Vedclass

Subject : Chemistry Paper Set : 1

Standard : 11,12 Demo Date : 06-09-2024
Total Mark : 160 Time : 0H:0M

(8) Order of electron affinity of F, Cl, Br and I is .....

............ Chemistry - Section A (MCQ) ............
(A) F < Cl > Br > I (B) F > Cl > Br > I
o
(1) The ionic radii (A) of C 4− and O2− respectively are 2.60 and (C) F < Cl < Br < I (D) F > Cl < Br > I
1.40. The ionic radius of the isoelectronic ion N 3− would (9) The chemistry of lithium is very similar to that of magnesium
even though they are placed in different groups
o
be........A
(A) 131 (B) 2.83 (A) Both are found together in nature
(C) 1.71 (D) 2.63 (B) Both have nearly the same size
(2) First ionization energy is the lowest with (C) Both have similar electronic configuration
(A) Lead (B) Carbon
(D) The ratio of their charge to size is nearly the same
(C) Silicon (D) Tin
(10) Which has the maximum atomic radius
(3) Which of the following statement is wrong ?
(A) Al (B) Si
(A) The first ionization potential of Al is less than the first
ionization potential of M g (C) P (D) M g
(11) If three electrons could be accomodated in an orbital, then
(B) The second ionization potential of M g is greater than
the element with atomic no 50 will belong to:-
the second ionization potential of N a
(A) 4th period and p block (B) 5th period and s block
(C) The first ionization potential of N a is less than the first
ionization potential of M g (C) 4th period and d block (D) 5th period and p block
(12) The property of attracting electrons by the halogen atom in
(D) The third ionization potential of M g is greater than the
a molecule is called
third ionization potential of Al
(A) Ionisation potential (B) Electron affinity
(4) The element having electronic configuration
(C) Electronegativity (D) Electronic attraction
[Kr]4d10 4f 14 , 5s2 5p6 , 6s2 belongs to
(A) s − block (B) p − block (13) To which of the following atom, the attachment of electron
is most difficult?
(C) d − block (D) f − block (A) Radon (B) Nitrogen
(5) The electronic configuration of three elements A, B and C (C) Oxygen (D) Radium
are given below. The molecular formula of the compound
formed from B and C will be (14) Which one of the following is a different pair?
A : 1s2 2s2 2p6 (A) Li, N a (B) Be, Ba
B : 1s2 2s2 2p6 3s2 3p3 (C) N, As (D) O, At
C : 1s2 2s2 2p6 3s2 3p5
(15) The first ionization enthalpies of Be, B, N and O follow the
(A) BC (B) B2 C
order....
(C) BC2 (D) BC3 (A) O < N < B < Be (B) Be < B < N < O
(6) Which one of the following ionic species has the greatest (C) B < Be < N < O (D) B < Be < O < N
proton affinity to form stable compound ?
(16) Which of the following represents the correct order of
(A) N H2− (B) F −
metallic character of the given elements ?
(C) I − (D) HS − (A) Si < Be < M g < K (B) Be < Si < M g < K
(7) Then choose the correct option (C) K < M g < Be < Si (D) Be < Si < K < M g
(17) Sodium generally does not shown oxidation state of +2,
because of its
(A) High first ionisation potential
(B) High second ionization potential
(C) Large ionic radius
(D) High electronegativity
(18) The correct order of electronegativity for given elements is:
(A) A : La (B) B : Sc (A) C > P > At > Br (B) Br > P > At > C
(C) E : Hf (D) All are incorrect (C) P > Br > C > At (D) Br > C > At > P

1
 (19) If the IP of N a is 5.48 eV , the ionisation potential of K will (31) Consider the following reaction
be ............ eV M nO4− + 8H + + 5e− → M n2+ + 4H2 O, E ◦ = 1.51V
(A) Same as that of N a (B) 5.68 The quantity of electricity required in Faraday to reduce five
moles of M nO4− is ..... .
(C) 4.34 (D) 10.88
(20) Incorrect statements among the following is/are (32) When 0.1 mol M nO42− is oxidised the quantity of electricity
required to completely oxidise M nO42− to M nO4− is ........ C.
(A) 2nd electron gain enthalpy is always endothermic
(33) The electrode potential of the following half cell at 298 K
(B) Electronegativity is the property of bonding atoms
X X 2+ (0.001M )∥Y 2+ (0.01M ) Y
(C) Al2 O3 and BeO are amphoteric oxide is ....... × 10−2 V (Nearest integer).
Given: Ex02+ |x = −2.36 V
(D) None of these are incorrect
EY0 3+ |Y = +0.36 V
(21) Saturated solution of KN O3 is used to make salt bridge 2.303 RT
= 0.06 V
because F

