JEE (MAIN+ADVANCED)

JEE ADV.2022

TARGET TEST PATTERN JEE (ADVANCED)

JEE (MAIN+ADVANCED)
EXAMINATION
ADVANCED MAJOR
TARGET YEAR 2024 TEST TYPE
TEST (AMT)
PAPER NO. TWO TEST CODE &
SEQUENCE
AMT 1
PAPER CODE 1 MAX. MARKS 180

CLASS XII TEST

3 Hrs
DURATION
COURSE NAME VIJETA TEST DATE 01ST DECEMBER 2023
TEST DAY FRIDAY
COURSE CODE JP
TEST TIME Start: 02:30 PM
PHASE CODE(S) 01,02,03,05JP,JAZP,03JPAH (PAPER-2) End : 05:30 PM
TOTAL NO. OF
BATCH CODE(S) 01,02,03,05JP,JAZP,03JPAH PAGES IN PAPER 36
BOOKLET

Full Partial Marks

Type No.
Subject Marks (–)ve Total Subject
Qs. No. Section No. of of If Three If Two If One If No
Sequence Per Marks Marks Total
Qs.* Qs. Options Options Option Option
Qs.
Correct Correct Correct Chosen
1 to 04 1 MCQ 4 3 - - - 0 –1 12
05 to 07 2 MSQ 3 4 +3 +2 +1 0 –2 12
Maths 60
08 to 13 3 NVQ 6 4 - - - 0 0 24
14 to 17 4 CBQ 4 3 - - - 0 0 12
18 to 21 1 MCQ 4 3 - - - 0 –1 12
22 to 24 2 MSQ 3 4 +3 +2 +1 0 –2 12 60
Physics
25 to 30 3 NVQ 6 4 - - - 0 0 24
31 to 34 4 CBQ 4 3 - - - 0 0 12
35 to 38 1 MCQ 4 3 - - - 0 –1 12
39 to 41 2 MSQ 3 4 +3 +2 +1 0 –2 12
Chemistry 60
42 to 47 3 NVQ 6 4 - - - 0 0 24
48 to 51 4 CBQ 4 3 - - - 0 0 12

Total 51 MAXIMUM MARKS 180

A. GENERAL INSTRUCTIONS B. DARKENING THE BUBBLES ON THE ORS :
1. Use a BLACK BALL POINT to darken the
1. Darken the appropriate bubbles on the original
bubbles in the upper sheet.
by applying sufficient pressure. 2. Darken the bubble COMPLETELY.
2. The original is machine-gradable and will be 3. Darken the bubble ONLY if you are sure of the
collected by the invigilator at the end of the answer.
examination. 4. The correct way of darkening a bubble is as
3. Do not tamper with or mutilate the ORS. shown here :
5. There is NO way to erase or "un-darkened
4. Write your name, roll number and the name of
bubble.
the examination centre and sign with pen in the 6. The marking scheme given at the beginning of
space provided for this purpose on the original. each section gives details of how darkened and
Do not write any of these details anywhere not darkened bubbles are evaluated.
else. Darken the appropriate bubble under each 7. Zero marks ‘0’ If none of the options is chosen
digit of your roll number. (i.e. the question is unanswered).

C. FOR INTEGER TYPE QUESTIONS OMR LOOKS D. FOR DECIMAL TYPE QUESTIONS OMR LOOKS
LIKE: LIKE:
1. For example, if answer ‘SINGLE DIGIT’ integer 1.
type below : COLUMN
0 1 2 3 4 5 6 7 8 9 1 2 . 3 4
2. For example, if answer ‘SINGLE DIGIT’ integer 0 0 0 0
with positive / negative type below : 1 1 1 1
0 2 2 2 2
– 1
3 3 3 3
2
4 4 4 4
3
5 5 5 5
4
6 6 6 6
5
7 7 7 7
6
8 8 8 8
7
9 9 9 9
8
9 2. If answer is 3.7, then fill 3 in either 1st or 2nd
3. For example, if answer ‘DOUBLE DIGIT’ integer column and 7 in 3rd or 4th column.
type below :
0 0 0 0 0 0 0 0 0 3. If answer is 3.07 then fill 3 in 1st or 2nd column ‘0’
1 1 1 1 1 1 1 1 1 in 3rd column and 7 in 4th column.
2 2 2 2 2 2 2 2 2 If answer is, 23 then fill 2 & 3 in 1st and 2nd
3 3 3 3 3 3 3 3 3 column respectively, while you can either leave
4 4 4 4 4 4 4 4 4 column 3 & 4 or fill ‘0’ in either of them.
5 5 5 5 5 5 5 5 5
6 6 6 6 6 6 6 6 6
7 7 7 7 7 7 7 7 7
8 8 8 8 8 8 8 8 8
9 9 9 9 9 9 9 9 9

TYPE WISE CODES FOR QUESTIONS

SR# QUESTION TYPE CODE
1 MULTIPLE CHOICE QUESTION (ONLY ONE CORRECT OPTION) MCQ
2 MULTIPLE SELECT (ONE OR MORE THAN ONE CORRECT OPTIONS QUESTION) MSQ
3 NUMERICAL VALUE QUESTION NVQ
4 COMPREHENSION / PARAGRAPH BASED QUESTION CBQ
5 MATCH THE LISTING QUESTION MLQ
6 COLUMN MATCH QUESTION CMQ
7 FILL IN THE BLANKS TYPE QUESTION FBQ
8 TRUE OR FALSE TYPE QUESTION TFQ
9 ASSERTION & REASON / STATEMENT TYPE QUESTION ARQ
10 SUBJECTIVE TYPE QUESTION STQ
 MATHEMATICS
PART-I (Hkkx-I) : MATHEMATICS (xf.kr)

SECTION-1: (Maximum marks: 12)

• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
[kaM 1 : (vf/kdre vad : 12)
 bl [kaM esa pkj (04) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +3 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

1. A box has 13 distinct pairs of socks. Let pr denote the probability of having at least one matching pair
among a bunch of r socks drawn at random from the box. If r 0 is the maximum possible value of r such
that pr < 1, then the value of pro is.
,d lanqd esa 13 fofHkUu ekstks ds ;qXe gSA ekuk lanqd ls pqus x;s r ekstks ds leqg esa de ls de ,d ekstks dk ;qXe
lgh feyku gksus dh izkf;drk pr gS ;fn pr < 1, gksus ds fy, r0 , r dk vf/kdre laHko eku gS rc pro dk eku gS&
12 13 213 212
(A) 1 26
(B) 1 26
(C) 1 26
(D) 1 26
C12 C13 C13 C12

