elemental analysis

Thermo Electron Corporation's

Product Specifications
Atomic Absorption Range offers
revolutionary stylish and fully
automatic AA Spectrometers
coupled with intelligent
accessories capable of
outstanding performance.

M & S Series
Atomic Absorption Systems
Technical Specification and Ordering Guide

M Series Dual Atomizer Systems Mi and Si Spectrometers

The concept of the M Series is simplicity
itself. Using a Stockdale double beam Enhanced M and S Series AA
Echelle optical system means that each Spectrometers with added Intelligence.
beam passes through a separate atomizer. Choosing the Mi or Si spectrometer gives
The user defines which is the sample beam you a truly unique instrument that is
and hence which atomizer will be used. As capable of Intelligent Spectrometer
a result flame to furnace changeover can be Qualification (iSQ). The iSQ module and
fully automatic and take place unattended. dedicated software automatically tests the
Productivity is significantly enhanced and spectrometer hardware performance and can
performance guaranteed. be set to perform the tests even before you
arrive in the lab. Arrive in the morning to
find an iSQ report confirming that you're
S Series Single Atomizer Systems good to go!
The radical S Series instruments offer the
highest levels of multi-element productivity
and reduced cost of ownership for no
compromise, single atomizer analysis.
Standard features include QuadLine
background correction, double beam optics,
Universal inert burner, furnace and burner
auto-optimization, plus full QC protocols.

Analyze • Detect • Measure • Control™

Product Specifications module consists of a motorized filter wheel
containing a set of calibrated filters (traceable
background with less than 2 % error, and is
fitted as standard to all instruments. AA
AA Series Atomic Absorption to a primary set held by the National Series spectrometers are fitted with a 6
Spectrometer Specification. Physical Laboratory, UK (NPL)), the iSQ position data-coded, auto aligning lamp
module is mounted in the instrument (LH carousel, with 6 independent power
Spectrometer Models side for S Series, RH side for M Series) and supplies modulated at 200/240 Hz. With the
Si Spectrometer provides the following suite of automated carousel, automatic analyses of up to 16
S Series Spectrometer with added system performance checks: elements in a single method are possible.
intelligence. Instrument capable of • Wavelength accuracy The standard range photomultiplier covers
performing Intelligent Spectrometer • Photometric stability the wavelength range from 185 nm to 760 nm,
Qualification (iSQ). • Monochromator resolution with a wide range option covering 180 nm
• Photometric stability to 900 nm. GFTV is an option on all systems.
S2 Spectrometer
• D2 Background correction accuracy
AA Spectrometer with standard or wide Flame System
• Lamp Peaking Test
range photomultiplier. 6 Lamp Automatic All AA flames are supported by the Universal
• Beam Selector Movement Test
Carousel. Semi-Automatic Gas System. 50 mm titanium burner with chamfered slot
Additionally for Zeeman instruments only
• Polarizer Orientation Test design giving high solids handling, excellent
S4 Spectrometer
• Polarizer Repeatability Test flame stability and low carbon build-up. The
AA Spectrometer with standard or wide burner height is automatically adjustable,
range photomultiplier. 6 Lamp Automatic The iSQ software can be programmed to and controls are provided for the burner
Carousel. Fully Automatic Gas System. start automatically. Run the iSQ tests once rotation and transverse position. An optional
a day, week, month or year to check the 100 mm burner for air/acetylene flames is
Mi Spectrometer performance of your spectrometer hardware also available. Automatic flame ignition is
M Series Spectrometer with added intelligence. and increase confidence in your data quality. provided by a high tension electric spark.
Instrument capable of performing Intelligent
Flame systems are controlled by either
Spectrometer Qualification (iSQ). S Series
a fully automatic gas control system (S4 and
Automatic Atomic Absorption Spectrometer
M5 Spectrometer M Series) or a semi-automatic gas control
system, with full multi-element capability,
system (S2). The S4 automatic gas control
Dual Atomiser AA Spectrometer with controlled with a data station running
system uses programmable array state logic
standard or wide range photomultiplier. SOLAAR software under Windows®. Flame
and binary flow switching technology for
Flame Atomization in LH Sample absorption /emission systems are extendible
reliability. Oxidant gas changeover, and fuel
Compartment. Furnace Atomization in RH to Graphite Furnace, Vapour or Mercury
and oxidant flow rates are software controlled
Sample Compartment. Vapour Atomization Cold Vapour absorption modes by ordering
and interlocked to prevent operation with
in either Sample Compartment. the appropriate accessory atomizer.
incorrect burners and gas flows. With the
M6 Spectrometer M Series S2 semi-automatic gas system, the fuel flow
Dual Atomizer Zeeman AA Spectrometer rate is controlled by a precision needle
Automatic Dual Sample Compartment
with wide range photomultiplier. Flame valve and rotameter display.
Atomic Absorption System, with full multi-
Atomization in LH Sample Compartment. Oxidant changeover and fuel gas flow
element capability, controlled by a data
Zeeman Furnace Atomization in RH Sample boost are software controlled, and the
station running SOLAAR software under
Compartment. Vapour Atomization in either burner interlock ensures burner/flame
Windows®. Flame absorption /emission
Sample Compartment. compatibility. On both systems, a flame
systems can be extended to Graphite
sensor, responding to all flame types
Furnace, Vapour or Mercury Cold Vapour
MQZ Spectrometer including hydrogen fuelled flames, ensures
absorption modes by ordering the appropriate
Zeeman Furnace AA Spectrometer with safe gas handling if the flame goes out. All
accessory atomizer. The MQZ and MQZe
wide range photomultiplier. Furnace or fuel gas lines are fitted with flame arrestors,
spectrometers must be ordered with a
Vapour Atomization. and with pressure sensors to provide automatic
Zeeman Graphite Furnace to provide a
safe shutdown if the line pressure falls below
working system.
MQZe Spectrometer the safe limits. Both gas control systems
Dual Atomizer Zeeman/Vapour AA Optical system shut down safely if the power fails.
Spectrometer with wide range All systems (except the MQZ) are supplied The totally enclosed, draught proof
photomultiplier. Vapour Atomization in LH with Stockdale double beam optics giving “kitchen” area has a safety door containing
Sample Compartment. Zeeman Furnace maximum signal-to-noise ratio during signal a heat and UV absorbing window. The inert
Atomization in RH Sample Compartment. measurement. All mirrors are silica coated, fluoroplastic spray chamber contains an
and the optics are sealed against dust ingress. inert adjustable impact bead and flow spoiler,
Main Spectrometer Descriptions and low memory hydrophilic disc chamber
The self-calibrating Ebert (S Series) or
Echelle (M Series) monochromator provides front end. It has built in over pressure relief
Mi or Si Spectrometers and automatic empty drain protection. The
automatic wavelength and bandpass set-up.
Choosing the Mi or Si will give you Intelligent standard spray chamber configuration is
The high energy QuadLine background
Spectrometer Qualification (iSQ). The iSQ suitable for all flame types. The inert nebulizer
correction system corrects for up to 2A of
with a Pt/Ir capillary and PTFE venturi is Data Station Control Background Correction
standard and is factory optimized. The spectrometer system and accessories QuadLine (continuum source) is standard on
are controlled via a Data Station running all spectrometers. Background signals below
Graphite Furnace Systems the SOLAAR AA Software Package under 2 A are corrected with less than 2 % error.
the Microsoft Windows® 98SE, Me, NT v4, Total signal up to 3 A.
S Series
2000 or XP operating systems. The Data
The GFS97 Integrated Graphite Furnace and Station is a Personal Computer, with a Gas Control
Furnace Autosampler can be fitted without typical configuration of:
removing the spray chamber or disconnecting Fuel Flow Range
800 MHz Pentium processor or equivalent.
the gas lines. 128MB RAM. Air/Acetylene - 0.8 to 2.3 l/min.
CD ROM Drive. Nitrous Oxide/Acetylene - 3.6 to 5.1 l/min.
M Series S2 - Needle valve and rotameter fuel flow
Fixed Disk Drive with at least 500 Mbyte
All Graphite Furnaces are fitted in the RH control.
free space.
Sample Compartment of the M Series S4 and M Series Automatic binary switching
SVGA Colour Monitor.
Spectrometers. The M5 Spectrometers will fuel flow control.
9 way Serial Port, with type 16550
accept the GF95 Graphite Furnace, while the
buffered RS232 interface chip.
M6, MQZ and MQZe Spectrometers will Safety
Parallel Port.
accept the GF95Z Zeeman Graphite Furnace. Automatic flame ignition.
Windows® 98SE, Me, NTv4, 2000 or XP
The GF95Z Zeeman furnace is mounted on a Software controlled, automatic oxidant
Professional.
prealigned Tilt Mount, which can be tilted changeover.
forward out of the sample compartment to Software controlled, automatic fuel gas
Additional requirements for GFTV:
allow access to the furnace for maintenance boost on oxidant changeover.
Free USB port or free PCI expansion slot.
purposes, and to allow other accessories to Automatic flame shutdown.
Video adapter that supports Direct Draw.
be fitted into the sample compartment. The Fuel line flashback arrestor.
GF95 Furnace is fitted with a pre-aligned Detailed Specifications Fuel line pressure regulator.
Fixed Mount as standard, but can be optionally Fuel and oxidant line pressure sensors.
fitted with the Tilt Mount if required. The Optics Flame Present sensor.
FS95 Graphite Furnace Autosampler is S Series Configuration - Double Beam Burner Type sensor.
