2

NCERT LINE BY LINE QUESTIONS

(1.) In hydrogen‐oxygen fuel cell, combustion of hydrogen occurs to
(a.) Produce high purity water (b.) Create potential difference between two
electrodes
(c.) generate hear (d.) remove adsorbed oxygen from electrode
surface
(2.) Fluorine is a best oxidising agent because it has
(a.) highest electron affinity (b.) highest E°red
(c.) highest E ooxid (d.) lowest electron affinity
(3.) (180.) E for the half cell Zn / Zn is −0.76 emf of the cell
o 2+

Zn / Zn 2+ (1M ) ‖2H + (1M ) | H 2 (1 atm ) is

(a.) −0.76V
(b.) +0.76
(c.) −0.38V
(d.) +0.38V

(4.) The electrolyte used in Leclanche cell

(a.) Paste of KOH and ZnO (b.) 38% solution of H 2SO 4
(c.) Moist paste of NH 4Cl and ZnCl2 (d.) Moist NaOH

(5.) Assertion: E Ag+ /Ag increases with increase in concentration of Ag + ions.

Reason: E Ag+ /Ag has a positive value.
(a.) Both and R are true and R is correct (b.) Both A and R are true and R is not correct
explanation of A. explanation of A.
(c.) A is true but R is false. (d.) Both A and R are false.

(6.) Hydrogen electrode is placed in the solution where pH is 10. The potential of this electrode
will be
(a.) +0.591 V (b.) −0.591 V
(c.) 0V (d.) none of these

(7.) For a reaction

A ( s ) + 2B+ → A 2+ + 2B ( s )
K C has been found to be 1012 . The E ocell is
(a.) 0.354 V (b.) 0.708 V
(c.) 0.0098 V (d.) 1.36 V

(8.) The order of equivalent conductance at infinite dilution of LiCl , NaCl and KCl ?
(a.) LiCl > NaCl > KCl (b.) KCl > NaCl > LiCl
(c.) NaCl > KCl > LiCl (d.) LiCl > KCl > NaCl

(9.) The reference electrode is made by using

9
(a.) ZnCl2 (b.) CuSO 4
(c.) HgCl2 (d.) Hg 2Cl2

(10.) Which one of the following is a strong electrolyte?

(a.) Ca ( NO3 ) 2
(b.) HCN
(c.) H 2SO3 (d.) NH 4OH

(11.) Which of the following decrease on dilution of electrolyte solution?

(a.) equivalent conductance (b.) molar conductance
(c.) specific conductance (d.) conductance

(12.) The variation of equivalent conductance of strong electrolyte with concentration is correctly
shown in which figure:

(a.) (b.)

(c.) (d.)

(13.) The quantity of charge required to obtain one mole of aluminum from Al2O3 is

(a.) 1P (b.) 6 F
(c.) 3 F (d.) 2 F

(14.) Electrolysis of H 2SO 4 (conc.) gives the following at anode?

(A) H 2 (B) O 2 (C) H 2S2O3 (D) H 2S2O8
X ×1000 2 ×1000
(a.) Λ= (b.) Λ=
0.1 X × 0.1
X ×1000 0.5
(c.) Λ= (d.) Λ=
0.5 1000X

(15.) Using the data given below find out the strong oxidising agent
E Cl O2 /Cr3+ = 1.33V E oCl /Cl− = 1.36V
2 7 2

E o
MnO 4 /Mn 2+
= 1.51V E o
Cr 3+ /Cr
= −0.74V

(a.) Cl−
(b.) Mn 2+
(c.) MnO −4

10
(d.) Cr 3+

(16.) E o for the cell Zn | Zn 2+ ( aq ) ‖Cu 2+ ( aq ) / Cuisl.10V at 25 C is 1. 10V at 25o C . The equilibrium
constant for the cell reaction
Zn + Cu 2+ ( aq ) � Cu + Zn 2+ ( aq ) is of the order of
(a.) 10−37 (b.) 1037
(c.) 10−17 (d.) 1017

(17.) When dil.HNO3 is electrolysed

(a.) H 2 ( g ) is formed at anode (b.) O 2 ( g ) is formed at anode
(c.) NO 2 is formed at anode (d.) N 2 is formed at anode

(18.) The equivalent conductivity of a solution containing 2.54 g of CuSO 4 per litre is 91Ω −1cm 2eq −1 .
Its conductivity would be
(a.) 2.9 ×10−3 Ω −1cm −1 (b.) 1.8 ×10−2 Ω −1cm −1
(c.) 2.4 ×10−4 Ω −1cm −1 (d.) 3.6 ×10−3 Ω −1cm −1

(19.) Prevention of corrosion of iron by zinc coating is called

(a.) electrolysis (b.) Photoelectrolysis
(c.) cathodic protection (d.) galvanization

(20.) Which of the following is not an anodic reaction?

(a.) Ag + → Ag − e − (b.) Cu → Cu 2+ + 2e −
(c.) Fe 2+ → Fe3+ + e − (d.) 4OH − → 2H 2O + O 2 + 4e −

(21.) When 0.1 mol MnO 24− is oxidised the quantity of electricity required to completely oxidise
MnO 24− to MnO −4 is
(a.) 96500 C (b.) 2 × 96500C
(c.) 9650 C (d.) 96.50 C

(22.) The oxidation potential of a hydrogen electrode at pH = 1 is ( T = 298K )

(a.) 0.059 V (b.) O
(c.) −0.059 V (d.) 0.59 V

(23.) On the basis of E  values, the strongest oxidizing agent is

3−
 Fe ( CN )6  →  Fe ( CN )6  + e − ;E  =
4
−0.35V
Fe 2+ → Fe3+ + e − ;E  =
−0.77V
(a.) Fe3+
3−
(b.)  Fe ( CN )6 
4−
(c.)  Fe ( CN )6 

(d.) Fe 2+

11
(24.) Molar conductance ( Λ om ) at infinite dilution of NaCl, HCl and CH 3COONa are 126.4, 425.9 and
91.0 Scm 2 mol−1 resp.
Λ om for CH 3COOH will be
(a.) 425.5Scm 2 mol −1 (b.) 180.5Scm 2 mol −1
(c.) 290.8Scm 2 mol−1 (d.) 390.5Scm 2 mol−1

(25.) The passage of electricity in the Daniel cell when Zn and Cu electrodes are connected is:

(a.) From Cu to Zn in the cell (b.) From Cu to Zn outside the cell

(c.) From Zn to Cu outside the cell (d.) In any direction of cell

(26.) KCl is used in salt bridge because [

(a.) it forms a good jelly with agar‐agar (b.) it is a strong electrolyte
(c.) it is a good conductor of electricity (d.) the transference number of K + and Cl−
ions are almost equal

(27.) The cell constant of a conductivity cell —

(a.) changes with change of electrolyte (b.) changes with change of concentration of
electrolyte
(c.) change with temperature of electrolyte (d.) remains constant for a cell

(28.) The number of electrons delivered at the cathode during the electrolysis by a current of 1 A in
= 1.6 ×10−19 C)
60 seconds is ( charge one electron
(a.) 6 ×1023 (b.) 6 ×1020
(c.) 3.75 × 1020 (d.) 7.48 × 1023

(29.) The specific conductance in ohm −1cm −1 of four electrolytes P, Q, R and S are given below:
P= 5 × 10−5
Q= 7 ×10−8
R = 1×10−10
S 9.2 ×10−3
=
The one that offers highest resistance to the passage of current is
(a.) P (b.) S
(c.) R (d.) Q

(30.) Which of the following is a cathode R × N ?

