Scribd
Upload
37 views15 pages

Polymers Notes

Notes on Polymers for JEE!!!

Uploaded by

harrypotterhrh3107
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
37 views15 pages

Polymers Notes

Notes on Polymers for JEE!!!

Uploaded by

harrypotterhrh3107
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
You are on page 1/ 15
Lod ro ers y mers ave very beh anotecutos. MA substances where each motécnmtf rc terved from very a Naw ber of Scmpe emohe whe qowned tpl bex? M a regular way. => Podge ears are formed vepeoteol fom 'not ov of rempdest umcts catled monomer 4£ Che paocem of formrtor of Poefwn ers fro simple mofeule Cmonomer) (4 Catheol polymer baton ap Peet if cH, Etim gael CeIn = Classefieotion of meat | AD Classcfcation based on Aype of monomer Unt ts: _ fom-H oe Pilecplondt LL pve % E ephint » potpcra fren yneopetne, (J teflon, stasch, cellulore eh. Sema synnetic polymers: These polymers ave found tn plapts 4 animot 4 ther anolufeol «n the Antony. 2K— Cellulose acetnte Crompon) 4 cellurore ncbote* iy Syndfhette podyrmess. > fe, polymers axe prepareal tn the Lobo rekorg sgt ts alsd cattle! man amadle petymer eke Polyethore , wydon- 6:5 » Buna S , Doce? ef: 2) Classifier _baseol on touche of Lodger: ct) Linear wes} Trese Miers (onsets of fog and sheauy at hatin. LK- High dens rd Wisk ‘i polyvinyl plonote ek: 7 haath, TE ONES & Ziegler Natta coblyst (24) : Cans), Ad + Teely > High density pryefrene Is wsed ab emanu force tut’ phate , dist bens» bott4es prpeA ek: : d GD) Branched chain ela These Polymers Gorton nears chouina nari Lome branches+ ex, Low dense’ fhene Ch d Pe) brytoacisvof N Hy =H 1200-1200 i, ; 280 - Fo wo ocansihy Prtythenc . O2 ow ok ae CHO Cwss linked or Netork rR ! “These ade ws free fone fro~ bi-funchone/ Omd Aet- fon ‘ono monomers L Contato stw Covolent bonds befpween Vastors Mn polymer chaln. ek: Pokelte, melamine e&: Eten eae ea at LD? Clasrcfeation bored upon vrnptecnton force: Edostomers : Polyraeré 00 whith the entermoke wlar feaces of athsahion befween the polyenes chun age weakut axe Called elarfemers- —> These ae rubber ke solids with ehostec Proper ties- ex- pPruna-S, Buna-W. Neoprene ae Gu Fe bres : Polyroert tn which the tnfervrotewar forces of “atfroction ase the strongest ae colled fy bees: —> These forves ase etther due to pH- bono) olipole-dipode attrah dn, e er- Nylon - br 6 CPotyava'ote ) — H bonoting. ah- Docyon Cpoty ester) — bipele ~ Aipete attra bin. 7 LUO are the thread forming codcds n3hy'oh beg ten stle shiecgth 4g hgh eel ee LIE or diy Thea-mophastte : Plymess tn wuch the intermote war fortes af attrathior age oo betwen elastomers € Ar bata > The platic are hood at worn temp gut toft wher heoted yewuse (he Cnelt'violinsA chet gan SAips on one gre ther ot elevateol fer? 4x~ polythene » prtystyrent - Pvc, Teflon ef. Gy Thea settry potynecs = 5 Vong. gag cd croptertals Can. Be obtatnsol of FAL pelgraen owns ase cyost Linked + ag ore en axe cyou-Linkeel & aw le a > There can't Ge re meol + et. Aokelite, aaen— fooro blotyele testn. envy Sranhed €? Classificedtiion based 0 1. Free Radlk mechanism 2 Cotton'c —mechow'sn 2. AoW e mechanism, LT. Bee radical mechanis ; Alkene, Atkacienes & they Lenin Att PLY ren sed to pretence of fee soll titi ntor UKE benzoyl Peyoxtole- dert- butyl Pernice et: ex. Hr=CHy , CHa-H= Ay 2 Ga = Aen = Hy ek: > pote intcadttig sep Cote- Eo -0-b-¢e He 2 cone -E-8 S 2 C6 He + coy Ce He + eta =H —> CoHr—H2- Hy, | chain