SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.

Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC:Sr.Super60_Elite, Target & LIIT-BTs EAPCET Date: 01-05-2024
Time: 09 A.M TO 12 NOON GTE-09 Max. Marks:160

KEY SHEET
MATHEMATICS
1 1 2 4 3 3 4 2 5 3
6 2 7 4 8 4 9 1 10 4
11 3 12 1 13 4 14 2 15 2
16 1 17 1 18 1 19 2 20 3
21 2 22 1 23 1 24 2 25 4
26 1 27 4 28 2 29 4 30 1
31 1 32 4 33 1 34 2 35 3
36 3 37 3 38 3 39 3 40 4
41 3 42 3 43 3 44 1 45 3
46 1 47 1 48 1 49 2 50 2
51 3 52 2 53 2 54 3 55 1
56 1 57 4 58 3 59 4 60 1
61 1 62 2 63 4 64 2 65 4
66 3 67 3 68 1 69 3 70 4
71 3 72 1 73 3 74 2 75 4
76 1 77 1 78 3 79 3 80 1

PHYSICS
81 2 82 1 83 3 84 1 85 4
86 2 87 4 88 1 89 1 90 4
91 1 92 4 93 2 94 3 95 2
96 1 97 1 98 2 99 4 100 1
101 2 102 2 103 4 104 2 105 1
106 3 107 3 108 2 109 3 110 4
111 4 112 3 113 2 114 1 115 1
116 4 117 4 118 4 119 4 120 4

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 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S

CHEMISTRY
121 2 122 1 123 4 124 2 125 3
126 3 127 2 128 2 129 1 130 2
131 1 132 4 133 3 134 3 135 2
136 2 137 3 138 3 139 3 140 1
141 1 142 3 143 1 144 3 145 3
146 1 147 3 148 4 149 4 150 3
151 2 152 1 153 1 154 3 155 3
156 2 157 1 158 2 159 4 160 1
SOLUTIONS
MATHEMATICS
1. The domain of log e {x  [ x]} is R ,because [ x]  0
2. Let y  x 2  1  x   y  1  f 1 ( y )   y  1  f 1 ( x)   x  1
 f 1 (17)   17  1  4 and f 1 ( 3)   3  1   4, which is not possible
3. gof ( x)  g{ f ( x)}  [ cos x ]
4. g ( x )  1  n  n  1, x  n  z
1 g ( x)  0
f ( g ( x))  0 g ( x)  0
1 g ( x)  0
5. tn  n term  3n 2  n
th

When n=1  tn  4
When n=2 ,  tn  14
n  3,  tn  30 etc
6. conceptual
7. conceptual
8. From the given equation
(1   ) x  3 y  4 z  0
3x  y   z  0
(1   ) 3 4
 1 (  3) 5  0    0, 1
3 1 
1 2 3
9.  4 7 0 3
3 2 5
   
10. (a b) 2  (a . b) 2  

 (ab sin  . n) 2  ( ab cos  ) 2  

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 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
 a b sin   a b cos   
2 2 2 2 2 2

^2 ^ ^
( n  n . n  1    a 2b 2
   
11. Given a b  8, a  2,  b  5
  2    2  2  
a b  ( a . b) 2  a b  64  ( a . b)2  4(25)
   
 (a . b) 2  36  a .b  6
       
12. a b  (2 i  j  k )  ( i  2 j  4 k )
       
 2 i  9 j  5 k and a c  2 i  3 j  k
   
Now ( a b).( a c)  26  26.
           
13. Given a i  j  a  x i  k  a . i  x( i . i )  (k . i )
 
 a . i  x  0  x  arbitrary scalar
14. conceptual
15. conceptual

   
cos 2      sin 2    
16. 6  6 
     
cos        cos       
6 6  6 6 
2 1
 cos cos 2  cos 2
6 2
m tan(120   )
0
17. 
n tan(  300 )
m  n tan(  1200 )  tan(  300 )
 
m  n tan(  1200 )  tan(  300 )
cos A 2 cos 2 A 1  cos 2 A
18. We have cot A   
sin A 2sin A cos A sin 2 A
10
1 1  cos15
0 0
A  7  cot 7  on simplification ,
Putting 2 2 sin150
10
We get cot 7  6 2 3 4
2
19. CONCEPTUAL
20. 2 tan 2   sec 2   2 tan 2   tan 2   1
  
 tan 2   1  tan 2      n 
4 4
21. Obviusly x  sin(   ) and y  sin(   )
1  xy  1  sin(   ) sin(   )
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 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
 1  sin   sin   sin   cos 
2 2 2 2

x tanh y
22. Let x  tanh y, then   sinh y
1  x 2 sec hy
 x 
 sinh 1  1 1
  sinh (sinh y )  y  tanh ( x)
 1 x 
2

23. In BC1M ; BM  (C1M ).cot 30

 BM  3
BC  3  3  2  2(1  3)
Hence side
3
 [2(1  3)]2  6  4 3 sq units
Area of equilateral triangle 4
24. Sides are 3,4,5 since 32  42  52
So triangle is a right angle triangle
R  5 / 2  2.5
25. In PQR, the radius of circum circle is PQ  PR
PQ QR PR
 PQ  PR   
2sin R 2 sin p 2 sin Q
1  2
sin R  sin Q   R  Q   P    R  Q 
2 6 3
z  1 ( x  1)  iy ( x  1)  iy
26. z  1  x  iy  1  x 2  y 2  1    
z  1 ( x  1)  iy ( x  1)  iy
( x 2  y 2  1) 2iy 2iy
  
( x  1)  y ( x  1)  y
2 2 2 2
( x  1) 2  y 2
27. CONCEPTUAL
28. We have z1  1 and z2 be any complex number
z1  z2 z1  z2 
 z1 z1  z1
2
 
 
;
1  z1 z2 z2
1 
z1
z1  z2   z1  z2 z1  z2
 z1 ; Given that  z1  1   1
 
z1  z2 z1  z2
z1  z2

29. z  z 1  1  z 2  z  1  0  z   or   2
For z   , z100  z 100  ( )100  ( ) 100
1
       2  1

z   2 , z100  z 100  (  2 )100  ( 2 ) 100
For
1 1
 200   2    2    1
 200
2
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30. Given ( x  1)  ( x  1)  (4 x  1)
2 ( x 2  1)  2 x  1
Squaring both sides , we get
Squaring again ,we get x=5/4 which does not satisfy the given equation . Hence
equation has no solution .
f ( x)  x3  3 x 2  4
31. Given
f ( x)  3 x 2  6 x  3x( x  2)  0  x  0, 0
f (2)  8  12  4  0.But f (0)  0
2 is repeated root
32. The number of sub-sets of the which contain at most n elements is
2n  1 C0  2n  1 C1  ........  2n  1 Cn  S ( Say )
2 s  2( 2 n 1 C0  2 n 1 C1  .......  2 n 1 Cn )
Then
=  (2 n 1 C0  2 n1 C2 n 1 )  ( 2 n 1 C1  2 n 1 C2 n )  ...... .....  ( 2 n 1 Cn  2 n 1 Cn 1 )
 2 n 1 C0  2 n 1 C1  ........  2 n 1 C2 n 1  2 2 n 1  s  2 2 n
33. The total number of 4 digits are 9999-999=9000.
The number of 4 digits number divisible by 5 are 90  20  1800 .
 1  1   1   1 
     1    2  ...    r  1
2 2 2 2
34. Coefficient of x r        (2) r

1.3.5...(2r  1) (1) r (1) r 2r 1.3.5...(2r  1) (1) r (1) r 2r

 .  .
2r r! r! r !r ! 2 r
35. Since 1  2 x  3x 2  4 x 3  ....  (1  x) 2
There fore ,we have (1  2 x  3x 2  4 x3  ....)1/ 2  {(1  x) 2 }1/ 2
 (1  x) 1  1  x  x 2  ....  x n  .....
36. Conceptual
37. Conceptual
38. Required probability is P ( getting 8)  p(9)  p (10)  p (11)  p (12)
5 4 3 2 1 15 5
      