mounted in front of the RH Sample Stockdale optical system. Burner Present sensor.
Compartment with a simple self-locating M5 Configuration - Double Beam Power failure protection.
'push in' mount. Stockdale system Empty drain protection.
M6, MQZe Configuration - Double Beam Spray chamber over-pressure protection.
Graphite Furnace TeleVision (GFTV)
Stockdale system, with self-referencing
Optional on all AA Series Spectrometers, Light Source
Single Beam Zeeman system
the GFTV accessory provides high definition Single or multi-element hollow cathode lamps.
MQZ Configuraion - Self-referencing
images of events inside the Graphite Furnace Uncoded and Data Coded hollow cathode
Single Beam Zeeman system
cuvette, allowing monitoring of the sample lamps.
injection, dry and ash phases of the furnace Monochromator 6 independent lamp power supplies, each
program. A CCD camera mounted in the S Series - Ebert configuration with nominal providing 0 to 20 mA.
instrument produces live video for display 0.2, 0.5 and 1.0 nm spectral bandwidths.
on the Data Station's screen through the Wavelength Range
Half height slit settings available.
GFTV Software and Interface Kit, or on an 180 nm to 900 nm with wide range
Reciprocal linear dispersion 1.5 to 2.0 nm/mm.
external monitor. The external monitor should photomultiplier.
Focal length 270 mm.
be monochrome, PAL compatible with a Grating 1800 l/mm. 185 nm to 760 nm with standard
minimum screen resolution of 400 lines, and photomultiplier.
a coaxial video cable with BNC plug for M Series - Echelle monochromator and
connection to the spectrometer. prism post-monochromator. Nominal 1.0, 0.5
and 0.2 nm spectral bandpass with 0.1 nm
Electronics
available below 400 nm. 0.5 nm/mm
Spectrometer electronics are based on the
reciprocal linear dispersion at 200 nm
Motorola 68340 microprocessor, with the
system firmware residing in Flash PROM. Absorbance Range
Firmware can be downloaded to the Flash -0.150 A to 3.000 A (including background
PROM from an external PC without removing signal).
any covers. Interfacing to the Data Station,
autosamplers, furnace and associated
accessories is via RS232C at 9600 baud. The
vapour system is interfaced via a dedicated
8 pin socket.
Product Specifications Data/Control Systems element analyses. Data coded HCLs are
fully supported, and facilities are provided
USA English, French, German, Russian,
Spanish, Japanese, Chinese and Polish
Spectrometer to record lamp usage. Up to 10 calibration languages.
Motorola 68340 microprocessor. standards and a blank can be used, with
512 kB Flash PROM. segmented curve, linear or quadratic least SOLAARsecurity Software
256 kB RAM. squares fit calibration algorithms. Normal, The SOLAARsecurity software package adds
4 general purpose RS232C ports. standard addition and standard curve additional facilities to the SOLAAR Data
Dedicated vapour port. calibration methods are supported, with full Station software. This provides the tools,
graphical display and print out of the facilities and functions required to allow an
Data Station calibration curve. Full alphanumeric sample organisation to comply with the requirements
Typically Pentium PC (see below). details including sample mass and dilution of the US Food and Drugs Administration
correction can be entered for each sample, set out in Part 11 "Electronic Records;
Local Control or imported via text files. Comprehensive Electronic Signatures" of Title 21 of the
Motorola 68340 microprocessor. furnace signal graphics are provided, and Code of Federal Regulations (the 21 CFR
512 kB Flash PROM. automated ash-atomize plots produce part 11 Rule). Network compatible, this
512 kB RAM. graphical data for furnace program package provides User Authentication, Access
optimization, and will even suggest optimum Controls, Audit Trails, Event Logs and Digital
Power Signatures for the Data Station client
values. For flame systems, fully automatic
100 to 240 V (±10 %) at 50 or 60 Hz. fuel gas flow and burner height optimization software, with central administration and
Consumption 300 VA. with graphical presentation are provided. storage of the user security settings.
Extensive on line, fully context sensitive, SOLAARsecurity is compatible with
Dimensions (mm)
Help facilities are available. Carefully Windows NTv4, 2000 and XP Professional
S Series 567W x 510H x 589D. operating systems.
structured “books” allow easy browsing and
M Series 780W x 520H x 595D.
searching as well as direct access to any Help
topic. Trouble-shooting and diagnostics Accessory Specifications.
Weight
sections describe simple experiments to
S Series Approximately 33 kg. Mi and Si Enhancement
first locate the problem then to rectify it. A
M Series Approximately 60 kg.
full “Cookbook” with default parameters for Mi enhancement for M Series instruments
SOLAAR Software. all elements, common interferences, and the and Si enhancement for S Series instruments.
means of overcoming them is included. The Intelligent Spectrometer Qualification
Data Station Software SOLAAR software provides comprehensive (iSQ) module is mounted on the LH side of
printer support through the Windows® the Spectrometer for S Series instruments
The SOLAAR Data Station Software runs on
operating system. Report formatting enables and on the RH side for M Series instruments.
the AA Series Data Station, and will control
both S Series and M Series spectrometers. customization of the sample details, results,
Standard Items
The software is aware of the type of summaries, methods, system parameters
and graphical displays that are to be included Intelligent Spectrometer Qualification
spectrometer that it is controlling, and will
in the Report, and all Reports, as well as module.
only provide relevant parameters and options
individual results, are time and date stamped. Coded Ca/Mg Hollow cathode lamp
for each instrument type and configuration.
Flexible and comprehensive Results database LH Accessory mount for Si option
The Data Station Software supports all the
filters select and display the required data, RH Accessory mount for Mi option.
facilities provided by all the AA Series
Accessories. which can be exported to other applications
Graphite Furnaces
The software features a range of Wizard for further processing. Fully undoable results
based procedures and a tabbed Methods editing is available and is automatically
GFS97 Integrated Graphite Furnace and
dialogue to make setting up even complex audit trailed. Integrated Auto QC software Autosampler
analyses fast and easy. All raw data, results provides comprehensive Quality Control
GFS97 is available for S Series
and parameters are stored in a single protocols automation with checking, testing
spectrometers only. GFS97 Furnace
database for easy retrieval. True Windows® and reanalysis options, SPC graphical results
specifications are as the GF95 Furnace
multi-tasking is available, so that SOLAAR display, report generation and data filing.
Specifications, and GFS97 Furnace
can be iconized while running an analysis, QC Blanks, QC Checks, QC Duplicates and
Autosampler specifications are as the FS95
allowing concurrent use of other applications. two forms of QC Spikes are all included,
Furnace Autosampler Specifications.
Methods can be created, edited and saved, each with user definable test criteria and
and earlier results can be reviewed, edited failure actions. Full QC reporting, including Standard Items
and printed, while an analysis is underway. pass/fail results and time and date stamps Furnace Head.
SOLAAR software enables full 16 is provided on the Results display, and hard Furnace Power supply.
element Methods to be performed copy reporting of all QC protocols, parameters, Furnace Autosampler.
automatically. The flexible and comprehensive results and actions is available. QC data is GFS97 Integrated Furnace and Autosampler
tabbed Methods dialogue box guides the linked to the results to which it applies, and Mount.
user through setting up complex, multi- can be exported with the results. Normal Electrographite cuvettes (10)
SOLAAR software is available in English,
Necessary Additional Items phase and non linear ramp. (Limited facilities Standard Items
Additional cuvettes as required. with Local Control). Individual temperature Furnace Autosampler
look-up tables for all cuvette types ensure Polypropylene Sample Cups (1000)