(a.) Fe 2+ → Fe3+ (b.) 4OH − → 2H 2O + O 2
(c.) 2H 2O → 2OH − + H 2 (d.) 2SO 24− → S2O82−

(31.) If the E ocell for a given reaction has negative value, which of the following gives the correct
relationship for the values of ΔG  and K eq ?
(a.) ΔG  >, K eq < 1 (b.) ΔG o > 0; K eq > 1
(c.) ΔG  < 0;K eq > 1 (d.) ΔG o < 0;K eq < 1

(32.) Cell reaction is spontaneous when

12
(a.) ΔG  is negative (b.) ΔG o is positive
(c.) ΔE ored is positive (d.) ΔE ored is negative

(33.) For a given half cell: Al3+ + 3e − → Al, ⋅ on increasing  Al3+  , the electrode potential
(a.) increase (b.) decrease
(c.) No change (d.) first decrease then increase

(34.) Assertion: Mercury cell does not give steady potential.

Reason: In the cell reaction, ions are not involved in solution.

(a.) Both A and R are true but R is correct (b.) Both A and R are true and R is not correct
explanation of A. explanation of A.
(c.) A is true bur R is false. (d.) A is false but R is true.

(35.) Which of the following statements is not correct about an inert electrode in a cell
(a.) It does not participate in the cell reaction. (b.) It provides the surface either for oxidation
or reduction reaction.
(c.) It provides surface for the conduction of (d.) It provides surface for redox reaction.
electrons.

(36.) The standard oxidation potentials for the half cell reactions are
Zn → Zn 2+ + 2e − ;E o =
+0.76V
Pe → Fe 2+ + 2e − ;E o =
+0.41V
The emf of the cell reaction:
Fe 2+ + Zn → Zn 2+ + Fe is
(a.) −0.35V (b.) +0.35V
(c.) +1.17V (d.) −1.17V

(37.) (186.) Zn cannot displace following ions from their aqueous solution:
(a.) Ag + (b.) Cu 2+
(c.) Fe 2+ (d.) Na +

(38.) Matrix match.

Column 1 Column 2

(A) Λ m (p) Scm −1

(B) E cell (q) m −1

(C) K (r) Scm 2 mol−1

(D) G  (s) V

(a.) A → r, B → p,C → q, D → s (b.) A → r, B → s,C → p, D → q

(c.) A → r, B → s,C → p, D → q (d.) A → r, B → q,C → p, D → s

13
(39.) What will be the emf for the given cell
Pt H 2 ( P1 ) H + ( aq ) ‖H 2 ( P2 ) | Pt
RT P RT P
(a.) log e 1 (b.) log e 1
F P2 2F P2
RT P (d.) none of the above
(c.) log e 2
F P1
(40.) How much electric charge is required to oxidize 1 mole of FeO to Fe 2O3 ?
(a.) 49600 C (b.) 2 × 96500C
(c.) 96500 C (d.) 4 × 96500C

(41.) Assertion: Λ m for weak electrolytes show a sharp increase when the electrolytic solution is
diluted. Reason: For weak electrolytes degree of dissociation increases with dilution of
solution.

(a.) Both A and R are true and R is correct (b.) Both A and R are true and R is nor correct
explanation of A. explanation of A.
(c.) A is true but R is false. (d.) Both A and R are false.

(42.) Which one is not called a anode reaction from the following?

(a.)
1 (b.) Cu → Cu 2+ + 2e −
Cl! → Cl2 + e −
2
(c.) Hg + → Hg 2+ + e − (d.) Zn 2+ + 2e − → Zn

(43.) The unit of equivalent conductivity is

(a.) ohm cm (b.) ohm −1cm 2 ( g equivalent )
−1

(c.) ohm cm 2 ( g equivalent ) (d.) S cm −2

(44.) The molar conductivity of a 0.5 mol / dm3 solution of AgNO3 with electrolytic conductivity of
5.76 × 10−3 Scm −1 at 298 K is
(a.) 2.88 S cm 2 / mol (b.) 11.52 S cm 2 / mol
(c.) 0.086 S cm 2 / mol (d.) 28.8 S cm 2 / mol

(45.) Assertion: Cu is less reactive than hydrogen.

Reason: E °Cu 2+ /Cu is negative.
(a.) Both A and R are true R is correct (b.) Both A and R are true and R is not the
explanation of A. correct explanation of A.
(c.) A is true but reason is false. (d.) Both A and R are false.

(46.) The emf of the cell

= Zn | Zn 2+ ( a 0.1/1M
= ) ‖Fe2+ ( a 0.01M ) / Fe is 0.2905 V . The equilibrium
constant for the cell reaction is
(a.) 100.32/0.591 (b.) 10032/0.0295
(c.) 100.26/0.0295 (d.) 10032/0295

14
 (47.) How many moles of electrons are needed for the reduction of 20 ml of 0.5 M solution of
KMnO 4 in acidic medium
(a.) 5 ×10−2 (b.) 5 ×10−3
(c.) 10−2 (d.) 10−5

(48.) Standard reduction potentials at 25 C, Li + / Li, Ba 2+ / Ba, Na + / Na and Mg 2+ / Mg are

−3.05, −2.90, −2.71 and −2.37V respectively. Which one of the following is strongest oxidising
agent?
(a.) Ba 2+ (b.) Mg 2+
(c.) Na + (d.) Li +

(49.) How many gram of cobalt metal will be deposited when a solution of cobalt (II) chloride is
electrolyzed with a current of 10 A for 109 minutes (1F = 96500C , atomic mass of Co = 59u)
(a.) 4.0 (b.) 20.0
(c.) 40.0 (d.) 0.66

(50.) In SHE, the pH of acid solution should be

(a.) 7 (b.) 14
(c.) 0 (d.) 4

TOPIC WISE PRACTICE QUESTIONS

TOPIC 1: Cells and Electrode Potential
1. The function of a salt bridge is to
1) maintain electrical neutrality of both half cells.
2) increase the cell potential at the positive electrode.
3) decrease the cell potential at the negative electrode.
4) eliminated the impurities present in the electrolyte.
2. Standard electrode potential of SHE at 298 K is:
1) 0.05 V 2) 0.10 V 3) 0.50 V 4) 0.00 V
3. The standard EMF of quinhydrone electrode is 0.699 V. The EMF of the quinhydrone electrode dipped
in a solution with pH = 10 is:
1) 0.109 V 2) – 0.109 V 3) 1.289 V 4) – 1.289 V
4. If E Fe2+ / Fe = −0.441V and E Fe3+ / Fe2+ = +0.771V the standard EMF of the reaction Fe + 2Fe3+ → 3Fe 2+ will
o o

be
1) 1.653 V 2) 1.212 V 3) 0.111 V 4) 0.330 V
5. In the electrolytic cell, flow of electrons is from
1) cathode to anode in solution. 2) cathode to anode through external supply.
3) cathode to anode through internal supply. 4) anode to cathode through internal supply.
6. Which device converts chemical energy of a spontaneous redox reaction into electrical energy?
1) Galvanic cell 2) Electrolytic cell 3) Daniell cell 4) both 1) and 3)
7. Which of the following reaction is possible at anode?
1) 2Cr 3+ + 7H 2 O → Cr2 O72− + 14H + 2) F2 → 2F−
3) (1/ 2 ) O 2 + 2H + → H 2 O 4) None of these
8. Which one is not called a anode reaction from the following?
1
1) Cl− → Cl2 + e − 2) Cu → Cu ++ + 2e − 3) Hg + → Hg ++ + e − 4) Zn
2+
+ 2e − → Zn
2

15
9. Which one of the following statement is true for a electrochemical cell?
1) H 2 is cathode and Cu is anode. 2) H 2 is anode and Cu is cathode.
3) Reduction occurs at H 2 electrode. 4) Oxidation occurs at Cu electrode.

10.
1) Weston cell 2) Daniel cell 3) Calomel cell 4) Faraday cell
11. If the following half cells have E° values as
A 3+ + e − → A 2 + , E o =
y2V
2+ −
A + 2e → A, E = o
− y1V
The E o of the half-cell A 3+ + 3e → A will be
2y1 − y 2 y − 2y1
1) 2) 2 3) 2y1 − 3y 2 4) y 2 − 2y1
3 3
12. A concentration cell is a galvanic cell in which
1) Decrease in free energy in a spontaneous chemical process appears as electrical energy.
2) Decrease in free energy in a spontaneous physical process appears as electrical energy.
3) Decrease in free energy in a spontaneous physical or chemical process appears as electrical energy.
4) A non-spontaneous physical or chemical process produces electrical energy.
13. Based on the cell notation for a spontaneous reaction, at the anode :
Ag (s) | AgCl (s) | Cl– (aq) || Br – (aq) | Br 2 (l) | C (s)
1) AgCl gets reduced 2) Ag gets oxidized 3) Br– gets oxidized 4) Br 2 gets reduced
14. Zn can displace:
1) Mg from its aqueous solution. 2) Cu from its aqueous solution.
3) Na from its aqueous solution. 4) Al from its aqueous solution.
15. The oxidation potential of a hydrogen electrode at pH = 10 and H 2 p = 1 atm is
1) – 0.59 V 2) 0.00 V 3) + 0.59 V 4) 0.059 V

16. The tendency of an electrode to lose electrons is known as

1) Electrode potential 2) reduction potential 3) Oxidation potential 4) e.m.f.
17. A smuggler could not carry gold by depositing iron on the gold surface since
1) Gold is denser 2) iron rusts
3) Gold has higher reduction potential than iron 4) Gold has lower reduction potential than iron
o 2+
18. The correct order of E M / M values with negative sign for the four successive elements Cr, Mn, Fe and
Co is
1) Mn > Cr > Fe > Co 2) Cr < Fe > Mn > Co 3) Fe > Mn > Cr > Co 4) Cr > Mn > Fe > Co
TOPIC 2: Nernst Equation
19. The E° at 25 °C for the following reaction is 0.22 V. Calculate the equilibrium constant at 25° C :
H 2 ( g ) + 2AgCl ( s ) → 2Ag ( s ) + 2HCl ( aq )
1) 2.8 × 10 2) 5.2 × 10 3) 5.2 × 10 4) 5.2 × 10
7 8 6 3

20. For the given Nernst equation

Which of the following representation is correct?

21. For a given reaction: M(x+n) + ne– → Mx+, E– red is

known along with M(x + n) and Mx+ ion concentrations. Then
1) n can be evaluated. 2) x can be evaluated.
3) (x + n) can be evaluated. 4) n, x, (x + n) can be evaluated.
22. Without losing its concentration ZnCl 2 solution cannot be kept in contact with
1) Au 2) Al 3) Pb 4) Ag
23. The oxidation potentials of A and B are +2.37 and +1.66 V respectively. In chemical reactions
1) A will be replaced by B 2) A will replace B

16
 3) A will not replace B 4) A and B will not replace each other
24. The emf of the cell
Ni | Ni2+ (1.0 M)| | Au3+ (1.0M)| Au is
[Given E0Ni2+ / Ni = – 0.25 V and E0Au3+/ Au = + 1.5 V]
1) 2.00 V 2) 1.25 V 3) – 1.25 V 4) 1.75 V
25. In the cell reaction
Cu(s) + 2Ag+ (aq) → Cu2+ (aq) + 2Ag(s) ,
Eo cell = 0.46 V. By doubling the concentration of Cu2+, Eo cell will become
1) Doubled 2) halved
3) Increases but less than double 4) decreases by a small fraction
26. Following cell has EMF 0.7995V.
Pt | H 2 (1 atm) | HNO 3 (1M) || AgNO 3 (1M) | Ag
If we add enough KCl to the Ag cell so that the final Cl– is 1M. Now the measured emf of the cell is
0.222 V. The K sp of AgCl would be –
1) 1 × 10–9.8 2) 1 × 10–19.6 3) 2 × 10–10 4) 2.64 × 10–14
27. In a cell that utilises the reaction
Zn(s) +2H- (aq ) → Zn2+ (aq )+ H 2 (g) addition of H 2 SO 4 to cathode compartment, will
1) Increase the E and shift equilibrium to the right
2) Lower the E and shift equilibrium to the right
3) Lower the E and shift equilibrium to the left
4) Increase the E and shift equilibrium to the left
28. At equilibrium:
1) E 0cell = 0, ∆ G° = 0 2) E cell = 0, ∆ G = 0 3) Both are correct 4) None is correct
29. Equivalent conductivity can be expressed in terms of specific conductance ( κ ) and concentration (N) in
gram equivalent dm–3 as :
κ ×1000 κ× N
1) κ × N 2) 3) 4) κ × N × 1000
N 1000
30. The ionic conductivity of Ba2+ and Cl– at infinite dilution are 127 and 76 ohm–1 cm2 eq–1 respectively.
The equivalent conductivity of BaCl 2 at infinity dilution (in ohm–1cm2 eq–1)
would be :
1) 203 2) 279 3) 101.5 4) 139.5
31. The increase in equivalent conductivity of a weak electrolyte with dilution is due to
1) increase in degree of dissociation and decrease in ionic mobility.
2) decrease in degree of dissociation and decrease in ionic mobility.
3) increase in degree of dissociation and increase in ionic mobility.
4) decrease in degree of dissociation and increase in ionic mobility.
32. For a relation
∆rG = − nFE cell
E cell = E 0cell in which of the following condition?
1) Concentration of any one of the reacting species should be unity
2) Concentration of all the product species should be unity.
3) Concentration of all the reacting species should be unity.
4) Concentration of all reacting and product species should be unity.
33. If x is the specific resistance of the solution and N is the normality of the solution, the equivalent
conductivity of the solution is given by
1) 1000 x/N 2) 1000/Nx 3)1000N/x 4)Nx/1000
–1
34. For an electrolyte solution of 0.05 mol L , the conductivity has been found to be 0.0110 S cm– 1. The
molar conductivity is
1) 0.055 S cm2 mol– 1 2) 550 S cm2 mol–1 3) 0.22 S cm2 mol–1 4) 220 S cm2 mol–1
35. On which of the following magnitude of conductivity does not depends?
1) Nature of material 2) Temperature 3) Pressure 4) Mass of the material
36. The resistance of 0.01 N solution of an electrolyte was found to be 220 ohm at 298 K using a
conductivity cell with a cell constant of 0.88cm–1. The value of equivalent conductance
of solution is –
1) 400 mho cm2 g eq–1 2) 295 mho cm2 g eq–1

17
 3) 419 mho cm2 g eq–1 4) 425 mho cm2 g eq–1
37. The correct order of equivalent conductance at infinite dilution of LiCl, NaCl and KCl is
1) LiCl > NaCl > KCl 2) KCl > NaCl > LiCl
3) NaCl > KCl > LiCl 4) LiCl > KCl > NaCl
38. Which of the following expression correctly represents molar conductivity?
K KA
1) ∧ m = 2) ∧ m = 3) ∧ m = KV 4)all of these
C 1
39. At 25°C, the molar conductance at infinite dilution for the strong electrolytes NaOH, NaCl and BaCl 2
are 248 × 10–4, 126 × 10–4 and 280 × 10–4 Sm2mol–1 respectively.
∧ 0m Ba ( OH )2 in S m 2 mol−1 is
1) 52.4 × 10–4 2) 524 × 10–4 3) 402 × 10–4 4) 262 × 10–4
40. The ion of least limiting molar conductivity among the following is
2+
1) SO 24− 2) H + 3) Ca 4) CH 3COO −
41. Specific conductance of a 0.1 N KCl solution at 23ºC is 0.012 ohm–1 cm–1. Resistance of cell containing
the solution at same temperature was found to be 55 ohm. The cell constant is
1) 0.0616 cm–1 2) 0.66 cm–1 3) 6.60 cm–1 4) 660 cm–1
42. The equivalent conductances of two strong electrolytes at infinite dilution in H 2 O (where ions move
freely through a solution) at 25°C are given below:
Λ 0 CH3COONa = 91.0S cm 2 / equiv.
Λ 0 HCl = 426.2S cm 2 / equiv.
What additional information/ quantity one needs to calculate
Λ 0 of an aqueous solution of acetic acid?
1) Λ 0 of chloroacetic acid (ClCH 2 COOH) 2) Λ 0 of NaCl
3) Λ 0 of CH 3 COOK 4) the limiting equivalent coductance of H + ( λ 0 H+ )

TOPIC 4: Electrolysis and Types of Electrolysis

43. The electric charge required for electrode deposition of one gram - equivalent of a substance is :
1) one ampere per second. 2) 96500 coulombs per second.
3) one ampere for one hour. 4) charge on one mole of electrons.
44. How many minutes will it take to plate out 5.2 g of Cr from a Cr 2 (SO 4 ) 3 solution using a current of 9.65
A?
(Atomic mass: Cr = 52.0)
1) 200 2) 50 3) 100 4) 103
45. Which of the following is the use of electrolysis?
1) Electrorefining 2) Electroplating 3) Both 1) & 2) 4) None of these
46. By virtue of Faraday's second law of electrolysis, the electrochemical equivalent of the two metals
liberated at the electrodes has the same ratio as that of their
1) atomic masses 2) molecular masses 3) equivalent masses 4) any of three
47. In electrolysis of very dilute NaOH using platinum electrodes
1) H 2 is evolved at cathode and O 2 at anode 2) NH 3 is produced at anode
3) Cl 2 is obtained at cathode
4) O 2 is produced at cathode and H 2 at anode
48. Reaction that takes place at graphite anode in dry cell is
1) Zn 2+ ( aq ) + 2e − → Zn ( s ) 2) Zn ( s ) → Zn ( aq ) + 2e
2+ −

3) Mn
2+
( aq ) + 2e− → Ms ( s ) 4) Mn ( s ) → Mn
+
( aq ) + e− + 1.5V
49. Electrolysis of fused NaCl will give
1) Na 2) NaOH 3) NaClO 4) None of these
50. An unknown metal M displaces nickel from nickel (II) sulphate solution but does not displace
manganese from manganese sulphate solution. Which order represents the correct order of reducing
power?
1) Mn > Ni > M 2) Ni > Mn > M 3) Mn > M > Ni 4) M > Ni > Mn

