Bansal Pathshala

Karna MHT-CET Physics Test (Objective)

Sub: P/C/M/B Batch: XI/XII/Repeater
Date: 16-10-2024 Max. Marks: 100
Topic: Rotational Motion, Newton’s Law of Motion

1. (a) : Here, 1
Initial angular speed of the wheel, 𝜔 = 𝜔0 + 𝛼𝑡 = 60 − × 120 = 60 − 24
5
2𝜋 = 36rad/s
𝜔0 = 1800 × rads −1 = 60𝜋rads −1
60 The angular momentum 𝐿 = 𝐼𝜔 = 2 × 36 =
Final angular speed of the wheel, 72 kg m2 /s
2𝜋 7. (d) : Moment of inertia of a solid sphere of mass 𝑀 and
𝜔 = 3000 × rads−1 = 100𝜋rads−1
60 radius 𝑅 about its diameter is,
Time during which this change of speed takes place, 2
𝑡 = 20 s 𝐼 = 𝑀𝑅 2
5
Let 𝛼 be angular acceleration of the wheel. When the radius of the solid sphere is doubled
As 𝜔 = 𝜔0 + 𝛼𝑡 keeping the mass constant, the new moment of
𝜔 − 𝜔0 100𝜋 − 60𝜋 inertia is,
∴ 𝛼= = rads −2 2 8 𝐼 2𝑀𝑅2 5 1
𝑡 20 𝐼′ = 𝑀(2𝑅)2 = 𝑀𝑅2 ∴ ′ = × =
= 2𝜋rads−2 5 5 𝐼 5 8𝑀𝑅2 4
2. (a) : Here, mass of the body, 8. (b) : The free body diagram of 3 kg block is as shown in
𝑚 = 0.05 kg the figure (a).
Acceleration 𝑎 = 9.5 m s −2 , 𝑔 = 9.8 m s−2 The equation of motion of 3 kg block is
∴ 𝑚𝑔 − 𝑓air = 𝑚𝑎 𝑇2 = 3(𝑎 + 𝑔) = 3(2 + 9.8) = 35.4 N
or 𝑓air = 𝑚(𝑔 − 𝑎) The free body diagram of 5 kg is as shown in the
figure (b).
= 0.05(9.8 − 9.5)
= 0.015 N

The equation of motion of 5 kg block is

𝑇1 − 𝑇2 − 5𝑔 = 5𝑎
𝑇1 = 5(𝑎 + 𝑔) + 𝑇2
= 5(2 + 9.8) + 35.4 = 94.4 N
(Using (i))
3. (a): Here, 9. (c) : In a conservative field work done does not depend on
Mass of the stone, 𝑚 = 0.05 kg the path. The gravitational field is conservative in nature.
The magnitude of net force on the stone is So, the work done is same for each path, i.e. 𝑊1 = 𝑊2 =
𝐹 = 𝑚𝑔 = (0.05 kg)(9.8 m s−2 ) = 0.49 N 𝑊3 .
Its direction is vertically downwards. 10. (c) : The necessary centripetal force needed for the
4. (b) : Torque of tangential force on a disc will rotate the particle to undergo circular motion is provided by the
disc tension in the string i.e., 𝑇.
𝑀𝑅 2 𝜔 𝑀𝑅𝜔 11. (a) : Reading of the spring balance = apparent weight of
𝜏 = 𝐼𝛼 ⇒ 𝐹 × 𝑅 = × ⇒𝐹= mass = 𝑚(𝑔 − 𝑎) = 50(𝑔 − 𝑔) = 0
2 𝑡 2𝑡 12. (d) : In vertical circular motion,
5. (c) : Moment of inertia of a body depends on the mass of
the body, distribution of mass in the body, position of axis
kinetic energy of particle at highest point,
1 1
of rotation of the body and also depends on the distance of 𝐾𝐻 = 𝑚𝑣𝐻2 = 𝑚𝑔𝑟
body from the axis of rotation. 2 2
6. (b) : Given, 𝐼 = 2 kg m2 , 𝜔0 = 60rad/s (∵ 𝑣𝐻 = √𝑔𝑟)
𝜔 = 0 (... it comes to rest) and that at lowest point,
𝑡 = 5 minute = 5 × 60 = 300 second 1 5
𝜔 = 𝜔0 + 𝛼𝑡 𝐾𝐿 = 𝑚𝑣𝐿2 = 𝑚𝑔𝑟
2 2
𝜔−𝜔0 0−60 1
or 𝛼 = = = − rad/s 2 (∵ 𝑣𝐿 = √5𝑔𝑟)
𝑡 300 5 𝐾 1
For 2 minute ( = 120 second) ∴ Required ratio = 𝐾𝐻 = 5 = 0.2
𝐿