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
2. If water is poured into an inverted hollow cone whose semi-vertical angle is 30° , its depth increase at
the rate of 1 cm/s. The rate at which the volume of water increase when the depth is 24cm is equal to :
(A) 150 cm3 /s (B) 180 cm3 / s (C) 192 cm3 / s (D) 200 cm3 /s

;fn ikuh dks [kks[kys 'kadq esa mMsyk tkrk gS ftldk v)Z 'kh"k dks.k 30° gSA ;fn bldh xgjkbZ 1 [email protected] dh
nj ls c<rh gSA ?ku dk vk;ru fdl nj ls c<sxk tcfd xgjkbZ 24 ls-eh- ds cjkcj gS&
(A) 150 ls-eh-3 /lSd.M (B) 180 ls-eh-3 /lSd.M (C) 192 ls-eh-3 /lSd.M (D) 200 ls-eh-3 /lSd.M

3. A rectangle is inscribed in curve |y| = sinx, 0 < x < such that sides are parallel to coordinate axes.
Maximum area of rectangle is
   
(A) 4(sinx0)  – x 0  , 0 < x0 < , where x0 + tanx0 =
2  2 2
  
(B) 4(sinx0)  – x 0  , 0 < x0 < , where x0 + tanx0 = 
2  2
(C) 2(sinx0) ( – x0), 0 < x0 < , where x0 + tanx0 = 
  
(D) 2(sinx0)  – x 0  , 0 < x0 < , where x0 + tanx0 =
 2  2
oØ |y| = sinx, 0 < x < ds vUrxZr ,d vk;r bl izdkj gS fd bldh Hkqtk,a funsZ'kh v{kksa ds lekUrj gS] rks vk;r
dk vf/kdre {ks=kQy gS&
   
(A) 4(sinx0)  – x 0  , 0 < x0 < , tgk¡ x0 + tanx0 =
 2  2 2
  
(B) 4(sinx0)  – x 0  , 0 < x0 < , tgk¡ x0 + tanx0 = 
2  2
(C) 2(sinx0) ( – x0), 0 < x0 < , tgk¡ x0 + tanx0 = 
  
(D) 2(sinx0)  – x 0  , 0 < x0 < , tgk¡ x0 + tanx0 =
 2  2

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
4. If |z| = 1, and if maximum and minimum values of | z  cos   i sin |  | z  cos   i sin | are M &
m then the value of M  m equals
 2

;fn |z| = 1 rFkk ;fn | z  cos   i sin |  | z  cos   i sin | dk vf/kdre o U;wure eku Øe'k% M rFkk
m gS rc M  m cjkcj gS&
 2

(A) 3 (B) 4 (C) 5 (D) 6

SECTION-2: (Maximum marks: 12)

• This section contains THREE (03) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s)
is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
[kaM 2 : (vf/kdre vad : 12)
 bl [kaM esa rhu (03) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
5. Let S = {1,2,...,n}. For any non-empty subset A of S, let l(A) denote the largest number in A.
If f(n) =  A S
IA  , that is. f(n) is the sum of the numbers l(A) while A ranges over all nonempty

subsets of S. then
(A) f(10) = f(9) + 3.211 (B) f(n) = 2n (n + 1) –1
(C) f(10) = f(9) + 3.210 (D) f(n) = 2n (n –1) +1
ekuk S = {1,2,...,n} gSA leqPp; S ds vfjDr mileqPp; A esa mifLFkr vf/kdre vo;oksa dh la[;k (A) ls iznf'kZr
gS ;fn f(n) ASIA  , vFkkZr f(n) , l(A) ds ;ksx Qy dks iznf'kZr djrk gS] tgk¡ A, S ds vfjDr leqPp; gS
rc f(n) gS&
(A) f(10) = f(9) + 3.211 (B) f(n) = 2n (n + 1) –1
(C) f(10) = f(9) + 3.210 (D) f(n) = 2n (n –1) +1

n  n   n  1
6. Let n Cr    . The product   ·  is a perfect square then
r  10   10 
(A) number of integer values of n is 1
(B) number of integer values of n is 2
(C) n can be 17
(D) n is a prime number
n  n   n  1
ekuk n Cr    gSA ;fn   ·  iw.kZ oxZ gS rc&
  r  10   10 
(A) n ds iw.kkZad ekuksa dh la[;k 1 gSA
(B) n ds iw.kkZad ekuksa dh la[;k 2 gSA
(C) n dk eku 17 gks ldrk gSA
(D) n vHkkT; la[;k gSA
Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
  2[x]  
7. If f(x) = cos1  sgn    , where sgn ( ) denotes the signum function and [ . ] denotes the greatest

  3x  [x]  
integer function, then which of the following is/are CORRECT ?
(A) lim f(x) = 0 (B) lim– f(x) = 0
x 1 x 1

(C) f(x) is derivable at x = – 1 (D) f(x) is derivable at x = 1

  2[x]  
;fn f(x) = cos1  sgn    , tgk¡ sgn ( ) flxue Qyu rFkk [ . ] egÙke iw.kk±d Qyu dks iznf'kZr djrk gS]
  3x  [x]  
rks fuEu esa ls dkSulk@dkSuls lgh gS?
(A) lim f(x) = 0 (B) lim– f(x) = 0
x 1 x 1

(C) f(x), x = – 1 ij vodyuh; gSA (D) f(x), x = 1 ij vodyuh; gSA

SECTION-3: (Maximum marks: 24)

• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if the correct numerical value is entered;
Zero Marks : 0 In all other cases.
[kaM 3 : (vf/kdre vad : 24)
 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u dk mÙkj xSj&_.kkRed iw.kkZad (NON-NEGATIVE INTEGER) gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
8. Let a, b, c be different nonzero real numbers and x,y,z be three numbers satisfying the system of
equations
x y z
+ + =1
a a –1 a 1
x y z
+ + =1
b b –1 b 1
x y z
+ + =1
c c –1 c 1
xyz
Then the value of is.
abc
ekuk a, b, c rhu v'kwU; fHkUu-fHkUu okLrfod la[;k,¡ gS rFkk x, y, z rhu la[;k,¡ tks lehdj.kksa ds fudk;
x y z
+ + =1
a a –1 a 1
x y z
+ + =1
b b –1 b 1
x y z
+ + =1
c c –1 c 1
xyz
rc dk eku gS
abc

9. Let A is a non – zero matrix of order ‘2’ such that A + adj A = A–1 then determinant of (2A–1) is equal to
ekuk A, ‘2’ Øe dk v'kwU; vkO;wg gS tcfd A + adj A = A–1 rc (2A–1) dk lkjf.kd eku gS -

10. Number of integral values of ‘a’ such that the quadratic equation x 2 + ax+ a + 1 = 0 has integral roots is
a ds iw.kk±d ekuksa dh la[;k gksxh tcfd f}?kkr lehdj.k x2 + ax+ a + 1 = 0 ds iw.kk±d ewy gS&

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
11. The general solution of the differential equation (x 2 + y2)dx = 2xy dy is
k|(xm – by2)| = |x|, where k is arbitrary constant. The value of (m + b)3 is
vody lehdj.k (x2 + y2)dx = 2xy dy dk O;kid gy k|(xm – by2)| = |x|, tgk¡ k LosPN vpj gS] (m + b)3 dk eku gS&

p
12. If the area  of a triangle ABC is given by   a2  (b  c)2 then tan (A/2) is equal to then least value
q
of p +q is equal to –
p
;fn f=kHkqt ABC dk {ks=kQy  gS] tks   a2  (b  c)2 gS rc tan(A/2) dk eku gS rc p +q a+dk U;wure eku gS-
q

The least prime value of n for which the inequality   C6  nC4    C5  nC5 does not holds is
n 1 n 2
13.

n dk U;wure vHkkT; eku gksxk tcfd vlfedk n  1 C6  nC4  n  2 C5  nC5 larq"B ugh gksrk gS -

SECTION-4: (Maximum marks: 12)

• This section contains TWO (02) question paragraphs.
• Based on each paragraph, there are TWO (02) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
[kaM 4 : (vf/kdre vad : 12)
 bl [kaM esa nks (02) vuqPNsn gSaA
 izR;sd vuqPNsn ij vk/kkfjr nks (02) iz'u gSSA
 izR;sd ç'u dk mÙkj ,d la[;kRed eku (NUMERICAL VALUE) gSSA
 ;fn la[;kRed eku eas nks ls vf/kd n'keyo LFkku gS] rks eku dks nks (02) n'keyo LFkkuksa rd lesVsa@'kwU;kar
(TRUNCATE/ROUND-OFF) djsaA
 izR;sd iz'u ds mÙkj dk ewY;kadu fuEu ;kstuk ds vuqlkj gksxk %
 iw.kZ vad % +3 ;fn fufnZ"V LFkku ij dsoy lgh la[;kRed eku çfo"V fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;kasa esa

Paragraph for Question Nos. 14 to 15

iz'u 14 ls 15 ds fy, vuqPNsn
  
Let r be position vector of a variable point in xy-plane such that r .(10 ĵ – 8 î – r ) = 40 and
 
M = max. (| r + 2 î – 3 ĵ |2) and m = min.( | r + 2 î – 3 ĵ |2)
  
ekuk r , xy-lery esa pj fcUnq dk fLFkfr lfn'k gS bl izdkj gS fd r .(10 ĵ – 8 î – r ) = 40 rFkk
 
M = max. (| r + 2 î – 3 ĵ |2) vkSj m = min.( | r + 2 î – 3 ĵ |2)

14. mM is equal to
mM cjkcj gS -

15. M + m is equal to
M + m cjkcj gS -

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 MATHEMATICS
Paragraph for Question Nos. 16 to 17
iz'u 16 ls 17 ds fy, vuqPNsn

/2
f(x) satisfies the relation f(x) – 
 sin x cos t f(t)dt  sin x
0
/2
ekuk f(x) lEcU/k f(x) –   sin x cos t f(t)dt  sin x dks lUrq"V djrk gSA
0

16. If f(x) = 2 has atleast one real root, then number of integral value of is
;fn f(x) = 2 ds de ls de ,d okLrfod gy fo|eku gS] rks ds iw.kkZd ekuksa dh la[;k gS&

/2
17. If
 f(x)dx  3 , then the value of 6 is
0

/2
;fn  f(x)dx  3 , rc 6 dk eku gS&
0

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
PART-II (Hkkx-II) : PHYSICS (HkkSfrd foKku)
SECTION-1: (Maximum marks: 12)
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
[kaM 1 : (vf/kdre vad : 12)
 bl [kaM esa pkj (04) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +3 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

18. Which of the following combinations should be selected for better tuning of an L-C-R circuit used for
communication? (That means whose quality factor will be the largest?)
lapkj gsrq fdlh L-C-R ifjiFk ds csgrj leLoj.k (V;wfuax) ds fy, fuEUkfyf[kr esa ls dkSu&Lkk la;kstu mi;qä
gksxk \ ¼vFkkZr~ fdl ifjiFk dk quality factor lcls T;knk gksxk \ ½
(A) R = 25 , L = 1.5 H, C = 45 F (B) R = 20 , L = 1.5 H, C = 35 F
(C) R = 25 , L = 2.5 H, C = 45 F (D) R = 15 , L = 3.5 H, C = 30 F

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
19. In a nonconducting sphere of large radius, charge density varies with radial distance (r) as (r) = 0 r
where o = constant.
Now two electrons are embedded in the sphere, in such a way that net electrostatic force on each of
them is zero. Then what should be distance between them? (Assume that introduction of electrons
does not alter the charge distribution of the sphere)
cM+h f=kT;k ds ,d vpkyd xksys esa] vkos'k ?kuRo f=kT; nwjh (r) ds lkFk (r) = 0 r ds vuqlkj ifjofrZr gksrk gS]
tgkW o = fu;r gSA vc xksys ds vUnj nks bysDVªkWu bl izdkj j[ks tkrs gS] fd izR;sd ij dqy fLFkj oS|qr cy 'kwU;
gksrk gSA rc muds e/; nwjh D;k gksuh pkfg, \ (ekfu;s fd bysDVªkWu ds j[kus ls xksys dk vkos'k forj.k ifjofrZr
ugha gksrk gSA)
1/ 4 1/ 4 1/ 3 1/ 4
 e   e   e   e 
(A)   (B) 2   (C) 2   (D) 4 
 40   40   40   40 