18
51. A solution of sodium sulphate in water is electrolysed using inert electrodes. The products at the cathode
and anode are respectively
1) H 2 , O 2 2) O 2 , H 2 3) O 2 , Na 4) O 2 , SO 2
52. If 0.5 amp. current is passed through acidified silver nitrate solution for 100 minutes. The mass of silver
deposited on cathode, is (eq.wt.of silver = 108)
1) 2.3523 g 2) 3.3575 g 3) 5.3578 g 4) 6.3575 g
53. Find the charge in coulombs required to convert 0.2 mole VO32− into VO34−
1) 1.93 × 104 2) 9.65 × 104 3) 1.93 × 105 4) 9.65 × 105
54. The amount of electricity that can deposit 108 g of Ag from AgNO 3 solution is:
1) 1 F 2) 2 A 3) 1 C 4) 1 A
55. Three faradays electricity was passed through an aqueous solution of iron (II) bromide. The weight of
iron metal
(at. wt = 65) deposited at the cathode (in gm) is
1) 56 2) 84 3) 112 4) 168
TOPIC 5: Commercial Cell and Corrosion
56. Which of the following statement is false for fuel cells?
1) They are more efficient 2) They are free from pollution
3) They run till reactants are active 4) Fuel burned with O 2
57. Among the following cells:
(i) Leclanche cell (ii) Nickel-Cadmium cell (iii) Lead storage battery (iv) Mercury cell
primary cells are
1) (i) and (ii) 2) (i) and (iii) 3) (ii) and (iii) 4) (i) and (iv)
58. Identify the correct statement :
1) Corrosion of iron can be minimized by forming a contact with another metal with a higher reduction
potential.
2) Iron corrodes in oxygen free water
3) Corrosion of iron can be minimized by forming an impermeable barrier at its surface.
4) Iron corrodes more rapidly in salt water because its electrochemical potential is higher.
59. Several blocks of magnesium are fixed to the bottom of a ship
1) make the ship lighter. 2) prevent action of water and salt.
3) prevent puncturing by under-sea rocks. 4) keep away the sharks.
60. Which of the following batteries cannot be reused?
1) Lead storage battery 2) Ni-Cd cell 3) Mercury cell 4) Both (2) and (3)

NEET PREVIOUS YEARS QUESTIONS

1. In the electrochemical cell :

Zn | ZnSO 4 (0.01M) | | CuSO 4 (1.0 M) | Cu, the emf of this Daniel cell is E 1 . When the concentration of
ZnSO 4 is changed to 1.0M and that of CuSO 4 changed to 0.01M, the emf changes to E 2 . From the
followings, which one is the relationship between E 1 and E 4 ? (Given,RT/F= 0.059) [2017]
1) E 1 < E 2 2) E 1 > E 2 3) E 2 = 0 ≠ E 1 4) E1 = E2
2. The pressure of H 2 required to make the potential of H 2 -electrode zero in pure water at 298 K is : [2016]
1) 10–14 atm 2) 10–12 atm 3) 10–10 atm 4) 10–4 atm
3. A device that converts energy of combustion of fuels like hydrogen and methane, directly into electrical
energy is known as : [2015]
1) Electrolytic cell 2) Dynamo 3) Ni-Cd cell 4) Fuel Cell
4. When 0.1 mol MnO 4 is oxidised the quantity of electricity required to completely oxidise MnO 42− to –
2−

MnO −4 is: [2014]

1) 96500 C 2) 2 × 96500 C 3) 9650 C 4) 96.50 C

19
5. The weight of silver (at wt. = 108) displaced by a quantity of electricity which displaces 5600 mL of O 2
at STP will be :-
[2014]
1) 5.4 g 2) 10.8 g 3) 54.9 g 4) 108.0 g
Θ
6. For a cell involving one electron E cell = 0.59V at 298 K, the equilibrium constant for the cell reaction is :-
2.303RT
[Given that = 0.059V at T = 298K ] [2019]
F
(1) 1.0 × 102 (2) 1.0 × 105 (3) 1.0 × 1010 (4) 1.0 × 1030
7. For the cell reaction 2Fe3+ ( aq ) + 2I − ( aq ) → 2Fe 2+ ( aq ) + I 2 ( aq )
E Θcell = 0.24V at 298 K. The standard Gibbs energy ( ∆ 0r G Θ ) of the cell reaction is : [2019]
–1
[Given that Faraday constant F = 96500 C mol ]
(1) –46.32 kJ mol–1 (2) –23.16 kJ mol–1 (3) 46.32 kJ mol–1 (4) 23.16 kJ mol–1
8. Following limiting molar conductivities are given as [2019-ODISSA]
x Scm 2 mol−1
l 0m( H2SO4 ) =
yScm 2 mol−1
l 0m( K 2SO4 ) =
z Scm 2 mol−1
l 0m( CH3COOK ) =

l 0m ( in Scm 2 mol−1 ) for CH 3COOH will be

( x − y) + z
(1) x − y + 2z (2) x + y − z (3) x − y + z (4)
2
9. The standard electrode potential (E.) values of Al /Al, Ag /Ag, K /K and Cr3+/Cr are .1.66 V, 0.80V, − −
3+ + +

2.93 V and − 0.74 V, respectively. The correct decreasing order of reducing power of the metal is :
[2019-ODISSA]
(1) Ag > Cr > Al > K (2) K > Al > Cr > Ag (3) K > Al > Ag > Cr (4) Al > K > Ag > Cr
10. Identify the reaction from following having top position in EMF series (Std.red. potential) according
to their electrode potential at 298 K. [2020-COVID-19]
2+ – 2+ –
(1) Mg + 2e → Mg (s) (2) Fe + 2e → Fe (s) (3) Au + 3e → Au (s) (4) K+ + le– → K (s)
3+ –

11. In a typical fuel cell, the reactants (R) and product (P) are :- [2020-COVID-19]
(1) R = H 2(g) , O 2(g) ; P = H 2 O 2(l) (2) R = H 2(g) , O 2(g) ; P = H 2 O (l)
(3) R = H 2(g) , O 2(g) , Cl 2(g) ; P = HClO 4(aq) (4) R = H 2(g) , N 2(g) ; P = NH 3(aq)
12. On electrolysis of dil sulphuric acid using platinum (Pt) electrode, the product obtained at anode will be
[2020]
1. SO2 gas 2. Hydrogen gas 3. Oxygen gas 4. H 2 S gas
13. The number of Faradays (F) required to produce 20g of calcium from molten CaCl 2 (Atomic mass of Ca
= 40 g mol–1) is [2020]
1) 4 2) 1 3) 2 4) 3
14. The molar conductance of NaCl, HCl and CH 3COONa at infinite dilution are 126.45,426.16 and 91.0 S
cm 2 mol −1 respectively. The molar conductance of CH 3COOH at infinite dilution is. Choose the right
option for your answer [NEET-2021]
−1 −1 −1
1) 390.71 S cm mol2 2
2) 698.28 S cm mol 3) 540.48 S cm mol2
4) 201.28 S cm 2 mol −1
15. The molar conductivity of 0.007 M acetic acid is 20 S cm 2 mol −1. What is the dissociation constant of
acetic acid? Choose the correct option. [NEET-2021]
Λ H + =
° 2
350 S cm mol −1

 ° 
 Λ CH3COO− = 50 S cm 2 mol −1 

−4 −1
1) 2.50 ×10 mol L 2) 1.75 ×10−5 mol L−1 3) 2.50 ×10−5 mol L−1 4) 1.75 ×10−4 mol L−1

20
16. Given below are half-cell reactions: [NEET-2022]
MnO -4 + 8H + + 5e- → Mn 2+ + 4H 2O, EoMn2+ /MnO- = -1.510V
4

