SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s

Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAM ILNADU, M AHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
SEC: JEE-MAIN Date: 00-00-0000
Time: 09.00Am to 12.00Pm GTM-02 Max. Marks: 300
KEY SHEET
PHYSICS
1 3 2 4 3 3 4 2 5 1
6 2 7 2 8 3 9 2 10 1
11 1 12 3 13 3 14 2 15 1
16 2 17 3 18 3 19 1 20 1
21 15 22 8 23 3 24 14 25 3
26 2 27 125 28 50 29 400 30 30
CHEMISTRY
31 2 32 3 33 2 34 4 35 2
36 3 37 2 38 2 39 2 40 1
41 1 42 3 43 1 44 1 45 1
46 3 47 3 48 1 49 1 50 2
51 3 52 48 53 3 54 4 55 5
56 6 57 4 58 1 59 0 60 10

MATHEMATICS
61 3 62 3 63 4 64 1 65 2
66 4 67 3 68 2 69 2 70 4
71 1 72 1 73 4 74 1 75 4
76 4 77 4 78 3 79 2 80 2
81 2 82 7 83 3 84 3 85 13
86 5 87 34 88 1558 89 22 90 12

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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s

SOLUTIONS
PHYSICS
1. Expressing time in terms of length, mass and force
2.  
About B: mg cos   ma sin   ma sin   a  g cot 
2 2
N1  ma
A
/2 N 2  mg
/2
FP  ma

B

W  mg

3. Mass of original sphere = M ; Radius of original sphere = R

M R
Mass of cavity = ; Radius of cavity M  V  r 3 
8 2
Mass of substituted (introduced) sphere = 2M [1/ 8 th volume
R
16 times denser] Radius of substituted (introduced) sphere =
2
At any point net potential [applying superposition]
 V0 (potential due to original sphere)- VC (potential due to cavity)
+ Vs (potential due to substituted sphere)
M 
G 
   8   G  2M   13GM  13 V
2
GM R
VD   3 R 2
     0
2R 3   2   R R 4R 4
4. m1x1  m2 x2 m y  m2 y2
xc  yc  1 1
m1  m2 m1  m2
5. 2gH1  2gH 2
The average velocity of efflux v 
2
Let t be the time taken to empty the tank from level H1 to H 2 . Then
A 2   H1  H 2   H1  H 2  
2gH1  2gH2  
 a  t  A  H1  H 2  
  
2 a g   H1  H 2  H1  H 2  
 


A 2
a g
  H1  H 2 
6. 3
kxR  mR 2α
2
7. 1  1 
 R  2 
  n1  n22 
8. B0 ( x  d )v0 d B xv d
  Blv, 1  ,  2  0 0 , 1   2
a a

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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s

9.  k p
E
r3
10. Behavior of RLC AC circuit and resonance
11.  4 2 8
T .I .R  C sin  l   sin  
g 3 3 9
12. See the hint of example 1.9
Least count of vernier calipers
a 1mm
   0.1mm  0.01cm
N  1 10
Side of cube = (10) (1 mm) + (1) (LC)
or a=10 mm+0.1 mm
or a=10.1 mm
or a=1.01 cm
mass m 2.736
  3  3
3 = 2.65553 g/cm = 2.66g/cm
3
volume a 1.01
 
2
13.  C V +V 
1 2 1
U1 = CV1 + CV2 U 2 = 
2 1 2 
2 2 4C
14. V  Ig  R  G 
15. 1 1 1
L  v0  ue  15  1 ve  D  25  
f e ue ve
 ue  5  v0  5  15  v0  10
1 1 1 1 1 1
     u0  2.5cm
f0 u0 v0 2 u0 10
16. 0i  1 1  0i
B 1    .....  
4a  2 4  6a
17. 1  qE  2  2 m 
  t  x0 t  3  qB 
2 m   
18. Switch open
 VC1C2 
QC1  QC2     36C When switch is closed
 C1  C2 
V for C1  6V V for C2  12V

19. v T
20. n eee 4I 5
n eee  n h eh  I . given  4
n h eh I 5

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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s
n ee n  4 8
or  4 or e  4 h   hence the correct choice is (a)
n h h nh e 2.5 5
21. 1  
C , r  ,r 
o o o o
22. 1 1 1 ΔR ΔR1 ΔR 2
= + = + 2
R R 2 R 2 R 2 R12 R2
23. dv
a
dt
24. ds dv
s  t 3  5  speed ,    3t 2 and rate of change of speed =  6t
dt dt
 Tangential acceleration at, t  2s, at  6  2  12 m / s 2