propegobin Step: | CoH -etla hy, += > CoHS~Ha—h, -U2-ty, | COWS “CH Ha ~eny-Eny + oh = tn > COME Edn Fay chain termination step Cos thon $M ha Cy Ene CGH Tq Coby €Chg Ch Fo MU toy os Lg ety yp Cope O 2. Catliome mechawhm: 3 Alkend& Aaving etetwn releasing TOP 2 pobyme rise ”y Catone mechants. ed. cy, = eH BH, 3- Artomte roethaniin | . z prkenes having etectoo withdrawl Op ae polymers ay an Oe tel pees ek Ya = wae 1 EN ROE Ee AM Ste TL gre te agtagee a aed ek et < Classufieation based on mocle of poly ot on Leo 0 Woke of men sot on } Adolit'on polyeer or Chui growth : my. me Oe yO ITH) poly ener The addthior portyerers are form eo! oa Sepeateol addlfon of monomers ue have’ double os triple yond: wo &e. Ly = Hr) > £4 Hg, Efhone jhe Podyethene 2 .nCcw. ccy—c) 7 f Hy Le, nt, Ucogk chlo nde. Potzutingl chlanlaCPye) 2. Teflon ( Poly detea Lluow efryere— PTFE) n fateh pesetphole ate fe Lebelner? oo ONE) ye on etry “Teton. hertlan 4: Poy acrylonitrile (p40) , Deden-s° 7 ctracep men LEE ete OF ee ie acrylo rifole Orton 5 Po: i ne n CHa =u-Ph ——_? semis Cer pray ay Condensottoo polymer £ step qrowth pobperess) The Condensation wer are fore aepeotenl Condensation seorbln yedween puso Mf gent bie frnctro ned o> dar. fucrhonal amonomer!C Unt'th- >To these polymenisob'or geaction. the elirtn ohn of gam wmolewmles such of 1207 aliohel Wing, Hel ete. takes place Ex 1 Nylons b* | ND Hon CHa Nr +n Ho0l <4, —7 Herorm ethylene Acli'pre quad | arr dn @ tun secngse wh Eteanr, 85. nylon -6, 6 ° Cheude LUnkese) 4 Myon -6* HW 0 : . n a he DAM {agzeon oat mea Copwoloctuw fuse ken eb wr dens) wyton—6 3. Nylon—6 Le? aan + Yonl€My Fp COON +3 fiw gen gun been yl egos aie: Seongie ae, Wydon-bi Lo» 4 ! %q- Doe / Terglene/ my ore | WO-Ms-en 0 | 7G Myiak wee <2) i > mceyo- bar, | Ted plhale “Dacvr/ Texlee) aud: S: Glyptol: bo n Ho-aiy-ea,con t 9 LOL, > fo-iny-ty,-0 bot =F ; nD 6 lyptot : G. phenol formololehyde peymers - Hu 2 hon the? Gre Gynt, eB on Ci) Novaloc gt cso Miner polymer of eS a phenol. on - f cao, OH, fe ae apy ey", Novotac CY Pokelte 94 ts cross —tokeed peace ciabced amet aa an tah finkolhirte. | Z Urea - forenal. Resins te Mae +H Oo L dy > few wreaks os | n Ulan me reag | 10H —_, fh Gn om 8. melamine - formaldehyde polyenty : aly re ee 2% eS Oa. SL Plyeacntio i: % " = mMetoren'oe ope Ymer € having clonhe Properties. > Naturd rubber! 9¢ C1 0 rene p form of Ceoprene C2-meftur(~ 1) ~ bude Aly Ws eS . Me =e cy cy, Ps ow Hy Eee mer Of CeK ‘ene) + Oopeene Pe “ny, i = ie hop rene Nartured wty bey Nett Gutta acho: Trans pro of Wopaene 4 colle Gutte pascal donbrt used it jy f Ling be 4eeth) K Vileam'2atin ’ Row rubber does rot have the propert'es of rubhbar With whith we are familar, Tr Osler 4o give At strength & dostuty, ct 1s vilcamz eof. Tn the Val canizoAvn proce, row rhb (s mixed volt, Smoll amountof Slphur £ heoted. Use Of exteanaf Sulphur tnegeases the erosr-tinkira and Lo ney) ; 1-37 Of Sulphus ps nseol th subbes banc aor. Sulphur (4 wreal jn ty re abba. m ty bey eg Eh ot oh 3 % igndtetic rubber: gntoetve mbhber ve subber MWke Polymer 4 WM Cr Crpnrsle Of getty stretched 4, fice tt Meth . However (t yetuans fo onginad Poe A Soon ay exfesnal st ly fo ete th 4. weopaene af ‘ CHy = EME My > fem b=“ F, CH ro paene Neoprene: | 2 Buna-W: YD Hy =H-hachg + 1 = = h— cy 13- Bubsolr'ene herylow/tné w Lm-u= cn, 0H, -d,, Bunaw. ef 3. Buna-s: My SUn- tn = Oy Moy Ory Ma Ds 3 i! = Revdegradpble petlyme = Tedraaile pie are a speuhe