1
O 2 + 2H + + 2e- → H 2O, EoO2 /H2O = +1.223V
2
Will the permanganate ion, MnO4− liberate O 2 from water in the presence of an acid?
o
1) Yes, because Ecell = +0.287V o
2) No, because Ecell = −0.287V
o
3) Yes, because Ecell = +2.733V o
4) No, because Ecell = −2.733V
17. At 298 K, the standard electrode potentials of Cu 2+ / Cu , Zn 2+ / Zn, Fe 2+ / Fe and Ag + / Ag are
0.34V , −0.76V , −0.44V and 0.80V respectively. [NEET-2022]
On the basis of standard electrode potential, predict which of the following reaction cannot occur?
1) CuSO ( ) + Zn( ) → ZnSO ( ) + Cu( )
4 aq s 4 aq s

2) CuSO4( aq ) + Fe( s ) → FeSO4( aq ) + Cu( s )

3) FeSO4( aq ) + Zn( s ) → ZnSO4( aq ) + Fe( s )
4) 2CuSO4( aq ) + 2 Ag( s ) → 2Cu( s ) + Ag 2 SO4( aq )
18. Find the emf of the cell in which the following reaction takes place at 298 K [NEET-2022]

Ni(s) + 2Ag + (0.001M) → Ni 2 + (0.001M) + 2Ag(s)

o 2.303 RT
(Given that Ecell = 1.05 V, = 0.059 at 298 K)
F
1)1.385 V 2) 1.385 V 3) 0.9615 V 4) 1.05 V

21
 NCERT LINE BY LINE QUESTIONS – ANSWERS
(1.) b (2.) b (3.) b (4.) c (5.) b
(6.) b (7.) a (8.) c (9.) d (10.) a
(11.) c (12.) b (13.) c (14.) d (15.) c
(16.) b (17.) b (18.) a (19.) d (20.) a
(21.) c (22.) a (23.) a (24.) d (25.) b
(26.) d (27.) d (28.) c (29.) c (30.) c
(31.) a (32.) a (33.) a (34.) d (35.) d
(36.) b (37.) d (38.) c (39.) b (40.) c
(41.) a (42.) d (43.) b (44.) b (45.) c
(46.) b (47.) a (48.) b (49.) b (50.) c

TOPIC WISE PRACTICE QUESTIONS - ANSWERS

1) 1 2) 4 3) 1 4) 2 5) 4 6) 4 7) 1 8) 4 9) 2 10) 2
11) 2 12) 2 13) 2 14) 2 15) 3 16) 3 17) 3 18) 1 19) 1 20) 3
21) 1 22) 2 23) 2 24) 4 25) 4 26) 1 27) 1 28) 2 29) 2 30) 2
31) 3 32) 3 33) 2 34) 4 35) 4 36) 1 37) 2 38) 4 39) 2 40) 4
41) 2 42) 2 43) 4 44) 2 45) 3 46) 3 47) 1 48) 2 49) 1 50) 3
51) 1 52) 2 53) 1 54) 1 55) 2 56) 4 57) 4 58) 3 59) 2 60) 3

NEET PREVIOUS YEARS QUESTIONS-ANSWERS

1) 2 2) 1 3) 4 4) 3 5) 4 6) 3 7) 1 8) 4 9) 2 10) 3
11) 2 12) 3 13) 2 14) 1 15) 2 16) 1 17) 4 18) 3

NCERT LINE BY LINE QUESTIONS – SOLUTIONS

(1.) (b) In H 2 − O 2 fuel cell, the combustion of H 2 occurs to create potential difference between the two
electrodes.
(4.) (c) The electrolyte used in Leclanche cell is moist paste of NH 4Cl and ZnCl2 .
+ −
(5.) (b) Ag + e → Ag
0.059 l
E=
Ag + / Ag E oAg+ /Ag − log
1  Ag + 
= E oAg+ /Ag + 0.059  Ag + 
On increasing  Ag +  , E oAg+ /Ag will increase and it has a positive value.
(6.) (b) −0.591V
(9.) (d) Calomel electrode is used as reference electrode.
(10.) (a) Weak acid
HCN → Weak acid 

NH 4OH → Weak base 
Ca ( NO3 )2 → Weak acid 
Weak electrolytes → Ca ( NO3 )2 → Strong Base →
Strong Acidic Salt → Strong electrolyte

22
(12.) (b)
i.e., on ↑ concentration dissociation of electrolytes decrease Λ m or Λ on decrease.
3+ 2−
(13.) (c) Al2O3 → 2Al + 3O
Al3+ + 3e − → Al ( For l mole )
3 F charge require to obtain 1 mole Al from Al2O3
(14.) (d) Electrolysis of Conc.H 2SO 4
H 2SO 4 → H + + HSO −4
at cathode 2H + + 2e − → H 2
at anode 2HSO −4 → H 2S2O8 ( Marshall'sacid ) + 2e −
(15.) (c)
0.059
E ocell =log K C 1.10 × 2
(16.) (b) 2 or = log K c
0.059
K=c 1.9 ×1037
(17.) (b) O 2 is formed at anode at anode and H 2 is formed at cathode.
(19.) (d) Prevention of corrosion by zinc coating is called galvanization.
+6
→ +7 − + e −
Mn O 2− 4 Mn O 4

(21.) (c) 0.1mol 0.1mol

Q = 0.1× F = 0.1× 96500 C = 9650 C
(22.) (a) 0.059 V
4−
 Fe ( CN )6  →  Fe ( CN )6  ;Bo =
3
+035V
(23.) (a) 
Fe3+ → Fe 2+ ;F :o =
+0.77V
Higher the positive reduction potential, stronger will be the oxidising agent. Oxidising agent oxidises
other compounds and get itself reduced easily.
(24.) (d) Λ NaCl = 126.4S cm mol
 2 −1

Λ HCl = 425.9 S cm 2 mol−1

Λ CH3COONa = 91.0 S cm 2 mol−1
Λ CH3COOH =
Λ CH3COONa + Λ HCl =
−Λ NaCl
=+91 425.9 − 126.4 = 390.5 S cm 2 mol−1
(25.) (b) From Cu to Zn outside the cell.
(27.) (d) The cell constant of a conductivity cell remain constant for a cell.
(28.) (c) Q = 1× t
Q =× 1 60 = 60C
Now,1.60 ×1019 C =
1 electron
60
∴ 60C = = 37.5 × 10
=19
3.75 ×1020 electrons
1.6 × 1019

