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Xii Chemistry Halo Alkane and Halo Arene Work Sheet-Ii 24-25

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32 views3 pages

Xii Chemistry Halo Alkane and Halo Arene Work Sheet-Ii 24-25

Uploaded by

Shami Immanuel
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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GOOD SHEPHERD MODEL SCHOOL, THOOTHUKUDI

WORKSHEET-2
STD XII CHEMISTRY
CHAPTER– 6

HALOALKANE AND HALO ARENE


1. For the preparation of alkyl halides from alcohols which among the following cannot be used:

a. PCl5 b. SOCl2 c. PCl3 d. NaCl

2. In the reaction ROH RedP/I RI + A; A is

a. H3PO2 b. H3PO3 c. H3PO4 d. HPO3

3. Ethylidene chloride can be prepared by the reaction of HCl and

a. Ethane b. Ethylene c. Acetylene d. Ethylene glycol

4. Which of the following is an example of vic-dihalide?

(a) Dichloromethane (b) 1, 2-dichloroethane (c) Ethylidene chloride (d) Allyl chloride

5. Ethylidene chloride is a/an:

(a) vic-dihalide (b) gem-dihalide (c) allylic halide (d) vinylic halide

6. In the preparation of alkyl halide from alkane and halogen, which of the following

reaction is involved?

(a) Free radical substitution (b) Nucleophilic addition

(c) Electrophilic substitution (d) Nucleophilic substitution

7.. Ethylene reacts with bromine to form:

(a) Chloroethane (b) Ethylene dibromide

(c) Cyclohexane (d) 1-bromopropane

8. The alkyl halide is converted into an alcohol by:

(a) Elimination (b) Dehydrogenation

(c) Addition (d) Substitution


9. Which of the following alkyl halides is hydrolysed by SN1 mechanism ?

(a) CH3Cl (b) CH3CH2CH2Cl

(c) CH3CH2Cl (d) (CH3)3C Cl

10. The halogen atom attached to C - atom in the benzene ring is:

(a) o-directing and activating (b) p-directing and activating

(c) o, p-directing and deactivating (d) m-directing and deactivating

2 MARKS

11. Arrange each set of compounds in order of increasing boililng points.


a)Bromomethane, Bromoform, chloromethane, Dibromomethane.
b)1-Chloropropane,Isopropyl chloride,1-Chlorobutane.
12.Although chlorine is an electron withdrawing group,yet it is ortho,para directing
In electrophilic aromatic substitution reactions .Explain why it is so?
13.Give reason
a)Alkyl halides, though polar , are immiscible with water
b)Grignard reagent should be prepared under anhydrous condition.
14. Why does p-dichlorobenzene have a higher melting point than its o and m isomers ?
15 .Why is (±)_ Butan -2 –ol is optically inactive ?

3 Marks

16. Give reason;

a) C-Cl bondlength in chlorobenzene is shorter than C-Cl bond length in CH3Cl.

b) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.

c) SN1 reactions are accompanied by racemization in optically active halides.


17.Following compounds are given to you:
2-Bromo pentane, 2- Bromo 2- methyl butane ,1-Bromopentane
( i) Write the compound which is more reactive towards SN2 reaction.
(ii) Write the compound which is optically active
(iii)Write the compound which is most reactive towards ß –elimination reactions.
18.Write the reactions involved in the following
( i) Sand meyer reaction
(ii) Wurtz reaction
(iii) Wurtz Fittig reaction
19. Write the reactions involved in the following
(i) Fittig reaction
(ii)Friedel craft reaction (iii)Finkelstein reaction
20.How do you convert the following
(a)Propene to fluoro propane
(b)chloro benzene to 2- chloro toluene
(c)ethanol to propane nitrile

5 marks

a) (CH3)3 C-Br +KOH 𝑒𝑡ℎ𝑎𝑛𝑜𝑙−ℎ𝑒𝑎𝑡 →


21. Write the structure of major product in each of following reaction :

c) CH3CH2 CH2 CH2-Br + NaI 𝑎𝑐𝑒𝑡𝑜𝑛𝑒−ℎ𝑒𝑎𝑡 →


b) CH3CH=C (CH3)2 + HBr →

d) The following haloalkanes are hydrolysed in presence of aq. KOH


(i) 1 Chlorobutane
( ii) 2-Chloro-2-methylpropane
Which of the above is most likely to give racemic mixture? Justify your answer
22. How do you convert
a)Aniline to bromobenzene
b)Chlorobenzene to 2-chloroacetophenone
c)Chlorobenzene to diphenyl
d)chloropropane to iodopropane
e)2-Bromopentane to Pent-2-ene

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