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PIKE Technologies FTIR Spectroelectrochemistry

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86 views34 pages

PIKE Technologies FTIR Spectroelectrochemistry

Uploaded by

timquiler
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 34

Jackfish SEC

A complete solution for surface-sensitive


FTIR spectroelectrochemistry.
Contents

Introduction to ATR-SEIRAS 3

How It Works 4

Jackfish Electrochemical Cells 6

Choose your VeeMAX model 8

VeeMAX and Electrochemical Cells 8

Pick your ATR Elements 9

Jackfish Cell Models 11

J1 model 12

Surface-Sensitive Spectroelectrochemistry 14

J2 model 16

Which do you need? 19

J3 “EEL” model 20

The EEL In Application 22

Additional reading 23

J4 H-Cell model 24

About PIKE 28

Our Technology 28

Research and Development 28

Contact Us 29
The PIKE
Technologies
Jackfish J1 cell.

ATR-SEIRAS:
A Powerful IR
Spectroelectro-
Chemistry
Measurement
Technique

Attenuated total reflection surface


enhanced infrared absorption
spectroscopy (ATR-SEIRAS)
has emerged as an alternative
to external reflection based IR
spectroelectrochemistry, and has
been shown to be a powerful,
highly surface-sensitive tool for the
analysis of molecules present at
electrode surfaces.

The ATR-SEIRAS method has


seen increasing popularity in small
molecule electrocatalysis, and is
particularly useful for elucidating
mechanistic details concerning CO2
electroreduction.

2
Introduction to ATR-SEIRAS
Attenuated total reflectance surface enhanced infrared absorption spectroscopy (ATR-SEIRAS) is a
surface-sensitive FTIR spectroelectrochemical technique which exploits the enhanced electromagnetic
field produced by surface plasmon polaritons (SPPs) at the interface of a textured metal film.

Experimental Requirements film is carefully cycled into oxidizing potentials over


a short period. With choice of suitable electrolyte,
Metal Deposition
this can promote the formation of ordered (111)
The key to successful ATR-SEIRAS is the metal
domains, allowing spectroscopic investigation of
film working electrode. There are two ways
primarily single crystalline surfaces.
to deposit the film onto the internal reflection
element (IRE). Physical vapor deposition (PVD) Jackfish Spectroelectrochemical Cells are
methods, e.g. sputtering or thermal evaporation, miniaturized three electrode cells which are
use high-vacuum chambers and allow control compatible with a wide range of electrolyte
of rate and thickness to achieve the necessary solutions. The Teflon or PEEK bases and
nanostructure. Chemical (“electroless”) deposition glass design ensure that they can stand up
uses an aqueous solution of gold salt precursor to the rigorous cleaning procedures used by
to lay down a nanostructured gold film onto a electrochemists.
hydrogen-terminated Si surface.
Spectroscopy
After an initial conductive layer is deposited
The coupling between the incident infrared beam
chemically or by PVD, the surface can be further
and the metal surface plasmon modes is highest
modified by electrodepositing a wide variety of
near 70 degrees from the interfacial normal for
metals. A major advantage of ATR-SEIRAS over
metals deposited directly on a Si substrate. Other
SERS is that surface-enhancing films are not
working electrode films may perform better at
limited to the coinage metals. Drop-cast catalyst
lower angles. The optimal angle of incidence
inks supported on a conductive underlayer are
can be rapidly determined using the PIKE
also able to be used as a working electrode.
VeeMAX III variable-angle ATR accessory. No
other special instrumentation is needed besides a
Electrochemistry
research-quality FTIR instrument.
The cleanliness and nanostructure (and thus
enhancement factor) of the film can be improved
by an electrochemical cleaning step where the Au

3
How It Works

ATR-SEIRAS typically uses a Si internal reflection element coated with a


thin (ca. 20 nm) layer of a noble metal such as gold. Nano-islands on the
continuous metal film support surface plasmon modes, which can couple
to the evanescent wave generated in the ATR sampling geometry. While
ATR probes roughly a quarter wavelength thick volume of bulk solution near
the interface, the surface plasmon polariton (SPP) modes generated at the
metal film are highly localized to the metal-solution interface. Furthermore,
the field intensity is enhanced by up to two orders of magnitude compared
to the incident field, greatly increasing the absorption cross section of
surface molecules. These two phenomena combine to make ATR-SEIRAS a
surface-sensitive technique with submonolayer sensitivity.

