/\RIA ~'T/\H NIVERSlfY 1,,uttU

lWP \ltfMI Nl OF P\ R AND lNll\ S flUI\L CllltMlSTRY

~
SI ( Ol"il> SI Ml- 1 f.lt r.x,oMINA1 ION nu 014 :10
CH\ 101• <,t:NUtJ\l CHF.MIS1 RY 11

lnslruct~ n; r\.ns
r, ,,o questions from ench section 1 \me. 3\n-s

Steno,·
1 ., \
Comp ct the fi llov, ing .
r.,~\)~-~~\ .......
.y.\ ~
• 1~
en ne s ....~).. isomer I
C ,_ ,2-ll romobu Iene " . rM '. .... isomer •
, 2-B romo butane is.½-':";_ t'. t.; :':, .~'. I ••• isomer (,o ,.st'
tuft s+-
1 t)V J. / J ,
C" 1
C l-1:: v, :II exhibit. ...... '.~; ........ isornerisrn •
, I nCII ,\ill exhibi< both.C:-,,,::1::, .. and .'-\'.':"'.~~- conformer i,q<\,.,.,._.l\ r-' ~-- <..
v :- \m,noprop,moie ,,cid and 2 - hydrox's,propanoic acids arc examples of ........... Isomers
1
, l . I .ti ano I .u1d cl 1111 clh y Iclher are .C".':: .'.+-: C...h .-:-'. ... ison1 ers (7 nm r l\s)
ll) bridi,..tion 1s ............................ (3mar\{s)
h. 1 1 Trn,wrn..::·s n is ........................... , (3nrnrks)

·11 Optical .,di\ it) is ...................... (4marks)

· D-!r·\,e a pl<.3, 3\ue Cora c:omp\etely ionized acid such as

\
\-\J\ ,1q) - • j I' 'I t\. • I t
!" <pla·m the types ol boo,d i ng stat in~ 1he bond and angle and the 'type of ljybridization
,, ct!"nc \ ii) 2 me1hylpropt111c ( iii) 2 mc\\1ylprop- \-ene (9rnarks)
, .. , .. th: l~..)\ll)V,tllg cornpou11ds in the ll~l>1\C way:

llhlt -- ;!'I- L'll.'Cll/'ll •CII,

C\\,l'\\),l'll, \Ir

11 C!+-Cl l.:~'H-C? l-Cl-h

OIi C\i

:, 'i) ( ., kt, lat,· ii ,e pc,·cc11lagc con1 pus ition of a compound thal on combustion of OA65 g of the
,1 T,"' ;nJ ,,.,vc 0.830g uf CO, and 0.338g of 1-l,O. Give the empirical formula of the compound.
<, vc· the po,stb le n II ml1cr or bonds formed by the following; (i) N (ii) S (iii) Br (iv) C (411\ar\<S)
, o, rnarl~~,
~15 • I

-I. (,1) WriteB three balanced equations that hclpc;d to disprove the theory of ••vita\ force". (6marks)
SE(.'TJOi\
C\
th Ji Li-.t live un:tiucncss or carbon colll\)OUnds (Smarks) ·
" I.isl ·: methods 1,f P"'i lication of organic eompinmds (3marks) k,
dJ W111c 1h.1 ll i'i\C names of the compounds: l)l (Cl h)2C~CI I, (ii) LJ (4,narks\

1.: th1.: t\.:, ~tll1'-> !or th-: ll>llo\\•tn~ ob-.;t..:hi1l1Lrns

< f I CO 11 ( I hC I l,l'02H (Cl h)2Cl \CO~H 0.89 '
l 7) l.33 l.28 ,\I t5m~\rks)
l \l \V

(U \ 1)2Nl {
Cl\ Nl b
11. '.'-ll I 3.23
3 3(> (Smarks)
b 4.75 Ill
\\
i
 CH1C •CH l t-J < N CIIJl I JJ
1 46A I. 1 -\ J 4A
l II Ill (Smark.t)
State whcthe t 1c f 'Ill " n~ t 1\h1h11 po lll\l •r 11c 'Ill • 111<.lu live ffc t
(i) NO, (11) B,. (ll!l l If (4ru,trk•,)