GF95 and GF95Z Graphite Furnaces accurate temperature calibration. A lifetime Polypropylene Reagent Cups (50)
GF95 is available for M Series M5 model display enables the cuvette to be changed Spare Capillary tips (10).
only. GF95Z is available for M Series M6, before failure becomes likely. A pre-
MQZ and MQZe models only. GFS97 programmed cuvette clean cycle is available, Carousel Capacity
Furnace Specification is as GF95. culminating in maximum temperature for 5 60 sample cups, 6 reagent cups.
seconds to ensure complete contamination
Standard Items removal. Comprehensive storage of the Cup Types
Standard (GF95) or Zeeman (GF95Z) Furnace furnace program, together with spectrometer Polypropylene sample cups.
Head. and autosampler parameters, is provided. Fluoroplastic sample cups.
Power supply. Full furnace and autosampler status can be Reduced volume sample cups.
Tilt Mount (GF95Z), Fixed Mount (GF95) or displayed, together with the results during Polypropylene reagent cups.
Integrated Mount (GFS97). the analysis (Data Station control only).
Normal Electrographite cuvettes (10). Cup Volume (nominal)
Complete monitoring of all furnace interlocks
is provided. Sample cups 2 ml.
Necessary Additional Items Reduced volume cups 1.5 ml.
Additional cuvettes as required. FS95 Furnace Autosampler Reagent cups 25 ml.
Optional Tilt Mount for GF95. The attractively styled Autosampler will
Inert Gas Pressure
accommodate up to 60 samples in the large
Furnace Head Nominal - 0.34 bar (5psi).
carousel. Carousel changeover allows up to
All cuvettes mount directly in an all-graphite 500 samples per run. 6 large reagent cups Minimum - 0.20 bar (3psi).
containment with end loaded contacts. enable up to 6 matrix modifiers to be Maximum - 0.68 bar (10psi).
Cuvettes are self aligning, and can be rapidly employed. Using the cup reducing ring,
exchanged with a single lever movement. Injection
smaller sample cups can be used in the
The binary flow controlled internal gas system, Sample Volume 1-70 uL.
reagent cup positions to reduce modifier
with gas stop, offers a choice of the inert Reproducibility - better than 1% (by mass)
consumption. The sample is collected and
gas or an alternate gas, and the fixed external at volumes equal to and greater than 10 uL.
dispensed via an inert PTFE capillary with
inert gas flow protects the cuvette and easily interchangeable tips. Viscous and
purges the optical temperature sensor. Normal modes of injection ensure that 221XL Flame Autosampler
samples are handled appropriately and an
Temperature Control System Random access flame and vapour
enhanced wash program eliminates
Voltage Feedback Control System. autosampler with 60 (Rack 21), 44 (Rack 22)
contamination. Fast furnace operation
Optical Temperature Feedback Control or 14 (Rack 24) sample capacities. Smaller
provides concurrent operation of the
System with a stabilized sensor and fiber sample capacities imply larger available
furnace, spectrometer, and autosampler
optic transmission system. volume per sample.
sample uptake procedures, minimising
Gas System overall furnace cycle time. The syringe is Standard Items
visible and easily accessible for routine Random access x-y autosampler mechanism.
Pressure 1.03+/-0.07 bar (15+/- 1psi) fixed
maintenance. A large 1 litre capacity wash Rack 21 (60 position).
external flow.
vessel for long unattended analysis is PTFE probe.
Adjustable internal flow with choice of inert
complemented by an on-board waste RS232C adaptor.
or alternate gas.
vessel, removing the need for inconvenient
Cooling Water waste collection on the laboratory floor. Necessary Additional Items
Mains or Recirculator. All facilities are programmed from the AA Wash Accessory.
Minimum flow rate 0.7 l/min. SOLAAR software and sampling facilities Polypropylene or glass sample/standard
Pressure 1.4 - 6.9 bar (20 - 100 psi). such as matrix modification (wet or dry tubes for Rack 21.
mixing), standards addition, dilution,
Furnace Control reconcentration and automatic standards Power
Control of the furnace is from the SOLAAR preparations can be rapidly set-up. 110 V, 120 V, 220 V, 240 V at 50 or 60 Hz.
Data Station or Local Control software via Automatic rescaling and re-calibration Consumption 50 VA.
the spectrometer. A full handshaking RS232C functions are provided. If a sample falls
link is provided to the furnace power supply. outside the calibration range the system
Furnace cycles are set up within a rapid fill automatically and intelligently calculates
table allowing up to 20 phases to be the most appropriate dilution factor required
programmed for temperature, time, ramp to bring the sample back within range.
rate, gas type and flow and special functions Autosampler loading guides indicate the
such as optical temperature control, read optimum carousel layout.
Product Specifications 222XL Flame Autosampler for flame measurements. It is based on a high
precision multi-piston pump that is calibrated
Tin (II) chloride may be used for mercury
analysis.
Random access, large capacity flame and
vapour autosampler with 70 to 254 sample for life, and does not require any consumable
items. It can be used with manual sampling Solution Transport
capacity, dependent on rack configuration.
Smaller sample capacities imply larger or with any of the flame autosamplers. Variable speed, 4 channel peristaltic pump,
available volume per sample. First rack (14 using continuous flow principle.
VP100 Continuous Flow Vapour
position) is used for blank and standards.
Generator Solution Flow Rates
Standard Items The VP100 Continuous Flow Vapour System Reductant - 3.2 ml/min.
Random access x-y autosampler mechanism. performs hydride and mercury vapour Sample - 7.8 ml/min.
Rack 24 (14 position). measurements with significant sensitivity
improvement over normal flame techniques. Carrier Gas Flow Rates
PTFE probe.
An air/acetylene flame or an electrically Variable 50 - 500 mL/min.
RS232C adaptor.
heated cell is used for atomization, avoiding Electronic control via Mass Flow Controller.
Necessary Additional Items the need to use hydrogen as the fuel gas.
Reagent Containers
AA Wash Accessory. The VP100 unit incorporates the reagent
reservoirs, a variable speed 4 channel Two 1 L plastic bottles.
Polypropylene or glass sample/standard
tubes for Rack 24. peristaltic pump, control electronics and
Power
4 of Rack 24 (14 positions), Rack 22 (44 Gas Liquid separator. A integrated Mass
220/240 V, 50 Hz or 110/120 V, 60 Hz.
positions) or Rack 21 (60 positions) with Flow Controller allows the carrier gas flow
Consumption 30 VA.
appropriate polypropylene or glass to be controlled and monitored through the
sample/standard tubes. system software, and the continuous flow Dimensions (mm)
principle eliminates the need to clean the
475W x 300H x 200D.
AA Wash Accessory reaction vessel after each sample. The
The AA Wash Accessory provides wash VP100 operates automatically under Data EC90 Electrically Heated Atomization
facilities for the 221XL and 222XL Station control and can provide full Cell
autosamplers. autosampling operation with a suitable The EC90 is an electrically heated atomization
autosampler. When used with the EC90 cell for flameless vapour generation AAS. It
Standard Items Electrically Heated Atomization Cell, provides improved analytical performance,
Constant Head wash reservoir. unattended operation is possible. unattended operation and reduced operating
Wash well for 221XL/ 222XL autosamplers.
costs in comparison with a flame heated
Standard Items
ASX-520 and ASX-260 Flame atomization cell. The EC90 must be used with
T-Cell (2) - Open ended, T-shaped silica cell the VP90 or VP100 and is suitable for all
Autosampler (120 mm long). hydride forming elements.
Random access, large capacity (ASX-520) or Mercury Cell - Long path (150 mm).
compact (ASX-260) flame/vapour autosampler Spare pump tubing. Standard Items
with 84 to 360 max.(ASX-520) and 42 to 180 Spare glass Beads. EC90 Furnace Head.
max (ASX-260). sample capacity, dependent Spare semi-permeable membrane. EC90 Furnace Power Supply.
on rack configuration. Optional racks for 21,
2 Silica T Cells.
24, 40, 60 or 90 samples. Smaller sample Necessary Additional Items
capacities imply larger available volume per An appropriate accessory mount is required Necessary Additional Items
sample. to fit the long path length cell to the VP90 or VP100 Continuous Flow Vapour
spectrometer. System.
Standard Items