Bansal Pathshala
13. (c) : 𝑦4 2
𝐸Sphere 𝑀𝑅 2 4
= 5 =
𝐸Cylinder 1 2 5
2 𝑀𝑅
23. (d) : Time taken by the ball to reach the floor of the lift is
2ℎ
The 𝑋 component of force 𝐹 is 𝑡=√
𝑎+𝑔
√3 √3
𝐹𝑥 = 𝐹cos 30∘ = 𝐹 × = 𝐹 Here, ℎ = 1.25 m, 𝑔 = 10 m s−2 , 𝑎 = 5 m s−2
2 2
The 𝑌 component of force 𝐹 is 2 × 1.25 m
1 𝐹 ∴𝑡=√ = 0.4 s
𝐹𝑦 = 𝐹sin 30∘ = 𝐹 × = (5 + 10)ms−2
2 2
14. (a) : As the aircraft is moving with uniform velocity of 24. (b) : As, the collision is perfectly elastic, so from
150 m/s in space and all forces acting on it are balanced. conservation of energy we can write,
So aircraft will keep moving with same velocity. initial kinetic energy = final kinetic energy
15. (b) : In first case: moment of inertia (𝐼1 ) =
𝑀𝐿2 1 1 1
12 ⇒ 𝑚𝑉 2 + 0 = 𝑚𝑉12 + 𝑚𝑉22
𝐿 2 2 2
∴ Radius of gyration (𝐾1 ) = ( 𝑉2 = speed of second block after collision)
√12
𝑀𝐿2
In second case : 𝐼2 = 3 ⇒ 𝑉22 = 𝑉 2 − 𝑉12 ⇒ 𝑉2 = √𝑉 2 − 𝑉12
𝐿 𝐾 𝐿 √3 1 1
∴ 𝐾2 = Hence, 𝐾1 = × 𝐿 = =2 25. (c) : Moment of inertia of a circular ring of radius 𝑟 and
√3 2 √12 √4 𝑀𝑟 2
16. (d) : No external force acts so the speed of centre of mass mass 𝑀 about its diameter is .
2
will be zero. 2
26. (b) : M.I of solid sphere about its axis = 𝑚𝑟 2
17. (a) 5
where ' 𝑚 ' is mass of solid sphere and ' 𝑟 ' is radius
18. (b): Here, 𝑟⃗ = 𝑖ˆ − 2𝑗ˆ + 𝑘ˆ of solid sphere.
So, M. I of system about 𝐴𝐴′ is
𝐹⃗ = 5𝑖ˆ + 2𝑗ˆ − 5𝑘ˆ 2 2
𝑖ˆ 𝑗ˆ 𝑘ˆ 𝐼 = 3 ( 𝑚𝑟 2 ) + 2 ( 𝑚𝑟 2 + 𝑚𝑟 2 )
Torque, 𝑖⃗ = 𝑟⃗ × 𝑖⃗ = |1 −2 5 5
1| (By parallel axis theorem)
5 2 −5 6 14 20
= 𝑖ˆ(10 − 2) − 𝑗ˆ(−5 − 5) + 𝑘ˆ (2 − (−10)) 𝐼 = 𝑚𝑟 2 + 𝑚𝑟 2 = 𝑚𝑟 2 ; 𝐼 ⇒ 4𝑚𝑟 2
5 5 5
= 8𝑖ˆ + 10𝑗ˆ + 12𝑘ˆ 27. (b) : For the motion in a vertical circle the velocity of
19. (a) Mass, m = 10 kg position 𝐵 is
Initial velocity, 𝑢 = 10 m/s 𝑣 = √3𝑟𝑔
Time, t = 10sec ∴ Centripetal accelcration =
final velocity, V = 0
using Newton's II nd law
𝐹 = 𝑚𝑎
𝑉−𝑢 10 × 10
= 𝑚( )= = 10
𝑡 10
𝐹 = 10 N
20. (b) : By conservation of momentum, 𝑛𝑚𝑣 = 𝑀𝑉
50
𝑛× × 240 = 60 × 12; 𝑛 = 60
1000
21. (b) : Here,
Speed of the aeroplane, 𝑣 = 720kmph 𝑣 2 3𝑟𝑔
5 = = 3𝑔
𝑣 = 720 × m s −1 = 200 m s −1 𝑟 𝑟
18 28. (b) : Here,
Angle of banking, 0 = 45∘ Moment of inertia of the body about 𝑋 axis, 𝐼𝑋 =
Let 𝑅 be the radius of the loop. 20 kg m2 and about 𝑌 axis, 𝐼𝑌 = 25 kg m2
𝑣2
As tan 𝜃 = 𝑅𝑔 By the theorem of perpendicular axes, the moment of