(A) Mobility of K ⊕ is greater than that of N O3Θ (34) In a metal oxide, there is 20% oxygen by weight. Its
equivalent weight is
(B) Mobility of N O3Θ is greater than that of K ⊕
(35) The cell potential for Zn Zn2+ (aq)∥Snx+ Sn is 0.801 V at
(C) Mobilities of K ⊕ and N O3Θ are almost the same 298 K. The reaction quotient for the above reaction is 10−2 .
(D) KN O3 is highly soluble in water The number of electrons involved in the given
electrochemical cell reaction is. .... (Given
(22) At 298 K find out the emf for the cell ................ V 0
EZn 2+ |Zn = −0.763 V, ESnx+ |Sn = +0.008 V and
0
Al(s) |Al+3 (0.1 M ) ||F e+2 (0.001 M ) |F e (s) If 2.303 RT


= 0.06 V
+3 /Al = −1.66 V and EF e/F e+2 = +0.44 V
o o F
EAl
(A) 1.29 (B) 1.15
(C) 2.03 (D) 1.08
(23) Aluminium displaces hydrogen from acids but copper does
not. A galvanic cell prepared by combining Cu/Cu2+ and
Al/Al3+ has an e.m.f. of 2.0 V at 298 K. If the potential of
copper electrode is +0.34 V , that of aluminium is .......... V
(A) +1.66 (B) −1.66
(C) +2.34 (D) −2.3
(24) The emf of the following three galvanic cells
1. Zn|Zn2+ (1 M ) ||Cu2+ (1 M ) |Cu
2. Zn|Zn2+ (0.1 M ) ||Cu2+ (1 M ) |Cu
3. Zn|Zn2+ (1 M ) ||Cu2+ (0.1 M ) |Cu
are represented by E1 , E2 , E3 . Which of the following
statement is true?
(A) E1 > E2 > E3 (B) E3 > E2 > E1
(C) E3 > E1 > E2 (D) E2 > E1 > E3
(25) When the sample of copper with zinc impurity is to be
purified by electrolysis, the appropriate electrodes are
Cathode , Anode
(A) Pure zinc , Pure copper
(B) Impure sample , Pure copper
(C) Impure zinc , Impure sample
(D) Pure copper, impure sample

.......... Chemistry - Section B (NUMERIC) ..........

(26) Count the number of properties which have higher value for
O atom than that of ′ S ′ : Ionisation potential, Electron
′ ′

affinity, Covalent radius, Electronegativity.

(27) Among the following, the number of elements showing only

one non-zero oxidation state is O, C1, F, N, P, Sn, T1, Na, Ti

(28) The atomic number of the element unnilennium is

(29) Total number of d electrons present an element with atomic

no. 78 is

(30) The ratio between radii of He+ ion and H atom is

2
 Vedclass
Subject : Chemistry Paper Set : 1
Demo Date : 06-09-2024
Standard : 11,12
Total Mark : 160 (Answer Key) Time : 0H:0M

Chemistry - Section A (MCQ)

1-C 2-D 3-B 4-D 5-D 6-A 7-D 8-A 9-D 10 - D

11 - A 12 - C 13 - A 14 - D 15 - D 16 - A 17 - B 18 - D 19 - C 20 - D
21 - C 22 - B 23 - B 24 - D 25 - D

Chemistry - Section B (NUMERIC)

26 - 2 27 - 2 28 - 109 29 - 29 30 - 1 31 - 25 32 - 9650 33 - 275 34 - 32 35 - 2

3
 Vedclass
Subject : Chemistry Paper Set : 1
Demo Date : 06-09-2024
Standard : 11,12
Total Mark : 160 (Solutions) Time : 0H:0M

............ Chemistry - Section A (MCQ) ............

B : 1s2 2s2 2p6 3s2 3p3
C : 1s2 2s2 2p6 3s2 3p5
o (A) BC (B) B2 C
(1) The ionic radii (A) of C 4− and O2− respectively are 2.60 and
1.40. The ionic radius of the isoelectronic ion N 3− would (C) BC2 (D) BC3
o
be........A Solution:(Correct Answer:D)
(A) 131 (B) 2.83 B represents phosphorus P and C represents Chlorine Cl.
(C) 1.71 (D) 2.63 The compound formed is P Cl3 i.e., BC3 .

