NURTURE/PRE-MEDICAL

BEWARE OF NEGATIVE MARKING

PRACTICE TEST # 1 (CHEMISTRY) BATCH : KOHINOOR

1. When a bottle of cold drink is opened, the gas 5. The figure shows the change in concentration of
comes out with a fizzle due to :- species A and B as a function of time.
(1) decrease in pressure suddenly which results in The equilibrium constant Kc for the
a decrease in solubility of CO2 gas in water. reaction A(g) 2B(g) is :-
(2) decrease in temperature
(3) increase in pressure
(4) none of these
2. Which of the following will not shift the
equilibrium, N2 + 3H2 2NH3 towards product
side (1) Kc > 1 (2) K < 1
(1) Cooling (2) Addition of reactants (3) K = 1 (4) data insufficient
(3) Addition of catalyst (4) Increasing pressure 6. In a system A(s) ⇌ 2B(g) + 3C(g), if the
concentration of C at equilibrium is increased by a
3. Assertion (A) : On addition of Ar gas at constant factor of 2, it will cause the equilibrium
volume of chamber, at the equilibrium of the concentration of B to change to :
following reactions, the reaction shifts towards let.
(1) two times the original value
N2(g) + 3H2(g) ⇌ 2NH3(g)
Reason (R) : On addition of Ar gas, at constant (2) one half of its original value
pressure, at equilibrium of the above reaction, the
reaction shifts towards right. (3) 2√2 times to the original value
(1) Both Assertion (A) and Reason (R) are the (4) 1
times the original value
true and Reason (R) is a correct explanation of 2√ 2
Assertion (A). 7. Statement-I :- The equilibrium constant of the
(2) Both Assertion (A) and Reason (R) are the exothermic reaction at high temperature decreases.
true but Reason (R) is not a correct Statement-II :- Since ln KK = ΔRH [ T1 − T1 ] and for
2
1
∘

1 2

explanation of Assertion (A). exothermic reaction,

K2
(3) Assertion (A) is true and Reason (R) is false. Δ H° = – ve and thereby; <1
K1
(4) Both Assertion (A) and Reason (R) are false. (1) If both statements are CORRECT, and
Statement II is the CORRECT explanation of
4. At certain temperature compound AB2(g) Statement I.
dissociates according to the reaction (2) If both statements are CORRECT, and
2AB2(g) ⇌ 2AB(g) + B2(g) Statement II is NOT the CORRECT
With degree of dissociation α , which is small explanation of Statement I.
compared with unity. The expression of Kp, in (3) If Statement I is CORRECT, but Statement II
is INCORRECT.
terms of α and initial pressure P is :
(4) If Statement I is INCORRECT, but Statement
(1) α3 (2) P α 3 (3) α3 (4) P α 2 II is CORRECT.
P P
2 3 3 2

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8. For the reaction, CH4(g) + 2O2(g) ⇌ CO2(g) + 2H2O(l), 11. The following questions consist of two statements.
Δ H = – 170.8 kJ mol-1
Mark the answer as follows.
Statement-I :- The partial pressure of pure solid or
Which of the following statements is not true? liquid also appear in the expression of the
(1) Addition of CH4(g) on O2(g) at equilibrium will equilibrium constant.
cause a shift to the right Statement-II :- Molar concentration of pure solid or
liquid is constant
(2) The reaction is exothermic
(1) both statements are CORRECT.
(3) At equilibrium the concentrations of CO2(g)
and H2O(l)are not equal (2) both statements are Incorrect.