type of polyren thle pranks davon! afer (tA indlencledl puapose bf! bacterval decoryo' on proces 40 FON to naturch ¢ prowech such af Gre Cee Me), woter & to Cag ant soll, —> Miphatre polyester ase one Of the timp 90 tant Clast of bio degoadesle polymers. ey Poly A-rydrony budge ode 2 Bele valerate (Fv): on Cty Ley, coon + gta CH Cy, Loon = LO-W ~*~ Ci de 0s PuBV . @ Mylon-a-nyton-6 : Nydon-2: agonist ; 7D Ha V-My-to0n Hw {inj E04 q Fly cdine Arti pwie aun hay 5 Cn ZOF, Name(s Formula CH2=CH2 Film wrap, Plastic Poly vinyl chloride (PVC) (vinyl chloride) Polyethy | fon deeay (LOPE) ~{CHe-CHa)n— (ethylene) Bags = Electrical insulation Pol CH2=CH2 thigh dere (HDPE)) | “(CH2-CHa)o- (ethylene) bottles, toys CH. Manufacture of Polypropylene i ° CHe=CHCHs raped ove. pose (PP) different grades foH—cH,} (propylene) fibres etc. a Manufacture of rain $ CHe=CHCI coats, hand bags, vinyl flooring, water Pipes etc. | Poly vinylidene chloride (Saran A) CH:=CChe (Vinylidene chloride) Seat covers, films & fibers As insulator, i rial, Polystyrene CHa=CHCsHs manufactures of (Styron) (styrene) toys, radio and Television cabinets wy Polyacrylonitrile CH=CHCN Rugs, Blankets (PAN, Orlon, Acritan) ess (acrylonitrile) clothing Polytetrafiuoroethylene ~(CF2-CF2), (CF2=CF2 Non-stick surfaces (PTFE, Teflon) 2 (tetrafluoroethylene) —_| electrical insulation Poly methy measryate a . Lighting covers, (PMMA, Lucite, CHe=C(CHs)CozcHs_| Ui Plexiglas, AACH2C(CHs) COC Hs) (methylmethacryiatey | Signs perspex) skylights Poly vinyl acetate 5 CH=CHOCOCHs | Latex paints, (PVAc) GICHOCOC HIE | (any actin Adhesives Naural Ra “Phe cH-C(CHe} CHa ChescH CH (cH =CHe ee tor is isoprene ‘ practical use ‘Synthetic rubber, oi Neopiig AICH2CH=CoLcHy, | CHe=CH-cciscHe | resrstan Seal, (chloroprene) gaskets, hoses & conveyor belts SBR. siyrene butadiene | {CHe-GH-CHeCH=CH-CH,F Tyres, flooriles, rubber (Buna-S) foot wear & cable insulation Nitrile Rubber (Buna-N) “CHa GH-CHeCH=CH-CHa)- Making oil seals, tank lining and hoses HOZC Cells COH (Terephthalic acid) Fabric, HO-CHaCH>-OH ‘Tyrecord Ethylene glycol HO2C—CeHs-CO2H (Phthalic acid) aa HO-CH2CH2-OH ~[CO(CH2)sCO-NH(CHz)eNH]~ tani oer g HOOC-{CH2)e-COOH C{CHa)e)-C-NH-{CH,)e-NHY HaN—(CH2)e-NH2 Rope & ~{CO(CHa)sNH}i~ Co 4 NH __Caprolactam Tyee Electrical oe ‘Switch, combs, Ha Handle of 4 He} PhOH + HCHO in (excess) Utensils, : ‘computer discs and Bowing Balls roskabh unbreakable HaN-CO-NH2 (Urea) (CNH-CO-NEE CHa" HCHO (Formaldehyde) a sheets. Fal NF HN-Y -HN-CH 7 ged tr NSN motamine) bpachiog NH NH, ene ! m | (formaldehyde) i iv, \-4 Para HO2C-CeHs-COHH rear We Para HaN-CeHe-NHe ve: Wf Ad, Oe Meta HOzC-CeHi-COzH Pojyamide Nomex y \ Meta HaN-CeHe-NHz H Hy HOGH:CH:O Hs Hy < Foams, Shoes, Automobile 1k seats and I ‘components ho DCH om Ss, ge a (HO-CoHts-)2C(CHs)2 Bike helmet, po (Bisphenol A) goggles, bullet ba Xe0=0 (X = OCHS or Cl) proof glass = In Sh aleion PY8 Cheese the coasect ophion(s7 from the fellowteg : (BTepton cu prepooeo by heating efyn f nor efhene ' Dion ose of a perculp Ante cooly? aft Mob prersure R : ®) No turk rbber a pou tsoprene contod tng tans alkene unt. (2 Nylon 6 hd amile Linkage. o@ ? Cetludnse hor 9 x- D-9/neo4e Units thot Fie joinedl 4 Thy caitic ankeges. Wet’ 9 ™y Moh mer hod Ded? aro r0nres(D 2 (A) Buna-NV (7 puay Nenpire & Ny-ton—b-& cet % joht'rh one of fhe following pipes ik prepaeeel “4 adoihoo pocpeceres rhs? HW 7eflon ® Nylon-& 6 O Novell ? Dac

You might also like