J)eftnc ,m ,I\ 1d mJ , b, · 111 tcr 111.., \1( , c,,l','nt "1th nppropri 11c ·x m1pl
)cp "I I t' -..1, r, 1 1,•, I t 11c ,·,•n1puund " B ,11no 1:lh) I ' X d1mcth;I~ }
(.2m., rl..i.)
\\ rill.! thl! cq;1,11iun of th1..• Do1.·tvr's l)rn~css. {2111111•k:,)
(c Complete the fhllo\\ mg cquJtion:;
. CfJI l K;\1n01. __ ► " t:?marks)
Cr20 3 \cOI f
N,t Dn etlwr ►
1
11. 2CI l3l'l ,~cl Iii
? (2nmrks)
(d \\'r,tC"
. ,).,t 1h, ._',uh. . 11 ,tructun.::s or (1)
n,'-- . C, ar(,L,n munnx1dc-
. .m d {11.. ) C 81·ban dioxide (..tmarl-.s)
SFCl'IOl\ C , .
'7.JL:;c ba anc.:-d c h "n'1cal eq11:1t1on~
· · on)f to I·11 ll'-lratc · I rcaL
,1 t)p1ca ~ of"• t1,c
, 'l1· L..,,, tullow11.g
i. C'ombustio• 1.:-,Kti,H1, ufalk~n,-~ , I
1i Deb) drnt1on of.iii.... 1wls (6111:1rks)
b. G , e the !>lnJcturcs of the /i.,1/o\\ ing .:omround~.
{i) Pent-2-cnc (ii) Prop,11e (iii) !1ut-1-) 111.: (iv) Mcth:1110I (v) Ethanoir acid (5 marb,)
c.(i) Give the gcncrnl for-nu .i:· 0f ,1lkl-nl· and ind l tc its tunctilmnl group (Jmurks)
(1 \ Outline lhc r1.:J1.:~i1)11.., or r\lk)11e~ (31/1 marks)

8.(a) Write the structur L~:, ur ,di th-: i::,onH:r., ur hcxc11e (6marJ...s)
(b1i Stare \1,trkorn,"off::, rnh: (2,narks)

1i I s~ CH,C:-i..1l.l tiC.l i~ C: i 2 ., :!!11,11·,l!e the abo'.e rule and :t.s Anti-markorniko:Ts rule on
add111on l0 an) named h) drogc,: ha!idcs (Gm.irk'iJ
(c) Define pol_vmcrwHion reaction .1nd give exampk. (3½ marks)

9.(a) How can u diffcrcnriatc bet,-\ ecn lhe fol lo\, mg pairs
i. l\fkencs and AJi,yl huli . .fcs
,,. Pure alcohols' and A.lkyne
ii 1. Terminal and \fon-renn1nnl .-\:kync (6marks)
{b) (J;c balanced chemical equJtion ooly td illuotratc·.typical reaction of the f611,,w,ng:
1 DchyJrohaloge;.1.il1on t,f' haloc;!L'noalkenes ,
ii Hydroly~1:s of' Ester (5½ marks) , 1

( c) Wn te the st rue tu re representing

I rJiiol Es.er
enc], of ll1 c lo llowin g carboxy lie add derh oth cs
11. l\cid anhyc.lrhk
iii. foster, I'\ 1· ,.
iv. 1cyl Chloride (6mari<s) V· l'f C '

c;oor)LOCK

\ I
. \
 C!Jl12 and C, 0 1-1;1, an.... ,. 1 .~:/~ •• ~l.(:~~-J:·(~ .t ......... '. ..............\\sc er
1

(lY/lO'r n}
t
1
•

C l-l3C Ha is an exa, 1ple l, '. .':'-J/f/: \°.' ! .l..f~i.'1.9,9~-Vcl. f.~ 1,lff~.. /\!. ls ~er
1

OH c. ' . \
1 . 11 \
: , ::•.l. : '.':'.\O·.. .'. \1.•.1........ : · \so 'er
•,- ) I '~. r
CH,, = C - CH3 .:i11cl CH 3 C Crh 2.rc, . 1•

\
~JC' "•\,4 B \

The fc ·rnalism (or basis) of~; ,-ct~f:l.•1 -~ .~ _1\J -~ _C/'.1:1_'~_,:i_.... \..: .. _:. \
J,:

. \ '

Which Qi- these bonding tl:,eo, iL-: '-'<Ji·rect. 1

c·~ ed,--:ted the ")ag tic \
properties 11 dic.Aygen; (..,. ~) .. VB·, h
'
MOL-
' -:::::--
\
Hi. VS& T
\ I
. \
Which of thesr bonding thedrie: is based 0 .1 lone i-)r; (Tick)?, \ Il

iii. VSERT,.' iv. LFT

- \
i. VBT, ii. \tl'JT,

One of these t xh'.b1~s resonances; (Tick) i. cu}-,

1 -~ •

\
Hi. :N .•
-~ I

.. ..
iv. 0::: O

\
"

'
•
I
 .' . ,,
r

SECTlON C

. in each case.·
· Define an acid and a base •. ith example t .
1.. Class1·cal
. term. (trar''t' ,. ):
I 101 ,a 1 dei..i1\,.,on .n1.1..
1.) ., . nL
t:-11(". L,--,
) t .L (,.,......•. ¥. :,.,
I .11.•. . . . ,'
~1-../,~ . /. ~
fVY(\ · h1Je
•. /
• .·• 1 ~.