20. A body of mass m moving with velocity V makes a head-on elastic collision with another body of mass
2m which is initially at rest. The ratio of kinetic energies of lighter body before and after collision will be -
,d m nzO;eku dh oLrq v osx ls xfr djrh gqbZ 2m nzO;eku dh fLFkj oLrq ls lEeq[k izR;kLFk Vdjkrh gS rks gYdh
oLrq dh xfrt ÅtkZ dk VDdj ls iwoZ rFkk VDdj ds i'pkr~ vuqikr gS&
(A) 9 : 1 (B) 1 : 1 (C) 4 : 1 (D) 2 : 1

21. Two Carnot heat engines are connected in series such that the sink of the first engine is heat source of
the second. Efficiency of the engines are 1 and 2 respectively. Net efficiency  of the combination is
given by :
nks dkuksZa batu dks bl izdkj tksM+k x;k gS fd izFke batu dk flad nwljs batu ds fy, Å"ek ds L=kksr dh rjg dk;Z
dj jgk gSA ;fn nksuksa dkuks± batu dh n{krk Øe'k% 1 vkSj 2 gks rks bl la;kstu dh rqY; n{krk  gksxh &
12
(A)  = 1 + 2 (B)  =
1  2
(C)  = 1 + 2 (1 – 1) (D)  = 1 – 2 (1 – 1)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
SECTION-2: (Maximum marks: 12)
• This section contains THREE (03) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.
[kaM 2 : (vf/kdre vad : 12)
 bl [kaM esa rhu (03) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqSpace
us gq, fodYi lgh fodYi
for Rough Work /gS(aAdPps dk;Z ds fy, LFkku)
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

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 PHYSICS
22. The figure shows a plot of binding energy per nucleon (B.E/A) vs mass number (A) for nuclei. Four
nuclei, P, Q, R and S are indicated on the curve. The process which is endothermic is:
;gk¡ ukfHkdksa ds fy;s 'izfr U;wfDyvkWu ca/ku ÅtkZ' (B.E/A) rFkk 'nzO;eku la[;k' (A) ds chp xzkQ n'kkZ;k x;k gS] bl
ij pkj ukfHkdksa P, Q, R vkSj S dks vafdr fd;k x;k gSA fuEukafdr esa ls dkSulh vfHkfØ;k m"ek'kks"kh gksxh\

(A) R  2S (B) P  Q + S (C) P  2R (D) Q  R + S

23. A nucleus X whose mass number is 36, is initially at rest. It is dis-integrated into  particle and a
daughter nucleus Y. If no -emission is there, then chose the correct alternative.
(A) De-Broglie wavelength of  particle and the daughter nucleus Y are equal.
(B)Kinetic energy of -particle is 8 times that of nucleus Y.
(C) Speed of  particle is 8 times that of nucleus Y.
(D) The nuclear radius of the daughter nucleus Y is 2 times that of -particle.
,d ukfHkd X ftldh æO;eku la[;k 36 gS] ;g çkjEHk esa fojkekoLFkk esaA ;g  d.k vkSj iq=kh ukfHkd Y ds :i esa
fo[kf.Mr gksrk gSA ;fn bl çfØ;k esa - mRltZu u gks rks lR; dFku pqfu;sA
(A)  d.k vkSj iq=kh ukfHkd Y ds fM&czksXyh rjaxnS/;Z leku gksasxsA
(B) -d.k dh xfrt ÅtkZ ukfHkd Y dh rqyuk esas 8 xquk gksxhA
(C) -d.k dh pky ukfHkd Y dh rqyuk esas 8 xquk gksxhA
(D) ukfHkd Y dh ukfHkdh; f=kT;kd.k dh rqyuk esas 2 xquk gksxhA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
24. An object of mass m is moving along X-axis, under conservative forces, whose potential energy varies
Kx
with X co-ordinate as U(x) = 2 where k and a are positive constants. Initially the object is at its stable
x  a2
equilibrium position and it is given an initial velocity of uiˆ . The potential energy curve is shown below. Choose
the correct alternative(s)
2K
(A) For the object to reach x  + , the value of u should be greater then
ma
K
(B) For the object to reach x  – , the value of u should be anything greater then
ma
 K 2K 
(C) For the object to reach x  – , the value of u should between u  ,
 ma ma 
K
(D) The total energy required so that the object can lie any where from – to +should be greater then
2a
U
–a x
+a

m nzO;eku dh ,d oLrq dsoy laj{kh cy ds vUrxZr X&v{k ds vuqfn'k xfr dj jgha gS ftldh fLFkfrt ÅtkZ dsoy x
Kx
funsZ'kkad ds lkFk U(x) = ds vuqlkj ifjofrZr gksrh gS] tgk¡ k rFkk a /kukRed fu;rkad gSA izkjEHk esa oLrq bldh
x  a2
2

LFkk;h lkE;koLFkk dh fLFkfr esa gS rFkk bls uiˆ izkjfEHkd osx fn;k x;k gSA fLFkfrt ÅtkZ oØ fp=k esa n'kkZ;k x;k gSA lgh
fodYi@fodYiksa dk p;u dhft,A
2K
(A) oLrq ds x  + rd ig¡qpus ds fy,, u dk eku ls vf/kd gksuk pkfg,A
ma
K
(B) oLrq ds x  –  rd igq¡pus ds fy,, u dk eku ls vf/kd dqN Hkh gksuk pkfg,A
ma
Space for Rough Work / (dPps K dk;Z2Kds fy, LFkku)
(C) oLrq ds x  – rd igq¡pus ds fy,, u dk eku u  ,  ds e/; gksuk pkfg,A
 ma ma 
K
(D) vko';d dqy ÅtkZ ftlls oLrq – ls + ds e/; dgh Hkh fLFkr gks lds] ls vf/kd gksuk pkfg,A
2a

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
SECTION-3: (Maximum marks: 24)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if the correct numerical value is entered;
Zero Marks : 0 In all other cases.
[kaM 3 : (vf/kdre vad : 24)
 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u dk mÙkj xSj&_.kkRed iw.kkZad (NON-NEGATIVE INTEGER) gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A

25. A lift is accelerating up with acceleration g/2 as shown in the figure. Find reading of the spring balance
(in Kgf) present in the lift. (g = 10 m/s2)
fp=kkuqlkj ,d fYk¶V g/2 Roj.k ls mij dh vksj Rofjr gks jgh gSA rks dekuhnkj rqyk dk ikB~;kad (in Kgf) Kkr
djksaA (g = 10 m/s2)
Lift a=g/2