(4) The equilibrium constant for the reaction is (3) Statement I is CORRECT and Statement II is
[CO2 ] INCORRECT.
given by Kp =
[CH4 ][O2 ] (4) Statement I is INCORRECT and Statement II
9. The value of KP for the following reaction is CORRECT
2H2S(g) ⇌ 2H2(g) + S2(g) is 1.2 × 10 – 2 at 106.5°. 12. For the reaction N2O4(g) ⇌ 2NO2(g), the relation
The value of Kc for this reaction is :- between the degree of dissociation of N2O4(g) at
pressure, P with its equilibrium constant Kp is
(1) 1.2 × 10 – 2
(1) KP /P
(2) < 1.2 × 10 – 2 α=
4 + KP /P
(3) 83 (2) α = KP
(4) > 1.2 × 10 – 2 4 + KP
(3) KP /P 1/2
10. For the reaction : N2g + H2g NH3(g) α=[ ]
Equilibrium constant is Kc. Some reactions are 4 + KP /P
written below in Column-I and their equilibrium (4) KP
1/2

constants in terms of Kc are written in Column-II. α=[ ]

4 + KP
Match the following reaction with the 13. In which of the following reactions, the
corresponding equilibrium constant concentration of product is higher than the
concentration of reactant at equilibrium? =
equilibrium constant):
(1) A ⇌ B; K = 0.001 (2) M ⇌ N; K = 10
(3) X ⇌ Y; K = 0.005 (4) R ⇌ P; K = 0.01
14. In the reaction
A2 (g) + 4B2 (g) ⇌ 2AB4 (g) , Δ H > 0. The
decomposition of AB4(g) will be favoured at .
(1) (a)-(i) ; (b)-(ii) ; (c)-(iv) (1) Low temperature and high pressure
(2) (a)-(iv) ; (b)-(iii) ; (c)-(ii) (2) High temperature and low pressure
(3) (a)-(ii) ; (b)-(i) ; (c)-(iii) (3) Low temperature and low pressure
(4) (a)-(iv) ; (b)-(ii) ; (c)-(iii) (4) High temperature and high pressure

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15. For the synthesis of NH3 by the reaction N2 + 3H2 18. Consider the water gas equilibrium reaction,
⇌ 2NH3 in the Haber process the attainment of C(s) + H2 O(g) ⇌ CO(g) + H2(g)
equilibrium is correctly predicted by the curve: Which of the following statement is true at
(1) equilibrium
(2)
(1) If the amount of C(s) is increased, less water
would be formed
(2) If the amount of C(s) is increased,
more CO and H2 would be formed
(3) (4) (3) If the pressure on the system is increased by
halving the volume, more water would be
formed
(4) If the pressure on the system is increased by
halving the volume, more CO and H2 would
be formed
16. Applying the law of mass action to the dissociation
19. Find active mass of H2 is 4g-molecules of H2
of hydrogen lodide 2HI (g) ⇌ H2 + I2 . We get
present in 10 L solution ?
(a − x) (b − x)
the following expression =K (1) 0.2 mol L – 1 (2) 0.4 mol L – 1
4x2
Where a is original concentration of H2 , b
(3) 0.1 mol L – 1 (4) 0.8 mol L – 1
is original concentration of I2, x is the number of
molecules of H2 and I2 reacted with each other. If 20. N2(g) + 3H2(g) ⇌ 2NH3(g), K1 ..........(1)
the pressure is increased in such a reaction then, N2(g) + O2(g) ⇌ 2NO(g), K2 ..........(2)
1
(1) (a − x) (b − x) H2(g) + O2(g) ⇌ H2O(g), K3 ..........(3)
K= 2
4x2 The equation for the equilibrium constant of the
(2) (a − x) (b − x) reaction.
K> 5
4x2 2 NH3(g) + O2(g) ⇌ 2NO(g) + 3H2O(g), (K4)
(3) (a − x) (b − x) 2
K< in terms of K1, K2 and K3 is :
4x2
(4) None of these (1) K1 K32 (2) K2 K33
K2 K1
17. According to Le Chatelier's principle adding heat to
(3) K1 K2 (4) K1K2K3
a solid and liquid in equilibrium with endothermic
K3
nature will cause the
21. For reaction 3A(g) + B(g) ⇌ 2C(g) at a given
(1) Amount of solid to decrease temperature, kc = 9.0. What must be the volume of
(2) Amount of liquid to decrease the flask, if a mixture of 2.0 mol. each of A, B and
C exist in equilibrium ?
(3) Temperature to rise
(1) 6 L (2) 16 L
(4) Temperature to fall
(3) 2 L (4) 9 L

