Target:2024-2025/01112024

CHEMISTRY (PRACTICE TEST)

1 Find the name of the hydrate isomer of 6 Which of the following are the limitation of
CrCl3.6H2O, which is having lowest electrical valence bond theory :
conductivity excluding zero value of conductivity. (1) It does not distinguish between weak and
(1) Hexaaquachromium(III) chloride strong ligands.
(2) Tetraaquadichloridochromium(III) (2) It does not give quantitative interpretation of
chloride dihydrate magnetic data.
(3) Pentaaquachloridochromium(III) (3) It does not explain the colour exhibited by
chloride monohydrate coordination compounds.
(4) Triaquatrichloridochromium(III) (4) All of these
chloride trihydrate 7 The Effective atomic number of Cr in Cr(CO)6 is
2 Hexafluorocobaltate(III) ion is found to be high (1) 36 (2) 38 (3) 28 (4) 54
spin complex, the probable hybrid state of cobalt in
it, is – 8 Of the following complex ions, which is
diamagnetic in nature?
(1) dsp2 (2) d2sp3
(1) [NiCl4]2 – (2) [Ni(CN)4]
(3) sp3d2 (4) sp3d
(3) [CuCl4]2 – (4) [CoF6]3 –
3 Which of the following facts about the complex
[Cr(NH3)6]Br3 is wrong :- 9 One mole of the complex compound Co(NH3)5Cl3,
gives 3 moles of ions on dissolution in water. One
(1) The complex involves d2sp3 hybridisation and mole of the same complex reacts with two moles of
is octaheadral in shape. AgNO3 solution to yield two moles of AgCl (s).
(2) The Complex is Paramagnetic The structure of the complex is
(3) The complex is an outer orbital complex. (1) [Co(NH3)3Cl3]. 2 NH3
(4) The complex gives pale yellow ppt with (2) [Co(NH3)4Cl2] Cl.NH3
AgNO3 solution (3) [Co(NH3)4Cl] Cl2. NH3
4 Which of the following cyano complexes would (4) [Co(NH3)5Cl] Cl2
exhibit lowest paramagnetic behaviour :
10 PtCl4.4NH3 is actually :
(1) [Co(CN)6]-3 (2) [Fe(CN)6]-3
(1) [Pt(NH3)2Cl4].2NH3
(3) [Mn(CN)6]-3 (4) [Cr(CN)6]-3
(2) [Pt(NH3)3Cl3]Cl.3NH3
5 Which of the following complex is an outer orbital
complex and exhibit paramagnetic behaviour : (3) [Pt(NH3)4Cl2]Cl2
(1) [Ni(NH3)6]+2 (2) [Zn(NH3)6]+2 (4) [Pt(NH3)Cl3]Cl.3NH3
(3) [Cr(NH3)6]+3 (4) [Co(NH3)6]+3 11 How many ions are produced from [Co(NH3)6]Cl3
in the solution ?
(1) 3 (2) 4 (3) 5 (4) 6

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12 Which of the following cannot act as electrolyte ? 17 The molecular formula of various hexacoordinate
(1) CoCl3 • 6NH3 complexes are given as below.
(1) CrCl3.6NH3
(2) CoCl3 • 5NH3 (2) CrCl3.5NH3
(3) CoCI3 • 4NH3 (3) CrCl3.4NH3
If the number of NH3 ligands attached to central metal
(4) CoCl3 • 3NH3
ion respectively are 6, 5 and 4, then the primary
13 In Ziesses salt C = C bond length is : valencies in (1), (2) and (3) respectively are :
Note :
(1) 3, 3, 3 (2) 0, 1, 2
(3) 3, 2, 1 (4) 6, 5, 4
18 Point out the correct statements amongst the
following
(1) 1.37Å (2) 1.19Å
(1) [Cu(CN)4]3 – has tetrahedral geometry and
(3) 1.87Å (4) 1.34 Å dsp2 hybridization
14 Which one of the following is an outer orbital (2) [Ni(CN)6]4 – is octahedral and Ni has d2sp3
complex and exhibits paramagnetic behaviour ? hybridization
(1) [Ni(NH3)6]2+ (2) [Zn(NH3)6]2+ (3) [ZnBr4]2 – is tetrahedral and diamagnetic
(3) [Cr(NH3)6]3+ (4) [Co(NH3)6]3+ (4) [Cr(NH3)6]3+ has octahedral geometry and
15 Increasing value of magnetic moments of : sp3d2 hybridization
(I) [Fe(CN)6]4 – (II) [Fe(CN)6]3 – 19 Which of the following pair the EAN of central
(III) [Cr(NH3)6]3+ (IV) [Ni(H2O)4]2+ is : metal atom is not same ?
(1) I < II < III < IV (1) [Fe(CN)6]3 – and [Fe(NH3)6]3+
(2) IV < III < II < I (2) [Cr(N3)6]3+ and [Cr(CN)6]3 –
(3) II < III < I < IV (3) [FeF6]3 – and [Fe(CN)6]3 –
(4) I < II < IV < III (4) [Ni(CO)4] and [Ni(CN)4]2 –
16 A, B and C are possible complexes of 20 The common features among the species CN – , CO
CoCl3.6H2O A shows maximum electrical and NO+ are :
conductance and C has maximum percentage of
(1) bond order three and diamagnetic
nonionisable Cl – . Then incorrect statement is :
(2) bond order three and weak field ligands
(1) No weight loss, when A is treated with conc.
H2SO4 (3) paramagnetic and strong field ligands
(2) Order of number of moles of AgCl ppt on (4) paramagnetic and π -acceptor lagands
adding excess AgNO3 solution is A > B > C 21 Which is inner orbital complex?
(3) Complex C is [Co(H2O)3Cl3].3H2O (1) [MnCl6]3 – (2) [FeF6]3 –
(4) Complex B is [Co(H2O)5Cl]Cl2.H2O (3) [CoF6] – 3 (4) [Co(C2O4)3]3 –

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22 The d electron configurations of Cr2+, Mn2+, 29 Complex :
Fe2+ and Ni2+ are 3d4, 3d5, 3d6 and
3d8 respectively. Which one of the following aqua Charge of Co is
complexes will exhibit the minimum paramagnetic (1) +2 (2) +3 (3) +1 (4) +4
behaviour? 30 The bond length of C—O bond in carbon monoxide
(At. No. Cr = 24, Mn = 25, Fe = 26, Ni = 28) is 1.128 Å. The C—O bond in Fe(CO)5 is
(1) [Fe(H2O)6]2+ (2) [Ni(H2O)6]2+ (1) 1.158 Å (2) 1.128 Å
2+ 2+
(3) [Cr(H2O)6] (4) [Mn(H2O)6] (3) 3.28 Å (4) 1.118 Å
23 Complex have diamagnetic behaviour :- 31 Which is wrong statement about CoCl3.5NH3?
–2
(1) [Cu(NH3)4]SO4 (2) [PtCl4] (1) It is cationic complex
(3) [Ni(H2O)6 ]+2 (4) [Ni(NH3)6 ]+2 (2) It is homoleptic complex
24 Hybridisation of [Co(H2O)6 ]3+ is (3) Reacts with AgNO3 to give two mole of AgCl
(1) d2sp3 (2) sp3d2 (4) One Cl – satisfy, primary as well as secondary
(3) d3s (4) dsp2 valency
25 A magnetic moment of 2.83 will be shown by : 32 The solubility of AgBr will be minimum in :-
(1) [Ni(H2O)6]+2 (2) [Cr(CN)6]+2 (1) pure water (2) 0.2 M NaCl
(3) [Ni(CN)4] – 2 (4) 1 & 2 (3) 0.1 M NH3 (4) 0.2 M NaBr
26 The geometry and magnetic behaviour of the 33 Total vapour pressure of mixture of 1 mol A(P0A =
complex [Ni(CO)4] are 150 torr) and 2 mol B(P0B = 240 torr) is 200 torr. In
(1) Square planar geometry and diamagnetic this case :-