1({ _1'1.l!.;,.. 1 ,J'?_l..•I.\(~. :711.d__;:t :'. s !i{'.((\ t .l'='·. j ~V(~: ftl. '.1.c.i,,1. _(.( -~·- }l/.~lhiJ( _tC hid, I,,.' ...
v! v<?d in 11,v•, /n fl~~v (c' h '/d\ 09t'n iorl c, 1 1il c' "" I y 1•osi ➔iv~
ion· · .· ; ·:.: · ·
~~f~
.~r :lb?. .l:!hO. -'-'~'-''" /.'. )_>'.,.~,,'.. f\ c:,!k ( n ... hyJx9.,C..i.d e.~ .."'- /irn h., $.q) v.0. .... ·"~,1 ff. .
I I .. ,
1

~ '~~
1 . ;- ..

i_i. Arrhenius's de fin iti? n: ~}\'· (! ?"c !P.. f ;:/c. h1:1 ( c:,1 ~->h., ch
I c•11 i_;,, ,, 1~ 3<11C h~drc'}' /I 10 •1 lft) i(\ tBr (\ IIC,. nCL --:7 )f
~-Vt~ t>o u -" u _
C ... H. L. j- Ho~rl HP t(L •+(,
i<'~·~\,. ic~
.A- .. J; :; -~ e. Ts .. :; "j'/)l~Sf~ ,I a; ij);[{h' ·er:,; 'i,~C>: jJ ~.'iii. (,6"(U~1'C:A .. +;;. lu -.n: ~ h c,'f' g; Ve'';
• /1,'{ ~- wr. .y. L .fr!! . a! ~-:--). •. . (~• }J1L"/l. 0.. /\1t t. J:-1. (/. ~- ............ •.. .. .. . '.ir._ · ' ~

owry -B·Ions ted det·n·1t·10 I l'-11,,.......

n .r .... ½{i'~
,,.................. t., ..•fjt-Ych·o
de11i,·/C\ ,,.r, i.......... .
!lf. L
.·J.-_: li}(.~1••• h'.•. ~.C ...'ia f'f !.'? ... F-'-~
d:1.0./. <_.,_!.-~rip:.:.. ::) .d .. .<'~t!'.'f (r.~.. : e<,peli; vel y.
.;( ,d- 1+c L(c,,i) t H2 0 C't) -::::9 rf10 t +CC . .
··;. :~i ~ ·Knr;~j ).. +··t-1; q; i·~ ·7\rn~+· "f ·NI" .. ·.. ·· ..... ··· .. ····!·.· .. · _
iv. Lewis definition: . ~11 ,'i_(_ J .-.,. S...'.i!1_:,. 5.~ f,5.b!!Ui ..~.~ ~iC.~. Jr!(l..t( c •f'-1
1 ~111 Un Sf,

k~:hr!!\: .. .t1 .. h'.,.? ~.'.• .( >. :.1.: ?.t,t.l. -~I'. -~-1( 1·: ..-.I .li.rJ ..c. j!), }g,1
. 11 • i:,: ~. ,cJ.. _(' rl' (I

. C cct ! t ,, ~ , ' ,r, l >ie ~ ~.,.1.

..
l
• ••• •• •
\' \".. •c'• /)\
X.,;
• . . . . . ~. ..
' :•.-.
1 , . . . .. H \ /(. ~. l'\. .I/.(~.I{... .. .. • .. • ..... '~
i ,· '\ I.\, •
(1 .. ~•(. , , ~, , I

,, /k ,a·- 1·\Ltl3 h( l:s Eti Ct('

a,h 0 H Jr I Jc s >-}
1 - I

.
·
 An Acid is measured by its
t .P.ls~.. v.iluo

How?~? r0s~n 9nc~ anu ,nduc'.iv,e ~f.ect, affe~: thi a .