Appropriate Accessory Mount.
Random access x-y autosampler Cell Heating
mechanism. Air/acetylene flame on 50 mm Universal Control System
Standards rack (10 position). burner. From external power supply.
ASX-520 4 sample racks (60 position each). Electrical heating using EC90.
ASX-260 2 sample racks (60 position each). AA Validator
10 standard and 240 sample polypropylene Carrier/Purge Gas
Available in three separate kits designed for
sample tubes. Argon or nitrogen. Flame, Furnace or Flame and Furnace
0.5 mm ID and 0.8 mm ID PTFE sample probes. installations, the unique AA Validator provides
Pumped wash facility. Gas Inlet Pressure
full system validation for S Series and
RS232C adaptor. 0.35 - 1 bar (5 - 14 psi). M Series AA systems, including comprehensive
qualification plans. Full SOP's and check
ID100 Autodilutor Gas Consumption
sheets, together with complete supplier
The ID100 Autodilutor provides rapid, in-line Up to 500 ml/min.
assessment questionnaires, are supplied in
preparation of calibration standards and the Validator Logbook for recording and
Reducing Agents
intelligent or fixed ratio dilution of samples demonstrating compliance. All necessary
Sodium borohydride.
consumables are provided and even method Standard Items Graphite Furnace Cuvettes
validation guidelines are included. The STAT Holder.
integrated PQ Test software contains a 5 Quartz STAT tubes. Normal (Electrographite) Cuvettes
complete set of SOPs and a Wizard to lead
the user through the tests needed to validate Necessary Additional Items Description
the instrument analytical performance against 50 mm Universal Titanium Burner. The normal cuvette is made from a form of
the manufacturer's specification. graphite called electrographite. This cuvette
Variable Flow Auxiliary Oxidant Kit is suitable for the determination of volatile
Major Contents (depends on kit type): The Variable Flow Auxiliary Oxidant Kit elements such as Pb, and Cd in simple
Validator Logbook. allows the flow rate of the auxiliary oxidant matrices, such as clean waters.
Ca/Mg Hollow Cathode Lamp. gas that can be supplied to an air/acetylene
Ni/Cr/Mn Hollow Cathode Lamp. flame to be varied over a wide range, in order (Pyrolytically) Coated Electrographite
Pyrolytically Coated Cuvettes. to allow the flame chemistry to be optimized Cuvettes
Manganese Validation Standard. when using less common organic solvents.
Nickel Validation Standard. Note that all flame instruments fitted with Description
Chromium Validation Standard. automatic gas control modules include a This coated cuvette is a modified
Water Blank Validation Standard. fixed flow rate auxiliary oxidant facility for electrographite cuvette, coated with a thin
air/acetylene flames that is suitable for the layer of pyrolytic graphite. Coated cuvettes
AA Validatorplus organic solvents most commonly used. The are required for the carbide forming, medium-
The Validatorplus accessory contains a set Variable Flow Auxiliary Oxidant Kit is not volatile and refractory elements and for
of traceable and certified filters. It is fitted compatible with the S2 spectrometer. samples with complex high salt matrices.
in the spectrometer and controlled by the
OQ Test software. Standard Items Extended Lifetime Cuvettes (ELC)
Variable Flow Auxiliary Oxidant Kit.
Standard Items Description
Calibrated Validation Unit (CVU). Solvent Resistant Flame Kit ELC's are unique to Thermo and have a
Power Supply. This kit contains the necessary replacement pyrolytic coating that is up to 10 times thicker
RS232 Data Lead. flame system parts recommended when the than the standard coating. This gives them
spectrometer is to be used extensively for more stable performance and much longer
Necessary Additional Items the analysis of organic solvents. It includes useful lifetimes than either of the
Either the Validator Logbook or the solvent resistant 'O' rings, a modified spray electrographite-based cuvettes. These
appropriate Validator Kit. chamber, and solvent resistant drain tubing. cuvettes are especially recommended for
RH Universal Accessory Mount for use with high throughout analyses with complex
M Series spectrometers. LH Universal Accessory Mount samples and when measuring the most
LH Universal Accessory Mount for use with Accessory Mount for use in the S Series refractory elements.
S Series spectrometers. and left hand M Series sample
compartments. This is necessary for Omega Platform Extended Lifetime
Aliquot Micro-sampling Accessory mounting the EC90 Furnace Head and the
This is a simple accessory that provides Description
Mercury Absorption Cell in these sample
manual Aliquot Micro-sampling facilities. compartments. It is also used for mounting Omega platform cuvettes have an integrated
Aliquot Micro-sampling is particularly useful the Validatorplus Calibration Validation Unit L'Vov platform built into the cuvettes, which
when the available volume of sample is in the S Series sample compartment. makes them particularly suitable for
limited, or the sample is too viscous, or determining the more volatile elements in
contains too high a concentration of dissolved RH Universal Accessory Mount heavy matrices where vapour phase
solids, to allow conventional aspiration. Accessory Mount for use in the RH M Series interferences cause severe problems. The
sample compartment. This is necessary for integral platform is designed to accommodate
Standard Items mounting the EC90 Furnace Head, the up to 50 µL volumes and so can provide
Teflon block. Validatorplus Calibration Validation Unit, excellent concentration limits. The Omega
Uptake tube. and the Mercury Absorption Cell in this cuvettes use the ELC coating technology
sample compartment. and have similar long, stable lifetime
Necessary Additional Items characteristics.
Adjustable Micropipette. Retrospective Accessory Mount Kit
This kit is required for mounting certain
Slotted Tube Atom Trap accessories in the LH sample compartment
The STAT accessory provides a useful of older (part number 9423 400 20###)
increase in flame analytical sensitivity for M Series Spectrometers, and earlier 969/989
certain more volatile elements, such as Cd, Spectrometers
Zn, Pb, and Cu.
Product Specifications Hollow Cathode Lamps. Data Coded Single Element Lamps Uncoded Single Element Lamps
High quality hollow cathode lamps optimized High quality hollow cathode lamps optimized
Data Coded Multi-element Lamps for use with the M Series and S Series for use with the M Series and S Series
High quality hollow cathode lamps optimized spectrometers. The spectrometers read the spectrometers. Single element lamps provide
for use with the M Series and S Series element contained in the lamp and the the best possible analytical performance.
spectrometers. The spectrometers read the maximum permissible lamp current from the All Thermo Electron Corporation Uncoded
list of elements contained in the lamp and Data Coding, providing maximum convenience Single Element Lamps carry a 5000 mA/hr
the maximum permissible lamp current from and removing the possibility of damaging lifetime guarantee.
the Data Coding, providing maximum the lamp with excessive currents. Single
convenience and removing the possibility of element lamps provide the best possible Value Range Lamps
damaging the lamp with excessive currents. analytical performance. All Thermo Electron A limited range of cost effective hollow
Multi-element lamps provide analytical Corporation Data Coded Single Element cathode lamps for use with the M Series
performance comparable with single Lamps carry a 5000 mA/hr lifetime guarantee. and S Series spectrometers. Value Range
element lamps, while reducing your lamp Single Element lamps provide analytical
inventory and increasing the ease of use. Uncoded Multi-element Lamps performance comparable with normal
All Thermo Electron Corporation Data Coded High quality hollow cathode lamps optimized lamps, at a significantly reduced cost. All
Multi-element Lamps carry a 5000 mA/hr for use with the M Series and S Series Thermo Electron Corporation Value Range
lifetime guarantee. spectrometers. Multi-element lamps provide Uncoded Single Element Lamps carry a
analytical performance comparable with 5000 mA/hr lifetime guarantee.
single element lamps, while reducing your
lamp inventory and increasing the ease of
use. All Thermo Electron Corporation
Uncoded Multielement Lamps carry a
5000 mA/hr lifetime guarantee.