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22. The equilibrium constant for the reaction :- 27. For decolourisation of 1.5 moles of KMnO4 the
ZnO(s) + CO(g) ⇌ Zn(s) + CO2(g) is :- moles of H2O2 requires
(1) PCO2 (2) [ZnO] (1) 3 (2) 9 (3) 15 (4) 21
PCO [Zn] 2 4 4 4
(3) [PZnO . PCO ] 28. 0.84 g of metal hydride contains 0.04 g of
(4) PZn
PZn . PCO2 hydrogen. The equivalent wt. of the metal is
PCO
_______.
23. Consider the following equilibrium in a closed
container (1) 80 (2) 40 (3) 20 (4) 60
N2O4(g) ⇌ 2NO2(g) 29. Given below are two statements one is labelled
At a fixed temperature, the volume of the reaction as assertion (A) other is labelled as reason (R).
container is halved. For this change, which of the
following statements holds true regarding the Assertion (A): Basicity of orthoboric acid
equilibrium constant (KP) and degree of in aqueous medium is one.
dissociation ( α ) ? Reason (R): It has one replaceable hydrogen.
In the light of above statements choose the
(1) neither KP nor α changes correct answer.
(2) Both KP and α change (1) Both (A) and (R) are correct and (R) is
(3) KP changes, but α does not change the correct explanation of (A).
(4) KP does not change but α changes (2) Bout (A) and (R) are correct but (R) is not
the correct explanation of (A).
24. When two reactants, A and B are mixed to give
products C and D, the reaction quotient Q, at the (3) (A) is correct but (R) is incorrect
initial stages of the reaction. (4) (A) is incorrect but (R) is correct
(1) is zero 30. The number of moles of MnO−4 required to oxidise
(2) decrease with time one mole of ferrous oxalate completely in an acidic
medium is-
(3) is independent of time
(1) 0.6 mole (2) 0.4 mole
(4) increases with time
(3) 7.5 moles (4) 0.2 mole
25. The following reaction occurs in the blast furnace
where iron are is reduced to iron metal : 31. The equivalent weight of KMnO4 in acidic medium is
Fe2O3(s) + 3CO(g) ⇌ 2Fe(l) + 3CO2(g) (1) M (2) M (3) M (4) M
Using the Le Chatelier's principle, predict which 2 3 5 4
one of the following will not disturb the 2+
32. Number of moles of Fe ions oxidized by 1 mole
equilibrium ? of Cr2 O2− ion in acidic medium is
7
(1) Removal of CO2 (2) Addition of Fe2O3 (1) 2 (2) 3 (3) 4 (4) 6
(3) Addition of CO2 (4) Removal of CO 33. Find the equivalent weight of H3PO4 acid
26. The equivalent weight of MnSO4 is half its 2NaOH + H3PO4 → Na2HPO4 + H2O
molecular weight when it is converted to [If molecular weight of H3PO4 = M]
(1) Mn2O3 (2) MnO2 (3) MnO4 (4) MnO42 – (1) M (2) M (3) 2M (4) 1
2 M
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34. The equivalent weights of an element of variable 39. The number of mole of oxalate ions oxidised
valency are 21 & 14. The atomic mass of the by one mole of MnO−4 is :
element may be (1) 1 (2) 2 (3) 5 (4) 5
(1) 35 (2) 42 (3) 70 (4) 126 5 5 2
35. What is the equivalent mass of Mn3O4 when it 40. When N2 is converted into NH3, the equivalent
undergoes disproportionation reaction as follows :- weight of nitrogen will be :
Mn3O4 → MnO4 – + Mn2+ (1) 1.67 (2) 2.67 (3) 3.67 (4) 4.67