6kg

12kg

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
26. On a plane mirror , a thin eqi-convex lens is placed whose refractive index is 1.5 and radius curvature
4
of both the surfaces are 10 cm. Water of reflective index is filled between the gap of the lens and the
3
mirror. At which height(in cm.) from the system should we place a needle, so that its image is formed on
its self?
lery niZ.k ij ,d iryk mHk;ksÙky ysal j[kk x;k gS] ftldk viorZukad 1.5 gS] vkSj ftldh nksuksa lrgksa dh
4
oØrk f=kT;k 10 cm gSA ysal vkSj niZ.k ds chp ds LFkku esa ikuh Hkjk tkrk gS] ftldk viorZukad gSA ,d lwbZ
3
dks fudk; ls fdruh Å¡pkbZ (in cm.) ij j[ks rkfd bldk vafre izfrfcEc mlh Å¡pkbZ ij cus \
Object pin

\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\

27. In the L–C circuit, the capacitor C1 is charged to a potential of 1 volt, and the capacitor C 2 and the
1.5 
inductor were initially uncharged. Now switch S1 is closed at t = 0, and at t = sec. switch S2 is
100
0.5 
closed and S1 is opened. After sec. , S2 is also opened. Find final potential difference across the
100
capacitor C2 in volt.
L–C ifjiFk esa, la/kkfj=k C1 dks 1 oksYV foHko rd vkosf'kr fd;k x;k o la/kkfj=k C2 rFkk çsjdRo çkjEHk esa vukosf'kr
1.5 
gSA vc le; t = 0 ij dqath S1 lEifdZr dh xbZ gS rFkk t = sec. ij dqath S2 lEifdZr o S1 vlEifdZr dh
100
0.5 
xbZ gSA sec. i'pkr~, S2 Hkh vlEifdZr dh xbZ gSA la/kkfj=k C2 ij foHkokUrj oksYV esa Kkr dhft,A
100

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
28. A small solid spherical ball is released from the top of a quarter circular surface of radius 7m. The ball rolls
without sliding on the surface, and then separates from the surface. At which horizontal distance (in meters)
from the edge of the surface will the sphere strike the ground ? (Neglect air friction, g = 10 m/s2)
,d NksVh Bksl xksykdkj xsan 7m f=kT;k dh ,d pkSFkkbZ o`Ùkkdkj lrg ds 'kh"kZ ls NksM+h tkrh gSA xsan lrg ij fcuk
fQlys yksVuh xfr djrh gS] rFkk fQj ;g lrg ls i`Fkd gks tkrh gSA lrg ds fdukjs ls fdruh {kSfrt nwjh
(in meters) ij xksyk /kjkry ij VDdjk;sxkA (ok;q ?k"kZ.k ux.; gS, g = 10 m/s2)

29. A block of weight 100 N is suspended by copper and steel wires of same cross sectional area 0.5 cm 2
and, length 3 m and 1 m, respectively. Their other ends are fixed on a ceiling as shown in figure. The
angles subtended by copper and steel wires with ceiling are 30° and 60°, respectively. If elongation in
 C
copper wire is (C) and elongation in steel wire is (s), then the ratio is ___ .
 S
(Young's modulus for copper and steel are 1 × 1011 N/m2 and 2 × 1011 N/m2, respectively)
,d 100 N Hkkj okys xqVds dks rkacs vkSj LVhy ds rkjksa] ftudk vuqizLFk dkV {ks=kQy (cross sectional area)
,dleku rFkk 0.5 cm2 gS vkSj yackbZ Øe'k% 3 m rFkk 1 m gS] }kjk yVdk;k tkrk gSA rkjksa ds nwljs Nksj Nr ij
fp=kkuqlkj tqMs gq, gSaA rkacs vkSj LVhy ds rkj Øe'k% Nr ls 30° vkSj 60° dk dks.k cukrs gSA ;fn rkacs ds rkj esa
 C
yackbZ o`f) (C) rFkk LVhy ds rkj esa yackbZ o`f) (S) gS rc = ___ gSA
 S
(rkacs vkSj LVhy dk ;ax xq.kkad (Young's modulus) Øe'k% 1 × 1011 N/m2 rFkk 2 × 1011 N/m2 gS)

30°
Space for Rough 60°
Steel wire
Work / (dPps dk;Z ds fy, LFkku)
Copper wire
1m
3

Block

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
30. A small block of mass m is initially at the lowest position of a vertical fixed cylindrical surface whose
inner surface is smooth. At the lowest point, the block is given as much speed so that it can just
complete the vertical cricle. If magnitude of its acceleration at position (A) and highest position (B) are
2 2
a1 – a 2
respectively a1 and a 2 the write the value of .
g2
,d m nzO;eku dk NksVk CykWd izkjEHk esa ,d Å/okZ/kj fLFkj csyukdkj lrg ftldh vkarfjd lrg ?k"kZ.kghu gS ds
fuEure fcanq ij j[kk tkrk gSA fuEure fcanq ij CykWd dks bruh T;knk pky nh tkrh gS fd ;g dsoy Å/okZ/kj
o`rh; xfr iw.kZ dj ldsA ;fn fcanq A rFkk mPpre fcanq B ij Roj.k dk ifjek.k Øe'k% a1 rFkk a 2 gS rks
2 2
a1 – a 2
dk eku fy[kksaA
g2
B

m A

SECTION-4: (Maximum marks: 12)

• This section contains TWO (02) question paragraphs.
• Based on each paragraph, there are TWO (02) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases
[kaM 4 : (vf/kdre vad : 12)
 bl [kaM esa nks (02) vuqPNsn gSAaSpace for Rough Work / (dPps dk;Z ds fy, LFkku)
 izR;sd vuqPNsn ij vk/kkfjr nks (02) iz'u gSSA
 izR;sd ç'u dk mÙkj ,d la[;kRed eku (NUMERICAL VALUE) gSSA
 ;fn la[;kRed eku eas nks ls vf/kd n'keyo LFkku gS] rks eku dks nks (02) n'keyo LFkkuksa rd lesVsa@'kwU;kar
(TRUNCATE/ROUND-OFF) djsaA
 izR;sd iz'u ds mÙkj dk ewY;kadu fuEu ;kstuk ds vuqlkj gksxk %
 iw.kZ vad % +3 ;fn fufnZ"V LFkku ij dsoy lgh la[;kRed eku çfo"V fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;kasa esa

