Periodic Properties of Elements
Periodic Properties of Elements
Across a
Period Down a Group
(Left to (Top to
Property Right) Bottom)
Atomic Radius Decreases Increases
Ionization Energy Increases Decreases
Becomes Becomes less
more negative or
Electron Affinity negative positive
Electronegativity Increases Decreases
Metallic Character Decreases Increases
Non-metallic Character Increases Decreases
Ionization Energy: Can be tested by asking which elements will require more
energy to remove an electron.
Electronegativity and Bonding: Questions often focus on which atoms will
form polar or non-polar bonds based on electronegativity differences.
Exceptions: Always keep an eye on specific exceptions to periodic trends (like
electron affinity for Group 2, 12, and noble gases).
Comparative Trends: Be prepared to compare properties of elements across
periods or groups (e.g., comparing electronegativity between two elements).
Exception:
Important Question:
Q: Why does Boron (B) have a lower first ionization energy than Beryllium (Be)?
Answer: Boron has an electron in the p-orbital, which is less tightly bound to
the nucleus and requires less energy to be removed compared to the s-
orbital in beryllium, which is more tightly held.
Important Question:
Exception:
Group 2 (Be, Mg, etc.) and Group 18 (Noble Gases):
Trend: Electron affinity is typically low or even positive in Group 2 (alkaline
earth metals) and Group 18 (noble gases), as these elements have stable
electron configurations.
Explanation: Adding an electron to a Group 2 element (e.g., Be, Mg) or a noble
gas (e.g., He, Ne) would result in a less stable configuration, so these elements
do not readily accept electrons, leading to a low or positive electron affinity.
Important Question:
Q: Why do noble gases have very low (or positive) electron affinity?
Answer: Noble gases have a completely filled valence shell, and adding an
electron would result in a less stable configuration, making their electron affinity
very low or even positive.
4. Electronegativity
Exception:
Group 1 (Alkali Metals) and Group 2 (Alkaline Earth Metals):
Trend: Electronegativity decreases down the group.
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Explanation: Alkali metals (e.g., Li, Na, K) and alkaline earth metals (e.g., Be,
Mg) have low electronegativity compared to other elements.
However, Lithium (Li), being the smallest in the alkali metal group, has an
unusually high electronegativity compared to other alkali metals
like Sodium (Na) and Potassium (K).
Important Question:
Q: Why does lithium (Li) have a higher electronegativity than other alkali
metals like sodium (Na) or potassium (K)?
Answer: Lithium has a small atomic radius and a high effective nuclear
charge compared to other alkali metals, which makes it more effective at
attracting bonding electrons.
Important Question:
Important Question:
Q: Why does chromium (Cr) have a half-filled d-orbital and not a full
4s orbital in its ground state?
Answer: The half-filled d-orbital configuration (3d⁵ 4s¹) is more stable due
to extra stability associated with a half-filled d-subshell, leading to a lower
energy configuration than the expected configuration (3d⁴ 4s²).
Important Question:
2. Electron Affinity
3. Electronegativity
Q4: Why does the atomic radius of Noble gases (e.g., Ne, Ar) not follow
the usual trend in periodic tables?
Answer: Despite having higher atomic numbers, noble gases have a full
outer electron shell, making their electron clouds more spread out due to a
stable configuration. This results in their atomic radius being larger than
halogens in the same period.
Q5: Why does the ionization energy of oxygen (O) decrease compared
to nitrogen (N)?
Answer: The ionization energy of oxygen is lower because oxygen
has paired electrons in its p-orbital (2p⁴), which experiences electron-
electron repulsion, making it easier to remove one of the electrons. In
contrast, nitrogen has a stable, half-filled p-orbital (2p³), which is more
difficult to ionize.
Q1: Which ion has the largest radius: O²⁻, F⁻, Na⁺, or Mg²⁺? Explain
why.
Answer: O²⁻ has the largest radius because it has the least nuclear
charge among the isoelectronic species (all having the same number of
electrons), leading to the weakest attraction on the electron cloud. In
contrast, Mg²⁺ has the highest nuclear charge and the smallest radius.
Potential for JEE 2025: This question is frequently asked as it tests both
the understanding of ionic radii and iso-electronic species.
2. Electronegativity Trends
4. Electron Affinity
Q4: Why do noble gases have almost zero or positive electron affinity
values?
Answer: Noble gases have a completely filled outer shell, which is
already in a stable configuration. Adding an electron would disrupt this
stability, making their electron affinity either zero or slightly positive.
Potential for JEE 2025: Noble gases' electron affinity behavior is often
tested.
Q5: Why does the ionization energy of chromium (Cr) deviate from the
general trend in transition metals?
Answer: Chromium prefers the 3d⁵ 4s¹ configuration, which is more stable
due to the half-filled d-subshell, leading to a lower ionization energy than
expected.
Potential for JEE 2025: Questions regarding the anomalous electron
configuration of transition elements are asked to test a deeper
understanding of the stability of electron configurations.
Q6: Which element has the smallest atomic radius: Na, Mg, Al, Si?
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Answer: Silicon (Si) has the smallest atomic radius because it is further
across the period, and the effective nuclear charge increases as we move
from left to right across the period.
Potential for JEE 2025: Periodic trends such as atomic
radius and comparison of elements across periods are very common in
JEE questions.
Q7: Why does the electron affinity of Group 2 elements (Be, Mg)
remain low or positive?
Answer: Group 2 elements have a full s-orbital configuration, and adding
an electron would result in a less stable, higher-energy configuration, so
they do not readily accept electrons.
Potential for JEE 2025: This is an important topic in understanding the
trends of electron affinity in s-block elements.
1.Nomenclature of Elements
For example:
For example:
Answer:
20
Answer:
Answer:
Answer:
Answer:
Answer: