for a particular purpose and suitable for user's method of use or application.

3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M

3M USA SDSs are available at www.3M.com

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