St. CHM W2
St. CHM W2
DATE: 15-19/1/2024
Class: S. S. 1
Period: 3 Periods
Duration: 70 minutes
Behavioural objective(s): By the end of the lesson, learner should be able to:
i. explain coordinate covalence bond and it examples
ii. explain hydrogen bond and metallic bond with examples
iii. explain vander waals bond and it examples
Previous knowledge: Leaners already understands the meaning of chemical combination, electrovalent bond
and covalent bonds.
Reference: (i) New School Chemistry for senior secondary schools by Osei Yaw Ababio (ii) Essential
Chemistry for senior secondary school by Odesina I.A. (iii) internet.
Step1:
Teacher’s Activity: Teacher introduces the lesson by showing learners the chart and video clips
Learner’s Activities: Learners are to discuss what they see on the video clips one after the other
Step 2:
Teacher’s Activity: Teacher discusses the topic extensively and writes the note on the board for the students to
copy.
Learners’ Activities: Learners listen and write down in their note, learners also ask questions when necessary
A co-ordinate convalency bond is formed when one of the reactants possesses a lone pair of electrons, i.e., a
pair of electrons not directly concerned in its existing valency bonds. The lone pair of electron is donated to an
atom needing them to complete an electron octet or duplet of great stability.
Consider the formation of a hydronium ion, H3O+, usually described as the ionization of water.
H2O + H+ ↔ H3O+
Other examples of compounds in which we have coordinate covalency bond are NH4+, hydrated copper (ii) ion
etc.
Hydrogen Bond
Hydrogen bond is a dipole – dipole intermolecular attraction which occurs when hydrogen is covalently bonded
to highly electronegative elements of small atomic size. The electronegative elements can be nitrogen, oxygen
or fluorine. Hydrogen bond is a weak bond, it has important effect on the physical properties of compounds like
hydrogen fluoride and water.
The strongest hydrogen bonds are in hydrogen fluoride, where the simple hydrogen fluoride molecules are held
together by hydrogen bonds to form larger aggregates of H2F2, H3F3, etc. Another common examples is in ice
crystals where the water molecules are held together by hydrogen bonds.
Hydrogen bonds provide the attractive force that keeps water molecules together.
Hydrogen bonds play an important role in determining the structures and properties of molecules of living
systems such as proteins. The characteristics crystalline shape of solid water is due to hydrogen bonds.
Evaluation: The teacher evaluates the lesson by asking the learners to:
i. state the types of chemical combination
ii. state the properties of covalent bond and dative bond
Period 3
Sub-topics: Metallic bond; Vander Waal forces
Duration: 35 minutes
Behavioural objectives: By the end of the lesson, the learners should be able to:
i. explain the metallic bond
ii. discuss extensively the vander waal forces
Metallic Bond
Metals atoms are held together in solid crystal lattices by metallic bond. Each metallic atom contributes its outer
(valence) electrons to the electron cloud, thus becoming positively charged. The residual ions tend to repel each
other but are held together by the moving electron cloud and over-lapping residual electron orbits.
This type of bonding is very strong in some metals such as iron and it is difficult to shatter but it is much
weaker in metals like sodium which can be cut with a knife.
Classwork: write three compounds each for covalent, dative, metallic bonds and vander waal forces
Assignment: Revision objective questions number 1 to 15, page 100 in Essential chemistry for S. S. Schools by
Odesina I.A.
Conclusion: Teacher concludes the lesson by checking the learners note and mark.
H.O.D’s Comment:
Date: 15-19/1/2024
Class: S. S. 2
Sub-topic:
Period: 3 Periods
Behavioural objective(s): By the end of the lesson, learner should be able to:
i. define solution and solubilty.
ii. explain the various types of solution
iii. solve calculations on pH
iv. state the factors affecting solubility
v. discuss solubility curves
vi. solve calculation on solubility
Previous knowledge: Learners are familiar with some solution prepared and used in their various homes like
paint solution, soap solution, tea, milk, salt solution, etc
Instructional materials: Charts and Video clips explaining the solution and solubility.
Step2:
Teacher’s Activity: Teacher asks the learners to say what they understand about the topic ‘Solution and
Solubility’.
Learners’ Activities: Learners are allowed to give their opinion on the concept ‘Solution and Solubility’ in
their own way and also listen to the teacher when correcting them.
Step 3:
Teacher’s Activity: Teacher explain the topic extensively and writes on the board for the learners to copy
down
Learners’ Activities: Learners listen and write down in their note, then ask questions when necessary
SOLUTIONS
A solution is a uniform or homogenous mixture of two or more substances.
Solution = Solvent + Solute
A solute is a dissolved substance which may be a solid, liquid or gas.
A solvent is a substance (usually liquid) which dissolves a solute.