How to Order Guide

Description Part Number
Si Spectrometers
to upgrade your S Series spectrometer to an Si instrument add the following Part number to your instrument order 9423 420 30001
S2 AA Spectrometer (standard photomultiplier) 9423 400 30021
S2 AA Spectrometer (wide range photomultiplier) 9423 400 30022
S4 AA Spectrometer (standard photomultiplier) 9423 400 30041
S4 AA Spectrometer (wide range photomultiplier) 9423 400 30042
Mi Spectrometers
to upgrade your M Series spectrometer to an Mi instrument add the following Part number to your instrument order 9423 420 20001
M5 Dual Atomizer AA Spectrometer (wide range photomultiplier) 9423 400 21052
M6 Dual Atomizer Zeeman AA Spectrometer 9423 400 21062
MQZ Zeeman AA Spectrometer 9423 400 21072
MQZe Dual Atomizer Zeeman/Vapour AA Spectrometer 9423 400 21572
Major Options and Accessories
Graphite Furnace and Furnace Autosampler
For S Series Spectrometers
GFS97 Integrated Graphite Furnace and Autosampler 9423 490 30001 or
9423 490 30002 (N. America)
For M Series Spectrometers
GF95 Graphite Furnace (for M5 spectrometers only) 9423 490 20001or
9423 490 20002 (N. America)
GF95Z Zeeman Graphite Furnace (for M6, MQZ and MQZe spectrometers) 9423 490 20051 or
9423 490 20052 (N. America)
GF95Z - with Rhodium Plated centre block 9423 490 20061 or
9423 490 20062 (N. America)
Rhodium Plated centre block for GF95Z - retrospective fitting 9423 490 20069
FS95 Furnace Autosampler 9423 480 20001
Graphite Furnace TeleVision
GFTV (for M Series Spectrometers, Factory Fitted, 50 Hz) 9423 410 20011
GFTV (for M Series Spectrometers, Factory Fitted, 60 Hz) 9423 410 20021
GFTV (for S Series Spectrometers, Factory Fitted, 50 Hz) 9423 410 30011
GFTV (for S Series Spectrometers, Factory Fitted 60 Hz) 9423 410 30021
GFTV Software and Interface Kit (USB version) 9423 393 96051
GFTV Software and Interface Kit (PCI version) 9423 410 20005
GFTV Software and Interface Kit is necessary if an external monitor is not used. It cannot be used if the spectrometer is controlled with a Local Control module.
An appropriate TV licence may be required.
GFTV Monitor 9423 420 20003
A GFTV Monitor is necessary if the GFTV Software and Interface Kit is not used, or if the spectrometer is controlled by a Local Control module.
Control Options
All spectrometers include SOLAAR software as standard.
Local Control module (Factory Fitted) 9423 410 20002
Data Station (110 V/120 V) 9423 393 10003
Data Station (220 V/240 V) 9423 393 10004
SOLAAR Upgrade Software (includes software for earlier systems) 9423 430 20001
SOLAARsecurity Software (ordered with spectrometer) 9423 430 30011
SOLAARsecurity Software (upgrade for existing systems) 9423 430 30001
Note that this includes the SOLAAR Upgrade software.
Product Specifications Description Part Number
Flame and Vapour Autosamplers
Gilson 221XL Autosampler 110 - 120 V/200 - 240 V 9423 470 03001
Gilson 222XL Autosampler 110 - 120 V/200 - 240 V 9423 470 03002
AA Wash Kit for Gilson autosamplers 9423 470 03501
CETAC ASX-520 Autosampler 110 - 120 V/200 - 240 V 9423 470 04001
CETAC ASX-260 Autosampler 110 - 120 V/200 - 240 V 9423 470 04002
Autodilutor
ID100 Autodilutor 9423 470 03201
Continuous Flow Vapour Generation System
VP100 Continuous Flow Vapour System 9423 460 10001
Electrically Heated Atomisation Cell
EC90 Electrically Heated Atomisation Cell 9423 393 60061
Must be used with a VP90 or VP100 Vapour System and a Universal Accessory Mount to provide a working system.
It is essential for vapour analysis with the MQZ and MQZe spectrometers.
Validator
Validator Log Book 9499 VAL 90006
FAAS Validator Package 9423 VAL 00001
GFAAS Validator Package 9423 VAL 00002
FAAS/GFAAS Validator Package 9423 VAL 00003
Validatorplus Accessory 9423 VAL 00004
Aliquot Sampling
Manual Aliquot Micro-sampling Accessory 9423 390 05201
Slotted Tube Atom Trap
STAT Accessory (requires use of 50 mm Universal Burner) 9423 390 35011
Variable Flow Auxiliary Oxidant
Variable Flow Auxiliary Oxidant Kit (Factory Fitted) 9423 393 46111
Solvent Resistant Flame Kit
Solvent Resistant Flame Kit 9423 420 31051
Universal Accessory Mounts
LH Sample Compartment Universal Accessory Mount 9423 420 21005
This is required for mounting certain accessories in the LH Sample Compartment of current (part number 9423 400 21###) M Series Spectrometers, and in the Flame Compartment
of S Series Spectrometers.
RH Sample Compartment Universal Accessory Mount 9423 420 20005
This is required for mounting certain accessories in the RH Sample Compartment of all M Series Spectrometers.
Retrospective Accessory Mount Kit 9423 420 22005
This is required for mounting certain accessories in the LH Sample Compartment of older (part number 9423 400 20###) M Series Spectrometers, and earlier 969/989 Spectrometers.
Air Supply
Air Compressor (220/240 V, 50 Hz) (includes filter/regulator unit) 9423 393 34225
Air Compressor (220/240 V, 60 Hz) (includes filter/regulator unit) 9423 393 34226
Air Compressor (110/120 V, 50 Hz) (includes filter/regulator unit) 9423 393 34115
Air Compressor (100/120 V, 60 Hz) (includes filter/regulator unit) 9423 393 34116
Printers
Colour inkjet printer (NOT suitable for use with Local Control module) 9423 440 20001
Epson compatible Dot Matrix Printer (220/240 V) 9423 393 50011
Epson compatible Dot Matrix Printer (110/120 V) 9423 393 50021
Parallel Printer Cable 4013 172 59554
General Accessories and Consumables
Description Part Number
Spectrometer
Wide Range Photomultiplier Field Upgrade 9423 390 08341
S Series Spectrometers GFTV Field Upgrade (50 Hz) 9423 410 30011
A GFTV Software and Interface Kit, or a GFTV Monitor will be required to make a working system.
S Series Spectrometers GFTV Field Upgrade (60 Hz) 9423 410 30021
A GFTV Software and Interface Kit, or a GFTV Monitor will be required to make a working system.
M Series Spectrometers GFTV Field Upgrade (50 Hz) 9423 410 20011
