S-781 Roll No. …………………..

BSCCH–101/CH–01
Inorganic Chemistry—I
¼vdkcZfud jlk;u—I½
Bachelor of Science (Chemistry) (BSC-12/16/17)
First Year, Examination, 2018
Time : 3 Hours Max. Marks : 40
Note : This paper is of forty (40) marks containing three
(03) Sections A, B and C. Learners are required to
attempt the questions contained in these Sections
according to the detailed instructions given therein.

uksV % ;g iz’u i= pkyhl ¼40½ vadksa dk gS tks rhu ¼03½

[k.Mksa ^d*] ^[k* rFkk ^x* esa foHkkftr gSA f’k{kkfFkZ;ksa dks
bu [k.Mksa esa fn, x, foLr`r funsZ’kksa ds vuqlkj gh iz’uksa
ds mŸkj nsus gSaA
Section–A / [k.M&d

(Long Answer Type Questions) / ¼nh?kZ mŸkjh; iz’u½

Note : Section „A‟ contains four (04) long answer type
1
questions of nine and half (9 2) marks each.
Learners are required to answer two (02) questions
only.

(A-88) P. T. O.
 [2] S-781

uksV % [k.M ^d* esa pkj ¼04½ nh?kZ mŸkjh; iz’u fn;s x;s gSaA
izR;sd iz’u ds fy, lk<+s ukS (9 12) vad fu/kkZfjr gSaA
f’k{kkfFkZ;ksa dks buesa ls dsoy nks ¼02½ iz’uksa ds mŸkj nsus
gSaA
1. What are interhalogen compounds ? How are they
prepared ? Discuss the structures of tetraatomic and
hexaatomic interhalogens stating the type of
1
hybridisation occurring in their central atoms. 2
,1, 8

vUrjgSykstu ;kSfxd D;k gksrs gSa \ ;s dSls cuk;s tkrs gSa \

prq‛ijek.kqd ,oa ‚kV~ijek.kqd vUrjgSykstuksa dh lajpukvksa
dh O;k[;k muds dsUnzh; ijek.kqvksa esa gksus okys ladj.k dks
crkrs gq, dhft,A
2. (a) Explain, why does SiCl4 hydrolyse but CCl4 does
not. 3
le>kb,] D;ksa S iC l 4 ty vi?kfVr gksrk gS ysfdu
C C l 4 ugha gksrk gS \

(b) State clearly the radius ratio effect and its causes.
Explain how do the shape and stability of an ionic
crystal depend upon the radius ratio ? 112, 2, 3

f=T;k vuqikr izHkko ,oa blds dkj.kksa dks Li‛V :i ls

crkb,A fdlh vk;fud fØLVy dh vkd`fr ,oa
LFkkf;Ro fdl izdkj f=T;k vuqikr ij fuHkZj djrs
gSa \ le>kb,A
(A-88)
 [3] S-781

3. Write a detailed note on structure and bonding in

Xenon compounds. 912
thukWu ;kSfxdksa dh lajpuk o cU/kqrk ij ,d foLr`r fVIi.kh
fyf[k,A
4. (a) Give an account of the method of preparation,
properties and structure of S4N4. 4
S4 N 4 ds cukus dh fof/k] xq.k/keks± ,oa lajpuk dk
fooj.k nhft,A
(b) Why are the hydrides of alkali metals alkaline but
those of halogens are acidic ? 3
{kkj /kkrqvksa ds gkbMªkbM {kkjh; ysfdu gSykstuksa ds
gkbMªkbM vEyh; D;ksa gksrs gSa \
(c) Write a note on Frenkel defect of ionic solids. 212
vk;fud Bkslksa ds Ýsady
s nks‛k ij ,d fVIi.kh fyf[k,A
Section–B / [k.M&[k
(Short Answer Type Questions) / ¼y?kq mŸkjh; iz’u½
Note : Section „B‟ contains eight (08) short answer type
questions of four (04) marks each. Learners are
required to answer four (04) questions only.
uksV % [k.M ^[k* esa vkB ¼08½ y?kq mŸkjh; iz’u fn;s x;s gaSA
izR;sd iz’u ds fy, pkj ¼04½ vad fu/kkZfjr gSaA
f’k{kkfFkZ;ksa dks buesa ls dsoy pkj ¼04½ iz’uksa ds mŸkj nsus
gSaA
1. (a) “BeCl2, BCl3 and SiCl4 molecules have zero
dipole moment.” Comment on this statement.
“BeCl2, BCl3 ,oa SiCl4 v.kqvksa dk f}/kzqo vk?kw.kZ
‘kwU; gksrk gSAÞ bl dFku ij fVIi.kh dhft,A
(A-88) P. T. O.
 [4] S-781

(b) Giving chemical reaction state how is SiC

prepared from SiO2 ?
jklk;fud vfHkfØ;k nsrs gq, crkb, fd SiO2 ls SiC
dSls cuk;k tkrk gS \
2. How does an ionic solid dissolve in water ? Explain
taking any example.
dksbZ vk;fud Bksl ty esa fdl izdkj foys; gksrk gS \ dksbZ
mnkgj.k ysdj le>kb,A
3. Discuss the type of hybridisation occurring in XeOF4
molecule and mention its geometry.
v.kq esa gksus okys ladj.k dh O;k[;k dhft, ,oa
X e O F4

bldh T;kfefr crkb,A

4. What is catenation ? Explain the uniqueness of carbon
to catenate. How does the catenation tendency vary in
group 14 elements and why ?
Ük`a[kyu D;k gS \ dkcZu fdl izdkj Ük`a[kyu djrk gS \
lewg 14 ds rRoksa esa Ük`a[kyu xq.k fdl izdkj c<+rk ;k
?kVrk gS] crkb;sA
5. Explain :
(a) Why Alkaline earth metal oxides are less basic
than those of alkoli metals.
(b) Calcium is more reactive than magnesium.
(c) The hydroxides of group 2 metals are less basic
than those of group 1.