36 36 36 36 36 36 12
13 4 1
39. Required probability =p(Diamond).P(king)  . 
52 52 52
40. Conceptual
 x1 , y1    3, 2 
41.  x2 , y2    3, 2 
 x3 , y3    0, h 

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  x1  x2   3 y  y2
3rd Vertex   1
 
y  y2  3  x1  x2  
, 1 

 2 2 
 
 3  3  3  2  2  2  2  3  3  3 
 o, h    , 

 2 2 
 o, h    0, 2  3 
3 , Since h  0, So, h  2  3 3
42.
A 1,1

P  1, 2  R  3, 2 

C
B Q 1,3
A  P  R Q
Q  P  R  A  1, 3

Centriod of ABC =Centriod of PQR  1, 

7
3  
43. PA  3  PB
Squareing on both sides
PA2  9  PB 2  6 PB
2 x  2 y  9  6 PB
Squareing on both sides
4 x 2  4 y 2  81  8 xy  36 y  36 x  36  x 2  4  4 x  y 2  1  2 y 
 32 x 2  8 xy  32 y 2  108 x  108 y  99  0
44.
C B  3,1

2 450

450

A  2, 0 

AB  r  2
slope of AB  m   1
tan   1    450

Total angle 
2
  
C   2  2 cos , 0  2 sin 
 2 2

 2, 2 
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45.  r bisector of PQ is  x1  x2  x   y1  y2  y   x12  x22    y12  y22 
2 

1  k  x   4  3 y 
1
2

1  6    k 2  9  
 1  k  x  y 
8  k 2 
2
y  int ercept  4
8 k2
 4  8  k 2  8  k 2  16, k  4
2
46. 1, 10  lies on 3x  y  7  0
47.
 L11 : L22  3 : 2
  3  k  : 8  k  3 : 2
 6  2k  24  3k
 5k  30
 k 6
48.

L
O  0,0 

x 2  y 2  2 x  4 y  2  0 .......... 1
x y
x y   1 ..........  2 

Homogenizing 1 with help of 2
x 2  y 2  2 x 1  4 y 1  2 1  0
2

2
 x y  x y  x y
x2  y 2  2 x    4y   2  0
        
 2
 2  2  x 2    2  4  2  y 2   6  4  xy  0 .............  3
since AOB=900
 2  2  2   2  4  2  0
2 2  6   4  0
 2  3  2  0
  1,   2

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 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
 L1  x  y  1  0
L2  x  y  2  0
2  1 1
Distance  
11 2
49. P divites QR in the ratio 4-2:5-4=2:1
2  2   11 3
Z-Coodinate of P    1
2 1 3
50.
a  b  c  0 ....... 1
2ab  2ac  bc  0
2a  b  c   bc  0
2a  b  c   bc  0
2

  b  2c  2b  c   0
b
 c  2b  or  
2
If c  2b then a : b : c  1:1: 2
b
If c   then a : b : c  1: 2 :1
2
a1a2  b1b2  c1c2 3 1 
cos       
a12  b12  c12 a22  b22  c22 6 2 3
51. Required equation of plane is  1   2  0
 2x  6 y  4z  7    x  y  2z  2  0
  2    x   6    y   4  2  z  7  2 ............. 1
1  r x  y  2 z  5  0
  2      6     2  4  2   0
4
  4 in 1  6 x  2 y  4 z  15  0
3  sin 3 x 
tan x  1  
tan 3 x  sin 3 x  tan 3 x 
52. lim  lim
x 0 x5 x 0 x5
tan 3 x 1  cos3 x 
 lim
x 0 x3 . x 2
1  cos3 x 3cos 2 x sin x 3
 lim  lim 
x 0 x2 x0 2x 2

x
 2 tan 2 x   2 x tan 2 x 
2 x tan 2 x 
1 
 1
 1  tan 2 x 
2
lim 1  tan 2 x
2
53.  lim
1  1  2sin 2 2 x    2sin 2 2 x 
x 0 2 x  0 2