At t  2s, vt  3  2   12 m / s  Centripetal acceleration

2

v 2 144
ac   m / s 2  Net acceleration = at2  ac2  14m / s 2
R 20
25. T1 1500
m2  m1  5000  3000 A0
T2 2500
26. 3.21019
eVs   2eV
1.61019
27. N 1
 n
N0 2
28. d 2  d1 2 RhR 5
d1  2 Rhr , d 2  2 RhT  2 RhT ,  100   100   100  50%
d1 2 RhT 20
29. T1  T2 WA T T W
A   B  2 3  B As A  B
T1 Q1 T2 Q2
 T2  T1  T3  800  200  400K
30. Light passes through first polarizer
I = I0/2 = 16 wm–2
If angle between P1 and P2 =  and angle between P2 and P3 =   +  = 900
I I
I1  0 cos 2 and I 2  I1 cos 2   0 cos 2 .cos 2   3
2 2

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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s

CHEMISTRY
31. 0.46 1
S   1.877 10 3
245 1
PbF2 IS AB2 , K sp  4 S 3
32. Electroplating is a process of coating one metal or metal object with a very thin
layer of another metal typically applying a direct electric current.
Electrolytes used in the electroplating of gold and silver are given in the table
below:

Article to be Pure metal block Electrolyte

process [plated out acts acts an anode by (aqueous solution)
as cathode which electroplating
will be done
Na[ Au (CN )2 ]
(a) Gold plating Article Au(s) (sodium auro-cyanide)

Na[ Ag (CN )2 ]
(b) Silver Ag(s)
plating Article (Sodium argento
cyanide
33. 2.303  CA   C A0 
k log  0  2.303  1  2.303log  
t  CA   CA 
C A0 1
 10  C A   0.1 rate after 1min r1  k .C A
CA 10
 2.303  0.1  0.2303M min 1
34. Lyophobic sols need stabilising agent
35. Dalton law p1v1  p2v2  p f v f 20  20  1 v  20   5  v  400  v  20  5v
380
 v  95L
4
36. nh h 13.6
 n  2 En  2  12  3.4ev P.E  2  T .E
2  2
37. 2 a  4R
38. IP of Nitrogen is more than Oxigen
O O
39.
|| ||
H  P O  P  H
| |
OH OH
40. Cromium with highest oxidation number is acidic
41. S8  0 S 2 F2  1 H 2 S  2 H 2 SO4  6
42. NaF  NaCl  NaBr  NaI
 L . E  M . P .
  M .P.
43. SO32  H 2 SO4  SO42  H 2O  SO2
SO2  K 2Cr2O7  H 2 SO4  K 2 SO4  Cr2  SO4 3  H 2O
44. Functional group is carboxamide
45.
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Tertiary amine with out conjugation.
Page 5
 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s
46. Same type of functional groups
47. 2.24
Vol.Strength H 2O2  5.6  N  N  0.4
5.6
48. Methyl-  -glucopyranoside is a monomer.
49. OH OH OH
H 
CH 3  C  C  CH 2  CH3 
CH3  C  C  C2 H 5
 H 2O

CH 3CH 2  CH 3 CH 3 C2 H 5
C2 H 5shift

50. 30 halide does not show wurtz reaction

Reactivity  stability of carbon free radical
51. pH  lower pH  log 2
52. For first order reacton , t99%  2  t90%
t99.9%  3  t90%
53. Total no. of p  d  bonds are  3
54. 2
Co3   Ar 3d 6 eg 3
t2 g
CoF6  has Co 3 CoF6  has Co 3
3 3

Total  4 unpaired e ' s present

55. X is
CH 2Cl CH 2CN
CH 2COOH

Y is Z is
56. A c t
m
v  96500
57. 1
1 80 
P  PAo  xB ( PB o  PAo ) 99  100  xb (20)  xB   y B  20  4
20 99 99
4
% mole B in vapour phase =  100  4
99
58. In melamine No of hydrogen atoms = 6 No of imine groups = 3
No of amine groups =3
59. pV 2.05  100
Total moles of gases at equilibrium   5.0
RT 0.082  500
Out of this 5 moles, 1.0 mole is for N 2 ( g ) and remaining 4 moles for PCl5 and its
PCl5  PCl3  Cl2
3- x x x
dissociation products. 3+ x =4  x =1
1
Degree of dissociation = = 0.33
3

Yashpatil TG~ @bohring_bot

60. Only 4 bonds=8 electorns
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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s

