REP Module 4
REP Module 4
MODULE IV
In closed cycle OTEC ammonia or other types of fluids are used as working fluid.
The heat is exchanged in boiler from the warm water on the ocean surface.
Thus steam is generated from the working fluid.
The steam generated is used to drive the turbine and generator.
After the energy conversion the steam is passed through the condenser in which it
is cooled using the cold water from the bottom surface of the ocean.
Fuel cells are energy conversion devices that generate electricity through an
electrochemical reaction between hydrogen (or a hydrogen-rich fuel) and oxygen
(from the air).
High Efficiency: Fuel cells can achieve high energy conversion efficiencies, typically
ranging from 40% to 60%.
Versatility: Fuel cells can be used in various applications, from stationary power
generation for buildings and backup power systems to transportation (e.g., fuel cell
vehicles), and even in portable devices like laptops and smartphones.
Continuous Power: As long as the fuel and oxidant are supplied, fuel cells can
produce a continuous flow of electricity.
Quiet Operation: Fuel cells operate quietly because they don't have any moving parts.
Scalability: Fuel cells can be designed in various sizes to suit different power
requirements.
Reliability: Fuel cells are known for their high reliability due to their simplicity and
lack of moving parts.
Reduced Dependence on Fossil Fuels: While hydrogen is commonly used as a fuel for
fuel cells, there are other options such as methanol, ethanol, and natural gas.
Potential for Off-Grid Applications: Fuel cells can operate independently of the power
grid, making them suitable for remote areas or in emergencies when grid power is
unavailable.
Long Lifespan: Properly maintained fuel cells can have a longer lifespan compared to
some other energy conversion technologies, reducing replacement and maintenance
costs over time.
Working Principle
A fuel cell is a device that uses hydrogen (or hydrogen-rich fuel) and oxygen to create
electricity by an electrochemical process.
A single fuel cell consists of an electrolyte sandwiched between two thin electrodes (a
porous anode and cathode) Hydrogen, or a hydrogen-rich fuel, is fed to the anode
where a catalyst separates hydrogen's negatively charged electrons from positively
charged ions (protons) At the cathode, oxygen combines with electrons and, in some
cases, with species such as protons or water, resulting in water or hydroxide ions,
respectively
The electrons from the anode side of the cell cannot pass through the membrane to the
positively charged cathode; they must travel around it via an electrical circuit to reach
the other side of the cell. This movement of electrons is an electrical current.
Hydrogen - Oxygen fuel cell
These are similar to cells which contain electrodes and electrolyte. Porous nickel or
carbon are used as electrodes in fuel cells.
The electrochemical reaction occurring at the electrodes of a hydrogen oxygen fuel
cell may vary with nature of electrolyte.
At the anode
2H2 4 H+ + 4e-
At cathode
O2 + 4 H+ + 4e- 2 H2 O
When hydrogen gas passed through the electrode it converted into hydrogen ions and
electrons
The electrolyte allows the positive ion movement and prevent electron flow.thus the
hydrogen ions reaches the cathode.
At cathode the hydrogen ions and oxygen gas combines with the electrons in the
external circuit to generate water as by product.
Disadvantages of fuel cell
1. Cost of Fuel cell technology can be expensive to manufacture and implement.
2. Hydrogen Production and Storage: Most fuel cells use hydrogen as a fuel source,
and producing, storing, and distributing hydrogen can be challenging and
energy-intensive.
3. Lack of Infrastructure: The infrastructure for hydrogen distribution and refueling
is limited and underdeveloped in many regions.
4. Fuel Availability: Limited widespread availability of hydrogen fuel.
5. Low Energy Density: This means that a larger volume of hydrogen is required to
produce the same amount of energy, which can impact the size and weight of fuel
cell systems.
6. Sensitivity to Contaminants: Some fuel cell types are sensitive to impurities and
contaminants present in the fuel or oxidant.
7. Limited Catalyst Availability: Some fuel cells require precious metal catalysts
like platinum to facilitate the electrochemical reactions.
8. Safety Concerns: Hydrogen is flammable and requires careful handling, storage,
and transportation.
Difference between battery and fuel cells
Aspect Battery Fuel cell
Energy source Chemical enrgy stored in Chemical energy from external
battery fuel source
Fuel Consumes stored chemicals Requires continous supply of
fuel
Power generation Limited by stored capacity Continous as long as fuels
supplied
Cost Varies with battery type and Expensive than batteries
capacity
Weight and size Generally lighter and small Bulkier and heavier
Start up time instantaneous Require warm up period
Environmental Depends on battery Low emissions
impact chemistry
MAGNETO HYDRODYNAMIC POWER PLANTS
MHD system need high temperature gas source. The atmospheric air is treated in
a combuster to raise the temperature level.
To increase the conductivity of air alkaline metals are seeded into the working
fluid before entering into the MHD system.
After the generation the high temperature air is used to generate steam from water
to drive the turbine.
The seeding metals are recovered from the air after the steam generation.
After the operation the air is removed through the exhaust systems.