Chemal }ngineexing icmodunamics

VandesusaalLs equation o she

axlix onlu PV RIox

TP
SV
2 V should he alculated
S6L V

_/p+a y- =RT a 2 7 RT
V 64 Pe

b RT
8Pe

y3-b+ gy+ay-abnlandencaals ean ai ae.

P P
eomple cubic eos

2 phoses L 373.15k
IO325 N/M

Prases2 bT oos 3

laKe SmallesV= yE
Laxaest Y: y
Antexmediate y has m phasical siqniicance
 messuxe is
Expe nmenlalasaph 2 ic HO 100'C & 10atm
tallina doLa
I0o°C
naim
Satd at ialm2 100°C

Disconhincus at 2 poins
P lia
latm 2Phases

ap
VV
V

HOat10 am/oec
Vandesuoml s 2 yeal12 camplex 1
ubic ens 3 os 1

ox31eal To6Ts_
9 1 xeal 2 complex

Aaim Plattedbusahun
cubic eas tox 100°C.
6aTm
and axious P
 SO SU UBATT
MPA
SO
uwur tpostgd sTT buudto
tAVd
JU WsTS N TOTpoUr|u
LOIRO
AA TA
S
Hdaxt do
mON
7DOKD
TOPTOpu
 N

N
 fo PR eas

2J2 b LV+(1-Jz)b
Rau t lind _da a Some
dT
Jn PR ml1-d d L

da - OH5 7218T Lda

dT dT
Pe
hexe
dok
dT
ztml-T m
T

T
do
dT T

da s OHG724RT ma
dT Pe TT

da = dl-m
JT

Nour
G 7-1-nz+ AT-p\d dcanst T
RT RT V
 P: RI
V- b
V 2V-
AT-P
V
RT
V
-RL
V-b v26V-B

1
V2- 2J2bl V+ b+SEL Vb-Sb
RT-Pdy RI n y g Sn V+b-Sb
V V-b 22b V+b+S2b

Put in G expxesslon
RT

RI In VL
RT RT V-b 2Sb V+b-Tb )|

n V+b+dZb
RT V 22RT V+b-S2b

GR 7-1-Onz- Ph-a Dn V+b+dZb

RT RT 22RT V+b- J b

150° C A 100 K t t 50C H5o

H5o KPa
sTeam
psat

FalloLas PR eos
A3H5

m= O815
1 =H23.15 O6539
6-7
 d-o3179
ba L818 xIo m>/mof

On sahving- cubic e0s ox state Enas pase Dasges zct)!

M= A D3H18 m3/mel

An sebing cubic eos o x s a t e 2 (Cans phase p*

sat P

67 A,S

V2=qE196 XIOS
Z2=A972

NoiT_da a a-m_ 1x0

dT
TT

H-1z-)AT +UR
(z-)RT+TdadT)-a In V+ ltE)L
22b V+ (t-SE)b)

H 67,316T/mol
H -314276 T/mel_
AH= A T same

AH HH -2H36 J/ms

foxsR SR HR-GR
T

sR Rh z- +daldT a V+litL
V+-2)b
22b
 SR
-ONOS

As Dn Pa - 31 JnHb
T

As -12.5

AS =As9 S2-S SAS= -12 8227T/od-R

A
Adiabatis
Na 1

Soo mot af ms taken ot dischaa

State 4 State 22
70 K loo bax T-?

AS=0 2nirop pes mde is constant in sudR cxpeximeiTs

VdLS

Givern- (p- 272 t H2xI0T h R C in T/me-H

I =12612K

bz2857XJ0S m3/m

Y 36KXOD V-S269X1O 0
aS VS-129 xlo

V: 9,43 x m/mol
1 eal 0dt
 is inaas phase V deser to k han_b
159047 mo
9,43xIoS

D2 1590.675C0 = I0.904l moP_

V2 = O 5 =315x lo m3/mo
o g 0 6S7

Nous
NoLr - ASG - C Dn Tz -R n Pz CanT be used as ci nat
T conshnt

ASG_Ce dT-ROn P2

212+HI2X10TdI-_ Rn P
P
T
T

Assumed yalue aiven - h =13313 R

Value LOaxecif As =o>_

fiss P RI 3a 63 bar
V2-b V2

As-_272 Dn T + 2 X 1 0 S - -ROn
T

AS4: o290 Jlmct-

 S=RDn p(v-b) -Z137 Jo?-K
RT
S AInAn p(V-b) =-8.629
RT

AS=- o 00n_ Assumed T as cozect

i) Using PR to solye

State 1 z0R lcobax

m= OH33_
tml-T =04304
d O930 0.2657

a - O1282 b a 2,XIO

eos > V-17xIO* V°+H3IxOV-2.12 XIOS 0

V : a.5)XoS m3/me LHner 2 complex

nas piase

= 1577.29 meP_
. 1 x I05

n2 = IO77 29 mel

V2= o5 3 9 X1 m3/mc
lO77.29
 Assume a 135 d o one sampla calcuation

At =o97O5

P= 3bax

NatL
SRalso depends on da
dT

Z oOXIOSx91LIx10 = O6129
2.34xI7O
Lda
dT

SK=-9 22 JImo- R_

As4- 272n tA2x10(TT-Ba uz.13

ASG= OL632 T/md-R

Z = O.BOq_ P=4L3a Vz34xl0

-

T2
P o1OR19- RIn[z- Bb 73
RT2 Rz

SE= - 10216

NoLzAS= o 632-101216--4122) O02s8

Assumed T_LS (Oxzect

#tosia) -H: Ropesies al aomponerat in mixtuxe

A1 2000.cm2 o an onti.heeze_onsisting of 3omeP/ settion ai

metdanc in uziter is xequired Nat voi1mes ai pue LantEx a
uxe meRane at 25°C must bemixed to am tRe sotutian alsa_.
at 25C Partiad mcdax yekumes teox methanc eatex in a
3- 30 me?o metBane scution at 25°C_axe ()metBone:32.632cmmo
( uatex 7.16Lcm3/me fox puxe species at 2E°C Re_mdkax
vume Axe lmetRant?: A0127 cm3/ms 2)1saex: 18.068 cm
m

2000cm

V=38.632 cm3/mel_V =17165.cm3/me

VT =nV = 2000(m
240251 cmmoR

nL n =2H 414mR n2= TDE S8 272mal_

Vtume o puxe meano? a nV E 2H,97Hx HOT27

1OU7,12cm

Vaume c puxe Ho=naa z

IO52 86 cm~
 Vetume befare mixing tM+XaV2 47,258 cm>/ma?
AVamix 7H2-17250= O.oRH cm/mk-
Lxpansion cuzs

S.3 He partial_mcax vcames ak acadone and Aloxcim in a-

mixtiein icB he mede kof CHC0z is oH643 ae 1.166cn2mo
and saz3Ecm/m, NRat isvelume af mixtine a mass 1Ha-

accone () O.S307

Clexo eaml2) X0H693_

V=71166 cmSm V= 20,235.cmS/ma

Y=mVt nV a 15422 cm3/me

Mdeculax ut of ()= 52.084 (2) l9 371

Mof mixtaxe =xiMtXaMa 24.854/mc

26.2Ba75422 cms

DHa 5.422 XI00O

86.85

VoRume
1Ra sdiion occupies Q62 42 cmS af
60AA 25 C Re densi fso st drone-uzatex-
mixtiize is Oa et/cm3 Given hat 4Ae paxtial vcRumne
Af uaer in tRe mizaxe is nAcm3/me calcuate pavtiak
metor veHame of ethanc
SA ethanek ) Mi H61OLa A/mc
P=o91H A Cms
Ho (2) Ma 18015 AJm
Let us assume

Mass o. hons!H6.O6G xmed

HO 18.015 A x mek
mo

Mass o ore H6.Oc9 x O5

Mass o HO+ EoreR H6 0643+18.O162

NoL V= 8m Cm/on6
G/cm
V= M =1Mi +I M2

V = 29.34 CmS /mo

And V-avts V= V-V

V 174 c /m LCGiven)

VE 5613 cm/mel
S) St is xequixed tD pxepore Oitaxaf an untizeze_mIRIUY
-atomdkh metñanedi) ome atx (2 Deterinint Re
vetumas a puxa nctaned puKeLtzx sBicA must e miked n
-pxapremixtxe at secRe patiad mekaz uekume ck rnetan
and n t r at 2s c g aivencompasition are: Va 38.632cmmoli-
N=n.2cE.cm3/meP Y H0127.cm3/melYa=la.068.cm2/mee
S O3 02e01

