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Thermal Properties

Thermal properties

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0% found this document useful (0 votes)
14 views4 pages

Thermal Properties

Thermal properties

Uploaded by

abhishekpayal402
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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THERMAL PROPERTIES OF MATTER:

Heat:
The energy transferred from one body to another due to the temperature difference between the
bodies.

SI unit: Joule (J)


CGS unit: calorie (cal)

Note:
1 cal = 4.2 J

Temperature:
A physical quantity that measures the degree of hotness or coldness of a body.

SI unit: Kelvin (K)

Other units of temperature include Celsius (°C) and Fahrenheit (°F)

Comparison between the Fahrenheit and Celsius scales:

𝑡𝐹 −32 𝑡𝐶 9
= ⇒ 𝑡𝐹 = (𝑡𝐶 × ) + 32
180 100 5

𝑡𝐹 - Fahrenheit temperature
𝑡𝐶 - Celsius temperature
Comparison between Kelvin and Celsius scales:

From the ideal gas equation, PV = μRT.


P – Pressure
V – volume
T – temperature
μ - number of moles in the sample of gas
R - universal gas constant:
R = 8.31 J mol–1 K–1
Hence, when V is a constant, P ∝ T resulting
in the given graph.

Note: The temperature corresponding to zero pressure is called absolute zero. Absolute zero is
equal to 0 Kelvin.

𝑇𝐾 = 𝑡𝐶 + 100
Where, 𝑇𝐾 is the temperature in Kelvin.

Thermal Expansion:
The increase in the dimensions of a body due to an increase in its temperature is thermal
expansion.

Types:
1. Linear Expansion:
𝛥𝑙
= 𝛼𝛥𝑇
𝑙
Where,
𝛼 is the co-efficient of linear thermal expansion
𝛥𝑙 is the change in length for a change in temperature of 𝛥𝑇
𝑙 is the original length
2. Area Expansion:

𝛥𝐴
= 𝛽𝛥𝑇
𝐴
Where,
𝛽 is the co-efficient of area thermal expansion
𝛥𝐴 is the change in area for a change in temperature of 𝛥𝑇
𝐴 is the original area

3. Volume Expansion:
𝛥𝑉
= γ𝛥𝑇
𝑉
Where,
γ is the co-efficient of volume thermal expansion
𝛥𝑉 is the change in volume for a change in temperature of 𝛥𝑇
𝑉 is the original volume

Relation between γ and 𝑇:

PV = μRT -------------------------------------------------- 1

At constant pressure:

PΔV = μRΔT ----------------------------------------------- 2

Dividing 2 by 1:
𝑃𝛥𝑉 μR𝛥𝑇
=
𝑃𝑉 μR𝑇
𝛥𝑉 𝛥𝑇
= -------------------------------------------------------3
𝑉 𝑇

𝛥𝑉
We know, = γ𝛥𝑇----------------------------------------------------4
𝑉

𝛥𝑇
Comparing 3 and 4, γ𝛥𝑇 =
𝑇
1
γ=
𝑇

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