~ rnblccult:? ..N~:.?:d 1 .'('. . . . w.. \LI.<, (!II.I...<. f.lL~ .1.. .111(.1• ~ ..,.\ f. • • • ,l,. >J~ii ,t
I .:J;_ i: t,.,, .'!\. !,:.. ,r,~\·; 1_;_,{\'.. iM,,,.I. i!(il'.. cHi :!'/: {:I.:r.).\. in.
I
1,.,
, ,J '
.S':, i. ,:, 'l<
•
<'It'( ,c··, <,(•<:, _b,; ,,: ;(, •'(. • .
iii. Explain why Cl 3C<tOOH
r
is more acidic than CH3COpH.
I

~ ._( J"J.\~ (C:.(i/1 ... i ~ .. /:~i.~ ~.' .. S( /~_1/.. 'J.l!~'i.~

. ..Vt.rt. p:/[1.<!:L. ~rr,:
\
..l. ~(~!~~.r .. .
:.lh <.' Yr1/~ ~'.~ .<~: .. 0'!'. .. (h l':'. I, .i'nc .-~ :( ~~: .n f~ ,(l,l,C, r: ..c:f .'.< J1,I_ ,"!. i.~-~> ·., nc\ (!•\it:~ :. . •.~
1
'
c,c,·,i;+,~. · · · ·
Using resonance cJnd inductive offecl3 (+I & -r), 'exp i'n the
.l
IV .
.
acidity )f phen.ol al7ld CH:f'H 2OH .... P~1J/1r./. .. [.s.. /;1~r.~,... i~'.i:d,·c
. I
i 1.'
.. :1:1~'.\I: .. (H. .C. tb.0.1-f: .. .h~·.('-i VH'.. _C>_-t .. ~~ . .(\t;f.CIJ( r:.. c+..' ... .lr.J (tj<?J/ ,• i I
. \ • . I
.••. -- _1_.. . •.••••' . .•• •.•. -· .....••.•••..••.. ·- ··· .......... ···' ··- .• \
' \
.l :NH:

y, c;J ' I ,
nd I lH, wh_ich is more bqsic (explain) ... N. H. , .. \ L /))!io:l".

...... ·. . ' ... -~·) ·. (<;, . P.t.'.C.c.hJ.~ '.-~ ..P/i... I. 1t_~-~ ... P"t_.('. $( r. ({: .. ~-j_ .. -~ ~~ .~: 9~ 0.'
\
.. ' ' ..... ·:· .......... . ....................... \ I

I •
 hiGyc.k \) ,l ,OJ hc.xnncf
r-
c,:.,.-_

f c (-{ ;). CH
C_:f 3 .:i:. '" ,_r<"J..~
v,.._~ 1.,.J.:.
~}i)\Z\)lC..
PbS + 'l ·.

0
\\ ' '. : ••• ;lhIi,·.. ,':,1 ru_<:1
. \\' ( i i:,t I(;
I•' un..:~ or l'oC"
H.: I y II oI Iv i11 t'- <ll 1d L•,i v1.: Llit..:i r l U'l' /\ C 'No 111 enc
I '
.
lutun;
..1 ·:,• •:c:i<:r;il ~Lmctural repn::;enti1tiun ol'.Lht..: following coinpouu,.b.
··I Sc·c1mdary
i 1 '-:11.. .\,:id anhydride amine. · ii) ar,i1na1 ic tcrthu·y arninc
i; ·1·1iiul 1,.'.stc.r
 ~ ~

, .,,cmU\~ \Sa .)~~~bit~iH~··· isomer

C,~ \.7-dibi-obulcl\~ \s n •:w: ... isomer
~
1
, , ..

'.'. • Uro1nobutunc is nn (: :-)·. \-:-. ..... ,somer \

~
,.. L'~ll ,~ ill e)l.bibil
. . .............
. <',·"'....
" )..i~o1neiisnu
.,, tJ-··t
~
i\"" ,, -t.,
·. CHJClh 12 will cxlub1l both .C.---\'L---· a11d •••• --,rolrunC!3
·.. cuiOCl-h a11d Cl·hCH, Oll arc ······-····-·-···· isorocrs I• \
:::>.-hydroxypropanoic _ucid, q~·o1nochlorofluoroiodomclhane ' ur~--\.!. ~ -
n,cr I '
ln ~ach of \he bo1rn:r(s) draw the• slr\.lclurc . I\
• t
• I I
1
~t1on
'.'.. Write shoiSc notes (using cxamplc(s) on lhe following
la) ~lcso11~_nccc lb) c1-_,'illorni:ri:;m (c) · Oplicu\ 1uclivily (,l)
1somcnsm _ _.,
3.(u) Mention \he types o[ hybridiz.ution in the following und U1cir bon l angl s.
(i).:'.hync (ii) propane (iii) bul-z-cnc I _·
(b) Whal is cn-,piricu\ [()nnudr·/ 0.--\G'.•is of u substu11ce B gave on cot bust\on
0.ll30g of C02anU 0.33llis ;n\{l, wh:il is the percentage of compositi ii oftl1c ·