V= XM+aV 2HO25 .cm3 Ams

omem A62
2.025cm/me
D2ENI = 2913 me

V = n=B0.69cm. V=mla 5232 cm

6) Nonit come in midsem_

A2) Dalarmins VXY foxNE Ol o.5,oLg Re second

ordex Redlich Kister polunamialiting aves
3377-2.aHEK33IX) udexe Avnix is in cm°/rok
AVmix =LI
V=18.osRA cma/mof Va o.221 cmS/ms

Radlich- ister
S Anix = a (-3.377 2.4HBLt 33AÝ
)(-3.377-21448T13RRL
AYmix = ( -
dAVmix (-2Y1C21445+ 6621
d
dCAMmix-(1-2x1)-3371-2145 331X +(u-)
da -2.9456.62)

ANnix Lo o)

O9 -Q302

dAVmA
3.l62
Q 093
2.4H93

V-Vi=AYmix tO dAmix-
dat
Foy IEO V= 1H 9363

V-Va 2 AVnia XdAVmix

d
Na= Ho 7062

V2 =34.611A

lox o a Q i 4 V=18,O620
V 3I674

la checK at a 2 0 V>V
X o V y2
An Jab hour e kindmaRax vofPume at a soRution
indkor 5 vP7 sefution ok metfanck ( 8 iaatex (
Taue m of d)& a5 ml af (2)_
Densitsttle
20em3
find Lt of emg baHHle sop oyK

HI Lsthe iait sciunio Sput dop conk

He soution iill be preciselu 20 em 2om)

Nota ind Lt ot 20ml ox 26cm seR_- MiE 32.0H

=19221l4- Ma : 18.AI5

P M_ 19.122l O9R61aLcm
V 20

Gaiven meanek e A not aven ind usina akove exp

Ymectñons= Q742a

Mdes o ) = 5xo7429
32.04

18.615

=O.023 2 1-o.023=a 769

n+n2

M scdion 2 010231X2.04+0197G9 X12.O1E =1g.3Ha/mel_

 O.9861 8/cm3
found usind densiu katle-
V1OLHLcm3
LCox 1Ha sePution)

nat seiution iRg)a 1ooo &= 54 629 md

1.34
May ume lo
5H529
S V 1815414 Cm/me
tox XEO.02311
 toinl 5-Fugoitu coeicient af a compoventt in mixTie
A gas pRase mitLxe af ntrogen ) and n-butanel2)_at
H6OA3 R and HlL368bax _contains HaH m % nitogan X
5O126 me? . n-butane Cakulate Rec aacitu cocSficient at
Diaansn-butane in he mixtune assumine, it fallauss
Yiriol aas eas 7al+ RP
RT

Component TCK) P.La Z

Ntogan 126,B 3, 4H_ O 287
n-butane 2S.18 311 7 O27 O193

N) H6O 43R 68bax

n-kutane 2)_ HeOHS7H H=o5026

9Component 1
T-4D.S3 =O 365
265

B -783XIO" m3/mo

(omponenT 2-

T HEO, 93
H25.1

Raz -2.66 XOm/mo

Nos cSS Coesicien>

Tn Ta 2316R

Za2 O 2205
 V ZATa O207 XezH X1265 =2 64X10 mLm
Pe 33.94K 10S

Vee 88.69 cm/mot

Vez =235.69 cm3/mce
Vaz Ve S
I57,5H Cm/mo

And Pei2Za Ra 3H28 XI0S N/m

Veiz_ =3H 22ax

H6O.93 =99
Ta 2316

LA2= QL9_

Biz -2.3HXIGS mosd

Sn 2Bn-B -B2 = o072x10 mS/mal

NaL n d P RI S

Q6615

AT

D.9833

Deiatimhomlcause P_is igA

 _of_seronitactanitzile()8 oataldekude2
AAaS-pRasemixixe
Susem at 313 Xbaz conain o m Fradion ace o n l e
Calauate d assuming sudTem a nlla a) Vicial aas eas b VdLe
eos c) RR eOS

Componen TeCH) PCbar V (cmrcR) Ze

H8 30 OR32 13
Acdantnle () SHSS
O291 15A 221
Acstaldtadel 55.50

S Acaoniile () 373H 1 bax

AcetaldeRude (a)

Vinal gas eOs

Bu 8.75X10 m/mel
B22 H24 X IomS/med
Bi2 -6.0HX1o m/moR

S nSn = 2 B2-Bu-B209xIo nm3/no

Qnd PRT + Sn--o1O258

Q 475

bVduy cubic_eos

Lox component
a:l97

b:117H X1O m*/me

B

E
 3
a:da+Ha +28 H,92 2615
b=HbitHb2 6126 xlo ma/mok

ubic ecs y5-oLORIy+u2gx0SY-85aXIO O -0

y-O0304 m/m (Laxgesrcst cause aospa

LS fox mixlure

Z PY O9867
RT
Noz

£stimate d fox equimckax vapour mixi+ae a c 8

pxopanel2) at HEOK S1Gobar usina RR eos
omponent T ()PCkar
73.83 O214 122
CO2C
POpone2) 364.8 H2,48 O1276 L52

Also find ugaci coeFicient aFmixture

HBOR
S Co»()
prapane (2)_ Hobax

ox component (
a 6HG-
be 21468 xlo m° /mol
 Fox compo nerit ()
a:18.292
b=6221XIO S m3/mol

Qn a a 10.87

a
HfatHa 28.H20zl 624
bib+Sh 62xIO 5 m/med
Gubis eos yS- ATV-L+ LRT - a_V-ab =o
P NTP NTP
V-2.67 XIoy+2 HKG XIOV-21xto =

So oiz due V= 187xlo4 m/ns (onlu a rod

RigRP
Z= PV OXIOS X27XlO = O7
8.314 2X H5O
Pb 0,I73
RT

Noa2
Dn - OlH62 0,26
In baInZ-P
V-b RT) ab 9n th
V
RT V+
- 2a22t 0in) An/vth
RTb V J

On -O5727

Deviatingc 4 due to P
 Nouz

OL698
GiecH
Pod= Dn CT a -On VV
V-b P(V-b) RT V+b b V+b

Qa A mixire _contains Homd? /% CO2 8 6omo? f acztglene t 320R2

1obar. he mixuge is in acylindez A Rat is connediedba-
riaid semi-pexmaable membxane tärougB LiA CO2 an ass
anothex qlindx e hot Ras pure c2 at 320k Dabmine Pon
side Bb sop difhusionAsume i) 4dea gas eas ai) RR eos
for CO2 T =30H2K P73.3bar and lox acetlene: T=308.3K
P L a bar

S
Co() CO2 Puxe
Hhso aceulene 320o
32oR P-? Find P d i usion sTops
1cobaz

SSemi pexmeable membxone \Par alloes onlu COL

pass
LRemical patenlial i= G

dai RTdInf Tmus be some

 Difuson_stops ifhemicapotentia is Came

Gacoa= Gco far diWusion tadop-

LO in mixixe

dai= RTdIn S

On inteaaling
Lac Gco RI n_fco o

AsstimingbeYavlouz as ie

Fox Jco2sco2 SPLHS PausS

oaI0= Pans->P= uaba

i ) AssumingRR-

Fo2 on LHS-

Lomp )
aE646
b 2.97 XIO 6 m/msR

Comp (2)

b3.62 XIOm3 /mo

C aQC 72
 For midure a7.39
beiz%xloS n3 /nel
ubic eos, y-2.66 xloy2z12xIoV. 1384 x10 .
V- 9.OH7 X10S mS/mck (Oaly xam

2= PV =OL3-
RT

Ol26

Noua On du -D4194

We HnOLfat
&.P
h= O.62 XOHx1co 248 bax-

NosP on AHS suc hat fe2= 28ma tosop diusion

ie NeT movemert of (O2 Lsill stcp

Staxsting value Assume value) =21 ar

RI= 425 x 10

LAT a=-034 x1o

P TP

2bz3,97X IO
TP

Hexe a b ase a l pUxeCD2

 V-4.eExlo"yL36xloV-3,47xl0
0
ubic eas

V- 81xIO m3/mo LoHhex 2 complexL

No
n +0aPv-b)
AT RT5V4 b V+b
V-

Dn F_ -O

Assumed P=27bax

27xA24E= 2H7 Lax

is close toH8 So Pis araund 27 bax

AR
loobax Ho
bar
O4