By controlling the interfacial potential of the Au film using a standard three


electrode configuration, electrochemical reactions can be studied with
molecular detail. The state of the Au/solution interface can be studied
at equilibrium by static potential difference measurements or in kinetic
conditions by time-resolved methods following an applied potential step.

4
Reconditioning Ag/AgCl
wires for the user-serviceable
reference electrodes.

5
Jackfish Electrochemical Cells

The Jackfish cells enable fundamental studies of the electrified


metal-solution interface and have applications in molecular self-assembly,
interfacial sensing, and next-generation energy solutions. High-quality
IR spectra can be obtained from sub-monolayer amounts of adsorbed
molecules. By controlling the electrical potential applied to the metal thin
film electrode on the ATR crystal surface, the user can perform vibrational
characterization of potential-dependent changes at the interface.

The ease-of-use of the cells lets you hit the ground running and also
provides a flexible platform to grow as the requirements for your
spectroelectrochemical experiments change. Configurations are modular,
meaning you can upgrade and add on at any time.

Configuring your SEC is as simple as 1, 2, 3:

1. Choose your VeeMAX model.

2. Pick your ATR elements.

3. Select your Jackfish cell.

6
About Jackfish
Jackfish SEC was founded in
2018 in Saskatoon, Canada by
electrochemists at the University of
Saskatchewan. The team has spent
15 years designing, innovating and
testing spectroelectrochemical
cells for attenuated total reflectance
surface-enhanced infrared
spectroscopy (ATR-SEIRAS). Over
a decade of experiment-based
design improvements has led to
an innovative and commercially
available ATR-SEIRAS cell
design. Jackfish SEC is dedicated
to making advanced infrared
spectroelectrochemical technology
easily accessible to new users with
off-the-shelf solutions that allow you
to easily equip your laboratory with
ATR-SEIRAS capabilities.

7
Choose Your VeeMAX Model

The VeeMAX III is a continuous variable-angle FTIR sampling accessory, and may
be configured for ATR and specular measurements. The angle of incidence may be
changed by simply turning an angular selection knob located at the bottom of the
VeeMax III. For more precise angular settings, an automated model is available.

Two optical configurations are available. The standard VeeMAX III fits into the
sample compartment of most commercial FTIR instruments and is designed
for use with a focused beam. For those using a collimated beam like found
with a laser-based instrument or optical tables, the VeeMAX III – Laser model
is recommended.

VeeMAX and Electrochemical Cells


The Jackfish Spectroelectrochemical Cells (SEC) are fully compatible with the
VeeMAX III, and offer a complete solution for spectroelectrochemical experiments
via ATR-SEIRAS technique. To prepare the VeeMAX III to accept the Jackfish
requires only the VeeMAX III top plate be replaced. This may be completed in
less than a minute.

8
Pick Your ATR Elements

Jackfish cells may be configured for use with VeeMAX face angled crystal (FAC) or micromachined
Si wafers. With the mix-and-match modular design, you can configure the cell to let you conduct
measurements with either ATR element format or the wafers. Each internal reflection element (IRE)
type has its advantages, and having access to either could be beneficial.

The FAC has high energy throughput to maximized sensitivity, and is available in several materials
including ZnSe, Si and Ge and face angles (45° and 60°). These are also easily polished. The Si FAC is
especially suitable for electroless gold deposition using an optional electroless deposition fixture.

The main advantage of the wafer is the reduced optical pathlength, which minimizes the attenuation
due to Si phonon modes. The wafers are low cost and can be reused; however, they are also more
fragile. The small dimensions of the wafer (9 x 11 mm) make it easy to deposit films on multiple wafers
at a time in a PVD chamber.

Two wafer models differing in the effective angle of incidence of the beam are available. The
ATR-SEIRAS optimized wafer model has a 55° micromachined prisms to couple the beam into
the wafer, and is ideal for direct coating with a metal film. The universal wafer model has a 35°
micromachined prisms, and is ideal for coating with a hybrid metal-metal oxide film. The hybrid film
offers a robust film that can hold over multiple uses.

If you still cannot decide on your IRE element, Jackfish combination cells are available, which includes
a single set of glassware, and both bases to allow you to use either crystal option, FAC or wafers.

Jackfish model J1W/J2W. Jackfish model J1F/J2F.

9
10
Jackfish Cell Models

Four cell models are available, J1, J2, J3 and J4. All are
fully compatible with the VeeMAX III variable-angle
ATR sampling accessory.

The polyether ether ketone (PEEK) and (PTFE)


base options are highly chemical resistant, and the
glassware is ideal for a broad range of aqueous or
organic solution conditions.

