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Unit 8 Review

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13 views

Unit 8 Review

Uploaded by

zacdecastro777
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Unit 8 review [30 marks]

1. Which statement is correct? [1 mark]


A. A strong acid is a good proton donor and has a strong conjugate base.
B. A weak acid is a poor proton acceptor and has a strong conjugate base.
C. A strong acid is a good proton donor and has a weak conjugate base.
D. A strong base is a good proton donor and has a weak conjugate acid.

2. What is the pH of a solution in which the hydroxide ion concentration is 1 [1 mark]


× 10−11 mol dm−3 at 298 K?
Kw = 1 × 10−14 at 298 K
A. 3
B. 7
C. 11
D. 14

3. What will happen if the pressure is increased in the following reaction [1 mark]
mixture at equilibrium?
CO2 (g) + H2O (l) ⇌ H+ (aq) + HCO3− (aq)
A. The equilibrium will shift to the right and pH will decrease.
B. The equilibrium will shift to the right and pH will increase.
C. The equilibrium will shift to the left and pH will increase.
D. The equilibrium will shift to the left and pH will decrease.

4. 10.0 cm3 of an aqueous solution of sodium hydroxide of pH = 10 is mixed [1 mark]


with 990.0 cm3 of distilled water. What is the pH of the resulting solution?
A. 8
B. 9
C. 11
D. 12

–3
5. Which statement is incorrect for a 0.10 mol dm –3 HCOOH solution? [1 mark]
A. pH = 1
B. [H+] << 0.10 mol dm –3
C. [HCOO–] is approximately equal to [H+]
D. HCOOH is partially ionized

6. Which is an acid-base conjugate pair? [1 mark]


A. H3O+ / OH–
B. H2SO4 / SO42–
C. CH3COOH / H3O+
D. CH3NH3+ / CH3NH2

7. Which 1.0 moldm–3 solution has the highest pH? [1 mark]


A. Ammonium chloride
B. Sulfuric acid
C. Sodium chloride
D. Ammonia

8. Which of the following is correct? [1 mark]


A. A weak acid is a proton donor and its aqueous solution shows good
conductivity.
B. A weak acid is a proton donor and its aqueous solution shows poor
conductivity.
C. A weak acid is a proton acceptor and its aqueous solution shows good
conductivity.
D. A weak acid is a proton acceptor and its aqueous solution shows poor
conductivity.

9. Which species produced by the successive dissociations of phosphoric [1 mark]


acid, H3PO4, are amphiprotic?
A. HPO42− and PO43−
B. H2PO4− and HPO42−
C. H2PO4− and PO43−
D. HPO42− only

−3 −3
10. What is the pH of 1.0 × 10−3 mol dm−3 sodium hydroxide, NaOH(aq)? [1 mark]
Kw = 1.0 × 10−14
A. 3
B. 4
C. 10
D. 11

11. Which species acts as a Lewis and Brønsted–Lowry base? [1 mark]


A. [Al(H2O)6]3+
B. BF3
C. NH4+
D. OH−

12. Which species behave as Brønsted–Lowry bases in the following [1 mark]


reaction?
H2SO4 + HNO3 H2NO3+ + HSO4-
A. HNO3 and HSO4-
B. HNO3 and H2NO3+
C. H2SO4 and HSO4-
D. H2NO3+ and HSO4-

13. What occurs when solid sodium hydrogen carbonate reacts with aqueous [1 mark]
sulfuric acid?
A. Bubbles of sulfur dioxide form.
B. Bubbles of both hydrogen and carbon dioxide form.
C. Bubbles of hydrogen form.
D. Bubbles of carbon dioxide form.

14. A student carried out a titration to determine the concentration of an acid [1 mark]
and found that his value had good precision but poor accuracy. Which
process explains this outcome?
A. Consistently overshooting the volume of solution from the burette into the
flask.
B. Collection of insufficient titration data.
C. Reading the meniscus in the burette at a different angle each time.
D. Forgetting to rinse the flask after one of the titrations.
15. HL: Which indicator is appropriate for the acid-base titration shown [1 mark]
below?

A. Thymol blue (pKa = 1.5)


B. Methyl orange (pKa = 3.7)
C. Bromophenol blue (pKa = 4.2)
D. Phenolphthalein (pKa = 9.6)

16. HL: What is the order of increasing acidity of the following acids? [1 mark]

A. chloroethanoic < ethanoic < hydrogen fluoride < hydrogen cyanide


B. ethanoic < chloroethanoic < hydrogen fluoride < hydrogen cyanide
C. chloroethanoic < ethanoic < hydrogen cyanide < hydrogen fluoride
D. hydrogen cyanide < ethanoic < hydrogen fluoride < chloroethanoic

17. HL: Which mixture is a buffer solution? [1 mark]


A. 25 cm3 of 0.10 mol dm-3 NH3 (aq) and 50 cm3 of 0.10 mol dm-3 HCl (aq)
B. 50 cm3 of 0.10 mol dm-3 NH3 (aq) and 25 cm3 of 0.10 mol dm-3 HCl (aq)
C. 25 cm3 of 0.10 mol dm-3 NaOH (aq) and 25 cm3 of 0.10 mol dm-3 HCl (aq)
D. 50 cm3 of 0.10 mol dm-3 NaOH (aq) and 25 cm3 of 0.10 mol dm-3 HCl (aq)
18. HL: Which salt solution has the highest pH? [1 mark]
A. NH4Cl
B. Ca(NO3)2
C. Na2CO3
D. K2SO4

Soluble acids and bases ionize in water.

Sodium hypochlorite ionizes in water.


OCl–(aq) + H2O(l) ⇌ OH–(aq) + HOCl(aq)

19a. Identify the amphiprotic species. [1 mark]

19b. Identify one conjugate acid-base pair in the reaction. [1 mark]


A solution containing 0.510 g of an unknown monoprotic acid, HA, was titrated
with 0.100 mol dm–3 NaOH(aq). 25.0 cm3 was required to reach the equivalence
point.

19c. Calculate the amount, in mol, of NaOH(aq) used. [1 mark]

19d. Calculate the molar mass of the acid. [1 mark]

19e. Calculate [H+] in the NaOH solution. [1 mark]


Many reactions are in a state of equilibrium.

The following reaction was allowed to reach equilibrium at 761 K.


H2 (g) + I2 (g) ⇌ 2HI (g) ΔHθ < 0

20a. HL: State the equilibrium constant expression, Kc , for this reaction. [1 mark]

20b. HL: The following equilibrium concentrations in mol dm–3 were obtained [1 mark]
at 761 K.

Calculate the value of the equilibrium constant at 761 K.

θ
20c. HL: Determine the value of ΔGθ, in kJ, for the above reaction at 761 K [1 mark]
using section 1 of the data booklet.

The pH of 0.010 mol dm–3 carbonic acid, H2CO3 (aq), is 4.17 at 25 °C.
H2CO3 (aq) + H2O (l) ⇌ HCO3– (aq) + H3O+ (aq).

20d. HL: Calculate [H3O+] in the solution and the dissociation constant, Ka , [3 marks]
of the acid at 25 °C.

–
20e. HL: Calculate Kb for HCO3– acting as a base. [1 mark]

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