(c) compound'?
Mention two methods of \Jnrif,c.;,tio n of Organic compounds
\
ss01ON e>
..\(a) Give [1vc special characteristics of carbon and its eompontids.
(b) Wri le lwo cqu'1'.ions that tlisprove:; the theory of vital force.
. \
(c) Arrange the following in order of ,\ccreasing stability. { c) C .
-It-.I/' '''
//,3 c-l__r I t fl J-'; '
1· ) ). 1 ff. ..)
) rt d~ . ?- (?1v1 w1c 9
,..l
v

(d \ Arrange the following in orflcr of increasing -1 Effect

Br. F, N02, OCllJ, Cll3Clt l
~
' \ • -,J , I
"Ur· " "( I'.;,
(d) Arrange the following in order ol'incrcusing
1 +l effect
(c) (CH1)JC+, CU/ CHiCU/, (Cl l'.1)2CH
\ J )-. '~
,.

ctl~
'
«-~ . . , c---\ \
\_

Ct\o
 ·'l,:1: ·::\pl,1ih the following ~b~crvaliun:i usi11g ~a,ilablc cqualions.

I.

( iii 'lh~ Co.rmation of ethane in the chlorination of methane in. the pr sence of
• •. I •
I" 1

\b) \\'ri(.:- ,Hit the cnnonical Mructurcs of (i) R-N0 2 (ii) CO 2

, (i)( ~,)Define ::m ncid and bnsc in terms of i:cugcnts 1

(i•) (ii\·~ the IUPAC, na.iucs of the following

, (' J C'cJI<,Ch
I .• •

''-··i Complete. the hdlowing ·cqtwlions

(.1 l 1~·ri:ic ti) Octane 1n11nbcr (ii) Dodor process

.. CG

' C 1\,l C\I-~ C1\J.-- ·cl\ J. )

•
'
 Markornikor'~ ..
(,·) Write the structure of the following
(i) s~condary amine 0

(i i)Tcrtiary amine
• (iii) Acid anhydride
(;v) Thiol cslcr
(v) l::than-2-diol.
. . · • . •\ l --t\1 ync usinu equation on\)'•
·. ,:(:1) (i) Write the a.J<ltl1on rcucl1on o 1 l)''-1rogcn o c . o .
t'ii) Write out the co111pou11ds that give:; synthesis ga~\.Aand waler gas.,.,._4• ma \ u,'\1
,
. '
,, .., C--\ \"· .
- \

"\ ...,
'
.....,
,(..
\
, I \\ - c- (_\
·~'" .'

I
l c) G ivc th rec ex amp ks of organic co rnpounds Lhal Lhc carbonyl is bonded lo U1 '
t•xygcn. · · \3. mu -s)
td) Explain th~ following 9i-ic11y. L 1 1, ..., '\lr.1 '\.~
( i) Bcnzoic acid i>stronger than c!hanoic ucid. ~""' ·c ,., i,,.i_., .
(ii) CICH COOII is stronger than ,ClhCOOH ~1 '-,Q+-<. "'--~'
-& J...
2
(iii) Formic acid (l!C021-I) is not ~scd in the preparation of kctones. (,<i mar c,) ~-\1
'
, (a) Differentiate between aldehyde <1m\ ketone using a based on their chcm.\ca t\st.
. . (3 ma -~
(b) (i) Give the 01\\cr of basic slrcnglh ol' amine. '\.a,\..,cv-) :- S: .._ c.."""Ji~ 'n Jr
,, (ii) Outline t·.to method~ of preparations of monocarbQxyli.c aci.ds. \4 mu. ~)
J(c) (i) Give three examples of organic compounds that contains a carbo11y\ it
(3 1nat )
(ii) Use cqti:'t ions only to represent a keto-cno\ tuat0111crisrn.
l41nat ~ )
(J) \Vritc equations lo ~,how tho oxidation of
Prinrnry amin(j
(i)
(4 1ua1·
(ii) Sl:condary amine
(c) Outline one mdhod or pr~paralion or kch.H\~$. (l nnn·

iJ I l \) I ~J. ·/ I ",,I tI I j J, r\ (,,a),'}-, o.J ''k ex «:\ S-< t'l"' }

3
 \lfl'
~H PNP,
,u, ~;~rn,
, ll \I l lll'l\11 l H \ II
toN
Ill\ lhl'l ,~m• ,,-.- - - --