TYPES OF SOLUTIONS
1. Aqueous Solution: This is formed when a solute is dissolved in water.
2. Chemical Solution: This is the apparent solution of a solute in a solvent accompanied by a chemical
change. For example, magnesium appears to dissolve in dilute hydrochloric acid, what actually happens is
that the magnesium attacks the acid to form magnesium chloride, which dissolves in water present.
TYPES OF COLLOIDS
1. Sols and Gels: These are colloids where solid particles are dispersed in liquid medium. Example: starch,
glue, jelly, etc
2. Aerosols: In aerosols, liquid particles are dispersed in a gas. Fog, smoke, spray of insecticide is examples
of aerosol.
3. Emulsion: For emulsions, a liquid is dispersedin another liquid. Examples of emulsions are milk, hair
cream; cleaning action of detergents is due to their ability to form emulsion.
SOLUBILITY
The solubility of a solute (substance) in a solvent at a particular temperature is the maximum amount of solute
in moles or grams that will dissolve in 1 dm3 of the solvent at that temperature.
The concentration in moldm-3 of a saturated solution is termed the solubility of the substance i.e.
Solubility (moldm3) = Concentration in gdm3
Molar mass
Solubility in mol/dm3 can also be expressed as = mass x 1000
Molar mass volume
Solubility in g/dm3 = mass x 1000
volume 1
Solubility of a solid solute in a solvent increases with rise in temperature while solubility of gases decreases
with rise in temperature.
DEFINITION OF TERMS
1. Saturated Solution: A saturated solution at a particular temperature is one which contains as much solute
as it can dissolves at that temperature in the presence of undissolved solute particles.
2. Unsaturated solution: This is a solution which contains less of the solute than it can dissolve at a particular
temperature.
3. Super saturated solution: This is a solution which contains more of the solute than it can dissolve at a
particular temperature.
DETERMINATION OF SOLUBILITY
Solute: KCl, Solvent: water
Method
1. A saturated solution of KCl is prepared by dissolving excess of the solid in water in a beaker
2. Allow the solution in the beaker to settle down to obtain a clear saturated solution
3. Decant a portion of clear solution into another beaker and measures its temperature
4. Transfer the solution into a weighed evaporation dish and record the mass of the solution
5. Evaporate the solution to a complete dryness in a water bath
6. Allow the resulting solid to cool and reweigh the basin with content
7. Obtain mass of the dissolved salt and calculate the mass of the salt that would dissolve in 1dm 3 of water
at that temperature.
CALCULATION
Mass of basin = xg
Mass of basin + solution = yg
Mass of basin + salt = zg
Mass of solution = (y-x)g
Mass of salt = (z-x)g
Mass of water used = (y-z)g
:. (y – z)g H2O dissolves (z – x)g salt
:. 100g H2O dissolves (z – x)/(y – z) x 100g salt
[Density of water = 1gcm3]
:. No of moles of salt = 100(z – x)
(y-z) x M.M
Period 3
Sub-topics: Solubility curves; Calculation on solubility.
Duration: 35 minutes
Behavioural objectives: By the end of the lesson, the learners should be able to:
i. state the factors affecting solubility
ii. discuss solubility curves
iii. solve calculation on solubility
CALCULATION ON SOLUBILITY
1. If 12.2g of Pb(NO3)2 were dissolved in 21cm3 of distilled water at 20oC. Calculate the solubility of the
solute in moldm-3
Solution:
Molar mass of Pb(NO3)2 = 331g
No of moles of Pb(NO3)2 = 12.2/331 = 0.037moles
If 21cm3 of water at 200C dissolved 0.037mole salt
:. 1000cm3 of water at 200C dissolves 0.037 x 1000/21
= 176moles Pb(NO3) per dm3 H2O
2. 1.0dm3 of an aqueous solution at 90oC contains 404g of KNO3 and 245g of KClO3.
a. Determine which of the two salts will separate out when the solution is cooled to 60oC
b. mass of salt that will separate out at 60oC
(Solubility of KNO3 in H2O at 60oC = 5.14moldm-3, solubility of KClO3 in H2O at 60oC = 1.61moldm-3)
Solution:
No of moles of KNO3 = 404/101 = 4.0moles dm-3
No of moles of KClO3 = 245/122.5 = 2.0 moldm-3
The solubility of KClO3 at 60oC (5.14 moldm-3) is higher than the amount in solution (4.0 moldm -3), then
KNO3 will remain in solution while KClO 3 will crystallize out at 60 oC since the solubility at 60 oC is
lower than the amount in solution.
b. Mass of salt that will separate out at 60oC = 2.0 – 1.61 = 0.39mole
Mass of salt = Number of moles x Molar mass
= 0.39 x 122.5 = 47.78g
3. The solubility of KNO3 is exactly 1800g per 1000g water at 83oC and 700g per 1000g water at 40oC.
Calculate the mass of KNO3 that will crystallize out of solution if 155g of the saturated solution at 83 oC is
cooled to 40oC.
