Chapter 1 Introduction 2021
Chapter 1 Introduction 2021
— Chapter 1. Introduction
Introduction
Combustion Thermodynamics Qi Fei 12
Reaction kinetics and Pollutants
Conservation Equations for Reacting Flows 6
Laminar Premixed Flame and Detonations 9
Laminar Non-premixed Flame Xi Xia 6
Droplet Evaporation and Combustion 6
Flame Dynamics and Combustion Instability 6
Discussion and Progress report 3
Working Group
Group Name
杨溢凡 廉天佑 童俊
1
Yang, Yifan Lian, Tianyou Tong, Jun
戴锦铖 王震 诸麟榆
2
Dai, Jincheng Wang, Zhen Zhu, Linyu
任勇智 石小祥 张宸
3
Ren, Yongzhi Shi, Xiaoxiang Zhang, Chen
王丹 卫思霁 邹豪
4
Wang, Dan Wei, Siji Zou, Hao
匡逊 白严 易帆
5
Kuang, Xun Bai, Yan Yi, Fan
Homework, Exam and Scores
The final scores are weighted basing on your homework, presentation
and the final report.
作业:每次课程之后会布置课后作业,小组成员一起讨论合作完成;下次上
课时每组选出一位代表,用PPT汇报该小组的作业;汇报时间8-10分
钟,讨论5分钟;所有学生都需要汇报。
References
Definition of combustion
The control of fire by early humans was a turning point in the cultural
aspect of human evolution.
Fire provided a source of warmth, protection, and a method for
cooking food.
Combustion and Civilization
Pottery Age (B.C. 6000) Bronze Age (B.C. 3000) Iron Age (B.C. 1510)
Most of energy sources comes from fossil fuels such as oil, coal, and
natural gas.
Renewable energy has been growing rapidly.
Combustion, Energy and Fuel
Status of world energy consumption
Combustion, Energy and Fuel
Utilization of Coal
boiler
electricity generation metallurgy
Combustion, Energy and Fuel
Biofuel is a fuel that is produced
through contemporary biological
processes, such as agriculture
and anaerobic (无氧的) digestion,
rather than a fuel produced by
geological processes such as
those involved in the formation
of fossil fuels, such as coal and
petroleum, from prehistoric
biological matter. Biofuels can be
derived directly from plants, or
indirectly from agricultural,
commercial, domestic, and/or
industrial wastes.
Combustion, Energy and Fuel
Energetic Fuels
Three types of energetic fuels
The gas turbines are complex machines, which are being installed in
many of today's natural-gas-fueled power plants.
The combustion produces a high temperature, high pressure gas stream
that enters and expands through the turbine section, where it expands
down to the exhaust pressure, producing a shaft work output in the
process.
Combustion and Power
Jet engine
NOx 6.406
HC 4.312
CO 3.440
PM 0.594
Total 45.709
The Great Chicago Fire was a conflagration that burned from October 8,
to October 10, 1871. The fire killed up to 300 people, destroyed roughly
3.3 square miles (9 km2) of Chicago, Illinois, and left more than 100,000
residents homeless.
Combustion and Fire Safety
Fire whirl (火旋风)
Fire is one of the classical elements with features hot and dry
The classical elements can be transformed by changing their features
Time Line of Combustion Research
Phlogiston Theory(燃素说)
1667, J. J. Becher, Germany J. J. Becher G. E. Stahl
(1635-1682) (1659-1734)
1703, G. E. Stahl, Germany
Substances contain phlogiston &
dephlogisticated air when burned
Challenges
What is the principle of phlogiston?
Why some substances gain mass when
they burned?
Why the volume of air is reduced when
combustion?
Oxidation Theory of Combustion(氧化说)
A. Lavoisier J. Priestley
1777, A. Lavoisier, France (1743-1794) (1733-1804)
D. A. Frank-Kamenetskii
(1910-1970)
Combustion Theory
Thomas Newcomen's atmospheric engine was the first commercial true steam
engine using a piston, and was used in 1712 for pumping in a mine.
Steam Engine
In 1781 James Watt patented a steam engine that produced continuous rotary
motion.
Watt's ten-horsepower engines enabled a wide range of manufacturing
machinery to be powered. The engines could be sited anywhere that water and
coal or wood fuel could be obtained.
Steam Engine
The stationary steam engine was a key component of the Industrial Revolution,
allowing factories to locate where water power was unavailable.
Internal Combustion Engine
In 1859, Lenoir developed the first internal combustion engine which burned a
mixture of coal gas and air ignited by a "jumping sparks" ignition system by
Ruhmkorff coil.