\ iUl\ \IH ii
••nhM\ll\ln
'~"'-'r T\\ o l
qll\'ttt,ous 1011 ' , •

. I

• 11. t'l l,-CI l.~~.'11-\l 1-t'l h

011 I )I I I. Sg, or the
I
i' ,, 1 · 1k11hlL' tlw 1wn-L·nl.1:'l' r11mpn,i1in1111ri1 n1111pnund lh;il CH\ combuo.;tion ofO.'\
1 :•~111 1,r11.I _,:,1, (' O.◊.Hlf. ul' l 'U~ .111d O•.LH;t.~ ul' 11,:~ ), liivc tlic c111p1ncal l'urn1ula or lh1..: C mpuumL
111; 11' I, . . ) .
( I ,:-,
(I' l ;j,._,. till· pt>ssiblc llttlllbcr or bnnd~ fon11cd hy the l'ulhrn:ing_; (i)' ~(ii)~ (iii) 1v (iv C (4marks)

or "vital fore
1
,, \\ 11t\·tlir~,_- h:d:,nl'nl l',lllalinns that lic\pccl In disprove the theory • (Gm.u·ks)
, 1: I i:--.l li,c uniqucm·ss ol'carbon compo1111ds ('.:;marks)
,~ I 1~l _; 111cthods olpurilicatiun tJl'o1\1,a:1ic cu1111H)Ul1Js (Jmarks)
\ \ I I I l' l hl' 1lJ I>/\(' l\~11 "' ·s l 11' l lie Cl) Ill puu 11d:;; \ i) \ C' l I \) ).c· ·C \ \ l ( j i)
(4m rks)
111

........, ."'.•. 1 I .\,1!.1111 the rc.isu11s for the l'nllowing obscrvalmns

ll~ ~).11 Cllif.Olll Cl\ 1Cll2COll (Cll1)1CIIC0 2 11 (Cl l1)3CC( .l l
1~) t.:n , J .28 0.89
l II lV \/ Sm.irks)
1l

j 1 'll1NII, (Cl l1),1NI I

I • ; .3 (1 J ·'-'· \
I\ 111 (Smarks)

i,

~
~·
I
\ 'I I

'I \
1·1.

I (
r\. \ ,•! l-...:h\.l I._ ' \ • I •

• l'•' \i ,j ',,, \ \ \
,y
n,..... ' \
'
 i ~i - cf f-----,--r.·
{J H lt ,~ -1:1

oxide (4marks)

__.G,)
u·110NC wing .;...:,;:::::C::. / C

V ,
.1 t 1,c b;1l.n1ccd chc1.iical cqu;{tim1s l>nly tu illustrate a typical reaction of t\~c fo\
.// ~.
i. ( ·on 1 bustion. ~act:r,ns or alktncs
ii. lkh_vdrnlion l f al~anols (61park;) . ,
'· ( ;!\'C tile sti·ucturcs ', ftlh· rolluwi1\g coinpou11ds; mnrl<S)
(.i) Pcnl-2-cnc (ii) ,'rop :nc (iii) nut-1-ync (iv) Methanol (v) Ethtmoic ':"d<l Cc• v
ks)
(11 ( iiv1.· thc~gcncrnl , )I, 'ti!~ll or alkcnc and i11,..lic,1l1~ its functionu\ gro_up. <rma
I I I) ( )l1{ I inc n11c r,cacti '!lS ,,r 1\ lkyncs (31/.1. marks) 1

;) \\ 1·iL- the structures u ·::di~\'! i•,c1:1crs orhcxcnc (<imarks)

•·ti. ~t;1ll' ivlarkornikolf' rule (.1, na ·l:::s)
.ii. l j,,c CH CH C, ·1 C 1-J,~C H2 t,. iII stralc the abo vc rule and iis Anti-markor iko ff' s rule on ,
3 2 2
ad~lilion lo any_ na,rn:d hyd1:c -~cjo 1v;:,1cs (Gmark,;) .
\l·) lk!J11c JJl)ly111cn1..al.tlll rca1:t10, ,pid _'IVl- -.:'-'~.1nplc. (3½ marks)
1 I!,.'\' l. 111 u diffcrcntiulc bctv•.'C\..'I' the rul\owing p. ;r!-i
1 .\I ,L't11..·s ;111d Alkyl h:didcs
1i. I I re aJcolwls a11d Alky11c \

:,i.
·1 crn1i11al and Non-tcrrnin;,d /\lky11c {(,marl,,,)
I, l 1 I,abrn.:~d clll:111 ical equal i1)11 only lo i I\u:-;tratc l' ,·1ica\ reaction 1J r the' Co\\ N\\p·
s,: -::,l

, !)_ 11ydrohalngc11alio11 of halnp:~noalki..~ncs

i, Ii, drnlysis or
1::-.tcr (5½ mark:-i)
• Ii, 1 :_1 "' ,1r'.1~l!J1'C rcprcscnlint: 'inch ul'thco fo\lo\\i,." carboxylic add do,rival vc, .
1
I, I 110. l·,::,tc1 ' C}Ci( \ 1
c} ··\
0

