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Gide Line of Aspen Hysys Simulation: by Taisir K. Abbas 2023

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Ahmed Tareq B
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11 views18 pages

Gide Line of Aspen Hysys Simulation: by Taisir K. Abbas 2023

Uploaded by

Ahmed Tareq B
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Gide line of Aspen Hysys

Simulation – Part 2

By
Taisir K. Abbas
2023
Theoretical Part 2

Equations of state (EOS)


It is a design equation that connects physical variables together in a mathematical model, for
example of this is, the ideal gas equation (general gas law).

The Ideal-Gas Equation of State - history

➢ The pressure of gases is inversely proportional to their volume


(for a fixed mass of gas at a constant temperature T).
Theoretical Part

Note:
➢ Many familiar gases such as air, nitrogen, oxygen, hydrogen, helium, argon, and
carbon dioxide follow the ideal gas relation with negligible error (less than 1 percent).

➢ Dense gases such as water vapor (steam) should not be treated as ideal gases.

Is water vapor an ideal gas?

At pressure below 10 kPa, water vapor can be treated as an ideal gas, regardless of
Temperature
No – high pressure steam in power plant applications
Yes – air conditioning applications
Theoretical Part

Solving equations of state (EOS) allows us to find the specific volume of a gaseous mixture of
chemicals at a specified temperature and pressure. Without using equations of state, it would be
virtually impossible for us to design a chemical plant. By knowing this specific volume, we can
determine the size and thus the cost of the plant
The first generalization of the ideal gas law was the van der Waals equation
𝑅𝑇 𝑎
Ρ= −
𝒱−𝑏 𝒱
The Redlich-Kwong equation of state is a modification of van der Waal’s equation of state
Modified further by Soave to give the Soave-Redlich-Kwong (SRK) equation of state
Another variation of the Redlich-Kwong equation of state is the Peng-Robinson (PR)
equation of state
Theoretical Part
The generalized compressibility chart

Z is a measure of deviation from Ideal-gas behavior


Z = 1, ideal gas Z <> 1, non-ideal or real gas

➢Experimental finding: Gases behave differently at a


given temperature and pressure, but they behave very
much the same at temperatures and pressures normalized
with respect to their critical temperatures and pressures.
Theoretical Part
Example
Find the specific volume (m3/kmole) of n-butane at (290 C), if the temperature between (250 C
to 300 C) and 18 atm and molar flow 100 Ibmole/hr using the following equation of state:
i. steam table,
ii. the generalized compressibility (z)

Fluid PPKgs :
•Soave-Redlich-Kwong (SRK)
•Peng-Robinson (PR)

Compare the results between two generalized gas equations


Theoretical Part
Start Aspen Hysys

Open
New

Aspen Hysys Simulation Programmer Interface, V 11


Start Aspen Hysys

2
1- Add
2- Select

Add
Raw Materials

Aspen speak with you

Aspen Hysys Simulation Programmer Interface, V 11


Start Aspen Hysys

Raw materials storage


file Search

Fluid Packages under


call

Instructions
Start Aspen Hysys

Selected “FPks” under


“Basis 1”

Method Assistant of
Thermodynamic state

Instructions
Start Aspen Hysys

Components and
“FPks” under “Basis 1”

Method Assistant of
Thermodynamic state

State is “Okay”

Inter to Simulation
Empty
Instructions
Start Aspen Hysys

Work tasks to conduct


the simulation

Environmental Work
Active or On hold

Model Palette

In Simulation
Waiting for instructions
Instructions
Start Aspen Hysys

Work tasks to conduct


the simulation

Environmental Work No properties and conditions


of the input raw material have
been added (arrow: light blue)

Model Palette

In Simulation

Instructions
Start Aspen Hysys
Soave-Redlich-Kwong (SRK)
Start Aspen Hysys
Peng-Robinson (PR)
Start Aspen Hysys
n-Butane @ T= 290C
Specification Soave-Redlich-Kwong (SRK) Peng-Robinson (PR)
Pressure (Kpa) 1824 1824
Phase Vapor , X= 1 Vapor , X= 1
Molar volume 2.41579 2.41579
(m3/kmole )
Mass enthalpy -1593.86
-1593.86
(KJ/Kg)
Molar entropy 183.481 183.481
(KJ/Kmole.C)
Z factor 0.941 0.941
Start Aspen Hysys

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