Recessed spring-loaded gold pins make robust,


reliable contact with the gold-coated crystal
surface everytime.

11
J1 Model

The J1 uses ground glass joints designed for use with aqueous electrolytes and
offers a reference arm separated with a stopcock, which acts as a salt bridge
preventing migration of the reference electrode filling solution into the cell
body. There are three ports at the top of the cell and side ports for a reference
electrode arm and a short bubbler. Typical uses of the ports are to support the
counter electrode, and to accommodate glass bubblers and an exhaust gas trap.
The long glass bubbler allows sparging of the solution volume with inert gas to
remove atmospheric oxygen, enabling high-quality electrochemistry and ensuring
stability of the thin film electrode. The short gas bubbler is used to create an inert
atmosphere above the electrolyte.

The minimum cell volume for the J1 is 20 ml.

12
Long bubbler.

Counter electrode.
Exhaust gas trap.

Reference electrode.

Short
bubbler.

13
APP NOTE
Surface-Sensitive
Spectroelectrochemistry

Attenuated total reflectance surface-enhanced infrared absorption spectroscopy


(ATR-SEIRAS) provides in situ surface-sensitive IR spectra of molecules at the
electrode-solution interface. A Au thin film electrode is deposited on the reflecting
plane of the ATR optic. Excitation of surface plasmon modes in the film provides up
to 10-fold electric field enhancement at the interface, enhancing IR cross-sections
of adsorbed species up to 100-fold. Controlling the applied potential on the
film allows vibrational characterization of potential-induced changes. Such
studies reveal fundamental details of electrochemical processes and inform the
development of next generation energy and sensing solutions.

Experimental Conditions
The VeeMAX III fitted with the J1 cell was used as the FT-IR sampling accessory.
We sputtered a ca. 30 nm Au film electrode on a 60° angled Si ATR crystal. We
then cycled the potential of the film in 50 mM KClO4 supporting electrolyte
between -100 and +1100 mV vs Ag/AgCl. This cleans the film and textures the
surface to improve SEIRAS intensity. The VeeMAX III was set to 60° to match the
crystal face angle. FTIR spectra were collected at 4 cm-1 resolution, 128 scans, and
40 kHz scanning velocity using an MCT detector.

14
Results
We used the potential-dependent adsorption of 4-methoxypyridine (MOP), a
nanoparticle shape-directing ligand, as a test system. We collected a reference
spectrum of supporting electrolyte, then a sample spectrum with 0.1 mM MOP,
both at the open circuit potential. The result is shown below. We observe two
strong ring vibrations (1) and the methoxy C-O-C asymmetric stretch (2). A third
ring vibration (3) has its transition dipole moment (TDM) mostly parallel to the
electrode-solution interface when adsorbed, so (3) is very weak. Only vibrations
with their TDM normal to the interface are IR active. This confirms the surface
sensitivity of the measurement.

ATR-SEIRAS spectra of
4-methoxypyridine (MOP).

(a) MOP adsorbed at open


circuit conditions.

(b) MOP
potential difference
spectrum. Sample: +200
mV (MOP adsorbed).
Reference: -700 mV.

The figure reveals changes in interfacial composition upon potential changes.


The negative absorbance band (4) represents loss of interfacial water. This band
is absent in (a) because, at open circuit conditions, water adsorbs in a flat state
on Au, rendering the H2O bending mode inactive in SEIRAS. We see also the
characteristic MOP bands, which shows that we have potential control over the
adsorption of MOP.

Conclusion
With PIKE’s variable-angle VeeMAX III ATR accessory and J1 cell, we have
demonstrated a surface-sensitive technique which can resolve minute changes in
interfacial composition.

15
J2 Model

The J2 offers a simple sealed design compatible with volatile solvents, where
the electrodes are inserted directly into the cell in close proximity to the
working electrode, reducing the impedance to the reference electrode. With a
compression-style fitting, the J2 accepts reference and counter electrodes having
diameters between 5 and 7 mm.

The completely sealed design can be used with Schlenk techniques or in a


glovebox. J2 is compatible with aqueous and volatile solvents.

The minimum cell volume for the J2 is 10 mL.

16
Liquid example

Here is a different example that demonstrates the benefit of increased number


of reflections.

Below are spectral data for the analysis of carbohydrate content in a soft drink
sample. The red (high) spectrum was collected using a 10-reflection HATR
accessory, while the blue (low) spectrum was collected using a single-reflection
ATR. Both use an identical scaling factor.