Internal Combustion Engine
Oxidizer
Flame front
Premixed flame
Mixing and then burning;
It is safe only in small scale; not used in the
industry.
Non-premixed flame
Mixing and burning simultaneously;
Safe, because the combustible mixture is
generated locally.
Flame Types
Laminar flame
The total heat production is small but large
heat production in some points.
Turbulent flame
Large fuel consumption, large total heat
production but small heat production in
each point!
The Combustion Processes
OXYGEN HEAT
FIRE
combustion
FUEL
The Combustion Processes
Ignition
piloted ignition spontaneous ignition
Formation mechanism
Thermal NO
N2 + O = NO + N
O2 + N = NO + O
N + OH = NO + H
Prompt NO
N2 + CN = NCN + H
N2 + CH2 = HCN + NH
NCN/HCN N NO
N2O mechanism
N2 + O + M = N2O + M
N2O + O = NO + NO
The Pollutant Formation Processes
PAH and soot formation
The Pollutant Formation Processes
PAH and soot formation
Thermodynamics
Chemical Kinetics
Fluid Mechanics
Heat Transfer
Mass Transfer
Physical Chemistry
………………………
Research Method
Theoretical analysis
Experimental measurement
Combustion
Numerical simulation
Experimental Measurement
Species concentration
………………………………………
Theoretical Analysis
Sep. 10-14, 1928. The First Symposium on Combustion held at the 76th Meeting
of ACS at Massachusetts .
Sep. 9-10, 1937, The Second Symposium on Combustion held at the 94th
Meeting of ACS at New York .
Sep. 7-11, 1948, The Third Symposium on Combustion at Wisconsin.
Standing Committee on Combustion Symposia
Sep. 1-5, 1952, The Fourth Symposium on Combustion at Massachusetts.
Aug. 30-Sep. 3, 1954, The Fifth Symposium on Combustion at Pennsylvania.
Aug. 19-24, 1956, The Sixth Symposium on Combustion at Connecticut. (the first
one held by The Combustion Institute)
Aug. 28-Sep. 3, 1958, The Seventh Symposium on Combustion at London and
Oxford.
…….
International Symposium on Combustion
Since 1949, in every second year
1990 23rd Symposium Orleans, France
1992 24th Symposium Sydney, Australia
1994 25th Symposium Irvine, USA
1996 26th Symposium Naples, Italy
1998 27th Symposium Boulder, USA
2000 28th Symposium Edinburgh, UK
2002 29th Symposium Sapporo, Japan
2004 30th Symposium Chicago, USA
2006 31st Symposium Heidelberg, Germany
2008 32nd Symposium Montreal, Canada
2010 33rd Symposium Beijing, China
2012 34th Symposium Warsaw, Poland
2014 35th Symposium San Francisco, USA
2016 36th Symposium Seoul, South Korea
2018 37th Symposium Dublin, Ireland
2020 38th Symposium Adelaide, Australia
Colloquia of Combustion Symposium
1. Gas-Phase Reaction Kinetics including the kinetics of hydrocarbons and
oxygenated fuels, formation of gaseous pollutants, elementary reactions,
mechanism generation, reduction and uncertainty quantification.
2. Soot, Nanomaterials, & Large Molecules including the formation, growth, and
destruction of soot, PAHs, carbon nanostructures, and other nanoscale materials.
3. Diagnostics including the development and application of diagnostic techniques
and sensors for the understanding and control of combustion and reacting flow
phenomena.
4. Laminar Flames including their ignition, structure, propagation, extinction,
stabilization, dynamics, and instabilities.
5. Turbulent Flames including their ignition, structure, propagation, extinction,
stabilization, dynamics, and instabilities.
6. Spray, Droplet, and Supercritical Combustion including atomization,
combustion of droplets, sprays, and supercritical fluids.
Colloquia of Combustion Symposium
7. Detonations, Explosions, and Supersonic Combustion including flame
acceleration, DDT, and pulse-detonation-, constant volume combustion-, and
scramjet-engines.
8. Solid Fuel Combustion including fundamental aspects related to pyrolysis,
oxidation, gasification, and ash formation from coal, biomass, and wastes, as
well as combustion of propellants and metals.
9. Fire Research including fundamental aspects of ignition, burning, spread and
suppression of fire, as well as applications to building fire and urban/wildland
fire safety.
10. Stationary Combustion Systems and Low Carbon Combustion Technologies
including combustion in stationary power generation, fluidized beds,
incineration, utility boilers, industrial applications, NOx and SOx reduction,
MILD combustion, oxy-fuel combustion, chemical looping, and CO2 capture.
Colloquia of Combustion Symposium