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
Paragraph for Question Nos. 31 to 32
iz'u 31 ls 32 ds fy, vuqPNsn
Gold Nucleus (79Au198) can decay into mercury nucleus (80Hg198) by two decay schemes shown in figure.
(i) It can emit a  particle (1) and come to ground state by either emitting one  ray(1) or emitting two 
rays (3 & 2)
(ii) It can emit one  particle (2) and come to ground state by emitting 2 ray. Atomic masses:
198
Au = 197.968 amu, 198Hg = 197.966 amu, 1 amu = 930 MeV/c2. The energy levels of the nucleus are
shown in figure.
lksus dh ukfHkd (79Au198) fp=k esa iznf'kZr nks ;kstukvksa ds vuqlkj ikjs (80Hg198) ds ukfHkd esa fo?kfVr gksrk gS - (i)
;g  d.k (1) mRlftZr dj ldrk gS rFkk ;g ,d  fdj.k (1) ;k nks  fdj.ksa (3 o 2) mRlftZr djds ewy voLFkk
esa vk tkrh gSA
(ii) ;g ,d  d.k (2) mRlftZr dj ldrh gS rFkk 2 fdj.k mRlftZr djds ewy voLFkk esa vk tkrh gSA ijek.kq Hkkj
Øe'k% 198Au = 197.968 amu, 198Hg = 197.966 amu, 1 amu = 930 MeV/c2 gSA ukfHkdksa ds ÅtkZ Lrj fp=k esa
iznf'kZr gSaA
198
79 Au

1
E3= –1 MeV Second excited state
 2 f}rh; mÙksftr voLFkk

1 3
E2= –1.6 MeV Frist excited state
izFke mÙksftr voLFkk
2
E1= –2 MeV
Ground state
198
80 Hg ewy voLFkk
31. What is the maximum kinetic energy of emitted 2 particles in Mev
mRlftZr 2 d.kksa dh vf/kdre xfrt ÅtkZ MeV esa Kkr dhft,A

32. What is the maximum kinetic

Spaceenergy
for Rough Work/1 (particle
of emitted dPps dk;Zin MeV.
ds fy, LFkku)
mRlftZr 1 d.k dh vf/kdre xfrt ÅtkZ MeV esa Kkr dhft,A

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 PHYSICS
Paragraph for Question Nos. 33 to 34
iz'u 33 ls 34 ds fy, vuqPNsn
The Young’s double slit experiment is done in water of refractive index 4/3. A light of wavelength 600 nm (in
water) is falling on the slits having 0.45 mm separation. The lower slit S2 is covered by a thin glass
sheet of thickness 10.4 m and refractive index 1.5. The interference pattern is observed on a screen
placed 1.5 m form the slits as shown.The intensity of light at the screen due to each slit is 0.
;ax ds iz;ksx dks 4/3 viorZukad okys ikuh ds ek/;e esa fd;k tkrk gSA fLyV ftuds chp dh nwjh 0.45 mm ij 600 nm
rjaxnS/;Z (ikuh esa rjaxnS/;Z) dk izdk'k Mkyk tkrk gSA uhps okyh fLyV dks ,d dkap dh iryh ifêdk ftldk
viorZukad 1.5 o eksVkbZ 10.4 µm ls <d fn;k tkrk gSA O;frdj.k izk:i insZ ij tks fLyV ls 1.5 m nwjh ij gS
ns[kk tkrk gSA çR;sd fLyV ds dkj.k insZ ij çdk'k dh rhozrk 0 gSA

33. If the intensity of light at the central point point O is n0 then write the value of n.
dsUnzh; fcUnq O ij ;fn çdk'k dh rqY; rhozrk n0 gks rks n dk eku fy[kksA

34. Now if 600 nm light is replaced by white visiable light of range   (300 nm to 525 nm) ,then the
1300 nm 1300 nm
wavelengths of the light which are absent at the central point O are and . Write the
x y
value of x +y : [All wavelengths in the problem are for the water]
;fn 600 nm çdk'k ds LFkku ij fLyV ij 'osr n`'; çdk'k fxjk,sa ftldh rjaxnS/;Z ijkl   (300 nm ls
1300 nm 1300 nm
525 nm) gks rks dsUnzh; fcUnq O ij vkSj rjaxnS/;Z ds çdk'k vuqifLFkr gSA rks x + y dk eku
x y
fy[kksA [lkjs rjaxnS/;Z ikuh ds lkis{k gSa]

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
PART-III (Hkkx-III) : CHEMISTRY (jlk;u foKku)
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION-1: (Maximum marks: 12)
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
[kaM 1 : (vf/kdre vad : 12)
 bl [kaM esa pkj (04) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +3 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

35. Which of the following statement(s) is/are correct

(I) [Cr(CO)6] is low spin complexes which follow EAN rule
(II) Na2S  Na2 [Fe(CN)5 (NO)]  (X), ON of Fe in the complex (X) is +2
(III) In complex [Ni(en)3]2+ total number of chelate rings is 3
(IV) The number of geometric isomers possible for the complex [M(AB)a2b2] is 4
(Where AB  Unsymmetric bidentate ligand. a, b  monodentate ligands)
(A) I only (B) II, III only (C) I, II, III, IV (D) I, II, IV only

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa\
(I) [Cr(CO)6] fuEu pØ.k (low spin) ladqy gS tks EAN fu;e dk ikyu djrk gSA

(II) Na2S  Na2 [Fe(CN)5 (NO)]  (X), tfVy (X) esa Fe dk ON +2 gSA
(III) ladqy [Ni(en)3]2+ es
dhysV oy; (chelate ring) dh dqy la[;k '3' gSaA
(IV) ladqy [M(AB)a2b2] ds fy, lEHko T;kfefr; leko;oh;ks dh la[;k 4 gSA
(tgk¡ AB  vlefer f}narqd fyxs.M a, b  ,dynarqd fyxs.M)
(A) dsoy I (B) dsoy II, III (C) I, II, III, IV (D) dsoy I, II, IV

36. Which of the following reaction produce Cl2 gas ?

fuEu esa ls dkSulh vfHkfØ;k Cl2 xSl mRikfnr djrh gS\

(A) NaCl  H2SO4  (B) KClO3 

(C) HCl  O3  (D) KCl  AgNO 3 

37. Gabriel phthalimide synthesis is preferred for the synthesis of

(A) Aliphatic primary amine (B) Secondary amine
(C) Tertiary amine (D) Aromatic primary amine
xsfczy FksfyekbM la'ys"k.k fuEu ds la'ys"k.k ds fy, fd;k tkrk gS &
(A) ,fyQsfVd izkFkfed ,ehu (B) f}rh;d ,ehu
(C) r`rh;d ,ehu (D) ,sjksefs Vd izkFkfed ,ehu

38. Which of the following is not a pyrimidine base ?

(A) Uracil (B) Guanine (C) Cytosine (D) Thymine
fuEu esa ls dkSu fifjfeMhu (pyrimidine) {kkj ugh gS \
(A) ;wjsfly (B) Xokuhu (C) lk;Vkslhu (D) Fkkbehu

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
SECTION-2: (Maximum marks: 12)
• This section contains THREE (03) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.
[kaM 2 : (vf/kdre vad : 12)
 bl [kaM esa rhu (03) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
for Rough Work / (dPps dk;Z ds fy, LFkku)
 vkaf'kd vad % +3 ;fnSpacepkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs
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 CHEMISTRY
39. Given that molar conductivities at infinite dilution (25ºC):
HCl = 426 –1 cm2 mol–1
NaCl = 126–1 cm2 mol–1
NaC (sodium crotonate) = 83 –1 cm2 mol–1
The conductivity of a 0.001 M Crotonic acid solution is 3.83 × 10–5–1 cm–1
Which of the following is/are correct?
(A) M of crotonic acid is = 383 –1 cm2 mol–1 (B) Ka of crotonic acid is 1.11 × 10–5
(C) Ka of crotonic acid is 1.11 × 10–7 (D)  of 0.01 M solution of crotonic acid is 0.1
vuUr ruqrk ij eksyj pkydrk nh x;h gS (25ºC) &
HCl = 426 –1 cm2 mol–1
NaCl = 126–1 cm2 mol–1
NaC (lksfM;e ØksVksusV) = 83 –1 cm2 mol–1
0.001 M ØksVksfud vEy foy;u dh fof'k"V pkydrk 3.83 × 10–5–1 cm–1 gSA
fuEu esa ls dkSulk@dkSuls lgh gS@gSa\
(A) ØksVksfud vEy dk M gS = 383 –1 cm2 mol–1 (B) ØksVksfud vEy dk Ka gS 1.11 × 10–5
(C) ØksVksfud vEy dk Ka gS 1.11 × 10–7 (D) ØksVksfud vEy ds 0.01 M foy;u dk  0.1 gSA

40. For the endothermic reaction

3A(g) B(g) + C(g)
select the option(s) by which equilibrium concentration of A(g) can be increased ?
(A) Decreasing the temperature (B) Increasing the volume of the container
(C) Decreasing the volume of the container (D) Adding B(g) at equilibrium
Å"ek'kks"kh vfHkfØ;k ds fy,
3A(g) B(g) + C(g)
mu fodYi@fodYiksa dk p;u fdft;s ftlds }kjk A(g) dh lkE; lkUnzrk esa o`f) dh tk ldrh gS \
(A) rki ?kVkdj (B) ik=k dk vk;ru c<+kdj
(C) ik=k dk vk;ru ?kVkdj (D) lkE; ij B(g) feykdj

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
41. Which of the following statements is/are correct ?
(A) I effect is distance dependent.
(B) I effect is temporary.
(C) The resonance structures are hypothetical structure and they do not represent any real molecule.
(D) The stability of resonance hybrid is more than stability of any resonating structure.
fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa ?
(A) I izHkko nwjh ij fuHkZj gksrk gSA
(B) I izHkko vLFkk;h gksrk gSA
(C) vuquknh lajpuk;sa dkYifud lajpuk;sa gS rFkk ;s fdlh Hkh okLrfod lajpuk dks iznf'kZr ugha djrh gSA
(D) vuquknh ladj dk LFkkf;Ro fdlh vU; vuquknh lajpuk ds LFkkf;Ro dh rqyuk esa vf/kd gksrk gSA

SECTION-3: (Maximum marks: 24)

• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if the correct numerical value is entered;
Zero Marks : 0 In all other cases.
[kaM 3 : (vf/kdre vad : 24)
 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u dk mÙkj xSj&_.kkRed iw.kkZad (NON-NEGATIVE INTEGER) gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
42. MX3 dissociates in M3+ and X– ions in an aqueous solution with a degree of dissociation () of 0.33. The
ratio of the observed depression of freezing point of the aqueous solution to the value of depression of
freezing point in the absence of ionic dissociates is :
MX3 fo;kstu dh ek=kk () 0.33 ds lkFk tyh; foy;u esa M3+ rFkk X– vk;uks es fo;ksftr gksrk gSA tyh; foy;u
ds fgekad ds izsf{kr voueu dk eku o vk;fud fo;kstu dh vuqifLFkfr esa fgekad ds voueu ds eku dk vuqikr
gksxk&

43. In a cubic unit cell, atoms A are present at all corner, B atoms are present at non-adjacent face center
and also at edge centers which are not common to the faces containing B atoms at the centres. C
atoms are present at body centre & remaining face centers. If the formula of given solid is A xByCz then
determine value of (x + y + z) :
,d ?kuh; ,dd dksf"Bdk esas ijek.kq A lHkh dksuks ij mifLFkr gSa] B ijek.kq vfudVorhZ (non-adjacent) Qyd
dsUnz ij rFkk mu dksj dsUnzksa ij Hkh mifLFkr gSa] tksfd dsUnzksa ij B ijek.kq ;qDr Qydksa ds mHk;fu"B ugha gksrh gSA
C ijek.kq dk; dsUnz rFkk 'ks"k Qyd dsUnzksa ij mifLFkr gSaA fn, x;s Bksl dk lw=k AxByCz gS] rks (x + y + z) dk
eku Kkr dhft;s&

44. How many of the following underlined element are sp3 hybridized
fuEu esa ls fdrus v|ksjs[kkafdr rRo sp3 ladfjr gSa \
[Cu(NH3)4]+2 , PCl3 , BCl3 , [Pt(en)2]+2 , [Ni(CO)4], CS2 ,

SO24 , SnCl2 SnCl4 , HgCl2 , ClO 4 , C2H4 , CH3 , CH3 ,

2
NH4 , C F3 , NO3 , ClO3 , PH3 , Ni  CN4  , PCl5 ,

CH2O , SF6 , Cl2 CO , 3 , H2 S

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
45. A(g) B(g)  C(g) is a Ist order reaction.
A graph of log (a – x) v/s t is shown in figure

A(g) B(g)  C(g) ,d Ist dksfV vfHkfØ;k gSA

log (a – x) rFkk t ds e/; xzkQ fp=k esa n'kkZ;k x;k gSA
le; ¼feuV½

–y
If the rate constant (in sec–1) is 7.7 × 10 then determine value of y.
–y
nj fu;rkad ¼lSd.M–1 es½ 7.7 × 10 gS] rks y dk eku Kkr djksA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
46. Find the number of cyclic isomers of C4H9N which are not 1º amine.
C4H9N ds pØh; leko;oh;ksa dh la[;k Kkr dhft, tks 1º ,ehu ugha gSA

O OH
– HO OH + HCOO
OH
47. + HCHO (Excess) HO OH

Total number of times aldol (x) and cannizzaro (y) have been taken place for the above conversion.
Report your answer (10x + y).
O OH
– HO OH + HCOO
OH
+ HCHO (vkf/kD;) HO OH

mijksDr :ikUrj.k ds fy, fdruh ckj ,YMksy (x) rFkk dSfutkjks (y) fd;k tkrk gS\
viuk mÙkj (10x + y) ds :i esa nhft,A

SECTION-4: (Maximum marks: 12)

• This section contains TWO (02) question paragraphs.
• Based on each paragraph, there are TWO (02) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
[kaM 4 : (vf/kdre vad : 12)
 bl [kaM esa nks (02) vuqPNsn gSaA
 izR;sd vuqPNsn ij vk/kkfjr nks (02) iz'u gSSA
 izR;sd ç'u dk mÙkj ,d la[;kRed eku (NUMERICAL VALUE) gSSA
 ;fn la[;kRed eku eas nks ls vf/kd n'keyo LFkku gS] rks eku dks nks (02) n'keyo LFkkuksa rd lesVsa@'kwU;kar
(TRUNCATE/ROUND-OFF) djsaA
 izR;sd iz'u ds mÙkj dk ewY;kadu fuEu ;kstuk ds vuqlkj gksxk %
 iw.kZ vad % +3 ;fn fufnZ"V LFkku ij dsoy lgh la[;kRed eku çfo"V fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;kasa esa

Paragraph for Question Nos. 48 to 49

iz'u 48 ls 49 ds fy, vuqPNsn
Rate of a chemical reaction is studied experimentally and expressed in the form of rate law. The power
of concentration term in the rate law is called order of reaction. Half life of a reaction is the time in which
the concentration of reactant becomes half of the intial amount.
Answer the following questions.

,d jklk;fud vfHkfØ;kvksa ds osxksa dk iz;ksxksa }kjk v/;;u gksrk gS o osx fu;e esa O;Dr fd;k tkrk gSA lkUnzrk in
dk ?kkrkad vfHkfØ;k dh dksfV dgykrk gSA v)Zvk;q dky og dky gS ftlesa vfHkdkjd dh lkUnzrk izkjaHk ls vk/kh gks
tkrh gSA fuEu iz'uksa ds mRrj nhft,A

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 CHEMISTRY
48. For a general reaction A+B  products, How many of the following rate laws express zero order
kinetics ?
(a) rate = k[A][B]–1
k1[A][B]0
(b) rate = (where [A]0)
1  k 2 [A]
(c) rate = k[A]2[B]–1
(Symbol have their usual meanings)
lkekU; vfHkfØ;k A+B  mRikn] ds fy;s fuEu esa ls dqy fdrus osx fu;e 'kwU; dksfV cy&xfrdh O;Dr djrs gSa\
(a) nj = k[A][B]–1
k1[A][B]0
(b) nj = (tgk¡ [A]0)
1  k 2 [A]
(c) nj = k[A]2[B]–1
¼izrhdksa ds lkekU; vFkZ ekudj½

49. Decomposition of A follows first order kinetics by the following equation.

4A(g)  B(g) + 2C(g)
If initially, total pressure was 800 mm of Hg and after 10 minutes it is found to be 650 mm of Hg. The
half-life of A is _______ mins. (Assume only A is present initially)

A dk fo;kstu izFke dksfV dh xfrdh dk fuEu lehdj.k }kjk ikyu djrk gSA
4A(g)  B(g) + 2C(g)
;fn izkjEHk esa] dqy nkc 800 mm, Hg ik;k x;k rFkk 10 m. i'pkr~ ;g 650 mm , Hg ik;k x;kA A dh
v)Z&vk;q _______ mins gksxhA ¼ekfu;s fd izkjEHk esa dsoy A mifLFkr gSa½

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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 CHEMISTRY
Paragraph for Question Nos. 50 to 51
iz'u 50 ls 51 ds fy, vuqPNsn
Compound (X) (C8H7N) on treatment with cold SnCl2/dil.HCl (aqueous), produces Y (C8H8O). (Y) on
heating with sodium acetate in acetic anhydride followed by acidification forms (Z) (C10H10O2). All these
compounds (X,Y,Z) on oxidation under severe conditions form a diacid which gives only one mononitro
isomer in nitrating mixture.
;kSfxd (X) (C8H7N) dh vfHkfØ;k B.Ms SnCl2/ruq HCl (tyh;), ls djkus ij Y (C8H8O) izkIr gksrk gSA (Y) dks
,flfVd ,ugkbMkbM esa lksfM;e ,flVsV ds lkFk xeZ djus ij rFkk vEyh;dj.k djus ij ;kSfxd (Z) (C10H10O2)
izkIr gksrk gSA ;s lHkh ;kSfxd (X,Y,Z) dk dfBu ifjfLFkfr;ksa esa vkWDlhdj.k djus ij Mkb,flM curs gS tks fd
ukbVªhdj.k feJ.k ls vfHkfØ;k djus ij dsoy eksuksukbVªks leko;oh nsrs gSaA

50. Compound (X) has how many carboxylic group after reaction with KMnO 4 /H+
;kSfxd (X) esa fdrus dkcksZfDlfyd lewg mifLFkr gksxs KMnO4 /H+ dh vfHkfØ;k ds ckn\

51. Compound (Y) react with excess of C2H5MgCl and after acidification give product alcohol. Alcohol
product has many carbon atoms.
;kSfxd (Y) C2H5MgCl ds vkf/kD; ls vfHkfØ;k djrk gS rRi'pkr mRikn ,Ydksgy cukrk gSA ,Ydksgy mRikn esa
fdrus dkcZu ijek.kq gksxsaA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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