𝑣2 (200)2 4 × 104 inertia of the body about the given axis (i.e., 𝑍 axis)
∴ 𝑅= = = is
𝑔tan 𝜃 10 × tan 45∘ 10 × 1 𝐼𝑍 = 𝐼𝑋 + 𝐼𝑌 = (20 + 25)kgm2 = 45 kg m2
= 4000 1m = 4 km 29. (c) : As, rate of change of momentum = force Let 𝑁
𝐸sphere 𝐼 𝜔2 𝐼𝑆
22. (d) : = 2 𝑆 𝑆
1 = (∵ 𝜔𝑆 = 𝜔𝐶 ) bullets per second can be fired. Thus, 𝑛𝑚𝑣 = 𝐹
𝐸cylinder 𝐼 𝜔2 𝐼𝐶
30
2 𝐶 𝐶
2
Here, 𝐼𝑆 = 𝑀𝑅 2 and 𝐼𝐶 = 𝑀𝑅 2
1 𝑛× × 1000 = 300; 𝑛 = 10
5 2 1000
30. (b) : The centre of mass of the system lies at point 𝐷
because half portion is filled with the sand.
Bansal Pathshala
31. (c) Fore is the mutual interaction between the bodies is Tension at the top or the highest point,
according to newton's third law of motion. 𝑚𝑣𝐻2 1 × (40)2
32. (b) : Square side = 𝑏; Radius of disc = 𝑅 Moment of 𝑇𝐻 = − 𝑚𝑔 = − 1 × 10 = 790 N
𝑀𝑏 2 𝐿 2
Inertia of square, 𝐼𝑠 = Tension at the bottom or the lowest point,
6
Moment of Inertia of disc, 𝐼𝑑 =
𝑀𝑅 2 𝑚𝑣𝐵2 1 × (40)2
2 𝑇𝐵 = + 𝑚𝑔 = + 10 = 810 N
So, 𝐼𝑠 = 𝐼𝑑 𝐿 2
∴ Ratio of the tension at the top and the bottom
𝑀𝑏 2 𝑀𝑅 2 𝑏 𝑇𝐻 790 N 79
= ; = √3: 1 = =
6 2 𝑅 𝑇𝐵 810 N 81
33. (b) : Given, force 𝐹⃗ = −5𝑖ˆ − 7𝑗ˆ + 3𝑘ˆ
42. (a) : The moment of inertia of the square frame 𝐴𝐵𝐶𝐷
Displacement, 𝑠⃗ = 3𝑖ˆ − 2𝑗ˆ + 𝑎𝑘ˆ about 𝑥-axis is
So, work done 𝑚𝑙 2 𝑚𝑙 2
𝑊⃗⃗⃗⃗ = 𝐹⃗ ⋅ 𝑠⃗ = (−5𝑖ˆ − 7𝑗ˆ + 3𝑘ˆ ) ⋅ (3𝑖ˆ − 2𝑗ˆ + 𝑎𝑘ˆ ) 𝐼= + + 𝑚𝑙 2
3 3
⇒ 14 = −15 + 14 + 3𝑎 5
⇒ 3𝑎 = 14 + 15 − 14 = 15 ⇒ 𝑎 = 15/3 = 5 units ⇒ 𝐼 = 𝑚𝑙 2
3
34. (b) : Here,
Mass of the man, 𝑚 = 60 kg
Acceleration of the lift, 𝑎 = 1.8 m s −2
As the lift moving down with acceleration 𝑎, the
force exerted by the floor on the man is
𝑁 = 𝑚𝑔 − 𝑚𝑎 = 𝑚(𝑔 − 𝑎)
= (60 kg)(9.8 m s−2 − 1.8 m s−2 )
= (60 kg)(8.0 m s−2 ) = 480 N 43. (d) : Let 𝜃 be the angle made by the wire with the vertical.
35. (a) : Time taken by hour hand to complete one rotation is 𝑣2
12 hrs. ∴ tan 𝜃 =
𝑟𝑔
2𝜋 Here, 𝑣 = 10 m/s, 𝑟 = 10 m, 𝑔 = 10 m/s 2
∴ 𝜔𝐼𝐼 = rad/hr
12 (10 m/s)2
Time taken by Earth to complete one rotation is ∴ tan 𝜃 = =1
24hrs. 10 m(10 m/s 2 )
𝜋
2𝜋 𝜃 = tan−1 (1) =
∴ 𝜔𝐸 = rad/hr 4
24 44. (b) : As, ℎ′ = 𝑒 2 ℎ = (0.6)2 × 1 = 0.36 m
𝜔
Required ratio, 𝐻 = 2: 1 45. (a) The centripetal force acting on the coin is balanced by
𝜔𝐸
36. (b) the frictional force.
1 𝑟 𝜔2
∴ 𝑚𝑟𝜔2 = 𝜇𝑚𝑔 or 𝑟 ∝ 𝜔2 ∴ 𝑟1 = 𝜔22
37. (a) : As no external force is applied on vertical circle 2 1

∴ The total energy at different positions along the Given, 𝜔2 = 2𝜔1

4 2𝜔 2 4
path is conserved. ∴ 𝑟2
= ( 𝜔 1 ) or 𝑟 = 4
38. (d) : Here, 1 2

Mass of the disc, 𝑀 = 1 kg ∴ 𝑟2 = 1 cm

Radius of the disc, 𝑅 = 2 m 46. (a) : As, 𝐿⃗⃗ = 𝑟⃗ × 𝑚𝑣⃗
Moment of inertia of the As perpendicular distance between 𝑟⃗ and velocity 𝑣⃗
circular disc about 𝑋𝑌 is are constant So, 𝐿 = constant
𝑀𝑅 2
𝐼𝑋𝑌 = = 2 kg m2
2
(Given)
According to theorem of parallel axes, the moment
of inertia of the circular disc about 𝑋1 𝑌1 is
𝑀𝑅 2 47. (a) : The relation 𝑣 = 𝑟𝜔 implies that 𝜔 does not depend
𝐼𝑋1 𝑌1 = 𝐼𝑋𝑌 + 𝑀𝑅 2 = + 𝑀𝑅 2
2 on ' 𝑟 '. As the particles of rigid body residing over the
3 3 axis of rotation will not have any linear velocity and
= 𝑀𝑅 2 = × (1 kg) × (2 m)2 = 6 kg m2 tangential acceleration. So, whatever be the value of ' 𝑟 ',
2 2
39. (a) : angular velocity and tangential acceleration will remain
40. (d) : Given : 𝜃0 = 0, 𝜔0 = 0, 𝜔 = 24rad/s, 𝑡 = 8 s same for all the particles.
𝜔 = 𝜔0 + 𝛼𝑡; 𝜔 − 𝜔0 = 𝛼𝑡 48. (d) : Initial angular speed,
𝜔 − 𝜔0 24 2𝜋 × 1200
⇒𝛼= = = 3rad/s2 𝜔0 = rads −1 = 40𝜋rads −1
𝑡 8 60
1 1 Final angular speed,
𝜃 = 𝜃0 + 𝜔0 𝑡 + 𝛼𝑡 2 = × 3 × 82 = 96rad 2𝜋 × 3120
2 2 𝜔= rads−1 = 104𝜋rads−1
41. (b) : Given, 𝑚 = 1 kg, 𝐿 = 2 m and 𝑣𝐻 = 𝑣𝐵 = 40 m s −1 60

Bansal Pathshala
 ∴ Angular acceleration,
𝜔 − 𝜔0 104𝜋 − 40𝜋
𝛼= = = 4𝜋rads−2
𝑡 16
49. (b) : From conservation of angular momentum
𝐼1 𝜔1 = 𝐼2 𝜔2
(∵ 𝜔1 = 𝜔, 𝐼1 = 𝐼 and 𝐼2 = 2𝐼)
𝜔
𝐼𝜔 = 2𝐼𝜔2 ∴ 𝜔2 =
2
1 𝜔 2 𝐼𝜔2
New 𝐾𝐸 = 2𝐼 ( ) =
2 2 4
1 𝐼𝜔2 𝐼𝜔2
Change in 𝐾𝐸 = 2
𝐼𝜔2 − 4 = 4
50. (d) : 𝜏 = 1.6 × 1 = 1.6 N m
𝜏 1.6
𝐹= = =4N
𝑑 0.4

Bansal Pathshala
 Bansal Pathshala
Karna MHT–CET Chemistry Test (Objective)
Sub: P/C/M/B Batch: XI/XII/Repeater
Date: 16-10-2024 Max. Marks: 100
Topic: d & f Block Element, Coordination Compound

1. (b) : Intramolecular hydrogen bonding occurs within two

atoms of the same molecule. 3
CrCl3 24 Cr
3+ [Ar]3𝑑3 (coloured
compound)

ZnCl2 30 Zn
2+ [Ar]3𝑑10 0
+
CuCl 29 Cu [Ar]3𝑑10 0
2-Hydroxybenzaldehyde (Salicylaldehyde)
2. (d)
𝜇𝑠 = √𝑛(𝑛 + 2) = 5.9 B. M. 7. (b)
Fe2+ (d6 ): Unpaired electrons (n) = 4
⇒ 𝜇2 = 𝑛(𝑛 + 2) = 34.81 ⇒ 𝑛 = 5
Thus, Mn will have five unpaired electrons so Mn ∴ 𝜇s = √4(4 + 2) = 2√6 = 4.89 ≃ 4.90BM
will be in +2 state with Br − being weak- field 8. (d) : Ln
heated with S
→ Ln2 S3
ligands. 9. (a)
Thus, 𝑥 = 2 for [MnBr4 ]2−
10. (b) : For stable molecule the value of bond order must be
positive as bond order
no. of bonding electrons - no, of antibonding
electrons = 2
The electrons in the bonding molecular orbital leads
to lowering in energy and hence stability whereas in
3. (c) : In a period, on moving from left to right, the antibonding molecular orbital leads to destability.
ionisation enthalpy increases which can be explained on (i) (-ve) bond order ⇒ greater number of elcctrons in
the basis of increased nuclear charge and decrease in antibonding molectlat otbital than bonding molecular
atomic radii. Both the factors increase the force of orbital. Therefore molecule is less stable compared
attraction of the electron towards the nucleus and to the separated atoms.
consequently, more energy is needed to remove the (ii) 0 bond order ⇒ number of bonding molccular
valence electrons and thus the ionisation enthalpies
orbital = number of antibonding molecular orbital.
increase. Thus, the order should be:
Therefore there is no gain in energy in forming the
C<N<O<F
molecule.
However, 𝑁 has stable 2𝑝3 electronic configuration,
(iii) ( +𝑣𝑒) bond order ⇒ number of electrons in
as a result of which, its ionisation energy is greater
bonding molecular orbital is more than those in
than that of oxygen and thus, the correct order is :
antibonding molecular orbital. Therefore there is a
C < O < N < F.
gain in energy while the bonding takes place.
4. (a) : The complex of calcium with EDTA is used for the
11. (b): This is an example of solvate isomerism. Solvate
treatment of lead poisoning.
isomers differ by whether or not a solvent molecule is
5. (c) : IUPAC name of Na 3 [Co(NO2 )6 ]
directly bonded to the metal ion or mainly present as free
sodium hexanitritocobaltate (III) solvent molecules in the crystal lattice.
Oxidation state: 3(1) + 𝑥 + 6(−1) = 0 12. (b) Coordination number refer to the total number of
or 𝑥 − 3 = 0 ⇒ 𝑥 = 3 ligands.
6. (c) : 13. (c)

Central No. of 14. (c) The IUPAC name of the compound is Ammonium
Electronic diaquabis (oxalato) nickelate(II).
Compound metal unpaired
configuration 15. (d)
ion electrons
16. (a)
4+ 0
TiCl4 22 Ti [Ar]3𝑑 0
17. (c) : [Pt(NH3 )6 ]Cl4 ⟶ [Pt(NH3 )6 ]4+ + 4Cl− The given
complex provide 5 ions on ionisation.
18. (a) : Electronegativity generally increases on moving
across a period from left to right and decreases from top to

Bansal Pathshala
 bottom in a group as atomic size increases. So, the order It contains one unpaired electron, hence
of electronegativity is: paramagnetic.
Si < P < C < N 30. (a) : Ammine (NH3 ) is a neutral ligand.
19. (c) : In homoleptic complexes, all the ligands connected Cyano, nitrato and chloro are negatively charged ligands.
with central atom are same or identical. 31. (b) :
20. (c) [Pt(NH3 )2 Cl(NO2 )]
Let 𝑥 be the oxidation state of platinum.
𝑥 + 2(0) + (−1) + (−1) = 0
𝑥 − 2 = 0 ⇒ 𝑥 = +2
[CoCl2 ( en )2 ]+
Let 𝑦 be the oxidation state of cobalt.
𝑦 + 2(−1) + 0 = +1
𝑦 − 2 = +1 ⇒ 𝑦 = +1 + 2 ⇒ 𝑦 = +3
So, oxidation number of central metal in
[Pt(NH3 )2 Cl(NO2 )] is +2 and in [CoCl2 (en)2 ]+ is +3
.
21. (d) Co binds with two bidentate ligands en and two
32. (d)
monodentate ligands.
∴ Its coordination number = 4 + 2 = 6
33. (c) : Coordination isomerism is shown by compounds in
22. (b) :
which both cations as well as anions are complexes and
Species At No. No. of 𝒆− ligands interchange their positions between two complex
ions.
Ca2+ 20 18 34. (d) : The electronic configuration of the elements are
− 1𝑠 2 2𝑠 2 ; 11 Na − 1𝑠 2 2𝑠 2 2𝑝6 3𝑠1
4 Be
K+ 19 18 2 2 6 2 6 1
19 K − 1𝑠 2𝑠 2𝑝 3𝑠 3𝑝 4𝑠
S 2− 16 18 The first ionization energy of Be is maximum
because electron is to be drawn from stable (fully
The species Ca2+ , K + and S 2− are isoelectronic. For
isoelectronic ions, the radius decreases as the nuclear filled) orbital. The 1st ionization energy of Na is
charge increases. Hence, the increasing order of their greater than K because size of the K is bigger than Na
radii is : Ca2+ < K + < S 2− which facilitates easy removal of electron from its
23. (d) : In [Fe(C2 O4 )3 ]3− , Fe is coordinated to three oxalate outermost shell. So, the sequence is K < Na < Be.
ligands which are didentate in nature. 35. (d) : During the formation of a chemical bond → energy
24. (a) decreases and therefore stability increases.
36. (c)
25. (d) Oxidation number of the metal in metal carbonyl 37. (c) : Coordination number or ligancy is the total number
compounds is zero. of monodentate or unidentate ligands surrounding the
26. (a) : The electronic configuration of 21 𝑋 is central atom in the coordination sphere or in the complex
⟶ 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 4𝑠 2 3𝑑i ion. c.g. [Co(NH3 )6 ]3+ - coordination number = 6.
21 𝑋
38. (a) : The bond order of superoxide ion O2− is O2 →
The last electron enters to 𝑑 orbital which means it
𝜎1𝑠 2 𝜎 ∗ 1𝑠 2 𝜎2𝑠 2 𝜎 ∗ 2𝑠 2 𝜎2𝑝𝑧2 𝜋2𝑝𝑥2
belongs to ' 𝑑 ' block elements or transition elements.
≈ 𝜋2𝑝𝑦2 𝜋 ∗ 2𝑝𝑥2 ≈ 𝜋 ∗ 2𝑝𝑦1
27. (d) : EAN = Atomic number of central atom + No. of
electrons donated by ligands - Oxidation state of central Bond order = 1/2[𝑁𝑏 − 𝑁𝑎 ] = 1/2[10 − 7] = 1.5
atom 39. (a)
]4+
(a) [Pt(NH3 )6 ; EAN = 78 + 2 × 6 − 4 = 86
(b) [Fe(CN)6 ]4− ; EAN = 26 + 1 × 6 + 4 = 36
(c) [Zn(NH3 )4 ]2+ ; EAN = 30 + 2 × 4 − 2 = 36
(d) [Cu(NH3 )4 ]2+ ; EAN = 29 + 2 × 4 − 2 = 35
28. (a) : Manganate ion, MnO2− 4 is green in colour and is
paramagnetic in nature.
29. (c) : Molecular orbital configuration of H2+ ⇒ 𝜎1𝑠1
It contains one unpaired electron, hence
paramagnetic. Hence the number of unpaired electrons in Ni in
O2 ⇒ 𝜎1𝑠 2 𝜎 ⋆ 1𝑠 2 𝜎2𝑠 2 𝜎 ⋆ 2𝑠 2 𝜎2𝑝𝑧2 𝜋2𝑝𝑥2 𝜋2𝑝𝑦2 [Ni(CN)4 ]2− is zero.
40. (d) : Nb belonging to second transition series and Ta
It contains two unpaired electrons, hence
belonging to third transition series have almost similar
𝜋 ∗ 2𝑝𝑥1 𝜋 ∗ 2𝑝𝑦1 paramagnetic, chemical properties due to lanthanoid contraction. Hence
Li2 ⇒ 𝜎1𝑠 2 𝜎 ⋆ 1𝑠 2 𝜎2𝑠 2 they are called chemical twins.
It does not contain any unpaired electron, hence 41. (d)
diamagnetic.
He+ 2 ⇒ 𝜎1𝑠 𝜎 1𝑠
2 ∗ 1 42. (c) The secondary valency of a central metal atom/ ion in a
complex represents the number of neutral or negatively
Bansal Pathshala
 charged groups called ligands. The primary valency
represents the oxidation state of the metal.
43. (a)