(31.) (a) ΔG 
= −nFE ocell
If E oceIl = − ve then ΔG o = + Ve

23
 i.e. ΔG o > 0
ΔG  = −nRT log k eq
For ∆G  =
+ ve, K eq =
− ve i.e., K eq < 1
 A1  3+

log 
0.059
= E +
E A

(33.) (a)
3 [ A1]
so, if  A13+  ↑= E ↑
(34.) (d) A is false but R is true.
(35.) (d)
(38.) (c)
A → r, B → s,C → p 2 D → q
(39.) (b) RHS 2H + + 2e − � H 2 ( P2 )
LHS H 2 (P1 ) � 2H + 2e −
Overall Rxn: H 2 ( P1 ) � ( P2 )
RT P2 RT P2 RT P1
= E −
E ln = 0 − ln = ln
nF P1 nF P1 nF P2
(41.) (a) For weak electrolyte, Λ m increase steeply on dilution due to increase in the no. of ions (or degree of
dissociation).
(42.) (d) Zn + 2e → Zn
2+ −

ohm −1cm 2 ( geq )

−1

(43.) (b)
K ×100
Λm =
Molarity ( M )
(44.) (b)
10−3 Scm −1 ×1000
= 5.76 × −3
= 11.52 S cm 2 mol− ’
0.5 mol cm
(45.) (c) Cu is less reactive than hydrogen because SRP E oCu 2+ /Cu = 0.34V and E oH+ /H = 0.0V
0.0591
= E −
E log Q
(46.) (b) n

= Eo −
0.2905
0.0591
, log
[0.1]
2 [0.01]
E° = 0.295 + 0.0295 = +0.32V
0.0591
0.32 = log K
2
K = 100.32/0.265
= 0.5 × 20 × 10−8 = 10−2
(47.) (a) KMnO4
n
Mn 7+ + 5e − → Mn 2+
So, 1 mole KMnO 4 → 5 mole of e −
10−2 mol KMnO 4 → 5 ×10−2 mole e −
(48.) (b) A cation with maximum value of SRP has the strongest oxidising power.
I×T× E
W=
(49.) (b) 96500 = 10 ×109 × 60 × 59 = 20
96500 × 2
(50.) (c) In SHE concentration of solution is 1M HCl
1M HCl → H + + Cl−
− log  H +  =
pH = − log1 =
0

24
 TOPIC WISE PRACTICE QUESTIONS – SOLUTIONS
1. (1) Maintain electrical neutrality of both half cells.
2. 4)
3. 1) E = E° – 0.059 Ph = 0.699 – 0.059 × 10 = 0.109 V
4. 2)

5. (4) In electrolytic cell the flow of electrons is from anode to cathode through internal supply.
6. (4)
7. (1) 2Cr 3+ + 7H 2 O → Cr2 O72− + 14H +
O.S. of Cr changes from +3 to +6 by loss of electrons. At anode oxidation takes place.

8. 4) It shows reduction reaction.

9. (2) In electrochemical cell H2 has greater tendency to release electrons.
∴ H 2 is liberated at anode and Cu is deposited at the cathode.
10. (2) The cell in which Cu and Zn rods are dipped in its solution is called Daniel cell.
11. 2)

12. 2) In concentration cell the spontaneous process is physical in nature involving transfer of matter from
higher concentration to lower concentration in indirect manner.
13. (2) Ag becomes oxidized and Br– becomes reduced.
14. 2)

15. 3) E oxidation= 0.059 pH= 0.059 × 10 = 0.59V

16. 3) The magnitude of the electrode potential of a metal is a measure of its relative tendency to loose or
gain electrons. i.e., it is a measure of the relative tendency to undergo oxidation (loss of electrons) or
reduction (gain of electrons).
M → M n + + ne − (oxida�on poten�al)
M n + + ne − → M (reduc�on poten�al)
2+
17. 3) Gold having higher E oRed oxidises Fe → Fe
18. 1)

25
 0.0591 2 × 0.22
19. 1) = = ⇒ 7.44 or K eq ≈ 2.8 ×107
o
E log K eq ;log K eq
2 0.0591
20. 3)
M ( x +n )

log  x + 
0.059
21. 1) E= E o
+
 M 
red red
n
22. 2) Without losing its concentration ZnCl 2 solution cannot kept in contact with Al because Al is more
reactive than Zn due to its highly negative electrode reduction potential.
23. (2) A will replace B.
24. (4) Here Ni is anode and Au is cathode
Given E oNi2+ / Ni = 0.25V and E oAu3+ / Au = +1.5V
E ocell= E oC − E oA= 1.5 − ( −0.25 )= 1.5 + 0.25= 1.75V
25. 4) emf will decrease
26. 1)

27. 1)

Addition of H 2 SO 4 will increase [H+] and E cell will also

increase and the equilibrium will shift towards RHS.
28. 2) At equilibrium, ∆= G 0, E= cell 0
κ ×1000
29. 2) Λ eq =
N
30. 2) Λ m ( BaCl2 ) =l ∞m ( Ba 2+ ) + 2l ∞m ( Cl− ) =127 + 2 × 76 =279 ohm −1cm 2 eq −1
∞

31. (3) On dilution degree of dissociation of a weak electrolyte increase, hence increase in ionic mobility.
32. (3) When the concentration of all reacting species kept unity, then E cell = E° cell and the given relation
will become
∆rG = −nFE cell
o

33. (2) Specific resistance = x

26
 1
∴ Specific conductance (or conductivity) = κ =
x
κ ×1000 1000
=
∴Λ eq =
N xN
κ ×1000 0.0110 ×1000
34. =
4) Λm = = 220Scm 2 mol−1
M 0.05
35. 4) Conductivity does not depend upon mass or weight of material.
1000 1  1000 1 1000 1 1000
36. 1) Λ eq =
κ× =× × =× cell cons tan t × = × 0.88 × = 400mho cm 2 g eq −1
N R a N R N 220 0.01
37. (2) As we go down the group 1 (i.e. from Li+ to K+), the ionic radius increases, degree of solvation
decreases and hence effective size decreases resulting in increase in ionic mobility. Hence equivalent
conductance at infinite dilution increases in the same order.
38. 4)
39. 2)

40. (4) Larger the size, lower the speed.

41. (2) Specific conductance of the solution ( κ ) = 0.012 ohm–1 cm–1 and resistance (R) = 55 ohm.
Cell constant = Specific conductance × Observed resistance = 0.012 × 55= 0.66 cm–1.
42. (b) According to Kohlrausch’s law, molar conductivity of weak electrolyte acetic acid (CH 3 COOH) can
be calculated as follows:

43. 4) A + + e − → A
1mole 1mole

∴ Charge of 1 mole electron is required for deposition of 1 equivalent of substance.