MATHEMATICS
61.   2n  1 
 x, x   A  sec 2 x  tan 2 x  1,  x  
 2 
 x, y   A  sec 2 x  tan 2 y  1   tan 2 x  1   sec2 y  1  1
 sec 2 y  tan 2 x  1   y, x   A
 x, y   A and  y, z   A   x, z   A
A is an equivalence relation
Rewriting the given function, we get,   x    x  6a   15  2a
2
62.
13
   x  is surjective on R  15  2a  2  2a  13  a 
2
63.

  x 1 x  1
1 0 1 2 3
 x 1 1  x  0

 1 x 0  x 1
f  x  
 x 1 1 x  2
3 x 2x3

 x 3 x3
64. 3 5 7 9 25 49
Let,   K    K2
| z1  z2 | | z2  z3 | | z3  z1 | | z1  z2 | | z2  z3 | | z3  z1 |
2 2 2


9
 K2 
9
 
 K 2 z1  z 2 Similarly. 
25

 K 2 z 2  z3 

 z1  z2  z1  z 2  z1  z2 z2  z3

And 
49
( z3  z1)  
 K 2 z 3  z1  9  25  49  K 2  z1  z 2  z 2  z 3  z 3  z1   0
z1  z2 z2  z3 z3  z1
65. ( p  q )  (  q  p) is always true
66. 4
Tangent to parabola with slope m is y  mx   1 This is tangent t
m
 4
xy  4  2 Eliminating y from 1, 2 x mx    4
 m
4 16
mx 2  x  4  0    0 2  16m  0 m3  1  m  1  The common tangent is
m m
y  x4.
dx
x4
 y  x is L.D.E I .F  e  x  e 2log x  x 2 G.S is yx 2   x 3dx   c
67. dy 2 2

dx x 4
2 2
x c 3 x 3 3
y   2 y 1  1  c   y  x    x 2  2
4 x 4 4 4 16
2
68. a ar b br abr xy r2
x  , y   xy  2   2
1
1 r 1
1
1 r 1 r 1 ab r  1
r r

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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s
2 2
c cr z r
z    2
1
1 r 1 c r 1
2

r2
69. (a, b) is the foot of the perpendicular from (12,10) on the line y  5 x  18
y

c 12,10 

(a,b)
x
O
M(4,-2)

a  12 b  10  10  5 12  18 
      2 +   a, b    2,8 
5 1  26 
 
70. Given circle x 2  y 2  20 x  4  0
c1 10,0 r1  96
Let c2  x, y  be the centre of the circle touching the line x  2  0
 r2  x  2  two circles cut orthogonally
c1c22  r12  r22  x  10   y 2  96   x  2   y 2  16x
2 2

Locus of c2 is y 2  16x
71. Given equation of the parabola can be rewritten as
 y  1  4  x  1 Axis of the parabola is y  1,
2

Equation of normal is  y 1  m  x 1  2m  m3

Let  h,1 is a point on its axis, then 0  m  h  1  2m  m3  m2  h  3
 h  3 for real & distinct values of m
72. 1  λ 2 2
For non trivial sol Δ  0  1 2λ 1 0
1 1  λ
1  λ   2λ  λ2  1  2   λ  1  2  1  2  λ   0
λ  1 Singleton set.
73.
Normal at '  '
14 x

5y
cos  sin 
 9 it passes through  14 cos 2, 5 sin 2 
74. The drawing procedure ends at 7th draw, if 3rd black ball comes at 7th draw. Hence,
in 1st six draws there will be 2 black balls and 4 white balls. So, required probability
10
C 3 C2 1 15
 134  
C6 7 286
75. Lines are coplanar  a  c b d   0

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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s
2 0 4
 1 2  2  0    0,  2 For 2
  2, we get parallel lines
1 2 2
76.  
As g    x    x  g  x    1  x  Differentiating, we get,

g '    x '  x  1  g '    x 

1
when   x   2  x2  4 x  3  2  x  5, x  1
  x '

1
 x  2  x  5 , g '  2 
1

 2x  4 x5 6
77. 1 0 0   1 0 0
P  3 1 0  
P   3 32
1 0 
9 3 1  9  9  9 3  3 1 
 
 1 0 0   1 0 0  1 0 0
 
P 3  3  3  3 1 0  P n   3n 1 0 P 5   5.3 1 0 
 n n 1
 6.9 3  3  3 1 
   32 3n 1  15.9 5.3 1 
 2 
 2 0 0
q q 15  135
Q  P5  I 3 Q   15 2 0  21 31   10
q32 15
135 15 2 
78.  3
4 4
R    cos x  sin x  dx   sin x  cos x  dx
0 
4
 3
  sin x  cos x    cos x  sin x 
4
0 
4   2 1   0  2   2 2  1
4
   