Solution:
Saturated solution of KNO3 at 83oC = 1000 + 1800 = 2800g
Saturated solution of KNO3 at 40oC = 1000 + 700 = 1700g
Mass of solute deposited = 2800 – 1700 = 1100g
From 83oC to 40oC, 2800 of saturated solution deposited 1100g of solute
155g of saturated solution will deposit 1100 x 155/2800 = 60.80g of salt.
EVALUATION
1. Define super-saturated solution
2. State two applications of solubility curves
3. Define the following terms: Solubility, Saturated solution, Unsaturated solution.
4. 1.33 dm3 of water at 70oC are saturated by 2.25 moles of lead (II) trioxonitrate (V) and 1.33 dm 3 of water at
18oc are saturated by 0.53 mole of the same salt. If 4.50dm 3 of the saturated solution are cooled from
70oC to 18oC, calculate the mount of solute that will be deposited in (a) moles (b) grams.
GENERAL EVALUATION/REVISION
1. Calculate the solubility of KCl in g/dm3 if 5g of the salt was dissolved in 50cm3 of water at 40oC
2. If 50cm3 of a saturated solution of potassium chloride at 30 oC yielded 18.62g of dry salt, calculate the
solubility of the salt in mol/dm3 at 30oC
3. Define solubility
4. A certain mass of a gas occupies 300cm3 at 35oC. At what temperature will it have its volume reduced by
half, assuming its pressure remains constant?
5. A certain mass of hydrogen gas collected over water at 10oc and 760mm Hg pressure has a volume of
37cm3. Calculate the volume when it is dry at s.t.p. (Saturated vapour pressure of water at 10 oC =
9.2mmHg)
WEEKEND ASSIGNMENT
SECTION A: Write the correct option ONLY
1. A saturated solution is a solution a. in which the solute is in equilibrium with the solvent b. in which the
solute saturates the solution c. the solvent can still accept more solute except when the temperature is
lowered d. whose solvent has low solubility at a given temperature
2. A graph of solubility against temperature is called a. sigmoid curve
b. supernant curve c. solubility curve d. dispersion curve
3. On heating 25g of a saturated solution to dryness at 60 oC, 4g of anhydrous salt was recovered. Calculate
its solubility in g/dm3. a. 160 b. 180 c. 200 d. 220
4. The solubility of alcohols in water is due to a. their covalent nature b. hydrogen bonding c. their low
boiling point d. their ionic character
5. A common solvent of sulphur is a. water b. carbon(IV)sulphide c. alcohol d. ethanoic acid
SECTION B
1. Define the following:
(a) Solubility (b) Saturated solution (c) Unsaturated solution
2. If the solubility of KNO3 at 0oC is 1.33mol/dm3, determine whether a solution containing 30.3g/dm3 at
0oC is saturated or unsaturated.
Conclusion: Teacher concludes the lesson by checking the learners note and mark.
H.O.D’s Comment:
Date: 15-19/1/2024
Class: S. S. 3
Period: 3 Periods
Duration: 70 minutes
Behavioural objective(s): By the end of the lesson, learner should be able to:
i. explain extensively fats and oils.
ii. explain soap and detergent.
iii. explain the structure, preparation and nature of soap and detergent
iv. discuss the properties of plastics and rubber
v. explain natural and synthetic polymer
Previous knowledge: Learners are familiar with some solution prepared and used in their various homes like
paint solution, soap solution, tea, milk, salt solution, etc
Instructional materials: Charts and Video clips explaining the solution and solubility.
Step2:
Teacher’s Activity: Teacher asks the learners to say what they understand about the topic ‘Organic Chemistry:
Fats and Oils; Amines; Natural Polymer; Soap and Detergent’.
Learners’ Activities: Learners are allowed to give their opinion on the concept ‘Organic Chemistry: Fats and
Oils; Amines; Natural Polymer; Soap and Detergent’ in their own way and also listen to the teacher when
correcting them.
Step 3:
Teacher’s Activity: Teacher explain the topic extensively and writes on the board for the learners to copy
down
Learners’ Activities: Learners listen and write down in their note, then ask questions when necessary
Hydrophilic
R - SO3- Na+
hydrophobic
tail
R is a long hydrophobic chain.
N.B:- All polymers are macromolecules, but not all macromolecule but it is not polymeric.
NATURAL POLYMERS:
These are organic compounds which can be found in living thing e.g. carbohydrates like starch and cellulose
and all proteins fats and oils are not large enough to be grouped as giant molecule or polymer.
SYNTHETIC POLYMERS
These are called plastics e.g. nylon polythene etc.
POLYMERIZATION
This is the process whereby two or more monomers link/join together to form a compound of high molecular
mass.