A GFTV Software and Interface Kit, or a GFTV Monitor will be required to make a working system.
M Series Spectrometers GFTV Field Upgrade (60 Hz) 9423 410 20021
A GFTV Software and Interface Kit, or a GFTV Monitor will be required to make a working system.
Accessory Trolley 9423 393 46131
User Spares Kit for older M Series Spectrometers 9423 450 20001
Older M Series Spectrometers have part numbers 9423 400 20###.
User Spares Kit for current M and S Series Spectrometers 9423 450 30001
Current M Series Spectrometers have part numbers 9423 400 21###.
Background Correction
QuadLine deuterium source for current M and S Series Spectrometers 9423 420 30004
Current M Series Spectrometers have part numbers 9423 400 21###.
QuadLine deuterium source for older M Series Spectrometers 9423 420 20004
Older M Series Spectrometers have part numbers 9423 400 20###.
Gas Handling
These items are suitable for British Oxygen Company equipment only.
Acetylene Gas Pressure Regulator 9423 352 43881
Acetylene Flashback Arrestor 9423 393 46061
Hydrogen Flashback Arrestor 9423 393 46071
Nitrogen/Argon/Air Gas Pressure Regulator 9435 179 21201
Nitrous Oxide Gas Pressure Regulator 9423 354 03111
Flame Compartment
Universal (50 mm) Titanium Burner 9423 420 31011
Air/acetylene (100 mm) Titanium Burner 9423 420 31021
Retrofit Universal (50 mm) Titanium Burner 9423 420 35011
Retrofit Air/acetylene (100 mm) Titanium Burner 9423 420 35021
The Retrofit Burners are required for older (part number 9423 400 20###) M Series Spectrometers, and earlier 969/989 Spectrometers.
Spare Inert Nebulizer 9423 390 05481
Nebulizer Uptake Tube - 0.4 mm ID (for reduced uptake rate) 9423 390 05411
Nebulizer Uptake Tube - 0.5 mm ID 9423 390 05421
Nebulizer Cleaning Probe 9423 390 05441
Variable Flow Auxiliary Oxidant Kit Field Upgrade 9423 393 46111
Spray Chamber Renovation Kit 9423 390 05461
Micro-adjustable Impact Bead Kit 9423 390 05401
5 litre Drain Vessel 9423 390 05471
Solvent Resistant Drain Tubing 9423 390 05491
LH Universal Accessory Mount (S Series and current M Series) 9423 420 21005
RH Universal Accessory Mount (M Series only) 9423 420 20005
Retrofit Accessory Mount Kit (for older M Series, part number 9423 400 20###, and earlier instruments) 9423 420 22005 Gilson Flame and Vapour Autosampler.
Polypropylene Tubes for Rack 21, 8 ml, 1000 per pack 9423 470 03311
Glass Tubes for Rack 21, 9 ml, 100 per pack 9423 470 03321
Rack 21 (60 position) 9423 470 03301
Polypropylene Tubes for Rack 22, 17 ml, 10 per pack 9423 470 03331
Glass Tubes for Rack 22, 20 ml, 100 per pack 9423 470 03341
Rack 22 (44 position) 9423 470 03391
Polypropylene Tubes for Rack 24, 50 ml, 10 per pack 9423 470 03351
Glass Tubes for Rack 24, 50 ml, 30 per pack 9423 470 03361
Rack 24 (14 position) 9423 470 03381
Spare Teflon Sample Probe 9423 470 03211
222XL Autosampler Rack Tray 9423 470 03471
Gilson Autosampler to Nebulizer capillary tube 9423 393 68121
Rack 81 Kit (supports 96 well microplates on 222XL only) 9423 470 03481
Product Specifications
Description Part Number
CETAC Flame and Vapour Autosampler
21 Position Sample Rack 9423 470 03901
24 Position Sample Rack 9423 470 03911
40 Position Sample Rack 9423 470 03921
60 Position Sample Rack 9423 470 03931
90 Position Sample Rack 9423 470 03941
Polypropylene Tubes for 21 position rack and Standards rack, 50 ml, 500 per pack 9423 470 04151
Polypropylene Tubes for 24 position rack, 30 ml, 500 per pack 9423 470 04111
Polypropylene Tubes for 40 position rack, 20 ml, 500 per pack 9423 470 04161
Polypropylene Tubes for 60 position rack, 14 ml, 1000 per pack 9423 470 04131
Polypropylene Tubes for 90 position rack, 8 ml, 1000 per pack 9423 470 04141
Sample Probe Assembly 9423 470 03981
Sample Probe, 0.5 mm ID 9423 470 03991
Sample Probe, 0.8 mm ID 9423 470 04171
Tray Sub-assembly with a Standards Rack 9423 470 03951
Rinse Station 9423 470 03961
Drain Pump Tubing and Connector Kit 9423 470 03971
Autodilutor
ID100 Autodilutor Consumables Kit 9423 450 03201
Graphite Furnace
Water Recirculator (50 Hz) 9423 393 97005
Water Recirculator (60 Hz) 9423 393 97003
GF95 Tilt Mount 9423 490 20005
Graphite Contact Cones for GF95/GFS97 9423 393 95011
Contact Cone Replacement Tool for GF95/GFS97 9423 393 95101
Graphite Contact Cones for GF95Z 9423 393 95161
Contact Cone Replacement Tool for GF95Z 9423 393 95181
Adjustable Micropipette, 0 - 20 µl 9423 357 05421
Pipette Tips, 20 µl, 1000 per pack 9423 357 05431
GF95 User Spares Kit 9423 450 20002
GF95Z User Spares Kit 9423 450 20003
GFS97 User Spares Kit 9423 450 30002
Furnace Autosampler
Polypropylene Sample Cups, 2 ml, 1000 per pack 9423 393 80031
Polypropylene Reagents Cups, 25 ml, 50 per pack 9423 393 80021
PTFE Sample Cups, 2ml, 20 per pack 9423 393 80051
Reduced Volume Sample Cups, 1.5 ml, 20 per pack 9423 393 80061
Cup Reducing Ring 9423 393 80071
Spare Capillary Tips 9423 393 81261
Replacement PTFE Sampling Capillary Tube 9423 393 82261
Carousel and Tray 9423 393 83261
Furnace Autosampler User Spares Kit 9423 450 20004
Slotted Tube Atom Trap
Spare Quartz Slotted Tubes, 5 per pack 9423 393 35021
Dot Matrix Printer
Spare Printer Paper 9423 299 40501
Spare Printer Ink Ribbon 9423 299 40801
Validation
Nickel Validation Standard 9423 VAL 00011
Chromium Validation Standard 9423 VAL 00012
Manganese Validation Standard 9423 VAL 00013
Water Blank Validation Standard 9423 VAL 00014
Re-calibration of Validatorplus and/or iSQ module Accessory 9423 VAL R0004
Graphite Furnace Cuvettes
Description Part Number
Graphite Furnace Cuvettes
Normal Graphite Cuvettes, Ridged and Uncoated, 10 per pack 9423 393 95031
Pyrolytically Coated Graphite Cuvettes, Ridged, 10 per pack 9423 393 95071
Extended Lifetime Cuvettes (ELC), 10 per pack 9423 393 95041
Extended Lifetime Cuvettes (ELC), 20 per pack 9423 393 95051
Omega Platform Cuvettes, 10 per pack 9423 490 20101