52 9.65
44. 2) 5.2 =× × t ( sec )
3 96,500
t ( sec ) = 3000
t ( min ) = 50
45. (3) Electrorefining and electroplating are done by electrolysis.
46. (3)
47. (1) Reduction and oxidation of H 2 O occurs to give H 2 at cathode and O 2 at anode.
48. (2)
49. (1) When molten or fused NaCl is electrolysed, it yields metallic sodium and gaseous chlorine.
Reactions involved are as follows:

50. (3) Oxidation potential of M is more than Ni and less than Mn. Hence reducing power Mn > M > Ni
51. (1) Water is reduced at the cathode and oxidized at the anode instead of Na + and SO 24−

27
52. (b) Given current (i) = 0.5 amp;
Time (t) = 100 minutes × 60 = 6000 sec
Equivalent weight of silver (E) = 108.
According to Faraday's first law of electrolysis
Eit 108 × 0.5 × 6000
=W = = 3.3575g
96500 96500
53. (1) Charge = 0.2 × 1 Faraday = 0.2 × 96500 coulombs = 19300 = 1.93 × 104 coulombs
54. (1) According to Faraday law's of electrolysis, amount of electricity required to deposit 1 mole of metal
= 96500 C = 1 F i.e., for deposition of 108 g Ag electricity required = 1 F
56
55. (2) Fe 2+ + 2e − → Fe; E Fe = =28
2
1 Faraday liberates = 28 g of Fe
3 Faraday liberates = 3 × 28 = 84 g
56. (4) Combustion takes place.
57. (4) Primary cells are those cells, in which the reaction occurs only once and after use over a period of
time, it becomes dead and cannot be reused again. e.g., Leclanche cell and mercury cell.
58. (3) Corrosion of iron can be minimized by forming an impermeable barrier at its surface.
59. (2) Magnesium provides cathodic protection and prevent rusting or corrosion.
60. (3) Mercury cell being primary in nature can be used only once.

NEET PREVIOUS YEARS QUESTIONS-EXPLANATIONS

1. 2)

2. 1) 2H + ( aq ) + 2e − → H 2 ( g )
0.0591 PH
∴ E = E0 − log +2 2
2 [H ]
PH2
0= 0 − 0.0295log
(10−7 )
2

PH2
=1
(10 )−7 2

PH2 = 10−14 atm

3. 4) A device that converts energy of combustion of fuels, directly into electrical energy is known as fuel
cell.

28
4. 3)
Quantity of electricity required = 0.1F = 0.1 × 96500 = 9650 C
5. 4) w=
O2 n O2 × 32
5600
w O2 = × 32 = 8g = 1 equivalent of O 2 = 1 equivalent of Ag = 108
22400
6. 3)

7. 1) 2Fe
3+
( aq ) + 2I− ( aq ) → 2Fe2+ ( aq ) + I2 ( aq )
n = 2 ; ∆G 0 =−nFE 0
=−2 × 96500 × ( 0.24 ) =−46320J
= −46.32 kJ mol−1

8. 4)

9. 2)
10. (3) According to electrode potential series,
Au+3 + 3e − → Au (s) (has topmost position ⇒ max. SRP)
11. (2) In typical fuel cell
Reactants = H 2 , O 2
Products = H 2 O
12. 3)On electrolysis of dil H 2 SO 4

29
 1
As anodes H 2O → 2 H + + O2 + 2e − oxygen gas is liberated
2
13. 2)E of Ca = 40/2 = 20 gr
For the deposi�on of 1gram equivalent wt (20gr) 1F is required

14. 1) ∧ m CH 3OOH = ∧ HCl + ∧CH 3COONa − ∧ NaCl

0 0 0
= 0
( 426.16 + 91) − 126.45 = 390.71S cm2mol −1
15. 2) λ0 =Λ °H + λ0 ( CH 3COO − ) = 350 + 50= 400 ; λ =20 ; C = 0.007 m
+

7 ×10−3 × ( 20 )
2
Cλ 2
=Ka = ; K= 1.8 ×10−5
λ0 ( λ0 − λ ) 400 ( 400 − 20 ) c

16. In this reaction CunO4− reduce at cathode and H 2 O oxidise at anode. So given EMnO
o
−
/ Mn +2
= +1.510V ,
4

E o
O2 /H 2 O = +1.223V
o
Ecell =
1.510 − 1.223 =
+0.287 so, the reaction is spontaneous
17. 2CuSO4 + 2 Ag → 2Cu + Ag 2 SO4 Ag cannot displace copper from CuSO 4 solute
0.001
18.: E= 1.05 − 0.0295log = 1.05 − 0.0295 × 3= 10.5 − 0.0885= 0.9615v
( 0.001) 10−3
2

30
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 SKILL MODULES BEING OFFERED IN
MIDDLE SCHOOL

Artificial Intelligence Beauty & Wellness Design Thinking & Financial Literacy
Innovation

Handicrafts Information Technology Marketing/Commercial Mass Media - Being Media

Application Literate

Data Science (Class VIII Augmented Reality /

Travel & Tourism Coding
only) Virtual Reality

Digital Citizenship Life Cycle of Medicine & Things you should know What to do when Doctor
Vaccine about keeping Medicines is not around
at home

Humanity & Covid-19 Blue Pottery Pottery Block Printing

 Food Food Preservation Baking Herbal Heritage

Khadi Mask Making Mass Media Making of a Graphic

Novel

Kashmiri Embroidery Satellites

Rockets
Embroidery

Application of Photography
Satellites
SKILL SUBJECTS AT SECONDARY LEVEL (CLASSES IX – X)

Retail Information Technology Automotive

Security

Introduction To Financial Introduction To Tourism Beauty & Wellness Agriculture

Markets

Food Production Front Office Operations Banking & Insurance Marketing & Sales

Health Care Apparel Multi Media Multi Skill Foundation

Course

Artificial Intelligence
Physical Activity Trainer Electronics & Hardware
Data Science
(NEW)

Foundation Skills For Sciences Design Thinking & Innovation (NEW)

(Pharmaceutical & Biotechnology)(NEW)
 SKILL SUBJECTS AT SR. SEC. LEVEL
(CLASSES XI – XII)

Retail InformationTechnology Web Application Automotive

Financial Markets Management Tourism Beauty & Wellness Agriculture

Food Production Front Office Operations Banking Marketing

Health Care Insurance Horticulture Typography & Comp.

Application

Geospatial Technology Electrical Technology Electronic Technology Multi-Media

 Taxation Cost Accounting Office Procedures & Shorthand (English)
Practices

Shorthand (Hindi) Air-Conditioning & Medical Diagnostics Textile Design

Refrigeration

Salesmanship Business Food Nutrition &

Design
Administration Dietetics

Mass Media Studies Library & Information Fashion Studies Applied Mathematics
Science

Yoga Early Childhood Care & Artificial Intelligence Data Science

Education

Physical Activity Land Transportation Electronics & Design Thinking &

Trainer(new) Associate (NEW) Hardware (NEW) Innovation (NEW)