Solution:(Correct Answer:C) (6) Which one of the following ionic species has the greatest
C 4− , N 3− and O2− are isoelectronic species. proton affinity to form stable compound ?
The ionic radius of isoelectronic species decreases with (A) N H2− (B) F −
increase in nuclear charge.
(C) I − (D) HS −
Hence, the order of ionic radius is
Species: C 4− > N 3− > O 2− Solution:(Correct Answer:A)
o
Ionic radii (A) : 2.60 > 1.71 > 1.40 In going from left to right across a period in the periodic
table, the basicity (i.e. proton affinity) decreases as the
(2) First ionization energy is the lowest with electronegativity of the atom possessing the lone pair of
(A) Lead (B) Carbon electrons increases. Hence basicity of NH− 2 is higher than F .
−

In moving down a group, as the atomic mass increases,

(C) Silicon (D) Tin basicity decreases. Hence F − is more basic than I− and
Solution:(Correct Answer:D) HO− is more basic than HS− . Hence among the given ionic
species, N H2− has maximum proton affinity.
Ionization energy decreases down the group. As charge
density is minimum for tin so first ionization energy is (7) Then choose the correct option
lowest for tin.

(3) Which of the following statement is wrong ?

(A) The first ionization potential of Al is less than the first
ionization potential of M g
(B) The second ionization potential of M g is greater than
the second ionization potential of N a
(C) The first ionization potential of N a is less than the first
ionization potential of M g
(A) A : La (B) B : Sc
(D) The third ionization potential of M g is greater than the
third ionization potential of Al (C) E : Hf (D) All are incorrect

Solution:(Correct Answer:B) Solution:(Correct Answer:D)

After removal of an electron sodium acquires stable noble
gas configuration. It is difficult to remove electron from (8) Order of electron affinity of F, Cl, Br and I is .....
stable noble gas configuration species. Therefore, second (A) F < Cl > Br > I (B) F > Cl > Br > I
ionization potential of M g is less than that of N a. (C) F < Cl < Br < I (D) F > Cl < Br > I
(4) The element having electronic configuration Solution:(Correct Answer:A)
[Kr]4d10 4f 14 , 5s2 5p6 , 6s2 belongs to (a) Electron affinity of Cl is greater than fluorine so the
(A) s − block (B) p − block order are as F < Cl > Br > I
(C) d − block (D) f − block (9) The chemistry of lithium is very similar to that of magnesium
Solution:(Correct Answer:D) even though they are placed in different groups
(A) Both are found together in nature
(5) The electronic configuration of three elements A, B and C (B) Both have nearly the same size
are given below. The molecular formula of the compound
formed from B and C will be (C) Both have similar electronic configuration
A : 1s2 2s2 2p6 (D) The ratio of their charge to size is nearly the same

4
 Solution:(Correct Answer:D) Solution:(Correct Answer:D)
A Diagonal Relationship is said to exist between certain
pairs of diagonally adjacent elements in the second and (15) The first ionization enthalpies of Be, B, N and O follow the
third periods of the periodic table. These pairs (Li and order....
M g, Be and Al, B and Si etc.) exhibit similar properties; for (A) O < N < B < Be (B) Be < B < N < O
example, Boron and Silicon are both semiconductors, form
(C) B < Be < N < O (D) B < Be < O < N
halides that are hydrolyzed in water and have acidic oxides.
Such a relationship occurs because crossing and descending Solution:(Correct Answer:D)
the periodic table have opposing effects. On crossing a 1st I.E. N3 > O4 > Be2 > B1
period of the periodic table, the size of the atoms (2p ) (2p ) (2s ) (2p )
decreases, and on descending a group the size of the atoms
increases. Similarly, on moving along the period the (16) Which of the following represents the correct order of
elements become progressively more covalent, less metallic character of the given elements ?
reducing and more electronegative, whereas on descending (A) Si < Be < M g < K (B) Be < Si < M g < K
the group the elements become more ionic, more basic and
(C) K < M g < Be < Si (D) Be < Si < K < M g
less electronegative. Thus, on both descending a group and
crossing by one element the changes cancel each other out, Solution:(Correct Answer:A)
and elements with similar properties which have similar Metallic character increases down the group and decreases
chemistry are often found - the atomic size, along the period.
electronegativity, properties of compounds (and so forth) of
the diagonal members are similar. (17) Sodium generally does not shown oxidation state of +2,
The chemistry of lithium is very similar to that of magnesium because of its
even though they are placed in different groups. Its reason (A) High first ionisation potential
is that the ratio of their charge to size is nearly the same
(B) High second ionization potential
(10) Which has the maximum atomic radius
(C) Large ionic radius
(A) Al (B) Si
(D) High electronegativity
(C) P (D) M g
Solution:(Correct Answer:B)
Solution:(Correct Answer:D)
Sodium generally does not show oxidation state of +2,
(d) M g, as we move across the period atomic radius
because :
decreases.
Due to High second ionization potential sodium does not
exhibit +2 oxidation state
(11) If three electrons could be accomodated in an orbital, then
B is correct
the element with atomic no 50 will belong to:-
(A) 4th period and p block (B) 5th period and s block (18) The correct order of electronegativity for given elements is:
(C) 4 th
period and d block (D) 5th
period and p block (A) C > P > At > Br (B) Br > P > At > C

Solution:(Correct Answer:A) (C) P > Br > C > At (D) Br > C > At > P

Solution:(Correct Answer:D)
(12) The property of attracting electrons by the halogen atom in
a molecule is called Atom E.N
(A) Ionisation potential (B) Electron affinity Br 3.0
(C) Electronegativity (D) Electronic attraction C 2.5

Solution:(Correct Answer:C) At 2.2

It’s Obvious P 2.1

(13) To which of the following atom, the attachment of electron (19) If the IP of N a is 5.48 eV , the ionisation potential of K will
is most difficult? be ............ eV
(A) Radon (B) Nitrogen (A) Same as that of N a (B) 5.68
(C) Oxygen (D) Radium (C) 4.34 (D) 10.88
Solution:(Correct Answer:A) Solution:(Correct Answer:C)
A) Radon is anoble gas or inert gas, it has stable filled shell (c) Ionization potential decreases down the group.
configuration. (Xe)4f 14 5d10 6s2 6p6
B) Nitrogen is Gr. 15thelement. it has half filled 2p orbital. (20) Incorrect statements among the following is/are
(He) 2s2 2p3 (He) 2s2 2p3
C) Oxygen is Gr, 16th element. (He) 2s2 2p4 (A) 2nd electron gain enthalpy is always endothermic
D) Radium is Gr, 2nd element. (Rn) 7s2 (B) Electronegativity is the property of bonding atoms
The attachment of electron is most difficult for Radon.
(C) Al2 O3 and BeO are amphoteric oxide
(14) Which one of the following is a different pair? (D) None of these are incorrect
(A) Li, N a (B) Be, Ba
Solution:(Correct Answer:D)
(C) N, As (D) O, At

5
 (21) Saturated solution of KN O3 is used to make salt bridge (26) Count the number of properties which have higher value for
because O atom than that of ′ S ′ : Ionisation potential, Electron
′ ′

(A) Mobility of K ⊕ is greater than that of N O3Θ affinity, Covalent radius, Electronegativity.

(B) Mobility of N O3Θ is greater than that of K ⊕ (27) Among the following, the number of elements showing only
one non-zero oxidation state is O, C1, F, N, P, Sn, T1, Na, Ti
(C) Mobilities of K ⊕ and N O3Θ are almost the same
(D) KN O3 is highly soluble in water Solution:
Na, F show only one non-zero oxidation state.
Solution:(Correct Answer:C)
(28) The atomic number of the element unnilennium is
(22) At 298 K find out the emf for the cell ................ V
Al(s) |Al+3 (0.1 M ) ||F e+2 (0.001 M ) |F e (s) If Solution:
+3 /Al = −1.66 V and EF e/F e+2 = +0.44 V
o
EAl o 109
un nil enn
(A) 1.29 (B) 1.15 Hence correct name → unnilennium
(C) 2.03 (D) 1.08
(29) Total number of d electrons present an element with atomic
Solution:(Correct Answer:B) no. 78 is
2Al(s) + 3Fe+2 −→ 2Al+3 + 3Fe(s)
E0cell = −0.44 − (−1.66) = 1.22 V Solution:
(10−1 )
2
78 P t = 3d
10
+ 4d10 + 5d9 = 29 e−1 s
Ecell = 1.22 − 0.06
6 log (10−3 )3
= 1.22 − 0.07 = 1.15 V (30) The ratio between radii of He+ ion and H atom is