(A-88)
 [5] S-781

dkj.k lfgr le>kb, %

¼v½ {kkjh; e`nk /kkrqvksa ds vkWDlkbM] {kkjh; /kkrqvksa ds
vkWDlkbM dh rqyuk esa de {kkjh; gksrs gSaA
¼c½ dSfY’k;e] eSXuhf’k;e ls T;knk lfØ; gksrk gSA
¼l½ lewg 2 ds gkbMªkWDlkbM lewg 1 dh rqyuk esa de
{kkjh; gksrs gSaA
6. Write a brief note on fullerenes.
Qqyjs huksa ij ,d laf{kIr fVIi.kh fyf[k,A
7. Draw MO diagram for NO molecule and mention its
bond order.
NO v.kq ds fy, MO fp= dks vkjsf[kr dhft, ,oa bldh
cU/k dksfV crkb,A
8. Write a brief note on preparation, properties, uses and
structure of sulphur dioxide.
lYQj MkbZvkWDlkbM cukus dh fof/k] xq.kksa] mi;ksfxrk rFkk
lajpuk dk o.kZu dhft,A
Section–C / [k.M&x
(Objective Type Questions) / ¼oLrqfu‛B iz’u½
Note : Section „C‟ contains ten (10) objective type
questions of half  12  mark each. All the questions
of this Section are compulsory.
uksV % [k.M ^x* esa nl ¼10½ oLrqfu‛B iz’u fn;s x;s gSaA izR;sd
iz’u ds fy, vk/kk  12  vad fu/kkZfjr gSA bl [k.M ds
lHkh iz’u vfuok;Z gSaA
(A-88) P. T. O.
 [6] S-781

1. The crystal co-ordination number of Cl– ion in CsCl

crystal is :
(a) 4
(b) 6
(c) 8
(d) 10
CsCl fØLVy esa Cl– vk;u dh fØLVy milgla;kstd
la[;k gS %
¼v½ 4
¼c½ 6
¼l½ 8
¼n½ 10
2. The dipole moment value of CCl4 molecule is zero.
(True/False)
CCl4 v.kq ds f}/kzqo vk?kw.kZ dk eku ‘kwU; gksrk gSA
¼lR;@vlR;½
3. According to MOT the bond order of CO molecule is :
(a) 2
(b) 2.5
(c) 3
(d) 3.5
MOT ds vuqlkj CO v.kq dh cU/k dksfV gS %
¼v½ 2
¼c½ 2-5
¼l½ 3
¼n½ 3-5
4. The number of pi    bonds in borazine is :
(a) 2
(b) 3
(c) 6

(A-88)
 [7] S-781

(d) 12
cksjt
s hu esa ikbZ  cU/kksa dh la[;k gksrh gS %
¼v½ 2
¼c½ 3
¼l½ 6
¼n½ 12
5. Boron shows diagonal relationship with :
(a) Al
(b) Si
(c) Be
(d) Mg
B ¼cksjkWu½ fod.kZ lEcU/k n’kkZrk gS %
¼v½ Al ls
¼c½ Si ls
¼l½ Bels
¼n½ Mg ls
6. The increasing order of the acidic strength of oxo-
acids of chlorine is :
(a) HClO4 < HClO3 < HClO2 < HClO
(b) HClO4 < HClO < HClO2 < HClO3
(c) HClO < HClO4 < HClO3 < HClO2
(d) HClO < HClO2 < HClO3 < HClO4
Dyksjhu ds vk¡Dlh vEyksa dh vEyh; lkeF;Z dk c<+rk Øe gS %
¼v½ HClO4 < HClO3 < HClO2 < HClO
¼c½ HClO4 < HClO < HClO2 < HClO3
¼l½ HClO < HClO4 < HClO3 < HClO2
(A-88) P. T. O.
 [8] S-781

¼n½ HClO < HClO2 < HClO3 < HClO4

7. Complete the following reaction :
2 X e F4  3 H 2 O  X e + ......  6 H F  a q   F2 g 
fuEufyf[kr vfHkfØ;k dks iw.kZ dhft, %
2 X e F4  3 H 2 O  X e + ......  6 H F  a q   F2 g 

8. Which of the following substances is used as

refrigerant ?
(a) Pyrene
(b) Tetrachloromethane
(c) Tetrafluoromethane
(d) Difluorodichloromethane
iz’khrd ds :i esa iz;qDr gksrh gS %
¼v½ Pyrene
¼c½ Tetrachloromethane
¼l½ Tetrafluoromethane
¼n½ Difluorodichloromethane
9. The state of hybridisation in S atom of SF6 molecule
is :
(a) sp3
(b) sp3d
(c) sp3d2
(d) sp2d3
S F6 v.kq ds S ijek.kq esa ladj.k dh voLFkk gksrh gS %
¼v½ sp 3

(A-88)
 [9] S-781

¼c½ sp 3d

¼l½ sp 3d 2

¼n½ sp 3d 3

10. Bi  V  salts do not exist because of :

(a) Lone pair effect

(b) Inert pair effect
(c) Bond pair effect
(d) All of the above

Bi V  yo.kksa dk vfLRkRo ugha gS %

¼v½ ,dkdh ;qXe izHkko ds dkj.k
¼c½ vfØ; ;qXe izHkko ds dkj.k
¼l½ cU/k ;qXe izHkko ds dkj.k
¼n½ mi;qZDr lHkh ds dkj.k

S–781 430

(A-88) P. T. O.