44. (b) : 𝑑-Block metal usually used as catalyst.

45. (b) Ionic radii of isoelectronic ions decreases with
increase in the magnitude of nuclear charge. If the species
is positively charged, then it has less ionic radii. Thus, [Ni(CO)4 ] is a square-planar and diamagnetic
Therefore; the correct order of ionic radii is K + > Na+ > complex.
Mg 2+ > Al3+ . Therefore, (ii) is incorrect and only (i) and (iii) are
46. (d) : Scandium compounds are colourless. correct.
Sc 3+ has zero 𝑑-electrons. 50. (c)
Sc(21): [Ar]3𝑑1 4𝑠 2 Ni2+ : [Ar]3𝑑 8
Sc 3+ : [Ar]3𝑑0 4𝑠 0 𝑑𝑠𝑝2 hybridisation
47. (b) : O2−
2 , no. of antibonding electron pairs = 4 pairs
(a) Shape : Square planar
( CN− causes pairing of
electron hence, diamagnetic)
Shape : Square planar
(CN −causes pairing of electron hence, diamagnetic)
(b) Ni (in zero O.S.) [Ar]3𝑑8 𝑠𝑝3 hybridisation
Shape : Tetrahedral
(Diamagnetic)
(c) Ni2+ : [Ar]3𝑑8 𝑠𝑝3 hybridisation
Shape : Tetrahedral
Cl− weak field ligant cause no pairing of electron
hence, paramagnetic)
Ni2+ : [Ar]3𝑑8
(d) 3 2
𝑠𝑝 𝑑 hybridisation
Shape : Octahedral, paramagnetic

Molecular orbital diagram of O2−

2 (peroxide ion)
48. (d): Zr and Hf belong to same group. Both have identical
atomic and ionic radii due to lanthanold contraction. Zr is
present in 5 th period whereas Hf is present in 6th period.
49. (b) [NiCl4 ]2− has Ni2+ that has the configuration
[Ar]3 d8 .
Since Cl− is a weak-field ligand, the configuration of
the complex will be:-
[NiCl4 ]2−

Thus, it is a tetrahedral complex.

