AW-l765

B.Sc. Part-I (SemcEter-Vl)Examination

CHEMISTRY
Time : 'l hree lloursl lMaximum Ma'ks : 80
Note :-(l) ALL quesrioos arc compulsory.
(a Question No. 1 canies 8 marks while each of the remaining SIX questions
carries 12 marks.
(3) Draw diagrams and write equations $herever necessary.
(4) Use of scientific calculators is allowed.
l. (A) Fill in the blants :

(i) According to qualtum theory the radiations consist of packets of energy

called

(ii) The range of firyer print region is _:

(iii) 'lhe elements [hich are absolutely neccssary for life proccss in a very small
amount are called as _.
(iv) The complexes showing reaction within one minute, I M concentration and al
room temperature are called as _ complexcs. 2

(B) Choose the cofiect altemative :

(i) The intermediate formed in SN'zmechanism shows _ geomeky.

(a) Pentagonal (b) Trigonal

(c) Octahedral (d) Pentagonal bipl,ramidal
(ii) Expression for energy of a particle in one dimensional box is :

(a)
n2h? (b)
nh2
8nra2 )ma'

n1,n' 2,
nn
(c) (d) - ;
4ma lma
(iii, :\lumber of )rtMR signals in propane is .

(a) Four (b) Threc

(c) Two (d) One

(iv) Geometrical shape of Cr(CO)u moleculc is :

(a) Linear (b) Octahcdral

(c) Tetrahedral (d) Pentagonal bipyanridal

YBC-t5332 I (Contd.)
 (C) Answer i[ ONE sentonce | 4

(i) D-finc the tenrl auxoclrrome.

(ii) Whal are phosph(,nitrilic polymers ?

(iii) $'hat is Compton cffect ?

(iv) U'hal is potentiomctri( litration ?
UNI'I'_I
(a) Describe the procedure of colourimetric dctermination o: conceotration of Cu:
.l
(b) Explain SNl-dissociative mechanism of substitution in octaledral complexgs. .1

(.) Describe thc process of desccnding chromatography. 4

OR
3 (p) What is Beer-Lamberl's la\v 'l Write its mechanical exprcssron and limitations 4
(q) Dcfine labile and incrt conrplexes rvith an example of each. .l
(r) What is paper chromatography ? Write its applications. I
UNI'!'_II
4 (a) Explain the structurc of l'e (CO)r molecule on thc basis of valence bond theory 4
(b) How is phosphonitriltu chloride prepared from PCL and NH{(ll ? Give its reaction with
arnmonia. 4
(c) Explain the role of K in biological activities. 4
OR
5 (p) What is thc action of follo\ring on Ni(CO),, : (i) Halogen and (ii) H,SOI ? 4
(q) What happens $,hen (PNClr)r reacts with :
(i) Alcohol
(ii) c6H6 ? 4
(0 Discuss the role of Car* in Inetabolic activity. 4
UNIT-III
6. (a) Calculate the vibrational degrees of iieedom for the fo]lowing molecules in [R
spectroscopy :

(i) co.
(iD NHI
(iii) Uenzene
(iv) CH.. 4
(b) Explain the lbllorving electronic transitions with suitable e:(ample :

(i) r-+nt 2
n -+ o* Transition.
(ii) 2
(c) Explain the lbllouing terms $ith diagram :

(i) Scissoring
(ii) 'lwisting. 4
OR

YBC_I53]2 l (Contd.)
'1 (p) Explaio the lbllowing terms :

(i) Hypsochromic shift

(ii) Hyperchromic effect. 4

(q) Differentiate the following pairs of compounds on the basis of lR spectroscopy :

(i) acetamide and acctic acid

(ii) acetonc and cthanol. 4

(r) \ll|at t}?es of elecEonic transitions do you expect in each of the following compounds ?

(D CH.
(ii) cHr = cHr
(iii) cH3--cl
(iv) CHr-CH=o 4

IJNIT_IV
8 (a) Hor will you disting,.rish following pairs by thcir NMR spectra ?

(i) CHTCOCH, and CHICHO

(iD CH3OCHT and CllrCIIz-OII 4

tb) Calculate m/z ralue ofeach ofthc following in Mass Spcctroscopy :

(i) (cH,),cHl-
(ii) [cH] NH,l- 4

(c) Explain thc following terms *ith an cxamplc :

(i) Spin-spin coupling

(ii) Chemical shift. 4

OR
9 (p) Explain in brief the principle of mass spectroscopy. 4

(q) Write the NMR signals shown by following compounds :

(i) Ethyl bromide
(ii) I, 3-dichloropropane
(iii) Ethyl acetate

(iv) Isopropyl bromide. 4

(r) Calculate m/z values for each of the following molecular ions :

(D [C6H5{Hr]1
(iD [cHrcH, oH]r 4

YBC-15332 l (Conrd.)
 I,NIT-V
10. (a) Derive an expression for the energy ofa free particle in on: dirnensional box. l
(b) What do you understand by dual character of maltcr ? 4

(c) The eork fulction of Cs metal is 2.14 eV Calculate the kin:tic energy and the speed
of the electrons emirted when the metal is irradiated with light of wavelength
700 nm. I
OR
lr. (p) What is the physical signilicance of y and y'] 2 4
(q) What is threshold frequency l How is this frequency relate(l to the work fulction ?
4
(r) An elec&on is confined in one dimensional box of width 4.tt x 16 ro m. Calculate its
ooerg) in the fourth energ] level. 4

UNIT-VI
12. (a) Define :

(i) pKa of the weak acid

(ii) Concentration cell
(iii) Q-value
(iv) Nuclear fusion rcactions. 4
(b) How pH of the solution is determined using the hydrogen las electrode ? 4
(c) Explain the nuclear forcc on the basis of meson theory. .l
OR
13. (p) Give any four evidences in favour of Magic numbers. 4
(q) Dcriv€ an equation for EMF of concentration cell without t ansferelce. 4
(.) (i) Give any two applications of radioisotopes in industry.
(ii) Give any two adrantages of glass electode. 4

YBC t5!2 4 525