(M represents molar mass of Mn3O4) 41. How many grams of I2 are present in a solution
(1) M (2) M which requires 40 mL of 0.11 N Na2S2O3 to react
13 2 with it :-
(3) 26M (4) 15M I2 + S2O32 – → S4O62 – + 2I –
15 26
(1) 12.7g (2) 0.558g
36. Statement-I : The number of g-equivalents in the
same mass of KMnO4 is in 5 : 3 : 1 ratio in acid, (3) 25.4 g (4) 11.4g
neutral and strong basic medium, respectively. 42. What is the hybrid state of carbon in diamond,
Statement-II : The oxidation state of Mn change graphite and ethyne?
from +7 state to +2, +4 and +6 states, respectively
(1) sp3, sp2, sp (2) sp2, sp, sp3
in acid, neutral and strong basic medium.
(3) sp3, sp, sp2 (4) sp, sp2, sp3
(1) Both Statements are Correct and Statement-II
is correct explanation of Statement-I 43. Which of the following molecules is formed by sp2
hybrid orbitals?
(2) Both Statements are Correct and Statement-II
is not correct explanation of Statement-I (1) CH4 (2) CO2
(3) Statement-I is correct and Statement-II is (3) BF3 (4) BeF2
incorrect 44. Among the given species, identify the isostructural
(4) Statement-I is incorrect and Statement-II is pairs.
correct (1) NF3 and BF3 (2) BF4− and NH4+
37. In the reaction, V O + +F e2 O3 → F eO + V2 O5 , (3) BCl3 and BrCl3 (4) NH3 and NO−3
the eq. wt. of V2 O5 is equal to its :
45. Consider the following statements
(1) Mol. wt. (2) Mol. wt./8
(i) H2O molecule has v-shape with two lone pairs
(3) Mol. wt./6 (4) Mol. wt./2 of electrons.
38. Equivalent weight of H3 P O4 in each of the (ii) SF4 molecule has see-saw shape with one lone
reaction will be respectively- pair of electrons.
H3 P O4 + OH − → H2 P O−4 + H2 O
(iii) ClF3 is T-shaped molecule with two lone pairs
of electrons.
H3 P O4 + 2OH − → HP O2−
4 + 2H2 O
Which of the following statements are correct?
H3 P O4 + 3OH − → P O3−
4 + 3H2 O
(1) i and ii (2) ii and iii
(1) 98,49,32,67 (2) 49, 98, 32,67
(3) i and iii (4) i, ii and iii
(3) 98, 32,67, 49 (4) 32,67, 49, 98
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46. Match column I with Column II 48. Among the following molecules: SO2, SF4, ClF3,
Column-I Column-II BrF5 and XeF4, which of the following shapes does
Molecule Geometry / shape not describe any of the molecules mentioned?
(P) H3 O+ (1) Linear (1) Bent
(Q) HC ≡ CH (2) Angular (2) Trigonal bipyramidal
(R) ClO−2 (3) Tetrahedral (3) See-saw
(S) NH4+ (4) Trigonal bipyramidal (4) T-shape
(5) Pyramidal 49. The hybridization states of the central atoms of the
ions I3− , ICl−4 and ICl−2 are respectively:
(1) P-5, Q-1, R-2, S-3 (2) P-1, Q-3, R-5, S-4
(1) sp2, dsp2 and sp3d
(3) P-2, Q-1, R-4, S-5 (4) P-4, Q-2, R-1, S-3
(2) sp3d, sp3d2 and sp3d
47. Choose the correct option with respect to shape of
(3) sp3d, sp3d, dsp2
the molecule and hybridisation.
(4) sp, sp, dsp2
(1) BrF5 – sp3d2 - square pyramidal
50. Which of the following elements can not exhibit
(2) PCl5 – sp3d - trigonal bipyramidal sp3d hybridisation stater-
(3) SF6 – Sp3d2 - octahedral (a) C (b) P (c) Cl (d) B
Correct answer is :-
(4) All of these
(1) a, c (2) a, d (3) b, c (4) b, d

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