It is paramagnetic due to unpaired electrons.
[Ni(CO)4 ] has neutral and strong-field ligand CO.
Thus,
[Ni(CO)4 ]

Bansal Pathshala
 Bansal Pathshala
Karna MHT-CET-2025 Mathematics Test (Objective)
Sub: P/C/M/B Batch: XI/XII/Repeater
Date: 16-10-2024 Max. Marks: 100
Topic: Mathematics Cummulative

1. (b) (sin2   cos 2  )3  (1)3  sin2 x  cos 2 x  2 sin x cos x 

1
 sin   cos   3 sin  cos   1
6 6 2 2 25
24 7 24
and sin4   cos 4   2 sin2  cos 2   1 sin 2 x   cos 2 x   tan 2 x  .
25 25 7
Both gives,
2 (sin6   cos 6  )  3 (sin4   cos 4  )  1  0 .  5 7
9. (b) We have k  sin sin sin
18 18 18
2. (c) (cos 1  cos 179)  (cos 2  cos 178)  ....      5    7 
(cos 89  cos 91)  cos 90  cos 180  1 .  cos   cos   cos  
 2 18   2 18   2 18 
 8
 3 5 7 sin 2 3 sin
sin2  sin2
 sin2  sin2  2 4 9 9
3. (d)  cos cos cos  
8 8 8 8 9 9 9 3  
2 sin 8 sin
2  2 3 2 3 2  9 9
 sin  sin  sin  sin
8 8 8 8  
 2 3  sin   
 2 sin  sin2   2 1  2 .   9 1
 .
 8 8   8
8 sin
9
5 5  5 
4. (c) cos A  sin A  cos
 sin ,  A  
4 4  4  10. (c)
  1 1 1 cos x cos x
  cos  sin    0.
4 4 2 2 (2 cos x  sin x ) 1 sin x cos x  0
1 cos x sin x

5. (b) We have tan A  

1
and tan B  
1 Applying, R 2  R 2  R1 and R 3  R 3  R1
2 3 1 cos x cos x
1 1
  (2 cos x  sin x ) 0 sin x  cos x 0 0
tan A  tan B
Now, tan ( A  B)   2 3  1 0 0 sin x  cos x
1  tan A tan B 1 1
1 .
2 3  (2 cos x  sin x )(sin x  cos x )2  0
3 3   
 tan ( A  B)  tan . Hence, A  B  .  tan x  2, 1 But tan x  2 in  ,  . Hence
4 4
 4 4

15 12 tan x  1  x 
6. (d) Given, sin  , tan   4
17 5
8 12 5
 cos   , sin   and cos    11. (b)
17 13 13 Since it is an identity in  so satisfied by every value
3 5
  ,  cos    of  . Now put   0 in the given equation, we have
2 13
0 1 3
171
sin(  )  sin  cos  cos  sin = . t 1 2  4  12  30  18
221
3 4 0

7. (a) cos 2   cos 2 (  120 o )  cos 2 (  120 o )


 cos 2   cos (  120 o )  cos (  120 o ) 
2

 2 cos (  120 o ) cos (  120 o ) 12. (c)

We know that if all the elements below the diagonal

 cos 2   2 cos  cos 120 o 
2

 2 cos 2   sin2 120 o  in a matrix are zero, then it is an upper triangular
 cos   cos   2 cos   2 sin 120
2 2 2 2 o
matrix.
3 3
 2 sin2 120 o  2   .
4 2 13. (d)
1 0 K
1 For invertible, | A |  0 i.e., 2 1 3 0
8. (d) sin x  cos x 
5 K 0 1

Bansal Pathshala
  1(1)  K(K)  0 | A |  K 2  1  0 , which is true for 22. (b) The given line can be written in this form
(3  2)x  (1  3)y  (5  4 )  0
all real K .
It is will be parallel to y-axis, if
1
14. (c)  1  3  0     .
3
Multiplication of square matrices is a square matrix
of same order and by property of transpose. 23. (c) The equation of line which cuts off equal intercepts from
x y
15. (b) axes a (say) is   1 or x  y  a
a a
log3 512 log4 3 log 2 3 log8 3 But it is passes through (1, –2), therefore 1  2  a

log3 8 log4 9 log3 4 log3 4  a  1 .
 log 512 log 9 log 3 log 8   log 3 log 4 log 3 log 4  Hence the equation of straight line is x  y  1  0 .
         
 log 3 log 4 log 4 log 3   log 2 log 3 log 8 log 3 
 log 2 9 log 3 2 log 2 3   log 2 2 log 2 2  24. (c) Here c  1 and m  tan   tan 45 o  1
       (Since the line is equally inclined to the axes, so   45 o
 log 3 log 2
2
log 2 2   log 2 log 2 3 
 )
92 3   2 Hence equation of straight line is y  (1. x )  1
    2    10
 2 2  3  x  y  1  0 and x  y  1  0 .

16. (d) 25. (b) The line perpendicular to the line x  y  1  0 is

2 1 1 y  x    0 . Also, it passes through the point (1, 2); 
D  1  2 1  3   6 . For no solution the   1 . Hence, required line is y  x  1  0 .
1 1 
necessary condition is 3  6  0    2 . It can be 26. (b) Given a  b  14  a  14  b
see that for   2 , there is no solution for the given Hence the equation of straight line is
x y
 1.
system of equations. 14  b b
Also, it passes through (3,4 )
17. (d) 3 4
   1  b  8 or 7
 0   0   2 0 14  b b
A2    ∵ A  B
2
 (given) Therefore equations are 4 x  3 y  24 and x  y  7 .
1 1  1 1    1 1 
Trick : This question can be checked with the options as
 2 0  1 0  the line 4 x  3 y  24 passes through (3, 4) and also cuts
     1 and   1  5 .
2
Then 
  1 1  5 1  the intercepts from the axes whose sum is 14.
Clearly no real value of 
21 23
27. (a) Point of intersection y   and x 
18. (a) 5 5
x  y 2x  z  4 7 3(23)  4 (21) 69  84
 3x  4y    3 .
We have    5 5
 x  y 2 z  w  0 10 
Hence, required line is 3 x  4 y  3  0 .
x  y  4, 2 x  z  7 , x  y  0 and 2 z    10
 x  2 and y  2, z  3, w  4
b
28. (b) The required equation is y  b   (x  a)
a
19. (b) x y
x + 2y + kz = 1   2.
a b
2x + ky + 8z = 3
1 2 k 29. (b) If the given lines represent the same line, then the length
= =  k=4 of the perpendiculars from the origin to the lines are equal, so
2 k 8
c p
one value of k for which there is no solution that 
1m 2
cos   sin2 
2

20. (c)  c  p 1m2 .

Put a = b = c = 1
–1 1 1 30. (d) Given form is 3 x  3 y  7  0
1 1 1 =  × 1 × 1 × 1 3 3
 x y 7  0
1 1 1 3 3
2 2
3  32
2

 = –1 (1 –1) – 1 (–1 –1) + 1 (1 + 1) 3 3 7 7 7

 x y ,  p  .
 = 0 + 2 + 2  = 4 3 2 3 2 3 2 3 2 3 2

21. (c) It is obvious.

 1  cos 2 
31. (c) f [ f (cos 2 )]  f  
 1  cos 2 

Bansal Pathshala
 1  tan 2  f (x )  1 
1
 Range  (1, 7 / 3] .
 f (tan 2  )   cos 2 . 42. (c) 2
1  tan 
2
 1 3
x   
 2 4
32. (b) f (xy )  sin log xy  sin(log x  log y) .....(i)
f (x / y)  sin log(x / y)  sin(log x  log y) .....(ii) 43. (b) As shown in graph
 f (xy )  f (x / y)  2 sin log x cos log y  Range is (–1, 0]. O (1,0) (2,0)

Hence required value of the function is

2 sin log x cos log y  2 sin log x cos log y  0 . y=–1

33. (a) We have f (x  y)  f (x  y)

x 2
1

 a x  y  a  x y  a x y  a  x  y
2
 44. (b) f (x ) 
| x  2|
1 x y

 a (a  a y )  a  x (a y  a y )
2
 1,
f (x )  
x  2
x  2
 1,
1 x
 (a  a  x ) (a y  a y )  2 f (x ) f (y) .  Range of f (x ) is {1, 1} .
2

1 | 1 |
45. (c) “The sun is a star” is a statement.
1  1
34. (b) f (1)    2.
| 1 | 1
46. (a) “Please do me a favour” is not a statement.
1  4 3 3  ~ ( p  q)  ~ p  ~ q .
35. (d) x 3 f   x 3  3  2   4 47. (a)
 
x x x x 
 4  3 x  3 x 2  4 x 3  f (x ) . 48. (b) p q ~ pq.

49. (b) (p  q)  (q  p) means p  q .

36. (c)
Y
50. (d) ~ p  q ~ (q  p) .
}x=1/2 X
O

Which is step function.

1
37. (b) f (x )  log  sin x  0  x  n  (1)n 0
| sin x |
 x  n . Domain of f (x )  R  {n , n  I} .

38. (c) f (x )  log( x  4  6  x )

 x  4  0 and 6  x  0  x  4 and x  6
 Domain of f (x ) = [4 , 6] .

39. (c) is to be defined when x 2  1  0

f (x )
 x 2  1,  x  1 or x  1 and 3  x  0
 x  3 and x  2
 Df  (3,  2)  (2,  1)  (1, ) .

40. (b) According to question, as sin 2 x can’t be

negative.
So the option (b) is correct
Domain of function sin 2 x is [n , n   /2] .

41. (b) Obviously, here | x |  2 and x  1

i.e., x  ( ,  2)  (2, ) .

Bansal Pathshala