Hollow Cathode Lamps

Multi-element lamps
Description Uncoded P/N Coded P/N Description Uncoded P/N Coded P/N
Ag/Cr/Cu 9423 393 21501 9423 393 31501 Co/Ni 9423 393 21211 9423 393 31211
Ag/Cu 9423 393 21491 9423 393 31491 Cr/Cu 9423 393 21131 9423 393 31131
Al/Mg 9423 393 21051 9423 393 31051 Cr/Mn 9423 393 21141 9423 393 31141
Al/Si 9423 393 21041 9423 393 31041 Cr/Ni 9423 393 21121 9423 393 31121
Ba/Sr 9423 393 21591 9423 393 31591 Cr/Ni/Cu/Mn 9423 393 21171 9423 393 31171
Cu/Fe/Zn 9423 393 21531 9423 393 31531 Cr/Ni/Mn 9423 393 21161 9423 393 31161
Ca/Ba 9423 393 21571 9423 393 31571 Cu/Fe 9423 393 21221 9423 393 31221
Ca/Ba/S 9423 393 21601 9423 393 31601 Cu/Fe/Mn/Zn 9423 393 21561 9423 393 31561
Ca/Mg 9423 393 21011 9423 393 31011 Cr/Ni/Cu 9423 393 21151 9423 393 31151
Ca/Mg/Si 9423 393 21061 9423 393 31061 Cu/Mn 9423 393 21231 9423 393 31231
Ca/Si 9423 393 21081 9423 393 31081 Cu/Mn/Zn 9423 393 21541 9423 393 31541
Ca/Sr 9423 393 21581 9423 393 31581 Cu/Ni 9423 393 21241 9423 393 31241
Cd/Zn 9423 393 21611 9423 393 31611 Fe/Mn 9423 393 21251 9423 393 31251
Co/Cu 9423 393 21181 9423 393 31181 Fe/Ni 9423 393 21261 9423 393 31261
Co/Cu/Fe 9423 393 21281 9423 393 31281 Fe/Zn 9423 393 21511 9423 393 31511
Co/Fe 9423 393 21191 9423 393 31191 Mg/Si 9423 393 21091 9423 393 31091
Co/Mn 9423 393 21201 9423 393 31201 Mn/Zn 9423 393 21521 9423 393 31521
Co/Mn/Ni 9423 393 21291 9423 393 31291 Na/K 9423 393 21021 9423 393 31021
Co/Mo 9423 393 21111 9423 393 31111 Si/Ti 9423 393 21101 9423 393 31101
Product Specifications

Hollow Cathode Lamps

Single element lamps

Description Uncoded Data Coded Value Lamp Description Uncoded Data Coded Value Lamp
Ag 20471 30471 2047 V Nb 20411 30411
Al 20131 30131 2013 V Nd 20601 30601
As 20331 30331 2033 V Ni 20281 30281 2028 V
Au 20791 30791 2079 V Os 20761 30761
B 20051 30051 P 20151 30151
Ba 20561 30561 Pb 20821 30821 2082 V
Be 20041 30041 Pd 20461 30461
Bi 20831 30831 2083 V Pr 20591 30591
Ca 20201 30201 2020 V Pt 20781 30781
Cd 20481 30481 2048 V Rb 20371 30371
Co 20271 30271 2027 V Re 20751 30751
Cr 20241 30241 2024 V Rh 20451 30451
Cs 20551 30551 Ru 20441 30441
Cu 20291 30291 2029 V Sb 20511 30511 2051 V
Dy 20661 30661 Sc 20211 30211
Er 20681 30681 Se 20341 30341 2034 V
Eu 20631 30631 Si 20141 30141
Fe 20261 30261 2026 V Sm 20621 30621
Ga 20311 30311 Sn 20501 30501 2050 V
Gd 20641 30641 Sr 20381 30381
Ge 20321 30321 Ta 20731 30731
Hf 20721 30721 Tb 20651 30651
Hg 20801 30801 2080 V Te 20521 30521
Ho 20671 30671 Th 20901 30901
In 20491 30491 Ti 20221 30221
Ir 20771 30771 Tl 20811 30811
K 20191 30191 2019 V Tm 20691 30691
La 20571 30571 U 20921 30921
Li 20031 30031 V 20231 30231
Lu 20711 30711 W 20741 30741
Mg 20121 30121 2012 V Y 20391 30391
Mn 20251 30251 2025 V Yb 20701 30701
Mo 20421 30421 2042 V Zn 20301 30301 2030 V
Na 20111 30111 2011 V Zr 20401 30401

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