(2) Tetrahedral geometry and diamagnetic (1) there is positive deviation from Raoult's law

(3) Tetrahedral geometry and paramagnetic (2) there is negative deviation from Raoult's law

(4) Square planar geometry and paramagnetic (3) there is no deviation from Raoult's law

27 Which of the following is paramagnetic? (4) none of these

(1) [Fe(CN)6]4- (2) [Ni(CO)4]2+ 34 Not considering the electron spin, the degeneracy
of first excited state (n = 2) of H-atom is :-
(3) [Ni(CO)4]2+ (4) [CoF6]3-
(1) 2 (2) 3 (3) 4 (4) 8
28 The value of the ‘spin only’ magnetic moment for
one of the following configurations is 2.84 BM. 35 Which of the following relationships is not correct?
The correct one is (1) Δ H = Δ E + Δ ngRT
(1) d5 (in strong ligand field) (2) Δ Hsub = Δ Hfusion + Δ Hvap
(2) d3 (in weak as well as in strong fields) (3) Δ Hr° = Σ H°f(reactants) – Σ H°f(products)
(3) d4 (in weak ligand fields) (4) Δ Hr° = Σ B.E. of reactants – Σ B.E. of
(4) d4 (in strong ligand fields) product

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36 Using the data given below find out the strongest 42 The correct order of bond order :-
reducing agent. (1) SO42 – < CO32 – < ClO4 – < PO43 –
(2) PO43 – < CO32 – < SO42 – < ClO4 –

(1) Cl – (2) Cr (3) CO32 – < PO43 – < SO42 – < ClO42 –

(3) Cr3+ (4) Mn2+ (4) ClO4 – < PO43 – < CO32 – < SO42 –

37 What is the maximum number of electrons in an 43 Choose the correct code of characteristic for the
given order of hybrid orbitals of same atom :-
atom that can have the quantum number n = 3 and
sp < sp2 < sp3
ℓ = 2 :-
(i) Electronegativity
(1) 2 (2) 5 (ii) Bond angle between same hybrid orbitals
(3) 6 (4) 10 (iii) Size
(iv) Energy level
38 For the manufacture of ammonia by the
reaction; N2 + 3H2 2NH3 + 2.19 kcal, the (1) (ii), (iii) and (iv)
favourable conditions are :- (2) (iii), (iv)
(1) Low temperature, low pressure and catalyst (3) (ii) and (iv)
(2) Low temperature, high pressure and catalyst (4) (i), (ii), (iii) and (iv)
(3) High temperature, low pressure and catalyst 44 Sucrose is a :-
(4) High temperature, high pressure and catalyst (1) Monosaccharide
39 Law of multiple proportions is verified by which of (2) Disaccharide
the following pairs of compounds ?
(3) Trisaccharide
(1) PH3, P2O3 (2) SO2, SO3
(4) Polysaccharide
(3) CO2, NO2 (4) NH3, PH3
45
40 Octet rule is not valid for the molecule :- X Y

(1) CO2 (2) NO

The final product (Y) is :-
(3) O2 (4) PCl3
(1) (2)
41 The first ionization potentials (eV) of Be and B
respectively are :
(1) 8.29 eV, 9.32 eV (3) (4)
(2) 9.32 eV, 9.32 eV
(3) 8.29 eV, 8.29 eV
(4) 9.32 eV, 8.29 eV

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46 CH4 B C D, D in the reaction is 48
:- Product (A) is :-
(1)

(1) (2)
(2)

(3) (3) (4)

(4) CH3 – NH2 49 The compound 'P' in the reaction :-

47

(1) (2)

(3) (4)
A, product A is :-
(1) (2)
50
+ H2O
Total no. of α -H present in (P) is :-
(1) 10 (2) 3 (3) 4 (4) 8
(3)
(4)

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