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2
tan 2 x
2 x tan 2 x 2
 lim 1  tan 2 2 x  lim x tan 2 x.tan 4 x
x 0 4sin 4 2 x x 0 4 sin 4 2 x
2
 tan 2 x   tan 4 x 
  . 
1  x   x  1 4 4 1
 lim 4
  
4 x 0  sin 2 x  4 16 4
 
 x 
54. f  x   x   x
  x discontinuous If x is an integer
55. x  
1 y   y 1 x
Squaring on both sides
x  
1  y  y 2 1  x 
x
y
1 x
dy

1  x 1  x 1
dx 1  x  2
1

1  x 
2

x
56. If x>0, f  x   is differentiable
1 x
If x<0, f  x  is differentiable
x
0
1
At x=0, f '  0   lt 1  x  lim 1
x 0 x0 x  0 1 x
x
0
1
f '  o   lt
 1  x  lim 1
x 0 x0 x  0 1 x
 f is diff at x  0 & hence everywhere
57.
r  radius
x  diameter
v  volume
 x  0.04
r  10
4
v   r3
3
3
4  x   x3
   
3 2 6

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 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
x 2
v  x
2
 x2
dx
v
100  2  100
v  x3
6
dx
3  100
x
3   0.04 
  100
20
 0.6
y12 1  m 2  dy
58. Area = where m  p
2m dx
x2  y 2  4
dy
2x  2 y 0
dx
dy  x

dx y
dy 1
m 
dx 1, 3 
3
 1
3 1  
 
3
2 3
1
2
3
59.
r  radius
v  volume
4
v   r 3  288
3
 r 3  216
 r  6 cm
4
v   r3
3
dv dr
 4 r 2 .
dt dt
dr 1
  cm / sec
dt 72
60. By L.M.V.T

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 10

 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
f b   f  a 
f 'c 
ba
1 f  3  f 1
 
c 3 1
1 1
  log 3e
c 2
 c  2 log3e
61. f  x    log x   x 2  x , x  0

 f ' x   2 x  1
x
f '  1  0    2   1....... 1
f '  2   0    8  2........  2 
 2   1  6  3
1
    ,  2
2
62. Ole : x  y  4 x  8 y  15  0
2 2

centre   2, 4  , radius  5
Ole meet line 3x  4 y  m in 2 distinct.Pts.
d  r
6  16  m
 5
32  42
 m  10  25
 25  m  10  25
 35  m  15
63.
S11  16
 1  36  4  36  a  16
 a  11
64.

c2  6,5

c1  r, r 

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 11

 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
c1   r , r  , r1  r
c2   6,5  , r2  3
Touch each externals
c1c2  r1  r2

 r  6   r  5
2 2
 r 3
r 2  36  12r  r 2  25  10r  r 2  9  6r
r 2  28r  52  0
 r  26  r  2   0
r  26, r  2
Rejected
 c1c2  5
65. Equation of common chord :-
10 x  10 y   c  12   0
Passes through centre  3, 2  of S2
10  3  10  2   c  12  0
c  62

Focus=  , 0   centre of ole

p
66.
2 
Radius of ole is “P”
2

Equation of ole :  x     y   p 2 ......... 1

p 2

 2
eq of parabola : y  2 px ........  2 
n 2

Solving (1) & (2)

2
 p
 x    2 px  p
2

 2 
 4 x  4 px  3 p 2
2

  2 x  3 p  2 x  p   0
p 3p
x ,x  
2 2
p
When  x   y 2  p 2
2
When
3p 6 p2
x  y2    rejected 
2 2
p  p 
 pt of intersection are  , p  and  ,  p 
2  2 
67.

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 12

 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
y  5 x  4a  5
2

5
a
4
25 25
x1 x2  a 2 y1 y2  4a 2 4 x1 x2  y1 y2  4   0
16 4
25 25
  4 
16 16
25

4
68.
x2 y 2
 1
25 16
a 2  25  a  5
b 2  16  b  4
SP  8
b2
e2  1 
a2
3
e
5
SS '  2ae
SS '  6
SP  S ' P  2a
8  S ' P  10
S 'P  2
SS '  6
 42
SS '  4  S ' P
69. hyperbola :
x2 y2
 1
144 81
25 25
144 2 81
a2  ,b 
25 25
a 2  b2
e
a2
b2
 1
a2

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 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S

81 15
 1 
144 12
foci    ae, 0 
  3, 0 
foci of ellipse    ae, 0 
  4e, 0 
4e  3
3
e
4
9
e2 
16
2
b 9
1 2 
9 16
 b2  7
70.
sin 2 x sin 2 x
I  e sin x cos x dx   e .cos3 x sin x dx
put sin 2 x  t
2sin x cos xdx  dt
dt
sin x cos xdx 
2
1 1 dt
  et  et   et . 1  t  .
2 2 2
1 1 1
 et  et   et .t dt
2 2 2
1 3 1
 et  tet  et   c  et  tet  c
2 2 2
1
 et 3  t   c
2
1 2
 esin x 3  sin x x   c
2
1 2
 esin x  2  cos 2 x   c
2
2  1 
 esin x 1  cos 2 x   c
 2 
71.

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 14

 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
25 x  8 2

 25 x 2  9
dx

25 x 2  9  1
 dx
25 x 2  9
1
  25 x 2  9dx   dx
25 x 2  9
Simplify (Apply formula)
72.
I min   x m  log x  dx
n

x m 1 n
 log x    log x  . x m1.x 1dx
n 1

n

m 1 m 1
m 1
x n
 log x  
n
 I m ,n 1
m 1 m 1
73.
1
I n   e x  x  1 dx
n

Put x  1  t
dx  dt
0
I n   et 1.t n dt
1
0
 e  et .t n dt
1

 0

 e  t n et   n  t n 1.et dt 
0

1
 1 
I n   1  nI n 1 ........... 1
n 1

n 1
1
I n   e x  x  1 dx
0
1
  e  x  1    e x dx
x 1

0
0

 e1 1  1  e0  0  1   e x 
1

I1  2  e
For n  2
I 2   1
2 1
 2 I1
 1  2  2  e 
 1  4  2e
 5  2e
Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 15
 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S

I 3   1
31
 3I 2
 1  3  5  2e 
 1  15  6e
 16  6e
n  3
74.

x x
I   1  4sin 2  4 sin dx
0
2 2
 2
 2 x
 1  2sin  dx
0  2

x
  1  2sin dx
0
2

3 
 x  x 
I   1  2sin  dx    2sin  1 dx
0
2   2 
3


 x3   
  x  4 cos    4 cos  x 
 2 0  2 
3


 4 3 4
3
75.
1
A  5x  4  9 x 2  dx
2

1
1
   4  4 x  dx
2

1
1
 x3 
4  x 1  4  
1

 3  1
8 16
 8 
3 3
76.
1  y  dx   tan
2 1
y  x  dy
dy 1 tan 1 y
 x 
dx 1  y 2 1 y2
dy
 p  x x  Q  y
dx
1
 1 y 2 dy 1
I .F  e  e tan y

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 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
77.
1
dy
D.E : 3 x.  3 y   x2  y2 2  0
dx
1
3 x.dy  3 ydx   x 2  y 2  2 dx  0
put y  vx dy  vdx  xdv
1
3 x  vdx  xdv   3vxdx   x 2  v 2 x 2  2 dx  0
3dv dx
3 x 2 .dv  x 1  v 2  2 dx  0
1

1

x
1  v 
2 2

1 1
3 dv   dx
1 v 2 x
3cos 1  v   ln x  c
 y
3cos 1    ln x  c
x
Given y 1  1
3cos 1 1  ln 1  c
c0
y
3 cos 1  ln x
x
78.
1
log 1  x 
I  8 dx
0
1  x2
put x  tan   dx  sec 2  d

4
log 1  tan  
I  8 sec2  d
0
1  tan 2

   
4
I  8 log 1  tan      d  I  8. log 2
0  4  8
I   log 2
79.
y

 1,0  0 1,0  x

y'

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 17

 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S
x  y  1............ 1
2 2

y 2  1  x .............  2 
solve 1 &  2 
x0 and 1
 
y  1 y0
Point of intersection
1, 0  ,  0,1 ,  0, 1
Area = area of semicircle
1
2  1  x dx
0
1
 3 
 r2   1  x  2 
 2 
2 3
 
 2 0
 2  4
  2    r  1
2 3 2 3
80. Put
log ex  t
x  et
dx  et dt

  log x  .dx   t 5 .et .dt

5

u.v

 UVdx  Uv  U v2  U II v3  U III v4  U IV v5 ...........

I
1

 t 5 .et  5t 5 .et  20t 3 .et  60t 2 .et  120t.et  120et

 et t 5  5t 4  20t 3  60t 2  120t  120 

 x  log x   5  log x   20  log x   60  log x   120  log x   120 

5 4 3 2
 
A  1, B  5, C  20, D  60, E  120, F  120
A  B  C  D  E  F  1  5  20  60  120  120  65  21  44

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 18

 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S

PHYSICS
1 1
B  [T ]
A
 LT 1 ; A  LT 2  Accelereation
B
1  cos  2sin 2  / 2 
2. A,B are unit vectors   tan 2
1  cos  2 cos  / 2
2
2
3. 60-Range =  (time of flight )
4. conceptual
5. conceptual
6. area under ABCD with x-axis
1 k1  k2
7. s pring are in parallel n 
2 m
8. F  mg sin 
g
9. y  Ax  Bx 2 A  tan  B
2u cos 2 
2

10. conceptual
11. Iw  const; I  T
12. l  l  (t2  t1 )
13. l  l  
dQ
14.  (m  0 )
dt
15. rreal  cons
16. conceptual
nR(T1  T2 )
17. w
r 1
18. conceptual
19. conceptual
20. Breaking strength is material property
1 T
21. n
2L 
4
22. AD   h  15  20
3
  3 3 I
23. I 1  I cos 2   x   I1 
2 4 2 2
q 2 3 kq
24. v1  v2  q  r; 1  q2   20  12  c v  2  18 103 v
q2 3 5 6
25. R  2
1 I
26. T OR.T  2
M B

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 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S

0i 0i 0 i 2 0 3i  r2
27. H1  H2    B cos t
4 r 4 r 4 r 4 2r 2
1
28.  B r 2 sin t
2
2 B 2 2 r 4 2 ( B r 2 )2
  sin 2 t 
R 4R 8R
1 2
29. kE  E   mv  h(v  v0 )
2
N 1
30.  t / T t2  t1  T  50
N0 2
31. conceptual
32. conceptual
33. conceptual
34. conceptual
E0
35. C
B0
1 2 15
36.  fm 
fm f2 2
1 1 1
 
v u 15 / 2
1
37. R.P 

h
38. 
mv
1 2 kq1q2
39. KE  u mv 
2 d
2
p kq q 1
 1 2 ;d  2
2m d p
3 108
40. c  v ;    10
30 106

h  2.5
4

Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 20

 SRI CHAITANYA IIT ACADEMY, INDIA 01-05-2024_Sr.Super60_Elite, Target & LIIT-BTs _EAPCET_GTE-09_KEY SOL’S

CHEMISTRY
121. KE1  2  KE2
hv1  hv0  2  hv2  hv0 
 hv0  2hv2  hv1
 v0  2v2  v1
 2  2  1016     3.2  1016 
 v0  8 1015 Hz
h
122. X A  m  0.05  .......  i 
4z
h
X B  5m  0.02  .......  ii 
4z
X A 5  0.02
  2
X B 0.05
123. Graham’s law of diffusing
v1 M2 1
 ,
v2 M1 M
M pcl3  137.33 g / mol
M So3  80.06 g / mol
M So2  64.066 g / mol
M Co2  44 g / mol
124. Let Fe2  x & Fe3   0.93  x 
By charge conjervation
 2  x   3  0.93  x   2 1  0
  x  0.79  0
 x  0.79
0.79
Fraction of Fe 2   0.85 Fraction of Fe3  1  0.85   0.15
0.93
5 3
125. C p  nR Cv  nR
2 2
C p 5nR 2 5
  
Cv 2 3nR 3

126. 2HI  H 2  I 2
initial 1 0 0
 
at equilibrium 1
2 2
Partial pressum    ptotal

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2
   
PH 2  PI 2  2  PT 
Kp  , Hence , K p     ,
PHI2 1   2 .PT2 
 
 
PH 2    PT
2
 
PI2    PT
2
PH I  1    PT
2 Kp
By solving above equation  
1 2 K p
127. ACC to henolerson equation
P H  p ka  log
 salt 
 Acid 
0.10
 4.57  log
0.01
 4.57  log10  4.57  1  5.57
128. More no of oxygen atony attached < Mon Acidity
HClO  HClO2  HClO3  HClO4
So, conjugate base order
 Clo 
 ClO2  ClO3  ClO4 
Z M da 3 NA
129. d   M  , for bcc, z  2
a3  N A Z
6.15   300 103   6.02 1023
3


2
1
 50gmol
130. Conceptual
131. E 0 cell  Ecathole
0
 E Anole
0

 0.16  0.34  0.50v

G   nFEcell
0

 2  96500  0.50  96500 J

132. k  2.303 103 J 1 , a  40 g  a  x   10 g
2.303 a
For 1st order reaction, t  log10
k a  x
2.303  40 
 3
log10  
2.303 10  10 
t  602 sec
133. Easily liquefiable gas have maximum value of enthalpy of physisorption.
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134. Acidic strength is inversely proportional to p ka values.

135. [ Meso compound is optically inactive compound inspite of having chiral carbon due to
presence of plane of symmetry]
136. Unsymmetrical alkanes can’t be prepared by wurthz reaction
137.
O
CH 2  OH
CH 2
CH

 i  B2 H6 PCC

 ii  H 2O2 / NaOH

H 2 O PhmgBr

 iii  Pcc Ph
 iv  phmgBr HO C
 v  H 2O

C 
138.
O
 i  O3 , cch
CH 3  CH 2  CH  C  CH 3 CH 3  CH 2  CHO  CH 3  C  CH 3
 ii  Zn / H 2O
CH 3
139. When alkynes an heated with NaNH3  bond moves towards end of the chair [ positional
isomension]
CH 3  C  C  CH 3  NaNH 2 CH 3  CH 2  CEC  Na   H 2O
140. Conceptual
141. Solvolysis  stability of carbocation

CH 2

( carbocation is stable due to resonance )

142. Conceptual
143.
OH H 3C  CH  CH 3 COOH

Zn AlCl3 KMnO4
 CH 3  CH 2  CH 2Cl KoH

a

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144. Conceptual
145.
O O O
O  C  CH 3 O  C  CH 3
C  CH 3
AlCl3
1600 C
HO

(Fries rearrangement)
146. Conceptual
147. Conceptual
148. (zeigler – NaHa atalyss)
Ticl7
nCH 2  CH 2 CH 2  CH 2 n
Al  CH 3 3
149.

 R  CH  COOH 

NO2
151. Conceptual ANS :- B
151. ANS :- B
152. ANS :- A
 1 
153.  degree of hydration 
 ionic mobility  
154. Ans :- C
155. Ans :- C
156. Ans :- B
157. Ans :- A
158. BM  n  n  2 
 n  no.of unparied e  

159. Ans :- D
160. Ans :- A

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