11 .\ :id a11hvdriJ~
., ,I
·
~\\ \' •✓ \'l..',;;,\
\\\vJ· ..:
\·~~
,•V'"i'', \
1i1. l: 'er / I
'--;.i-... \ 1
r'-l\·
,;'-

~ \ / ~(..,.' (_\
1\. ·\c_, I Cl~lnridc ,.'(>marks') '. . '\ / , 1 \i·--\ \'\ i._

1/ ,>( ' I~ L,;· L,v' "

,\'
i, ' ) - ~ --\ \ ~

~,~
L' . ,GOOD LO CJ·.
~
}..,1\. .
,G c\/'
. -d--S'S
.
t
t
/l; ,./J
"
(
I_/
'

\\ i \ ,'
\\"' ✓L
 \Bl\ SI Al F. l Nl\!1 RS11 Y UI Ult\
"'.
~
'ltF.t'AR. l'l\tll!'N I 01 Pt IU /\Nil JNnt STftlAI en M T
Sl• l ON{)~· ~u SI Ii K t;XAMINATION 2n1 1201+
(:. <IIF 102. (;tc'Nl•'Ri\L ('lllt'MIS IR\ ll H
• ,,, ~~ l lU (' I ION \11sW\.'l SIX q11cst1on~ 1111111 I WO 110111 l.' 11.:h 1.:ll m
(!N.A
( ompl tl thl' h1lh1\\ i11p \ 1
( t It.II\\. I 4-.."\..,
. . ·I•
◄ lhL'--'-
.J .
.
. . l.,Ollll I'
( t Bl'Olll\lh\llCI\(' '~·.: ~~•.Ill~~": ... ISOllll.'I
I nio11whul,llh. IS ... , . ~ ~ ~ ~ ' . ?.~~~~'-!'Jome,
I\ {. JI • ·I ll'l)I I • • , ~-l)i)
\"' II \.:X • • • . • •'fu, "-(
••••• • . , .•• I.S ome1··!Sill

' <'H l 'l h w,11 cxhihll hoth~~:-r.-:-:C .. and~~~ .. Confoimcr

' 1 \m111(1prop,11101l' .1l'id and;::, l!ivdroxvprnp:111oic acid-; an.' example of
11, .. 1 ,111d d11111..·th.) kt lier ,11c . , l,t,1-),v~~~:-,:-: ...... isomer:, ~7111:trks)

(II) , /hh, d,
1 ,1
t,,,,\ 1 4wt;
1>,v'\ftt'q '\>I lclcaf"\H.CCd
111111 1:-;.~ . . . . . .1. . . . . . . . . . . .:'\" ....... (_1111a1·k1-)
.~d-vu~J.Qn
'!. I .111lt1J1ll'1t:-.111 ,s ............... :............. (3marks)
11 1 Opt1l·,il .tl'ti, it) is .......................... (Jmarl<s)
1
(:'>::?., (,t)l)\'l'l\1.' .i 11/\(,,ql · > ll 1 /\-
pl,a ,·.ll11\' for,1 l·on1pklcly ioni1.cd acid such as:
(h) l~,pl.1111 llw l\'pcs ofb1>11di11g stalin1! 1lw bond :111d ;rnpk .,nd 1\w 1vp1' nl'lwhr \i/atinn ·n
' t•> \·Lh) Ile (ii) 2 rndh¥1pwpanc {iii) 2 - mcthylprop-l1~nc marks)
(t·~ ,'\ .1111l' the rollllwi11l: cn111ppunds in the IUPAC way: (4 marks)
1

( i'
('fl,t,'II ~-i, l'llil'll,\II l'll,I (ii). C]l3-ClbCl.ll-Cll-Cl\3
l·fl,l II CII, l\r 011
I
011
·1

()J.( a J <',i/ctd, 1k (he pcrCL'lll:1gL' c..:umposition uJ' n compound tlial on corn bus lion of 0.4 Sg. o[ the compour,J
""' c ci): Wg or ( '0., a11d 0.:138g ur I JiO. ,:, ivc the crnpiricul rorrnub oC the cori1 )U\10.. (\'2 marks)
1h) l iiH' fliv nussihk number ol'bonds i'nrn1L·,I by tlw l<, llnwi1w : (i) N (ii)~ (iii1 Br iv)(' (4m:,rk..,)
3·
.. 2- \ '-r
I.
SI'( Tl<>N B h features (8 rnrk:-;)
<) I. (:1)ll llllllll'l'cllC 5 distinctive kalurcs ()~-~'lrganic chcrnistr~ nnd give 3 rcrtsons for SU
Ii) ~ tllh' ,111CI . . IH1\\ Ilic 111o<,( likely lwml l1ss1011 typl':; 111 tl1c (ulluw1111!.
1 1
(i)('I, (ti)Cll 1 B·· (iii)Cl!iCll)CN (6marks)
(l'\ \ 1:1nµ.1,.· the l'olluwi11~ in decrca;-;ing order ot'stability:
1 Cll1
11 11 Cl Ii
I I I .I
(2 nu -ks)
t I) ( ii . ( 11 C c11.~. c
I
1
:
lli:--C
I
I I
11. 11 \Cl 13 ll

