Scribd
Upload
75 views26 pages

Periodic Classification 10 - Class Notes - Arjuna JEE 2.0 2024

Uploaded by

kattarchallange
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
75 views26 pages

Periodic Classification 10 - Class Notes - Arjuna JEE 2.0 2024

Uploaded by

kattarchallange
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 26

-JEE 2024 Exam-

❑ Subject – Inorganic Chemistry


❑ Chapter – Periodic Table
OM PANDEY , IIT Delhi
Lecture No.- 10
1 Revision - Lecture - 09

2 Electronegativity, Oxidation State

Today’s Targets
Question

Kya aap seriously padna chahte hain IIT-JEE ke liye ????

A han

B Jaroor

C nhi
D Mujhe nhi karna , m kar lunga apna

Mai Sab Bhool Jata Hu , KYA Karu ????


Revision
Question

Identify the least stable ion amongst the following:

A Li–

B Be–

C B–
D C–
Revision

Li Be B C N O F Ne

Na Mg Al Si P S Cl Ar
NCERT Table

Group 1 egH Group 16 egH Group 17 egH Group 0 egH


H –73 He +48
Li –60 O –141 F –328 Ne +116
Na –53 S –200 Cl –349 Ar +96
K –48 Se –195 Br –325 Kr +96
Rb –47 Te –190 I –295 Xe +77
Cs –46 Po –174 At –270 Rn +68
Question
In which of the following pairs, electron gain enthalpies of constituent
elements are nearly the same of identical?
(1) Rb and Cs (2) Na and K
(3) Ar and Kr (3) I and At
Choose the correct answer from the options given below :
[2022/28 July/Shift-1]
A (1) and (2) only

B (2) and (3) only

C (1) and (3) only

D (3) and (4) only


Question
Inert gases have positive electron gain enthalpy. Its correct order is
[2023/24 Jan/Shift-1]
A Xe < Kr < Ne < He

B He < Ne < Kr < Xe

C He < Xe < Kr < Ne

D He < Kr < Xe < Ne


I.E. & E.G.E.

Neutral Atom

Anion
Electronegativity & Pauling Scale

Li Be B C N O F

Na Mg Al Si P S Cl

Br

I
Home Work

Question

The correct option with respect to the Pauling, electronegativity values of the
elements is :
A Te > Se

B Ga > Ge

C Si < Al
D P>S
Question

Which of the following does not represent the correct order of the properties
indicated?
A O2– > Ne > Mg2+ > Al3+ (size)

B N3– < O2– < F– < Na+ (Nuclear charge)

C Li > Be > B > C (Electron gain enthalpy)


D Li > Na > K > Cs (I.E.)
Question

Which one of the following arrangements represents the correct order of


electron gain enthalpy (with negative sign) of the given atomic species?
A Cl < F < S < O

B O < S < F < Cl

C S < O < Cl < F


D F < Cl < O < S
Polarity and Ionic Character
Hetero-nuclear Diatomic molecule

Homo-nuclear Diatomic molecule


Difference in Electronegativity and Ionic / Covalent Bond

% ionic character = 16 ( EN ) + 3.5 ( EN )2

Example - Find % ionic character in LiF ?


Question

For AB bond if percent ionic character is plotted against electronegativity


difference (A – B). The shape of the curve would look like :

A A B

Percent ionic character


C
100
A
B B D
50

C C
1 2 3
0 (A – B)
D D
Mulliken Scale

Example - Find electronegativity if ionisation energy & Electron Affinity of


an element is 13 ev/atom , 4 ev / atom ?
Diagonal Relationship

Li Be B C N

Na Mg Al Si P

Li Li+ Li+

Mg Mg+ Mg2+

Some elements of certain groups of second period resemble much in properties with
the elements of third period are diagonally related in properties.

Diagonal relationship arises because of similar size of atom and ions.


Question

The set of elements that differ in mutual relationship from those of the other
sets is : [2021/17 March/Shift-2]

A Li – Mg

B B – Si

C Be – Al

D Li – Na
Oxidation State
The oxidation states of an atom in a molecule or in an ion is the charge the atom
would have if the electron in each bond were located on the more electronegative
atom.

Rule :

1. F : Group 1 : Group 2 : Al & Ga :

2. H :

3. O :

4. N : 5. Cl, Br , I :
Na+ N3- NO3- NH4+

LiH H2SO4 Na2O Na2O2


Effect Electronegativity on XOH
Question

The first ionization enthalpy of Na, Mg and Si, respectively, are: 496, 737 and
786 kJ mol–1. The first ionization enthalpy (kJ mol–1) of Al is:
[2022/29 July/Shift-1]
A 487

B 768

C 577

D 856
Question

The electronegativity of aluminium is similar to :

A Lithium

B Carbon

C Boron

D Beryllium
Question
For electron gam enthalpies of the elements denoted as eg H, the incorrect
options is : [2023/1 February/Shift-2]

A egH (Cl) < egH(F)

B egH (Se) < egH(S)

C egH (I) < egH(At)

D egH (Te) < egH(Po)

You might also like