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Class15 Chemistry Contest Homework Dec 19

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8 views

Class15 Chemistry Contest Homework Dec 19

Uploaded by

imwinstonyu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Class 15 Homework Name_________ Marks __________/27

1. Circle the least reactive compound in an SN2 reaction.

2. Circle the best leaving group in an elimination reaction.

3. Circle the best nucleophile in a substitution reaction at a primary carbon.

4. Circle the least reactive compound in an SN1 reaction.

5. Circle the best solvent for an SN2 reaction.


Class 15 Homework Name_________ Marks __________/27

6. Consider the following reactions:

or

The mechanism for these reactions is:

a. SN1
b. SN2
c. E1
d. E2

7. Consider the pair of reactions below to answer the following question(s).

a.

or

b.

a) The alkyl bromide starting materials in these reactions are classified as:

a. 3°
b. 2°
c. 1°
d. 4°

b) The solvent in these reactions is:

a. nonpolar aprotic
b. polar aprotic
c. polar protic
d. nonpolar protic

c) The nucleophile in these reactions is:

a. K+
b. alkyl group
c. Br−
d. I−
Class 15 Homework Name_________ Marks __________/27

d) The mechanism for these reactions is:

a. SN2
b. E2
c. SN1
d. E1

8. Consider the reaction below to answer the following question(s).

a) The substrate in the reaction is:

b) Compound B is the:

a. SN2 product
b. SN1 product
c. E2 product
d. E1 product

c) Compound C is the:

a. SN2 product
b. SN1 product
c. E2 product
d. E1 product
Class 15 Homework Name_________ Marks __________/27

9. Consider the reaction below to answer the following question(s):

a) Write the product that results from the electron flow in the reaction, clearly indicating any
stereochemistry. (4 marks)

b) Draw a Newman projection of the reactive conformation of the starting material. (4 marks)

10. Draw the structure of the major organic product(s) for each of the following reactions.
Indicate the stereochemistry for each reaction when appropriate. (2 marks each)

a)

b)

c) .

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