In this case, the minor carbohydrate bands are more readily apparent in the
multi-reflection ATR
Top cap with accessory.
septum
for Schlenk technique.

Ag/AgCl reference
electrode.

Counter electrode.

Soft drink sample using 10-reflection (red, high) and 1-reflection (blue, low) ATR.

Lower side port.

17
18
Which Do You Need?

J1 Model J2 Model

All wetted components Under normal use, the wetted


are made of glass, Viton, materials are glass, Viton,
Perfluoroelastomer and PEEK/ Perfluoroelastomer and PEEK/
Materials PTFE. All components can be PTFE. The rubber septum is
rigorously cleaned according exposed to solvent vapours.
to standard electrochemistry Celcon compression caps
procedures (see footnote). cannot be acid washed.

Completely sealed cell design is


Ground glass joints designed for
Electrolyte options compatible with both aqueous
use with aqueous electrolyte.
and volatile solvents.

Jackfish offers a choice of Pt Jackfish offers a choice of Pt


or Au CE. Extra 7/15 ground or Au CE. Standard 6-mm
Counter
glass joints are supplied for diameter compression-style
electrode (CE)
users to utilize a metal wire fitting accommodates a variety
of their choice. of commercial electrodes.

Electrodes are inserted directly


Reference arm is separated
into the cell in close proximity to
with a stopcock which acts
the working electrode, reducing
as a salt bridge preventing
the impedance of the RE.
migration of RE filling solution
Reference into the cell body. A standard Ag/AgCl RE is
electrode (RE) included with each J2. The 6-mm
Jackfish offers Ag/AgCl
diameter compression-style
RE*, or the user can supply
port accommodates a variety
their own to fit in the 18 mm
of aqueous and non-aqueous
ID reference arm.
commercial electrodes.

Only possible by applying


vacuum grease to the ground
Completely sealed design
glass joints. Wetted ground glass
Air-sensitive chemistry can be used with Schlenk
joints slowly evaporate water
techniques, or in a glovebox.
to the environment and are
unsuitable for use in a glovebox.

Minimum cell volume 20 mL (including reference arm) 10 mL

Glass components can be cleaned in warm acid baths.


PTFE, Viton, Perfluoroelastomer and PEEK can be cleaned in room temperature piranha solution.
*RE is an optional add-on and is not included in standard J1 model.
Appropriate caution and safety measures must be taken when working with acid solutions.

19
J3 “EEL” Model

Combining spectroscopy, electrochemistry, and pumped flow, the J3 “EEL” flow


cell is a highly versatile research tool that enables scientists to more easily
investigate complex surface phenomena at the molecular level. In addition to the
dynamic studies that a flow cell enables, the small volume of the EEL cell (2 mL
total internal volume without electrodes installed) is advantageous for static
experiments where its flow capabilities enable rapid and efficient changing of
solutions, reducing experimental time.

In ATR-SEIRAS experiments, it is often desirable to modify the surface of the


working electrode, for example by electrodepositing a metal on the surface of a
conductive metal oxide. A flow cell enables the plating solution to be introduced,
the deposition carried out, the cell rinsed, and the analytical electrolyte to be
introduced, all without disassembling the cell and disturbing the delicate film.

20
Gas trap.

Reference electrode.

Inlet fitting. Outlet fitting.

21
APP NOTE
The EEL In Application

The most apparent use of a flow cell is for dynamic studies, in particular,
irreversible reactions where reagents must be continually introduced. ATR-SEIRAS
can provide information to help determine electrocatalytic reaction mechanisms
by providing structural information of surface species. Noteworthy applications
include CO2 electroreduction as well as electro-oxidation of small molecules such
as methanol and formic acid. Any catalyst material that can be deposited as a thin
film on the ATR internal reflection element can be studied with the EEL cell.

Above: cyclic voltammogram of 5 mM K3(Fe(CN)6), collected as the flow rate


was periodically increased. The scan rate was 50 mV/s. The EEL cell enables
electrochemistry under flow without breaking electrical contact. At low flow rates,
the resulting CV is as expected, with both reduction and oxidation peaks observed.
At high flow rates, there is a large anodic current as Fe(III) is continually supplied
to the working electrode and is reduced to Fe(II). Conversely, there is hardly any
cathodic current at these high flow rates, since the Fe(II) is flushed away before it
has a chance to be reduced.

The small volume of the cell enables high flow rates without excessive electrolyte
use. Note: the pulsed flow from the use of a peristaltic pump induces current
fluctuations which increase in frequency as the flow rate is increased.

22
Additional Reading

» Optimization of a Commercial Variable-angle Accessory for Entry Level


Users of Electrochemical Attenuated Total Reflection Surface Enhanced
Infrared Absorption Spectroscopy (ATR-SEIRAS). Applied Spectroscopy. 2019;
73(12), 1394-1402.

» Hybrid Gold−Conductive Metal Oxide Films for Attenuated Total Reflectance


Surface Enhanced Infrared Absorption Spectroscopy. ACS Applied Nano
Materials. 2019; 2, 1274.

» Electrochemical ATR-SEIRAS Using Low-Cost, Micromachined Si Wafers.


Analytical Chemistry. 2017; 89, 11818–11824.

» Surface Enhanced Infrared Studies of 4-Methoxypyridine Adsorption on Gold


Film Electrodes. Langmuir. 2016; 32, 2184-2191.

» Charge Transfer and SEIRAS Studies of 1,4-Benzoquinone Functionalized


Mixed Monothiol/Dithiol Self Assembled Monolayers. Electrochimica Acta.
2011; 56, 4361-4368.

» Surface Enhanced Infrared Absorption Spectroscopy Studies of DMAP


Adsorption on Gold Surfaces. Langmuir. 2009; 25, 2241-2247.

» Electrodeposited Gold Nanodaggers on Conductive Metal Oxide Films


Provide Substrates for Dual-Modality Surface Sensitive Vibrational
Spectroscopy. Journal of Physical Chemistry C. 2020; 124, 13356-13364.

» Microsecond Resolved Infrared Spectroelectrochemistry Using Dual


Frequency Comb IR Lasers. Analytical Chemistry. 2020; 92, 6241-6244.

» Oxygen Vacancies Alter Methanol Oxidation Pathways on NiOOH. Journal of


the American Chemical Society. 2024; 146(7), 4830-4841.

» Evaluating the ATR-SEIRAS Performance of Electrodeposited Copper CO2


Reduction Catalysts using a Flow-Through Spectroelectrochemical Cell.
Canadian Journal of Chemistry. 2024. May 7.

23
J4 H-Cell Model

H-cells enable researchers to avoid unintentional redox reactions from occurring


by controlling the electrolyte which is in contact with the counter electrode (CE)
and working electrode (WE). The electrodes are housed in separate compartments
partitioned by a semipermeable membrane so that the electrolyte in each
compartment can have a unique composition. Precursors can be selectively
introduced into the WE compartment without concern of side reactions at
the CE and products from the WE are prevented from participating in further
reactions at the CE.

A quartz window provides direct observation of the working electrode surface


and also enables the possibility of photochemical experiments. The included
low-profile magnetic stirrer may help to discriminate between active and inactive
catalyst sites by recording IR spectra when mass transport is a limiting factor and
then resuming stirring and observing spectral changes.

Multiple ports are provided to facilitate the introduction of gases to the cell and
accommodate a wide variety of experimental setups.

The J4 H-cell requires a horizontally mounted VeeMAX III model. To


provide the maximum flexibility, the Horizontal VeeMAX III includes
mounting hardware to position vertical for use with J1, J2, or J3 cells and
for other non-electrochemical applications.

24
Gas sparger.

Top cap without


ports for exhaust
gas collection.

Reference
electrode.

Counter electrode.
H-union for
semipermeable membrane.

Quartz window.

25
DID YOU
KNOW?

Electrolessly
deposited films require
scrupulously clean
surfaces, while the
cleanliness conditions
are relaxed somewhat
if a conductive metal
oxide underlayer
is used for electro-
depositing a metal film.

Electrochemical Cleaning
After deposition of gold on a Si internal reflection element (IRE), electrochemical
cleaning is required to obtain a SEIRAS active gold layer. The guidelines below
give a brief description on how to perform electrochemical cleaning and
determine the SEIRAS activity of a gold thin film using acetate adsorption.

Prepare and Purge Solutions


Use 50–100 mm acetate buffer as electrolyte with a pH range between 3.6 and 5.6.
Choose a solution acidity similar to the experimental conditions that will be used
after completing the cleaning procedure. Using an inert gas, purge the electrolyte
for at least 30 minutes using a rate of ~1–2 bubbles/second.

Cyclic Voltammetry for Electrochemical Cleaning of Gold Electrode


Measure the open circuit potential (OCP).

Cyclic voltammetry (CV) parameters:

» Starting potential: OCP


» Potential window: ±200 mV from the OCP
» Scan rate: 20 mV/sec

Complete three cycles at this potential window, increase the positive limit by 100
mV and perform an additional three cycles. When the positive limit has reached
+600 mV (vs Ag/AgCl) start monitoring the IR activity of adsorbed acetate
following the steps outlined here.

IMPORTANT: Ensure not to enter hydrogen evolution as this will be detrimental


to the gold film.

26
IR Monitoring of Acetate Adsorption during Cleaning
The symmetric COO- stretching of acetate adsorbed on gold is observed at 1400 cm-1. The
potential dependence of acetate adsorption/desorption on the gold surface is an indication
of the SEIRAS activity of the gold layer. Use the following method during the electrochemical
cleaning procedure.1

Start monitoring acetate adsorption/desorption as the positive potential limit extends beyond
+600 mV (vs Ag/AgCl). After three cycles at each potential window hold the potential at -100
mV (vs Ag/AgCl) for reference potential and +600 mV (vs Ag/AgCl) for sample potential.
Measure an IR spectrum at each of the sample and reference potentials. Monitor COO-
stretching vibration at 1400 cm-1 and continue the electrochemical cleaning.

Figure 1. (a) Typical CV of gold electrochemical cleaning using acetate buffer,100 mM acetate at pH 3.6
and 20 mV/sec scan rate and Ag/AgCl reference electrode. (b) Potential dependence of symmetric COO-
stretching of adsorbed acetate on clean gold surface after electrochemical cleaning procedure. Absorbance
spectrum for 630 mV, 430 mV, 230 mV, and 30 mV (vs Ag/AgCl) all referenced to -100 mV (vs Ag/AgCl).

This is a delicate balance to determine the appropriate amount of electrochemical cleaning.


Monitor the COO- stretching vibration with each potential window increase and continue the
cleaning procedure until the COO- band reaches a maximum. If the acetate signal remains
steady and SEIRAS signal is undesirably low, two methods of cleaning can be used: prolonged
cycles in the current potential window or extending the window further into gold oxidation.
Closely monitor the potential-dependant acetate adsorption every 3–5 cycles with both
methods. A decrease in acetate absorbance is an indication of film failure. Additional cycling
typically will not improve the signal after a decrease.

When gold oxidation and reduction is reached in the CV, increase the potential limits by 50
mV increments. Gold oxidation typically starts at about +1.0 V (vs Ag/AgCl). Refer to Figure 1
for a typical CV of electrochemical cleaning of gold on Si IRE and the potential dependence of
COO- stretching at 1400 cm-1 on a clean gold surface.

1
Delgado, J. M.; Orts, J. M.; Pérez, J. M.; Rodes, A. Journal of Electroanalytical Chemistry 2008, 617, 130.

27
Contact Us
As you review our catalog, know that our team is always available to help
you choose the best accessory for your application and answer any technical
questions you may have.

To place an order
Please include the following information when placing an order: your name, phone
number, product part number, quantity, ship to address, bill to address, purchase
order number and spectrometer model on which the accessory will be used.

Orders may be placed via mail, phone, and e-mail:

608-274-2721 PIKE Technologies, Inc.


[email protected] 6125 Cottonwood Drive
www.piketech.com Madison, WI 53719

28
About PIKE

In 1989, Phil and Irene Brierley had a dream. They envisioned an enterprise that
would specialize in imaginative design and manufacture of custom spectroscopic
accessories. They wanted to integrate new technology that would make the life of
a spectroscopist easier and more efficient—all at an outstanding value. Together,
Phil and Irene founded PIKE Technologies.

Throughout the years, Phil and his team created a comprehensive line of sampling
accessories. Phil passed away in 1999, but his legacy lives on.

Our Technology
AT PIKE Technologies, we manufacture a wide range of spectroscopic accessories
and sampling solutions:

» Attenuated total reflectance (ATR)


» Diffuse reflectance
» Specular reflectance
» Integrating spheres
» Polarization
» IR microscope and objectives
» Beam condensers
» Remote sensing
» Transmission

» Heating and Automation: Many of our products include heating and


automation options to further enhance productivity. Our proprietary software,
AutoPRO and TempPRO, will make your routine measurements easy,
consistent and reliable.

Research and Development


We also offer design and consulting services for development of specialized and
custom products for a wide range of spectroscopy applications.

Contact us for more information.

We look forward to serving you.

- Team PIKE

29
Notes

30
Notes

31
© PIKE Technologies, Inc.
6125 Cottonwood Drive,
Madison WI 53719
608.274.2721
[email protected]
www.piketech.com

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