(11\;; ( '1 !J-CH--=Cl!Cl l]; C'lb"- (2 marl\.~)

( j I) I J l 3( 'I I:',_' I l /,, c·-- Cll
., 2,·
C111
"I
'1

Q_p aL ll I ~
·111d l'nsl'S in lCI JtlS or reagent s (It) marks) '- f q
(a) t k' I 11\l: < ' • •
11
predict till' pred , 111 in,rnt ,,r 1duc1 in 1lw cl ·h, lr
1
l . , il 11 I •
10
he'/ ,1t1.:,· R, cam1 us<.: I' 1111• 1111llup11.tt1..•cq 11.1l1011', (8 maJl\.s) 011
II , Ill.I.. 11I ,ll ll l ' t'l l 'I
 of d1mrni1tio1t · ,HH \
H\H:t1on~ I l\tlH
' I ol •-1<ilhlto11 r,•11111,,11~ ill
;1) \,1--;I I l·11,1s
u

timph."k he t t'al~lion ·
~ndrnu1 nr
~
I)
0) < \I ( \
<'l I 1 ' ► (l.. ma• hs)
~,11d!ln11di:
\
n, \
')
\ l 1) l \1 lt, ► (2 rnarlrn)

Sli11,~inp vuur i.•~ikul.ltinns ck irly stalt; il'llic lollowi11u. i~, mon1alic Orn
1

~i) (\)Tlopcntndicnyl nuinn (ii) Cyd1)prnpene (iii) Cydot1cp

I
I
l't(llij_: ~
a) Nan11.t. the following compounds
( i) < •1~1 c 1-1 l c112CH.1rn 2on
1
(ii). c1-11Cl r✓cn :"'.c112 OH). c11i:112
(iv) (' l l, Cl\/ ~H.,Cl 10 lv). Cl Jj( 'l liCl I2CO( 'I I.1 )'
(i) i'vk111io11 lhrc.~t.' cx;unplcs or orgunic m~it!s llit1l co11l;1ins a carbonyl grou
(ii) With balanced chcmicnl cqtwtions <'mly show two 111clhods of' synq1cs
(i) I)iffcrcntiatc between aldehyde and ketone 12 marks I
•(ii) Hl~.w can the to differcnl\alc the following solution of c..:hcmi~a]s
chloride and propcne f6 mark~l
I

r
t
(a) h1,J,tin the Collowing observation
( i) !~oiling point of (dknnols arc· higlic.:r than thc~ir co1TL'SJ1on<ling alk:incs .
(i,) _Cl1;('1lCOOll i~s slro_1~ger lhwn CH .1(:(?Vll_ _ [4:-ma•~~c~J., j
) WntcI structures ol spcc1tic examples of (1) Prnnary animc (u). Secondary
·) With specific examples classil)1monobyclric alcohols [6 ½ marks] 1
ti) OuLline the methods used in the synthesis of alkync 13 marksl

(a) l lsc the addition or Hllr to l1kcnc to illustrate tlic li.,llowing

( i) '.vlarkornikov addi lion '
(ii) i\nli11wrkorri .
knv :,ddi l inn j ,t marks I
(i) Mention the carboxylic acid.derivative? [2½ marks} ~o
(ii) Mention the n1onocar~oxylic acids that will have the highest s·olubjlit
(iii) I lighlighl 3 l "upcrtic.:s of monocarboxylic acids I3rnks.l ! ,

l)di11c the followins with example 1

(i) l'nlymcrization rcaclion (ii) condcnsalion rcnction (iii) Hydrogcnatibn 1

l ,1 ,. 1 "' \o, ..j , \
\J'l' Qq f(\w.'..vw ~ "-.,
o~C\ . r .-. ~ ~
~~~,,Iv
•)c·Cn -\~~ 1)'l'f'(~I,<_,. 0

.f6rr0 V II
fl..

&) tl Afri) ~ H~ 1- f
?lLr.\
fl<.-, . (1~·i i'tl t"<1.,u1't1-1olo\-

p/l - ~J\ ·/c,~\