79. let, ABCD be the tetrahedron and position vectors of A, B, C, D be a, b, c, d
   
respectively Given b  a  12& d  c  15

    
      
 d  b . b  a  d  c 
Shortest distance = 
    
  10... 1
b  a    d  c
Also, volume =  d  b . b  a    c  a    200... 2  , From (1) and (2), we get,
1      
6
       
  
b  a  d  c 10  6  200
2
b  a d  c sin  120 sin     sin
3
2
3
1

80. Let A and B be the centers of the two circles where the poles of height 10m and 20m
respectively stand making angles 300 and 600 respectively at the point O where
these circles touch each other externally

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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s

O
20 10
300
600
B A

The sum of the radii of two circles = The distance between the centres of the two
20 30  20
circles  10 cot 300  20 cot 600 = 10 3   meters
3 3
81. Let f (x) = x3  3x2  6 x  3  2cos x  '  x   3x 2  6 x  6  2sin x
 
 '  x   3 x 2  2 x  2  2sin x  '  x  is always positive as the minimum value of
3 x2  2 x  2 is 3 and that of 2sin x is 2, so   x  is increasing in  0,1
  0   1,  1  13  2cos x  0   x   0 has no solution in  0,1 n  0  n  2  2
82. cos 4 xdx sec2 xdx
Let, I   3  3

sin x 1  cot x
6 5
 5   1 5  5
tan x 1  
6 
 
  tan x  
 
Substituting, 1 
1
5  t and 
5
sec2 x dx  dt  
 tan x  6
tan x  
2
2
1 dt  1  t 5
I    3/5   
5 t  5  2
1
 C   1  cot 5 x 5  C Hence, K  2, P  5
2  
 
5
83.

2

O 

  
Max | sin x |,| sin 1  sin x  | is | sin 1  sin x  |  sin 1  sin x  is a periodic function of 
1   n 2 6 2
period  I n  n  area of    n       I2  I4 
2 2 4 4
84.  f(x) has one root between 1 and 3  f(1). f(3) < 0  (1-6+9+k)(27-54+27+k)<0
 (K+4) (k) < 0  k  (-4, 0)K=-3,-2,-1 Number of integral values of K is 3
   
85. Since, x , y and x  y are 3 non-coplanar vectors
Hence,  a  3 2  b  4    c 1  0  a  3  2   b  4     c 1  0
 a  3  2  b  4    c 1  0 We can say that  a  3 x2   b  4 x   c 1  0 has

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roots  ,  ,  Since, quadratic equation has 3 roots so it becomes an identity
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 SRI CHAITANYA IIT ACADEMY, INDIA GTM-02 _KEY &Sol’s

a  b  c 26
2 2 2
 a  3  0, b  4  0, c 1  0  a  3, b  4, c  1    13
2 2
86. 2 10  4 10
Combined mean, x   3 d1  x1  x  1
20
n112  n2 2  n1d12  n2d22
d2  x2  x  1Combined variance 
n1  n2
11 10  4 10  k 10 1 10 1
   K 5
2 20
87.  x 2 x3   x 2 
a 1  x    ..  b 1   ...   c  dx
2! 3!   2!
Using expansions, we get, lim  2
 3
x0
 x 3 
x  x   .... 
 3! 
 in the denominator lowest power of x is 3
For the limit to be finite, the numerator should also have the least power of x as 3
 Constant, coefficient of x and coefficient of x2 and 0 in NR
a b
a  b  c  0....1 a  d  0... 2   0... 3 Also, coefficient of x3 NR >3
2
a
6
Now,    3  a  18 From 1 ,  2  ,  3 , we get, a  18, b  18, c  36, d  18
1
abd  18
3
1
3  3 
c 8 18  8
88. 35  5 7 n is either divisible by 5 or 7 Sum of such n is
=sum of no of divisible by 5+sum of number of divisible by 7-sum of number of
divisible by 35  15  20  ..  95  14  21  ....98    35  70 
1  x 1  2 x    1 8 C1 x 1  2 x  8 C2 x 2 1  2 x 
8
89. 2

8 C3 x3 8 C4 x 4 1  2 x  .........
4

The coefficient of x4 is
8
C2.22 8 C3.2.3 8 C4
8  7 2 8 7  6 8 7  6  5
 2  .3.2   112  336  70  154
2 3 2 4  3 2
90. 1 1
 2 2
cos x sin x
sin x  cos x  2 sin 2 x
 
sin 2 x  sin  x  
 4
n  
2 x  n  1  x   , x  one between 0 and 2 
 4 4

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