(23) Aluminium displaces hydrogen from acids but copper does Solution:
not. A galvanic cell prepared by combining Cu/Cu2+ and (b) Value of Z for hydrogen =1
Al/Al3+ has an e.m.f. of 2.0 V at 298 K. If the potential of Value of Z for helium = 2
copper electrode is +0.34 V , that of aluminium is .......... V Value of n for both is = 1
(A) +1.66 (B) −1.66
2
rH = 0.52×1
1

r + = 1 : 1 or rHe : rH = 1 : 1
2
(C) +2.34 (D) −2.3
rH
rHe+ = 0.52×1
1
+
He

Solution:(Correct Answer:B) (31) Consider the following reaction

It’s obvious. M nO4− + 8H + + 5e− → M n2+ + 4H2 O, E ◦ = 1.51V
The quantity of electricity required in Faraday to reduce five
(24) The emf of the following three galvanic cells moles of M nO4− is ..... .
1. Zn|Zn2+ (1 M ) ||Cu2+ (1 M ) |Cu
2. Zn|Zn2+ (0.1 M ) ||Cu2+ (1 M ) |Cu Solution:
3. Zn|Zn2+ (1 M ) ||Cu2+ (0.1 M ) |Cu The reaction given is:
are represented by E1 , E2 , E3 . Which of the following M nO4− + 8H + + 5e− → M n2+ + 4H2 O
statement is true? In this reaction, 1 mole M nO4 − reduces to form M n2+ and
(A) E1 > E2 > E3 (B) E3 > E2 > E1 for this reaction 5F e− are required.
M nO4 − → M n2+
(C) E3 > E1 > E2 (D) E2 > E1 > E3
+7 +2
Solution:(Correct Answer:D) Now,
1 mole M nO4− = 5 F
With an increase in the concentration of Zn (II) ions, the
5 mole M nO4− = (5 × 5) F
emf of cell decreases. With increase in the concentration of
= 25 F
Cu (II) ions, the emf of cell increases.
[Zn2+ ] Therefore, the quantity of electricity required to reduce five
◦
Ecell = Ecell − 0.0592
2 log [Cu2+ ] moles of M nO4 − is 25 F .

(25) When the sample of copper with zinc impurity is to be (32) When 0.1 mol M nO42− is oxidised the quantity of electricity
purified by electrolysis, the appropriate electrodes are required to completely oxidise M nO42− to M nO4− is ........ C.
Cathode , Anode
(A) Pure zinc , Pure copper Solution:
The oxidation reaction is
(B) Impure sample , Pure copper MnO2−4 −→ MnO4 + e
− −

(C) Impure zinc , Impure sample 0.1mol 1mol

Q = 0.1 × F = 0.1 × 96500C = 9650C
(D) Pure copper, impure sample
(33) The electrode potential of the following half cell at 298 K
Solution:(Correct Answer:D) X X 2+ (0.001M )∥Y 2+ (0.01M ) Y
(d) Impure metal made anode while pure metal made is ....... × 10−2 V (Nearest integer).
cathode. Given: Ex02+ |x = −2.36 V
EY0 3+ |Y = +0.36 V
.......... Chemistry - Section B (NUMERIC) .......... 2.303 RT
F = 0.06 V

6
 Solution:
X + Y 2+ → Y + X 2+
0
ECell = 0.36 − (−2.36) = 2.72 V
2 log 0.01
ECell = 2.72 − 0.06 0.001

= 2.72 + 0.03 = 2.75 V

= 275 × 10−2 V

(34) In a metal oxide, there is 20% oxygen by weight. Its

equivalent weight is

Solution:
(d) O2 % = 20%
Metal % = 80% = 80
20 × 8 = 32 g of metal.

(35) The cell potential for Zn Zn2+ (aq)∥Snx+ Sn is 0.801 V at

298 K. The reaction quotient for the above reaction is 10−2 .
The number of electrons involved in the given
electrochemical cell reaction is. .... (Given
2+ |Zn = −0.763 V, ESnx+ |Sn = +0.008 V and
0 0
EZn
2.303 RT


F = 0.06 V

Solution:
E = E 0 − 2.303RT
nF log Q
Here, E = +0.801 V, E 0 = 0.008 − (−0.763)
= +0.771 V
n log 10
−2
∴ 0.801 = +0.771 − 0.06
n=4