TYPES OF POLYMERIZATION
1. Addition polymerization:- these occur when two or more of the same monomers join together to form the
polymer without elimination of any small molecules.
CHARACTERISTICS OF MONOMER
- It must be simple.
- Unsaturated
- There should be double bonds between the carbon atom.
e.g. n[CH2CH2 ] ……..CH2CH2[CH2CH2]nCH2CH2……
EVALUATION: The teacher evaluates the lesson by asking the learners to:
1. Draw the structure of soapless detergent.
2. State one advantage of soapless detergent over soapy detergent.
Period 3
Sub-topics: Plastics; Amines.
Duration: 35 minutes
Behavioural objectives: By the end of the lesson, the learners should be able to:
i. explain plastics, rubber, resins and vulcanization
ii. explain the preparation and classification of amine
iii. state the physical properties, chemical properties and uses of amine.
PLASTICS
Plastics are synthetic which can be heated or pressured to form any shape.
THERMOPLASTIC
Thermoplastics are type of synthetic materials which can be heated and remoulded to any shape e.g. nylon,
polythene, polypropene, Perspex etc.
THERMOSETS
Thermosets, on the other hands cannot be softened or melted by heat and remoulded once they are formed e.g.
uera-methanal, bakelite.
Thermoplastics and thermosets
Thermoplastics Thermosets
Polythene Bakelite
Polypropene Urea-methanal
Polystyrene
Nylon
Terylene
Perspex
RESINS
This is obtained from the rubber tree. The fluid obtained from the tree can be heated and changed to elastic
solid known as rubber. The rubber consists of 2-methyl but-1, 3- diene monomers known as isoprene.
CH3
nCH2 = C CH = CH2
2 – methylbuta -1, 3-diene.
VULCANIZATION:
This is the process of heating natural rubber with sulphur to give rubber a greater tensile, strength, durability
and elasticity over a wide range of temperature.
SYNTHETIC RUBBER:
Examples of synthetic rubbers are poly 2-chlorobuta -1,3diene, styrenebutadiene rubber (SBR), poly bute -1, 3-
diene and poly 2-methyl propene.
AMINES:
It has a functional group of NH2.
GENERAL MOLECULAR FORMULAR/STRUCTURE:
It has a general molecular formula of RNH2 or structure of R–N–H
H
PREPARATION:
They are derivatives of ammonia where one or more hydrogen atoms have been replaced by alkyl or aryl groups
e.g. RNHz, R2NH.
CLASSIFICATION:
Amines can be classified according to alkyl group.
CHEMICAL PROPERTIES
1. As bases they neutralize acids.
2. They dissociate/ionize in water e.g. CH3NH2 + H2O CH3NH3++ OH-
USES
1. Used in making nylon
2. They can also be used in making polyamide.
EVALUATION
1. State two (2) physical properties and two (2) chemical properties of amine.
2. Give the classes of amine according to the number of their alkyl groups.
3. State a difference between natural polymers and synthetic polymer with example each.
4. What is another name for synthetic polymer?
Classwork
1. The structure of soap according to suponification process is
A. CH3(CH2)16COONa B. CH3CH2COOCa C. CH3CH2CH2COONa
D. C2H5COONa
2 . The example of soapless detergent is
A. alkyl B. ethylethanoate C. alkanol D. alkylbenzenesulphonates
3. Hydrophobic tail of soap dissolves in grease while hydrophilic dissolves in
A. benzene B. water C. propanol D. kerosene
4. Fats and oils belong to a general group of compounds known as ………..
A. glycerol B. soap C. margarine D. lipids
5. Hydrolysis of fat and oil to yield alkanol and soap is called …………
A. esterification B. hydrogenation C. hydrolysis D. saponification
THEORY
1. Explain the structure of soapless detergent and its mode of action.
2. Explain the following;
(a) saponification (b) hydrogenation
WEEKEND ASSIGNMENT
1. The following are examples of small molecules based during polymerization process.
A. acid B. HCl C.H2O D. NH3
2. Polymerisation of ethane produces ……………
A. Perspex B. isoprene C. polythene D. ammonia
3. Bakelite is a good example of …………..
A. natural rubber B. thermoset C. thermoplastic D. additional polymerization
4. Starch and cellulose are good examples of …………
A. polythene B. natural polymer C. synthetic polymer D. food
5. Joining together of smaller molecules to form a giant molecule is called ………..
process. A. hydrogenation B. saponification C. esterification D. polymerization
THEORY
1 (a) What are the conditions necessary for polymerization.
(b) List two types of polymerization.
2 (a) Write an equation for the preparation of polythene from ethane.
(b) What are the monomer present in the following:
- polythene
- polyvinyl/chloride
- polytetrafluoro ethane
- polypropene
Conclusion: Teacher concludes the lesson by checking the learners note and mark.
H.O.D’s Comment: